九州大学 研究者情報
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基本情報 研究活動 教育活動 社会活動
李 秦宜(り ちんい) データ更新日:2019.06.23

助教 /  工学研究院 航空宇宙工学部門 航空宇宙熱・流体力学講座


主な研究テーマ
ナノスケール相変化
キーワード:固液界面
2018.10~2023.10.
ナノスケール伝熱
キーワード:低次元材料
2016.08.
熱物性
キーワード:測定技術
2016.08.
エネルギー利用
キーワード:エネルギーデバイス
2016.08.
研究業績
主要原著論文
1. Qin-Yi Li, Ryo Matsushita, Yoko Tomo, Tatsuya Ikuta, Koji Takahashi, Water Confined in Hydrophobic Cup-Stacked Carbon Nanotubes beyond Surface-Tension Dominance, The Journal of Physical Chemistry Letters, 10.1021/acs.jpclett.9b00718, 2019.06.
2. Qinyi Li, Koki Katakami, Tatsuya Ikuta, Masamichi Kohno, Xing Zhang, Koji Takahashi, Measurement of thermal contact resistance between individual carbon fibers using a laser-flash Raman mapping method, Carbon, 10.1016/j.carbon.2018.09.034, 141, 92-98, 2019.01, [URL], Thermal contact resistance (TCR) between individual carbon fibers (CFs) can dominate heat dissipation rates in CF-based composite materials. Here, we develop a totally non-contact “laser-flash Raman mapping” method to simultaneously measure the TCR at the CF-CF junction and their thermal conductivities. Laser power is used to heat the sample and the laser absorptivity is experimentally determined by a transient laser-flash Raman technique. The laser heating positions are changed along two connected CFs, and the change of temperature rise with varying positions is in-situ measured from the temperature dependent Raman band shifts. The high spatial resolution of the micro-Raman mapping allows direct observation of the abrupt jump of thermal resistance at the CF-CF junction, from which we extracted the TCR as well as the thermal conductivity. The laser absorptivity of the 11 μm-diameter CFs is measured to be 0.12 ± 0.03, the thermal conductivities of the individual CFs are around 200 W/mK, and the TCR of the CF-CF junction is (2.98 ± 0.92) × 105 K/W. This work provides indispensable knowledge for the design of CF-based composite for thermal management, and the novel non-contact measurement method can stimulate characterization and manipulation of contact/interface heat conduction between various micro- and nano-materials..
3. Qinyi Li, Koji Takahashi, Xing Zhang, Frequency-domain Raman method to measure thermal diffusivity of one-dimensional microfibers and nanowires, International Journal of Heat and Mass Transfer, 10.1016/j.ijheatmasstransfer.2019.01.057, 539-546, 2019.05, [URL], Thermal property measurement of individual micro- and nano-materials has been very challenging and the development of measurement methods is crucial for the experimental investigation of microscale and nanoscale heat transfer. Here we present a noncontact frequency-domain Raman method to measure thermal diffusivity of individual 1D microfibers and nanowires without the need of knowing laser absorptivity. Cosine-wave modulated laser is used to heat the sample, while the laser-intensity-weighted spatiotemporal average temperature is simultaneously detected from the sample's Raman band shift. Transient heat conduction models under periodic heating are established and analytically solved in the frequency domain with considerations of the Gaussian laser distribution and thermal contact resistance. By varying the laser modulation frequency as well as the laser spot size, we can eliminate the laser absorptivity by a normalization technique and extract the thermal diffusivity with high sensitivity. Typically, if the thermal diffusivity is on the order of 10 −4 m 2 /s, we need to use the modulation frequencies on the order of 10 Hz to measure millimeter long microfibers, and ∼MHz frequencies to measure micrometer long nanowires. We also demonstrate that any kind of periodic laser modulation can be decomposed to a series of cosine modes and readily analyzed by this frequency-domain approach, which can greatly broaden the applications of transient Raman techniques..
4. Qinyi Li, Koji Takahashi, Hiroki Ago, Xing Zhang, Tatsuya Ikuta, Takashi Nishiyama, Kenji Kawahara, Temperature dependent thermal conductivity of a suspended submicron graphene ribbon, Journal of Applied Physics, 10.1063/1.4907699, 117, 6, 2015.02, [URL], Thermophysical characterization of graphene is very important for both fundamental and technological research. While most of the existing thermal conductivity measurements are for graphene sheets with sizes larger than 1 μm, the thermal conductivities for suspended submicron graphene ribbons are still very few, although the thermal conductivity of graphene ribbons at the submicron scale is predicted to be much smaller than large graphene and strongly size dependent for both length and width due to the 2D nature of phonon transport. Here, we report the temperature dependent thermal conductivity of a 169-nm wide and 846-nm long graphene ribbon measured by the electrical self-heating method. The measured thermal conductivities range from (12.7 ± 2.95) W/m/K at 80 K to (932 ± 333) W/m/K at 380 K, being (349 ± 63) W/m/K at 300 K, following a ∼ T2.79 law for the full temperature range of 80 K to 380 K and a ∼ T1.23 law at low temperatures. The comparison of the measured thermal conductance with the ballistic transport limit indicates diffusive transport in this narrow and short ribbon due to phonon-edge as well as phonon-defect scattering. The data were also combined with an empirical model to predict possible width dependence of thermal conductivity for suspended graphene ribbons. These results help understand the 2D phonon transport in suspended submicron graphene ribbons and provide knowledge for controlling thermophysical properties of suspended graphene nanoribbons through size manipulation..
5. Qinyi Li, Wei Gang Ma, Xing Zhang, Laser flash Raman spectroscopy method for characterizing thermal diffusivity of supported 2D nanomaterials, International Journal of Heat and Mass Transfer, 10.1016/j.ijheatmasstransfer.2015.12.065, 95, 956-963, 2016.04, [URL], 2D nanomaterials have been attracting extensive research interests due to their superior properties and the accurate thermophysical characterization of 2D materials is very important for nanoscience and nanotechnology. This paper presents a transient "laser flash Raman spectroscopy" method for measuring the thermal diffusivity of 2D nanomaterials in the supported form without knowing the laser absorption coefficient. Square pulsed laser rather than continuous laser is used to heat the sample and the accumulated Raman signals are used to determine the time-averaged temperature rise of both the supported 2D material and the substrate. The laser absorption coefficient can be eliminated by comparing the temperature rises measured with different laser spot sizes and laser pulse durations. The method sensitivity is also analyzed by case studies for typical 2D nanomaterials. This method is useful for measuring the thermophysical properties of 2D materials in the most applicable forms and figuring out the difference between the supported and free-standing 2D material..
6. Qinyi Li, Kailun Xia, Ji Zhang, Yingying Zhang, Qunyang Li, Koji Takahashi, Zhang Xing, Measurement of specific heat and thermal conductivity of supported and suspended graphene by a comprehensive Raman optothermal method, Nanoscale, 9, 10784-10793, 2017.07, The last decade has seen the rapid growth of research on two-dimensional (2D) materials, represented by graphene, but research on their thermophysical properties is still far from sufficient owing to the experimental challenges. Herein, we report the first measurement of the specific heat of multilayer and monolayer graphene in both supported and suspended geometries. Their thermal conductivities were also simultaneously measured using a comprehensive Raman optothermal method without needing to know the laser absorption. Both continuous-wave (CW) and pulsed lasers were used to heat the samples, based on consideration of the variable laser spot radius and pulse duration as well as the heat conduction within the substrate. The error from the laser absorption was eliminated by comparing the Raman-measured temperature rises for different spot radii and pulse durations. The thermal conductivity and specific heat were extracted by analytically fitting the temperature rise ratios as a function of spot size and pulse duration, respectively. The measured specific heat was about 700 J (kg K)−1 at room temperature, which is in accordance with theoretical predictions, and the measured thermal conductivities were in the range of 0.84–1.5 × 103 W (m K)−1. The measurement method demonstrated here can be used to investigate in situ and comprehensively the thermophysical properties of many other emerging 2D materials..
主要学会発表等
特許出願・取得
特許出願件数  0件
特許登録件数  1件
学会活動
所属学会名
日本応用物理学会
日本伝熱学会
学会大会・会議・シンポジウム等における役割
2019.04.26~2019.04.28, The 7th International Symposium on Micro and Nano Technology, Session Chair.
2017.03.19~2017.03.22, The 6th International Symposium on Micro and Nano Technology (ISMNT6), Local Organization Committee Member; Session Chair.
学術論文等の審査
年度 外国語雑誌査読論文数 日本語雑誌査読論文数 国際会議録査読論文数 国内会議録査読論文数 合計
2018年度   10    16 
2017年度 10  15 
受賞
Honored Bachelor Graduate, Tsinghua University, 2011.07.
Honored Ph.D. Graduate, Tsinghua University, 2016.07.
Outstanding PhD Thesis (1st Place) in Power Engineering and Engineering Thermophysics, Tsinghua University, 2016.07.
Wu Zhong-Hua Student Honor Award, Chinese Academy of Sciences, 2015.10.
Best Presentation Award, the Fourth International Forum on Heat Transfer, The Heat Transfer Society of Japan, 2016.11.
Best Paper Award (Second Place), ASME 5th Micro/Nanoscale Heat and Mass Transfer International Conference, ASME, US, 2016.01.
American Chemistry Society Best Poster Award, NT18: 19th International Conference on the Science and Application of Nanotubes and Low-Dimensional Materials, 2018.07.
研究資金
競争的資金(受託研究を含む)の採択状況
2018年度~2023年度, 戦略的創造研究推進事業 (文部科学省), 分担, 二次元材料とナノ計測の融合による相変化伝熱の革新.

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