Kyushu University Academic Staff Educational and Research Activities Database
List of Papers
Shinji Kanegawa Last modified date:2018.08.31

Assistant Professor / Department of Fundamental Organic Chemistry / Institute for Materials Chemistry and Engineering

1. KANG SOONCHUL, 金川 慎治, 塩田 淑仁, 吉澤 一成, 佐藤 治, A ferromagnetically coupled Fe-42 cyanide-bridged nanocage, Nature Communications, 10.1038/ncomms6955, 6, 2015.01.
2. Yao, Zi-Shuo, 蒲池 高志, 塩田 淑仁, 吉澤 一成, KANG SOONCHUL, 金川 慎治, 佐藤 治, Molecular motor-driven abrupt anisotropic shape change in a single crystal of a Ni complex, NATURE CHEMISTRY, 10.1038/NCHEM.2092, 6, 12, 1079-1083, 2014.12.
3. Tao Liu, Hui Zheng, KANG SOONCHUL, Yoshihito Shiota, Shinya Hayami, Masaki Mito, Osamu Sato, Kazunari Yoshizawa, Shinji Kanegawa, Chunying Duan, A light-induced spin crossover actuated single-chain magnet, NATURE COMMUNICATIONS, 10.1038/ncomms3826, 4, 2013.11, Both spin-crossover complexes and molecular nanomagnets display bistable magnetic states, potentially behaving as elementary binary units for information storage. It is a challenge to introduce spin-crossover units into molecular nanomagnets to switch the bistable state of the nanomagnets through external stimuli-tuned spin crossover. Here we report an iron(II) spin-crossover unit and paramagnetic iron(III) ions that are incorporated into a well-isolated double-zigzag chain. The chain exhibits thermally induced reversible spin-crossover and light-induced excited spin-state trapping at the iron(II) sites. Single-chain magnet behaviour is actuated accompanying the synergy between light-induced excited spin-state trapping at the iron(II) sites and ferromagnetic interactions between the photoinduced high-spin iron(II) and low-spin iron(III) ions in the chain. The result provides a strategy to switch the bistable state of molecular nanomagnets using external stimuli such as light and heat, with the potential to erase and write information at a molecular level..
4. Zhao-Yang Li, Jing-Wei Dai, Yoshihito Shiota, Kazunari Yoshizawa, Shinji Kanegawa, Osamu Sato, Multi-Step Spin Crossover Accompanied by Symmetry Breaking in an Fe-III Complex: Crystallographic Evidence and DFT Studies, CHEMISTRY-A EUROPEAN JOURNAL, 10.1002/chem.201302272, 19, 39, 12948-12952, 2013.09.
5. Dai Jingwei, Shinji Kanegawa, Li Zhaoyang, KANG SOONCHUL, Osamu Sato, A Switchable Complex Ligand Exhibiting Photoinduced Valence Tautomerism, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 10.1002/ejic.201300531, 2013, 24, 4150-4153, 2013.08.
6. KANG SOONCHUL, Shinji Kanegawa, Osamu Sato, Slow magnetic relaxation in a 4,2-ribbon like Fe-III Co-2(II) heterobimetallic chain, DALTON TRANSACTIONS, 10.1039/c2dt31168b, 41, 44, 13575-13577, 2012.09.
7. Shinji Kanegawa, KANG SOONCHUL, Osamu Sato, Spin Crossover Behavior of Dinuclear Fe-II Complexes with Bis-Tetradentate Bridging-Type Ligands, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 10.1002/ejic.201201069, 5-6, 725-729, 2013.02.
8. Shinji Kanegawa, KANG SOONCHUL, Osamu Sato, Preparation and Valence Tautomeric Behavior of a Cobalt-Dioxolene Complex with a New TTF-functionalized Phenanthroline Ligand, CHEMISTRY LETTERS, 10.1246/cl.130118, 42, 7, 700-702, 2013.07.
9. Liu, T; Dong, DP; Kanegawa, S; Kang, S; Sato, O; Shiota, Y; Yoshizawa, K; Hayami, S; Wu, S; He, C; Duan, CY , Reversible Electron Transfer in a Linear {Fe2Co} Trinuclear Complex Induced by Thermal Treatment and Photoirraditaion, Angewandte Chemie International Edition, 10.1002/anie.201201305, 51, 18, 4367, 2012.03, A linear cyanido-bridged Fe2Co compound (see picture) exhibits a reversible, thermally induced cooperative charge transfer transition accompanying spin transition and polar–nonpolar transformation in the trinuclear cluster. The change in magnetic properties and polarity could also be induced by irradiation with light..
10. Dong, DP; Liu, T; Kanegawa, S; Kang, S; Sato, O; He, C ; Duan, CY, Photoswitchable Dynamic Magnetic Relaxation in a Well-Isolated {Fe2Co} Double-Zigzag Chain, Angewandte Chemie International Edition, 10.1002/anie.201105987, 52, 21, 5119, 2012.04, Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated FeIII2CoII chains of {[Fe(pzTp)(CN)3]2Co(4-styrylpyridine)2}⋅2 H2O ⋅2 CH3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin)..
11. Liu, T; Zhang, YJ; Kanegawa, S; Sato, O, Photoinduced Metal-to-Metal Charge Transfer toward Single-Chain Magnet, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 10.1021/ja1027953, 132, 24, 8250, 2010.06.
12. T. Liu, Y.-J. Zhang, S. Kanegawa, *O. Sato, Water-Switching of Spin Transitions Induced by Metal-to-Metal Charge Transfer in a Microporous Framework, Angew. Chem. Int. Ed., 10.1002/anie.201002881, 49, 46, 8645-8648, 2010.11.
13. H. Xu, G. Juhász, K. Yoshizawa, M. Takahashi, S. Kanegawa, *O. Sato,, “Mixed-metal complex [Fe(bipe)(Au(CN)2)2MeOH] with gold clusters: a novel two-dimensional polyrotaxane net clipped by aurophilic interaction”, CrystEngComm, 12, 4045-4047, 2011.06.
14. Zhang Yan-Juan, Liu Tao, Kanegawa Shinji, Sato Osamu, Interconversion between a Nonporous Nanocluster and a Microporous Coordination Polymer Showing Selective Gas Adsorption, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 10.1021/ja908670u, 132, 3, 912, 2010.01.
15. Zhang, Yan-Juan, Liu, Tao, Kanegawa, Shinji, Sato, Osamu, Reversible Single-Crystal-to-Single-Crystal Transformation from Achiral Antiferromagnetic Hexanuclears to a Chiral Ferrimagnetic Double Zigzag Chain , Journal of the American Chemical Society, 10.1021/ja901539y, 131, 23, 7942, 2009.06.
16. Gergely Juhsz, Ryotaro Matsuda, Shinji Kanegawa, Kaori Inoue, Osamu Sato* and Kazunari Yoshizawa, Bistability of Magnetization without Spin-Transition in a High-Spin Cobalt(II) Complex due to Angular Momentum Quenching , Journal of the American Chemical Society, 10.1021/ja808448j, 131, 13, 4560, 2009.04.
17. Shinji Kanegawa, Satoru Karasawa, Masataka Maeyama, Motohiro Nakano, and Noboru Koga, Crystal Design of Monometallic Single-Molecule Magnets Consisting of Cobalt-Aminoxyl Heterospins, Journal of the American Chemical Society, 10.1021/ja0767579, 130, 10, 3079-3094, 2008.03.