九州大学 研究者情報
論文一覧
山内 敬明(やまうち のりあき) データ更新日:2019.06.20

准教授 /  理学研究院 地球惑星科学部門 太陽惑星系物質科学講座


原著論文
1. Noriaki Yamauchi, Ryo Tanoue, Deuterium incorporation experiments from (3R)- and (3S)-[3-2H]leucine into characteristic isoprenoidal lipid-core of halophilic archaea suggests the involvement of isovaleryl-CoA dehydrogenase Biosynthesis., 81, 2062-2070, 2017.10.
2. Noriaki YAMAUCHI, Preparation, and analysis of 2-hydroxyarchaeol isomeric mixture prior to the determination of stereochemistry, Reserches in Organic Geochemistry, 30, 33-36, 2014.12, A mixture of 2-hydroxyarchaeol isomers is chemically synthesized from commercially available racemic isophytol. In the gas chromatogram of TMS-derivative of the synthesized material, two peaks of equal intensity are observed, suggesting the occurrence of two stereoisomers at C-3 (hydroxylated carbon in the isoprenoid chain). The 13C NMR spectrum of the synthesized material is slightly different from that of 2-hydroxyarchaeol from microbial origin, which is also consistent with the occurrence of two isomers in the former. By contrast, natural 2-hydroxyarchaeol from microbes and sediments is inferred to consist of a single stereoisomer at C-3..
3. 山内 敬明, アルキルジエーテルグリセロール化合物のTMS化体の質量分析スペクトルのフラグメント解析による一般的構造推定法, Reserches in Organic Geochemistry, 29, 71-78, 2013.12, General method for the structure determination of alkyl diether core-lipid was presented by the fragmentation analysis of trimethylsilyl (TMS) derivative of corresponding diether. At first, the precise analysis of TMS ether C25-C20 and C20-C20archeal diether core-lipids with a partially deuterated compounds. Then, the general fragmentation pattern of the TMS ether of diether lipid was anticipated. The number of carbon, and the position bonded at the secondary and primary hydroxyl group can be determined with the three intense fragments around the mass number of corresponding alkyl groups (R1 and R2), m/z R1+131, R2+145, and R2+88. This hypothesis was proved with the analysis of several synthetic standards of bacterial diether equivalent..
4. YAMAUCHI Noriaki, NAKAYAMA Yusuke, Biosynthetic Mechanism of L-Gulose in Main Polar Lipid of Themoplasma acidophilum, its Possibility of Resemblance to Plant Ascorbic Acid Biosynthesis., Biosci. Biotechnol. Biochem., 10.1271/bbb.130442, 77, 10, 2087-2093, 2013.10.
5. 山内 敬明, 石炭基礎講座( 2 ) 石炭の起源, 日本エネルギー学会誌, 89, 10, 1019-1024, 2010.10.
6. 山内 敬明, 講座 エネルギーの起源(4) 植物の進化と陸上への進出, 日本エネルギー学会誌, 89, 9, 914-919, 2010.09.
7. 山内 敬明, 講座 エネルギーの起源(2) 地球上の有機物,そして生命の誕生, 日本エネルギー学会誌, 89, 6, 577-582, 2010.06.
8. 山内 敬明, The Pathway of Leucine to Mevalonate in Halophilic Archaea: Efficient Incorporation of Leucine into Isoprenoidal Lipid with the Involvement of Isovaleryl-CoA Dehydrogenase in Halobacterium salinarum, Biosci. Biotechnol. Biochem., 2010.02.
9. 山内 敬明, 好塩性アーキアに特有なC25-C20ジエーテルのESI-MSとGC−MSによる分析:高塩分環境指標としての検討, Researches in Organic Geochemistry, 23/24, 123-130, 2008.12.
10. 山内 敬明, 古細菌の特異な膜脂質の生合成—極限環境への適応の理解と新たな膜分子設計への情報提供に向けて, 有機合成化学協会誌, 2007.06.
11. Noriaki Yamauchi, Norisuke Kamada, Hideyoshi Ueoka , The Possibility of Involvement of Cyclase Enzyme of the Calditol Carbocycle with Broad Substrate Specificity in Sulfolobus acidcaldarius, a Typical Thermophilic Archaea, Chem. Lett., 35, 1230-1231, 2006.07.
12. Noriaki Yamauchi, Satoshi Endoh, Improved Isotopic Deuterium Labeling at the Diastereotopic Methyl Group of Leucine : a Synthetic Route to (4S)- and (4R)-[5-2H1]Leucine, Biosci. Biotechnol. Biochem.,, 70, 276-278, 2006.01.
13. Noriaki Yamauchi, Wakana Toyodome, Kiyomi Umeda, Noriyoshi Nishida, and Tatsushi Murae, Structural Features of Humic Acid of the Coastal Sediment in Ariake Sea Tidelands
: Use of Humic Acid as an Environmental Indicator of the River Basin and the Coastal Region, Analytical Sciences, 10.2116/analsci.20.1453, 20, 10, 1453-1457, 1453-1457, 2004.09.
14. Noriaki Yamauchi, Hideyoshi Ueoka, Norisuke Kamada, and Tatsushi Murae, Resemblance of carbocycle formation from carbohydrates between archaea and eucarya/eubacteria. Biosynthesis of calditol, the characteristic lipid-content molecule in Sulfolobus acidocaldarius., Bull. Chem. Soc. Jpn, 10.1246/bcsj.77.771, 77, 4, 771-778, 771-778, 2004.04.
15. Noriaki Yamauchi, Takamasa Suzuki, Yuusuke Kubo, and Tatsushi Murae, The minimum prerequisite of the primordial membrane- the function of liposome made from the C-20 isoprenoidal lipids., Geochimica Cosmochimica Acta., 67, 18, A557-A557, A557, 2003.09.
16. T. Murae, Y. Takamatsu, R. Muraoka, S. Endou, and N. Yamauchi, Facile Distinction of Neutral and Acidic Tetraether Lipids in Archaea Membrane by Halogen Atom Adduct Ions in Electrospray Ionization Mass Spectrometry, J. Mass. Spectrom.,, 10.1002/jms.276, 37, 2, 209-215, 209-215, 2002.07.
17. Noriaki Yamauchi, Satoshi Endoh, Keiko Kato, and Tatsushi Murae, The observation of the pathway from lysine to the isoprenoidal lipid of halophilic archaea, Halobacterium halobium and Natrinema pallidum, using regiospecifically deuterated lysine, Bull. Chem. Soc. Jpn.,, 2001.09.
18. Noriaki. Yamauchi, Yoshiaki Natsubori, and Tatsushi Murae, Practical Synthesis of [3-(2H3)methyl]Mevalonolactone and Incorporation Experiment of [3-(2H3)methyl]Mevalonolactone and [13C]Labeled Acetate in the Biosynthesis of Isoprenoidal Diether Lipids of Halophilic Archaea, Bull. Chem. Soc. Jpn.,, 10.1246/bcsj.73.2513, 73, 11, 2513-2519, 2000.07.
19. Eva Gotze, Kraus Kis, Wolfgang Eisenreich, Noriaki Yamauchi, Katsumi Kakinuma and Abelbert Bacher, Biosynthesis of Rivoflavin. Stereochemistry of the 3,4-Dihydroxy-2-butanone 4-phosphate Synthase Reaction, J. Org. Chem, 1998.11.
20. Noriaki Iwase, Fumitaka Kudo, Noriaki Yamauchi and Katsumi Kakinuma, Substrate Specificity of 2-Deoxy-scyllo-inoosose Synthase, the Starter Enzyme for 2-Deoxystreptamine Biosynthesis, toward Deoxygluocose-6-phosphates and Proposed Mechanism, Biosci. Biotechnol. Biochem, 1998.06.
21. Noriaki Yamauchi, Masashi Kishida, Keiju Sawada, Yuji Ohashi, Tadashi Eguchi and Katsumi Kakinuma, Solvent-dependent Stereochemical Anomaly in the Nucleophilic Addition of Ester-derived Enolate to Bicyclo[3,3,0]octan-2-one System of Diacetone Glucos-3-ulose, Chem. Lett, 1998.04.
22. Mikio Morita, Noriaki Yamauchi, Tadashi Eguchi, and Katsumi Kakinuma, Structural Diversity of the Menbrane Core Lipid of Extreme Halophiles, Biosci. Biotechnol. Biochem, 1998.03.

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