Updated on 2024/10/10

Information

 

写真a

 
YAMAMOTO EIJI
 
Organization
Faculty of Science Department of Chemistry Associate Professor
School of Sciences Department of Chemistry（Concurrent）
Graduate School of Sciences Department of Chemistry（Concurrent）
Title
Associate Professor
Tel
0928024141
Profile
Organic Synthesis、Asymmetric Synthesis、Catalysis
External link

Research Areas

  • Nanotechnology/Materials / Synthetic organic chemistry

  • Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Catalyst and resource chemical process

Degree

  • Science

Research History

  • Department of Chemistry, Graduate School of Science, Kyushu University Associate Professor

    2024.3 - Present

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  • Kyushu University Department of Chemistry, Graduate School of Science, Catalysis Organic Chemistry Lab Assistant Professor

    2016.3 - 2024.3

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  • (株) クラレ 技術系総合職I

    (株) クラレ 技術系総合職I

Education

  • Hokkaido University   Faculty of Agriculture   Department of Applied Bioscience

    - 2005.3

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Research Interests・Research Keywords

  • Research theme：Organometallic Chemistry

    Keyword：Organometallic Chemistry

    Research period： 2024

  • Research theme：Organocatalysis

    Keyword：Organocatalysis

    Research period： 2024

  • Research theme：Organic Chemistry

    Keyword：Organic Chemistry

    Research period： 2024

  • Research theme：Asymmetric Synthesis

    Keyword：Asymmetric Synthesis

    Research period： 2024

  • Research theme：触媒化学

    Keyword：触媒化学

    Research period： 2024

  • Research theme：Developing catalytic asymmetric reactions using oxygen nucleophiles、 Development of solid catalysts

    Keyword：Asymmetric Synthesis、Phase-Transfer Catalyst、Supported Catalyst、Organocatalysis

    Research period： 2016.3 - 2022.4

Awards

  • 奨励賞

    2022.10   有機合成化学協会 九州山口支部   高効率的な均一系・不均一系触媒反応の開発

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  • 有機合成化学協会九州山口支部奨励賞

    2022.6   有機合成化学協会九州山口支部  

  • 日本化学会第93春季年会優秀講演賞（学術）

    2013.4   日本化学会   シリルボランとアルコキシ塩基を用いた有機ハロゲン化合物の形式的求核ホウ素置換反応

  • 平成24年Symposium on Molecular Chirality Asia 2012 ポスター賞

    2012.4   分子不斉研究機構 MCRO   Phase-Transfer Catalytic Base-Hydrolysis of Esters

  • 平成23年度有機合成化学協会九州山口支部ポスター賞

    2011.4   有機合成化学協会九州山口支部   キラル相間移動触媒を用いたエステル類の不斉加水分解

  • 院生プロジェクト優秀研究賞

    2011.4   九州大学グローバルＣＯＥ   人工触媒を用いたエノールエステル類の不斉加水分解に関する研究

  • ファインケミカルズ合成触媒国際会議2011“Oral Presentation”

    2011.4   触媒学会   Asymmetric Hydrolysis of Esters Catalyzed by Phase Transfer Catalysts

  • 平成17年度クラーク賞

    2005.3   北海道大学   成績優秀者〔２２６０人中、４６人選出〕

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Papers

  • Heterogeneous Cobalt-catalyzed H2S-reagent-free dialkylpolysulfane synthesis from alkenes, elemental sulfur, and hydrogen Reviewed International journal

    @Eiji Yamamoto #Yuta Takaki #YKawai, Y.; Takakura, K.; Kimura, M.; Murayama, H.; Nagao, T.; Kamachi, T.; Matsueda, H.; Otsuki, S.; Sakata, H.; Tokunaga, M.

    ACS Catalysis   13 ( 21 )   14121 - 14130   2023.10

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： https://doi.org/10.1021/acscatal.3c03545

    Other Link： https://pubs.acs.org/doi/10.1021/acscatal.3c03545

  • 水やアルコールを求核剤として用いるエステル基の触媒的不斉変換反応 Invited Reviewed

    有機合成化学協会誌   81 ( 8 )   798 - 808   2023.5

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    Language：Japanese   Publishing type：Research paper (scientific journal)  

    DOI： https://doi.org/10.5059/yukigoseikyokaishi.81.798

    Other Link： https://www.jstage.jst.go.jp/article/yukigoseikyokaishi/81/8/81_798/_article/-char/ja/

  • Theoretical Mechanistic Investigation of the Dynamic Kinetic Resolution of N-Protected Amino Acid Esters using Phase-Transfer Catalysts Invited Reviewed International journal

    @Eiji Yamamoto,#Kaoru Kobayashi,#Kodai Wakafuji,@Takashi Kamachi,@Makoto Tokunaga

    Journal of Organic Chemistry   2023.2

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    Language：Japanese   Publishing type：Research paper (scientific journal)  

    DOI： https://doi.org/10.1021/acs.joc.2c02352

    Other Link： https://pubs.acs.org/doi/full/10.1021/acs.joc.2c02352

  • Aerobic oxidation of isoprene glycol with platinum-bismuth nanoparticles catalysts supported on metal oxides Reviewed International journal

    #Yasutaka Kawai, #Kazuki Haruguchi, #Keisei Sumikawa, #Mai Kawada, @Eiji Yamamoto, @Haruno Murayama, @Makoto Tokunaga

    Applied Catalysis A: General   643   2022.8

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： https://doi.org/10.1016/j.apcata.2022.118781

    Other Link： https://www.sciencedirect.com/science/article/pii/S0926860X22003040?via%3Dihub

  • Intramolecular cyclization of alkynoic acid catalyzed by Na-salt-modified Au nanoparticles supported on metal oxides Reviewed International journal

    #Qi-An Huang, #Takaaki Ikeda, #Kazuki Haruguchi, #Seiya Kawai, @Eiji Yamamoto, @Haruno Murayama, @Tamao Ishida, @Tetsuo Honma, @Makoto Tokunaga

    Applied Catalysis A: General   643   2022.8

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： https://doi.org/10.1016/j.apcata.2022.118765

    Other Link： https://www.sciencedirect.com/science/article/pii/S0926860X22002885?via%3Dihub

  • Dynamic Kinetic Resolution of Azlactones via Phase-Transfer Catalytic Alcoholysis Invited Reviewed International journal

    #Kodai Wakafuji, #Satsuki Iwasa, #Kina N. Ouchida, #Hyemin Cho, #Hirotsugu Dohi, @Eiji Yamamoto,* @Takashi Kamachi, @Makoto Tokunaga*

    ACS Catalysis   11 ( 22 )   14067 - 14075   2021.11

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： https://doi.org/10.1021/acscatal.1c03076

    Other Link： https://pubs.acs.org/doi/10.1021/acscatal.1c03076

  • Convenient Unsymmetrical Disulfane Synthesis: Basic Zeolite-Catalyzed Thiol-Disulfane Exchange Reaction Reviewed International journal

    @Eiji Yamamoto,* #Yasutaka Kawai, #Kei Takakura, #Moemi Kimura, @Haruno Murayama, @Hironobu Matsueda, @Shujiro Otsuki, @Hiroshi Sakata, @Makoto Tokunaga*

    ChemCatChem   13 ( 22 )   4694 - 4699   2021.9

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    Language：English   Publishing type：Research paper (scientific journal)  

    Other Link： https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cctc.202101092

  • Enantioselective Protonation of Enol Esters with Bifunctional Phosphonium/Thiourea Catalysts Reviewed International journal

    @Eiji Yamamoto#Kodai Wakafuji#Yusuke#Mori Gaku#Teshima#Yuki Hidani@Makoto Tokunaga

    Organic Letters   21 ( 11 )   4030 - 4034   2019.5

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.orglett.9b01216

    Other Link： https://pubs.acs.org/doi/10.1021/acs.orglett.9b01216

  • Dynamic Kinetic Resolution of N-Protected Amino Acid Esters via Phase-Transfer Catalytic Base Hydrolysis Reviewed International journal

    Eiji Yamamoto, Kodai Wakafuji, Yuho Furutachi, Kaoru Kobayashi, Takashi Kamachi, and Makoto Tokunaga

    ACS Catalysis   8   5708 - 5713   2018.5

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acscatal.8b00693

    Other Link： https://pubs.acs.org/doi/10.1021/acscatal.8b00693

  • Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer Reviewed International journal

    Eiji Yamamoto, Margaret J. Hilton, Manuel Orlandi, Vaneet Saini, F. Dean Toste, Matthew S. Sigman

    Journal of the American Chemical Society   2016.11

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/jacs.6b11367

  • Direct Introduction of a Dimesitylboryl Group Using Base-Mediated Substitution of Aryl Halides with Silyldimesitylborane Invited Reviewed International journal

    Eiji Yamamoto, Kiyotaka Izumi, Ryosuke Shishido, Tomohiro Seki, Noriaki Tokoda, Hajime Ito

    Chemistry -A European Journal   22 ( 49 )   17547 - 17551   2016.8

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/chem.201604021

  • Copper(I)-Catalyzed Diastereoselective Borylative Exo-Cyclization of Alkenyl Aryl Ketones Reviewed International journal

    Eiji Yamamoto, Ryoto Kojima, Koji Kubota, Hajime Ito

    Synlett   27   272 - 276   2015.11

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  • Reaction Mechanism of the Anomalous Formal Nucleophilic Borylation of Organic Halides with Silylborane: Combined Theoretical and Experimental Studies Reviewed International journal

    Ryohei Uematsu, Eiji Yamamoto, Satoshi Maeda, Hajime Ito, Tetsuya Taketsugu

    Journal of the American Chemical Society   137 ( 12 )   4090 - 4099   2015.3

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  • Boryl Substitution of Functionalized Aryl-, Heteroaryl-, and Alkenyl Halides with Silylborane and Alkoxy Base: Expanded Scope and Mechanistic Studies Reviewed International journal

    Eiji Yamamoto, Satoshi Ukigai, Hajime Ito

    Chemical Science   6   2943 - 2951   2015.3

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  • Copper(I)-Catalyzed Enantioselective Synthesis of α-Chiral Linear or Carbocyclic (E)-γ-Alkoxyallylboronates Invited Reviewed International journal

    136 ( 47 )   16515 - 16521   2014.10

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  • Hydrolytic Enantioselective Protonation of Cyclic Dienyl Esters and a b-diketone　with Chiral Phase-transfer Catalysts. Reviewed International journal

    14 ( 24 )   6178 - 6181   2012.12

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  • Anomalous Reactivity of Silylborane: Transition-Metal-Free Boryl Substitution of Aryl, Alkenyl, and Alkyl Halides with Silylborane/Alkoxy Base Systems Reviewed International journal

    Eiji Yamamoto, Kiyotaka Izumi, Yuko Horita, Hajime Ito

    Journal of the American Chemical Society   134 ( 49 )   19997 - 20000   2012.11

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  • Catalytic Asymmetric Hydrolysis: Asymmetric Hydrolytic Protonation of Enolesters Catalyzed by Phase Transfer Catalysts Reviewed International journal

    Eiji Yamamoto, Ayano Nagai, Akiyuki Hamasaki, Makoto Tokunaga

    Chemistry -A European Journal   17 ( 26 )   7178 - 7182   2011.5

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  • Supported Noble Metal Catalysts and Adsorbents with Soft-Lewis Acid Functions Reviewed International journal

    @Haruno Murayama @Qi-An Huang @Eiji Yamamoto @Makoto Tokunaga @Tamao Ishida @Mitsutaka Okumura @Tetsuo Honma @Tadahiro Fujitani @Atsuko Isogai

    The Chemical Record   e202300148   2024.7

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    Language：Japanese   Publishing type：Research paper (scientific journal)  

    DOI： https://doi.org/10.1002/tcr.202300148

    Other Link： https://onlinelibrary.wiley.com/doi/full/10.1002/tcr.202300148

  • Supported Noble Metal Catalysts and Adsorbents with Soft Lewis Acid Functions Reviewed

    Haruno Murayama, Qi‐An Huang, Eiji Yamamoto, Makoto Tokunaga, Tamao Ishida, Mitsutaka Okumura, Tetsuo Honma, Tadahiro Fujitani, Atsuko Isogai

    The Chemical Record   23 ( 11 )   e202300148   2023.11   （ ISSN:1527-8999 eISSN:1528-0691 ）

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    Language：English   Publishing type：Research paper (scientific journal)   Publisher：Wiley  

    Abstract

    Heterogeneous noble metal catalysts exhibit various functions. Although their redox functions have been extensively studied, we focused on their soft Lewis acid functions. Supported Au, Pt, and Pd catalysts electrophilically attack the π‐electrons of soft bases such as alkynes, alkenes, and aromatic compounds to perform addition and substitution reactions. Hydroamination, intramolecular cyclization of alkynyl carboxylic acids, isomerization of allylic esters, vinyl exchange reactions, Wacker oxidation, and oxidative homocoupling of aromatics are introduced based on a discussion of the active species and reaction mechanisms. Furthermore, the adsorption of sulfur compounds, which are soft bases, onto the supported AuNPs is discussed. The adsorption and removal of 1,3‐dimethyltrisulfane (DMTS), which is the compound responsible for the stale odor of “hine‐ka” in alcoholic beverages, particularly Japanese sake, is described.

    DOI： 10.1002/tcr.202300148

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  • Heterogeneous Cobalt-Catalyzed H<sub>2</sub>S-Reagent-Free Dialkylpolysulfane Synthesis from Alkenes, Elemental Sulfur, and Hydrogen Reviewed

    Eiji Yamamoto, Yuta Takaki, Yasutaka Kawai, Kei Takakura, Moemi Kimura, Haruno Murayama, Takafumi Nagao, Takashi Kamachi, Hironobu Matsueda, Shujiro Otsuki, Hiroshi Sakata, Makoto Tokunaga

    ACS Catalysis   13 ( 21 )   14121 - 14130   2023.10   （ ISSN:2155-5435 eISSN:2155-5435 ）

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    Authorship：Lead author,　Corresponding author   Language：English   Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acscatal.3c03545

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  • Supported gold nanoparticles prepared from NHC-Au complex precursors as reusable heterogeneous catalysts Invited Reviewed International journal

    #Qi-An Huang #Mayu Takaki @Haruno Murayama @Akina Yoshizawa @Eiji Yamamoto @L. X. Dien @Tamao Ishida @Tetsuo Honma, @N. V. Tzouras @T. Scattolin @S. P. Nolan @Makoto Tokunaga

    Molecular Catalysis   113460   2023.10

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    Language：Japanese   Publishing type：Research paper (scientific journal)  

    Other Link： https://www.sciencedirect.com/science/article/pii/S2468823123005436

  • Supported gold nanoparticles prepared from NHC-Au complex precursors as reusable heterogeneous catalysts Reviewed

    Qi-An Huang, Mayu Takaki, Haruno Murayama, Akina Yoshizawa, Eiji Yamamoto, Luong Xuan Dien, Tamao Ishida, Tetsuo Honma, Nikolaos V. Tzouras, Thomas Scattolin, Steven P. Nolan, Makoto Tokunaga

    Molecular Catalysis   549   113460 - 113460   2023.10   （ ISSN:2468-8231 ）

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    Publishing type：Research paper (scientific journal)   Publisher：Elsevier BV  

    DOI： 10.1016/j.mcat.2023.113460

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  • Catalytic Asymmetric Transformation of Ester Group with Water and Alcohol as Nucleophiles

    Yamamoto Eiji, Kamachi Takashi, Tokunaga Makoto

    Journal of Synthetic Organic Chemistry, Japan   81 ( 8 )   798 - 808   2023.8   （ ISSN:00379980 eISSN:18836526 ）

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    Language：Japanese   Publisher：The Society of Synthetic Organic Chemistry, Japan  

    <p>An ester group is one of ubiquitous and important functional groups in the field of organic chemistry. Stereoselective transformations of substrates having ester groups using artificial catalysts such as metal complexes and organocatalysts have been developed such as 1,4-addition of α,β-unsaturated esters and functionalizations at α-carbon of esters. However, stereoselective transformations of the ester group itself have been still highly limited.</p><p>Hydrolase-catalyzed asymmetric hydrolysis of esters, which is a basic and important reaction categorized as the latter reaction type, has long been studied, and widely used from the lab scale to the industrial scale synthesis. However, enzymatic reactions generally have several issues such as their low specific activity and high cost. Under these circumstances, we hypothesized that stereoselective base hydrolysis of esters would be achieved by using liquid-liquid biphasic system with chiral onium salt catalysts. Herein, we describe the asymmetric base hydrolysis of esters using chiral onium salt catalysts derived from Cinchona alkaloids and chiral amino acids as well as the related dynamic kinetic resolution of azlactones via phase-transfer catalytic base alcoholysis. In addition, we also demonstrated the computational investigations using ConFinder program with pseudo-transition state conformational search (PTSCS) method.</p>

    DOI： 10.5059/yukigoseikyokaishi.81.798

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  • Catalytic Asymmetric Transformation of Ester Group with Water and Alcohol as Nucleophiles Invited Reviewed

    81   798 - 807   2023.8

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    Authorship：Lead author,　Corresponding author   Language：Japanese   Publishing type：Research paper (scientific journal)  

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  • A new strategy to exploit maximum rate performance for aqueous batteries through a judicious selection of MOF-type electrodes Reviewed

    Kosuke Nakamoto, Junwen Bai, Minyan Zhao, Ryo Sakamoto, Liwei Zhao, Masato Ito, Shigeto Okada, Eiji Yamamoto, Haruno Murayama, Makoto Tokunaga

    RSC Advances   13 ( 32 )   22070 - 22078   2023.7   （ eISSN:2046-2069 ）

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    Language：English   Publishing type：Research paper (scientific journal)   Publisher：Royal Society of Chemistry (RSC)  

    [Zn(dmpz)<sub>2</sub>NDI]<sub>n</sub>-MOF serves as a high rate capable anode for aqueous batteries thanks to its large pores. K<sup>+</sup>-based aqueous electrolytes may exploit its maximum rate performance, possibly because its hydrated ions can move freely in the electrode.

    DOI： 10.1039/d3ra03187j

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  • A new strategy to exploit maximum rate performance for aqueous batteries through a judicious selection of MOF-type electrodes Invited Reviewed International journal

    @Kosuke Nakamoto #Junwen Bai #Minyan Zhao @Ryo Sakamoto #Liwei Zhao @Masato Ito @Shigeto Okada @Eiji Yamamoto @Haruno Murayama @Makoto Tokunaga

    RSC Advance   13   22070   2023.7

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    Language：Japanese   Publishing type：Research paper (scientific journal)  

    DOI： DOI: 10.1039/d3ra03187j

    Other Link： https://pubs.rsc.org/en/content/articlelanding/2023/ra/d3ra03187j

  • Oxidative Decomposition Mechanism of Ethylene Carbonate on Positive Electrodes in Lithium-Ion Batteries Reviewed

    Yi-Fei Qiu, Haruno Murayama, Chisaki Fujitomo, Seiya Kawai, Asahi Haruta, Takumi Hiasa, Hiroki Mita, Kazunari Motohashi, Eiji Yamamoto, Makoto Tokunaga

    Bulletin of the Chemical Society of Japan   96 ( 5 )   444 - 451   2023.5   （ ISSN:0009-2673 eISSN:1348-0634 ）

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    Publishing type：Research paper (scientific journal)   Publisher：The Chemical Society of Japan  

    DOI： 10.1246/bcsj.20230027

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  • Oxidative Decomposition Mechanism of Ethylene Carbonate on Positive Electrodes in Lithium-Ion Batteries Reviewed International journal

    Qiu, Y.- F.; @Haruno Murayama #Chisaki Fujitomo #Seiya Kawai #Asahi Haruta @Takumi Hiasa @H. Mita @K. Motohashi @Eiji Yamamoto @Makoto Tokunaga

    Bull. Chem. Soc. Jpn.   96 ( 5 )   444 - 451   2023.4

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    Language：Japanese   Publishing type：Research paper (scientific journal)  

    DOI： https://doi.org/10.1246/bcsj.20230027

    Other Link： https://academic.oup.com/bcsj/article-abstract/96/5/444/7332876?redirectedFrom=fulltext

  • Investigation of reusability and deactivation mechanism of supported platinum catalysts in the practical isomerization of allylic esters Reviewed

    Qi-An Huang, Haruno Murayama, Eiji Yamamoto, Tetsuo Honma, Makoto Tokunaga

    Catalysis Today   410   215 - 221   2023.2   （ ISSN:0920-5861 eISSN:1873-4308 ）

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    Publishing type：Research paper (scientific journal)   Publisher：Elsevier BV  

    Metal oxides supported platinum catalysts with residual chloride are known to be reusable soft Lewis acid catalysts for the isomerization of allylic esters. To deepen the understanding of the industrial application of the catalytic system and optimize the catalyst design, an investigation on the reusability and deactivation mechanism of supported platinum catalysts in the isomerization of but-3-ene-1,2-diyl diacetate was conducted. A great reactivation effect was observed by treating the used catalysts with HCl, rather than that of calcination. Pt-Cl/CeO2 showed the best reusability among the catalysts prepared with other metal oxides, and it was uncovered that the reduction of PtOxCly species should be the main reason for deactivation with the assistance of X-ray absorption fine structure (XAFS) analysis. Besides, a relatively stable state was also observed from the XAFS spectra of Pt-Cl/CeO2 catalysts in the reusing test, and it could effectively prevent the active species from further deactivation. Furthermore, in an extended evaluation of the stability of the catalysts, reusability, and a limited deactivation were also verified through a 10-run batch reaction. Additionally, the continuous flow reaction was also proven to be feasible.

    DOI： 10.1016/j.cattod.2022.06.007

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  • Theoretical Mechanistic Investigation of the Dynamic Kinetic Resolution of N-Protected Amino Acid Esters using Phase-Transfer Catalysts Invited Reviewed

    Eiji Yamamoto, Kaoru Kobayashi, Kodai Wakafuji, Takashi Kamachi, Makoto Tokunaga

    Journal of Organic Chemistry   88 ( 12 )   7748 - 7754   2023.2   （ ISSN:0022-3263 eISSN:1520-6904 ）

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    Authorship：Lead author,　Corresponding author   Language：English   Publishing type：Research paper (scientific journal)  

    A detailed theoretical mechanistic investigation on the dynamic kinetic resolution of N-protected amino acid esters using phase-transfer catalysts is described. Semiautomatic exhaustive conformation search of transition state (TS)-like structures were carried out using the ConFinder program and the pseudo-TS conformational search (PTSCS) method. This conformational search method successfully provided reasonable TS structures for determining the stereoselectivity in the asymmetric base hydrolysis of hexafluoroisopropyl (HFIP) esters as well as the racemization mechanism. Furthermore, the independent gradient model (IGM) analysis of the TS structures suggested that the H-bonding interactions with the oxyanion hole and π-stacking interactions are the common important features of the proposed TS structures that determine the stereoselectivity.

    DOI： 10.1021/acs.joc.2c02352

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  • Catalytic Asymmetric Transformation of Ester Group with Water and Alcohol as Nucleophiles

    Yamamoto, E; Kamachi, T; Tokunaga, M

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   81 ( 8 )   798 - 808   2023   （ ISSN:0037-9980 ）

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  • A new strategy to exploit maximum rate performance for aqueous batteries through a judicious selection of MOF-type electrodes

    Nakamoto Kosuke, Bai Junwen, Zhao Minyan, Sakamoto Ryo, Zhao Liwei, Ito Masato, Okada Shigeto, Yamamoto Eiji, Murayama Haruno, Tokunaga Makoto

    RSC Advances   13 ( 32 )   22070 - 22078   2023   （ eISSN:20462069 ）

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    A metal–organic framework (MOF) having a redox active 1,4,5,8-naphthalenetetracarboxdiimide (NDI) derivative in its organic linker shows excellent rate performance as an electrode material for aqueous batteries thanks to its large pores. Among aqueous electrolytes examined, K+-based ones exhibit the highest rate performance, which is caused by the highest mobility of the smallest hydrated K+ ion not only in the aqueous electrolyte but also in the electrode. Since the use of a counter electrode with insufficiently small pores for the full-cell configuration offsets this merit, our study may lead to a conclusion that the maximum rate performance for aqueous batteries will be accomplished only through further elaboration of both electrode materials with sufficiently large pores, in which hydrated ions can travel equally fast as those in the electrolyte.

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  • Ultraviolet light-induced decomposition of benzothiophene and dibenzothiophene derivatives for efficient sulfur removal without additives and catalysts Reviewed

    Taka-Aki Shinozaki, Masahiko Suenaga, Yohan Ko, Eiji Yamamoto, Haruno Murayama, Makoto Tokunaga

    Journal of Cleaner Production   370   133402 - 133402   2022.10   （ ISSN:0959-6526 eISSN:1879-1786 ）

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    Publishing type：Research paper (scientific journal)   Publisher：Elsevier BV  

    When producing liquid fuels from petroleum, hydrodesulfurization methods reduce the concentration of sulfur to ≤10 mg(S)/L (weight/volume concentration of sulfur), namely, ≤ 0.31 mmol/L. Dibenzothiophene derivatives (DBTs), which are known as particularly difficult desulfurizing substances, have been decomposed reductively in severe conditions of high temperatures (270–372 °C) and high pressure (50–102 atm of H2). In this study, we developed a UV light irradiation-based desulfurization method for aromatic sulfur compounds such as benzothiophene derivatives (BTs) and DBTs under room temperature and atmospheric pressure without the use of catalysts or additives. This method is simple, location-independent, and low-cost, and has low environmental impact. BTs and DBTs completely decomposed in approximately 8 h and 16 h, respectively, under ultraviolet (UV) light irradiation (λ = 254 nm) from a 8 W lamp. The yellow precipitates that were produced upon decomposition were confirmed to be sulfur allotropes (Sn). The residual hydrocarbon portion of DBT after sulfur removal was determined to be benzene. The decomposition reaction was determined to exhibit pseudo-first-order reaction. DFT calculations confirmed the degradation mechanism as follows: UV light irradiation induces a photochemically excited triplet state of DBTs. The excited DBTs reacts with O2 to form a π-complex, which isomerizes to a more stable σ-complex. The DBTs-O2 (σ-complex) then reacts with free DBTs to afford two molecules of dibenzothiophene-5-oxide derivatives (DBTOs), which are excited to singlet states on photoirradiation. The excited DBTOs isomerize through a minimum energy intersection eventually to dibenzofuran episulfides from which sulfur extrusion occurs.

    DOI： 10.1016/j.jclepro.2022.133402

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  • Aerobic oxidation of isoprene glycol with platinum-bismuth nanoparticles catalysts supported on metal oxides Reviewed

    Yasutaka Kawai, Kazuki Haruguchi, Keisei Sumikawa, Mai Kawada, Eiji Yamamoto, Haruno Murayama, Makoto Tokunaga

    Applied Catalysis A: General   643   118781 - 118781   2022.8   （ ISSN:0926-860X eISSN:1873-3875 ）

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    Authorship：Corresponding author   Publishing type：Research paper (scientific journal)   Publisher：Elsevier BV  

    β-Hydroxy β-methylbutyric acid (HMB) is expected as a promising therapeutic agent or a supplement. For industrial production of HMB, Pt-catalyzed aerobic oxidation of isoprene glycol is a potent synthetic method. However, the previous report using Pt-Bi catalyst supported on active carbon suffered from low tolerance to high substrate concentration conditions, which leads to low volumetric productivity. Herein, we report aerobic oxidation of isoprene glycol using Pt-Bi catalysts supported on ZrO2 or TiO2, showing high tolerance to the high substrate concentration conditions. In addition, these catalysts exhibited high recyclability. Scanning transmission electron microscopy analyses suggested the Pt-Bi species supported on ZrO2 or TiO2 are less likely to aggregate than those supported on activated carbon. Additionally, these metal oxides supported catalysts showed lower metal leaching than the carbon supported catalysts. Besides, the results of the various control experiments indicated the prevention of dehydration of an aldehyde intermediate is important for further improvement.

    DOI： 10.1016/j.apcata.2022.118781

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  • Intramolecular cyclization of alkynoic acid catalyzed by Na-salt-modified Au nanoparticles supported on metal oxides Reviewed

    Qi-An Huang, Takaaki Ikeda, Kazuki Haruguchi, Seiya Kawai, Eiji Yamamoto, Haruno Murayama, Tamao Ishida, Tetsuo Honma, Makoto Tokunaga

    Applied Catalysis A: General   643   118765 - 118765   2022.8   （ ISSN:0926-860X eISSN:1873-3875 ）

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    Authorship：Corresponding author   Language：English   Publishing type：Research paper (scientific journal)   Publisher：Elsevier BV  

    Zirconia-supported sodium-salt-modified Au(0) nanoparticles (NPs) (Na-Au/ZrO2) catalyst was prepared, and it was stable and recyclable in the intramolecular cyclization of alkynoic acids. In particular, the effect of sodium species in Na-Au/ZrO2, which has been overlooked in previous studies, was studied, and they were found to play an essential role in the reaction. In addition, the relationship between the kinetics and size of Au NPs revealed that the active sites of the catalyst are located on the surface of the supported Au NPs. Moreover, detailed kinetic studies revealed that the cyclization was a zero-order reaction with respect to substrate concentration, and the rate-determining step of the reaction is presumed to be protodeauration. The maximum turnover number (TON) of the reaction of 5-hexynoic acid in a continuous flow reactor exceeded 9000, which is the highest TON obtained in the presence of a heterogeneous Au catalyst.

    DOI： 10.1016/j.apcata.2022.118765

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  • Ultraviolet light-induced decomposition of benzothiophene and dibenzothiophene derivatives for efficient sulfur removal without additives and catalysts Invited Reviewed International journal

    #Taka-Aki Shinozaki, @Masahiko Suenaga, #Yohan Ko, @Eiji Yamamoto, @Haruno Murayama, @Makoto Tokunaga

    Journal of Cleaner Production   370 ( 10 )   2022.8

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    DOI： https://doi.org/10.1016/j.jclepro.2022.133402

    Other Link： https://www.sciencedirect.com/science/article/pii/S0959652622029857?via%3Dihub

  • Investigation of reusability and deactivation mechanism of supported platinum catalysts in the practical isomerization of allylic esters Reviewed International journal

    #Qi-An Huang, @Haruno Murayama, @Eiji Yamamoto, @Tetsuo Honma, @Makoto Tokunaga

    Catalysis Today   2022.6

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    DOI： https://doi.org/10.1016/j.cattod.2022.06.007

    Other Link： https://www.sciencedirect.com/science/article/pii/S0920586122002292

  • C-H bond functionalization using Pd and Au supported catalysts with mechanistic insights of the active species Reviewed International journal

    Ishida, T.; Zhang, Z.; @Murayama, H.; @Yamamoto, E.; @Tokunaga, M.

    Synthesis in press. Special Issue - Bond Activation in Honor of Prof. Shinji Murai DOI: 10.1055/a-1468-1455   2021.6

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    Language：Japanese   Publishing type：Research paper (scientific journal)  

    DOI： 10.1055/a-1468-1455

  • Pt/CeO2 with residual chloride as reusable soft Lewis acid catalysts: application to highly efficient isomerization of allylic esters Reviewed International journal

    Huang, Q.-A.; Haruta, A.; Kumamoto, Y.; @Murayama, H.; @Yamamoto, E.; Honma, T.; Okumura, M.; Nobutou, H.; T@okunaga M.

    Appl. Catal. B, Environ., 2021, 296, 120333. DOI: https://doi.org/10.1016/j.apcatb.2021.120333   2021.6

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  • 担持金ナノ粒子を用いた老香成分DMTS除去技術の実用化に向けた検討 Reviewed

    @磯谷敦子,村山美乃,#木村萌水,#篠﨑貴旭,山本英治,@藤井力,@飯塚幸子,徳永信

    日本醸造協会誌   114   779 - 786   2019.12

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  • The additive effect of amines on the dihydroxylation of buta-1,3-diene into butenediols by supported Pd catalysts. Reviewed International journal

    #Zhenzhong Zhang,#Tetsuya Mamba,#Qi-An Huang,Haruno Murayama,Eiji Yamamoto,@Tetsuo Honma,Makoto Tokunaga

    Molecular Catalysis   475   110502   2019.10

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    DOI： doi.org/10.1016/j.mcat.2019.110502

  • The additive effect of amines on the dihydroxylation of buta-1,3-diene into butenediols by supported Pd catalysts Invited Reviewed International journal

    #Zhenzhong Zhang,#Tetsuya Mamba,#Qi-An Huang, Haruno Murayama, Eiji Yamamoto,@Tetsuo Honma, Makoto Tokunaga

    Molecular Catalysis   2019.10

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    DOI： 10.1016/j.mcat.2019.110502

    Other Link： https://www.sciencedirect.com/science/article/pii/S2468823119303402?via%3Dihub

  • Direct transformation of terminal alkenes with H2O into primary alcohols over metal oxide-supported Pd catalysts. Invited Reviewed International journal

    #Zhenzhong Zhang,#Tetsuya Mamba, Eiji Yamamoto, Haruno Murayama,@Tamao Ishida,@Tetsuo Honma,@Tadahiro Fujitani, Makoto Tokunaga

    Applied Catalysis B: Environmental   246 ( 5 )   100 - 110   2019.6

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    Language：Japanese   Publishing type：Research paper (scientific journal)  

    DOI： 10.1016/j.apcatb.2019.01.031

  • Formal Nucleophilic Silyl Substitution of Aryl Halides with Silyllithium Reagents via Halogenophilic Attack of Silyl Nucleophiles Reviewed

    Eiji Yamamoto, Satoshi Ukigai, Hajime Ito

    Synlett   28 ( 18 )   2460 - 2464   2017.11

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    DOI： 10.1055/s-0036-1590835

  • Mechanistic Investigations of the Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Benzyl Acrylates Reviewed

    Manuel Orlandi, Margaret J. Hilton, Eiji Yamamoto, F. Dean Toste, Matthew S. Sigman

    Journal of the American Chemical Society   139 ( 36 )   12688 - 12695   2017.9

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    DOI： 10.1021/jacs.7b06917

  • Tris(trimethylsilyl)silylboronate Esters Novel Bulky, Air- and Moisture-Stable Silylboronate Ester Reagents for Boryl Substitution and Silaboration Reactions Reviewed

    Eiji Yamamoto, Ryosuke Shishido, Tomohiro Seki, Hajime Ito

    Organometallics   36 ( 16 )   3019 - 3022   2017.8

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.organomet.7b00476

  • Wacker Oxidation of Terminal Alkenes Over ZrO2-Supported Pd Nanoparticles Under Acid- and Cocatalyst-Free Conditions Reviewed

    Zhenzhong Zhang, Yuhya Kumamoto, Taishin Hashiguchi, Tetsuya Mamba, Haruno Murayama, Eiji Yamamoto, Tamao Ishida, Tetsuo Honma, Makoto Tokunaga

    ChemSusChem   10 ( 17 )   3482 - 3489   2017.8

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/cssc.201701016

  • Copper(I)-Catalyzed Carbon–Halogen Bond-Selective Boryl Substitution of Alkyl Halides Bearing Terminal Alkene Moieties Invited Reviewed International journal

    51   9655 - 9658   2015.5

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  • Silicon-Tethered Strategy for Copper(I)-Catalyzed Stereo- and Regioselective Alkylboration of Alkynes Reviewed International journal

    Koji Kubota, Iwamoto Hiroaki, Eiji Yamamoto, Hajime Ito

    Organic Letters   17 ( 3 )   620 - 623   2015.1

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  • Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aldehydes: an Efficient Route to Enantiomerically Enriched α-Alkoxyorganoboronate Esters Reviewed International journal

    137 ( 1 )   420 - 424   2014.12

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  • Regio- and Enantioselective Monoborylation of Alkenylsilanes Catalyzed by an Electron-Donating Chiral Phosphine–Copper(I) Complex Reviewed International journal

    355   3527 - 3531   2013.12

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  • Copper(I)-Catalyzed Borylative Exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond Reviewed International journal

    Koji Kubota, Eiji Yamamoto, Hajime Ito

    Journal of the American Chemical Society   135 ( 7 )   2635 - 2640   2013.1

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  • Bacteroides thetaiotaomicron VPI-5482 glycoside hydrolase family 66 homolog catalyzes dextranolytic and cyclization reactions Reviewed International journal

    Young-Min Kim, Eiji Yamamoto, Min-Sun Kan, Hiroyuki Nakai, Wataru Saburi, Masayuki Okuyama, Haruhide Mori, Kazumi Funane, Mitsuru Momma, Zui Fujimoto, Mikihiko Kobayashi, Doman Kim, Atsuo Kimura

    The FEBS Journal   279 ( 17 )   3185 - 3191   2012.8

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  • Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes Reviewed International journal

    Eiji Yamamoto, Yuko Horita, Hajime Ito

    Chemical Communication   48   8006 - 8008   2012.6

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  • Kinetic resolution of P-chirogenic compounds by Pd-catalyzed alcoholysis of vinyl ethers Invited Reviewed International journal

    Itoh Hisashi, Eiji Yamamoto, Shigeyuki Masaoka, Ken Sakai, Makoto Tokunaga

    Advanced Synthesis & Catalysis   351 ( 11/12 )   1796 - 1800   2009.7

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  • Kinetic resolution of phosphoryl and sulfonyl esters of 1,1′-bi-2-naphthol via Pd-catalyzed alcoholysis of their vinyl ethers Reviewed International journal

    19 ( 13 )   1593 - 1599   2008.7

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Presentations

  • Bifunctional Phosphonium/Thiourea Salts as Phase-Transfer Catalysts: Enantioselective Protonation of Alkenyl Esters International conference

    #Kodai Wakafuji, #Yusuke Mori, #Gaku Teshima, #Yuki Hidani, @Eiji Yamamoto, and @Makoto Tokunaga

    24th Joint symposium between KB-CSJ and BB-KCS  2019.6 

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    Event date： 2019.6

    Language：English  

    Country：Japan  

  • Phase-Transfer Catalyzed Asymmetric Alcoholysis of N-Protected Amino Acid Esters and Azlactones via Dynamic Kinetic Resolution International conference

    #Kodai Wakafuji , #Hyemin Cho, @Takashi Kamachi, @Eiji Yamamoto, @Makoto Tokunaga

    2018.11 

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    Event date： 2018.11

    Language：English  

    Country：Japan  

  • Bifunctional Thiourea-Quaternary Phosphonium Salts Catalyzed Enantioselective Protonation of Alkenyl Esters International conference

    #Gaku Teshima, #Yusuke Mori, #Yuki Hidani, @Eiji Yamamoto, @Makoto Tokunaga

    IRCCS-JST CREST Joint Symposium  2018.1 

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    Event date： 2018.1

    Language：English  

    Country：Japan  

  • Asymmetric Base Hydrolysis of 2–Arylpropanoic Acid Esters Catalyzed by Chiral Phase-Transfer Catalysts. International conference

    2016.11 

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    Event date： 2016.11

    Language：English   Presentation type：Oral presentation (general)  

    Venue：Taipei   Country：Taiwan, Province of China  

  • 担持Pt-Bi 触媒を用いたアルコール類の空気酸化

    ＃春口 一騎・＃山本 向洋・河合 靖貴・＠山本 英治・村山 美乃・＠吉澤 明菜・＠徳永 信

    日本化学会第104春季年会  2024.4 

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    Event date： 2024.4

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉   Country：Japan  

  • 二官能性アミノ-チオウレア触媒を用いたアズラクトン類のヒドラジンによる不斉開環反応とそれに伴う優先富化現象

    #向野 友稀 ・ 河合 靖貴 ・ #市川 聖人 ・ @山本 英治 ・@吉澤 明菜 ・@徳永 信

    日本化学会第104春季年会  2024.4 

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    Event date： 2024.4

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉   Country：Japan  

  • 固体コバルト触媒を用いた、水素、硫黄、アルケンを原料とするポリスルファン合成

    ＠山本英治・＃髙城悠太・河合靖貴・＠村山美乃・松枝宏尚・坂田浩・大槻周次郎・＠徳永信

    第132回触媒討論会  2023.9 

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    Event date： 2023.9

    Language：Japanese  

    Venue：札幌   Country：Japan  

  • ジルコニア担持パラジウム触媒によるアルケン類のアルコキシカルボニル化反応

    白倉那桜・＃春口一騎・＠村山美乃・＠山本英治・＠吉澤明菜・＃迫水裕斗・本間徹生・＠徳永信

    第132回触媒討論会  2023.9 

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    Event date： 2023.9

    Language：Japanese  

    Venue：札幌   Country：Japan  

  • マンガン修飾チタニア担持金ナノ粒子触媒によるメタクロレインの液相選択酸化反応

    ＃沈思婷, 邱逸飛, ＠山本英治, ＠村山美乃, 加藤裕樹, 二宮航, ＠徳永信

    第60回化学関連支部九州地区合同大会  2023.7 

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    Event date： 2023.7

    Language：Japanese  

    Venue：北九州   Country：Japan  

  • 水素ガスを使用したアセタールの選択的還元反応の開発

    ＃市川聖人,＠ 山本英治,＠ 村山美乃, ＠徳永信

    第60回化学関連支部九州地区合同大会  2023.7 

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    Event date： 2023.7

    Language：Japanese  

    Venue：北九州   Country：Japan  

  • リチウムイオン電池電解液の充電正極による酸化分解反応の解析

    ＠村山　美乃、邱　逸飛、藤友千咲希、＠山本　英治、＠徳永　信

    第33 回万有福岡シンポジウム  2023.6 

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    Event date： 2023.6

    Language：Others   Presentation type：Oral presentation (general)  

    Venue：福岡   Country：Japan  

  • チウムイオン電池電解液の充電正極による酸化分解反応の解析

    村山　美乃、邱　逸飛、藤友千咲希、山本　英治、徳永　信

    第33 回万有福岡シンポジウム  2023.6 

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    Event date： 2023.6

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：Fukuoka   Country：Japan  

  • Titanium oxide catalyzed photo-oxidation of dibenzothiophene for desulfurization of liquid fuel International conference

    #Takahiro Yamauchi, Taka-Aki Shinozaki, Yohan Ko, @Haruno Murayama,@ Eiji Yamamoto, @Makoto Tokunaga

    19th Korea-Japan Symposium on Catalysis  2023.5 

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    Event date： 2023.5

    Language：Japanese  

    Country：Korea, Republic of  

  • Titanium oxide catalyzed photo-oxidation of dibenzothiophene for desulfurization of liquid fuel International conference

    9th Korea-Japan Symposium on Catalysis  2023.5 

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    Event date： 2023.5

    Language：Japanese   Presentation type：Oral presentation (general)  

    Country：Korea, Republic of  

  • Supported Au Nanoparticles-Catalyzed Isomerization of Allylic Esters with a Flow Reactor International conference

    19th Korea-Japan Symposium on Catalysis  2023.5 

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    Event date： 2023.5

    Language：Japanese  

    Country：Korea, Republic of  

  • Supported Au Nanoparticles-Catalyzed Isomerization of Allylic Esters with a Flow Reactor International conference

    19th Korea-Japan Symposium on Catalysis  2023.5 

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    Event date： 2023.5

    Language：Japanese  

    Country：Japan  

  • 固体コバルト触媒を用いた、水素、硫黄、アルケンを原料とするジアルキルポリスルファン類の新合成法

    ＠山本 英治、＃髙城 悠太、河合 靖貴、＠村山 美乃、松枝 宏尚、坂田 浩、大槻 周次郎、＠徳永 信

    日本化学会第103春季年会  2023.3 

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    Event date： 2023.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉   Country：Japan  

  • 担持酸化タングステン触媒を用いたジベンゾチオフェンの可視光酸化と光脱硫

    #山内 崇弘、#篠﨑 貴旭、@村山 美乃、@山本 英治、@徳永 信

    日本化学会第103春季年会  2023.3 

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    Event date： 2023.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉   Country：Japan  

  • シリカ担持貴金属ナノ粒子上への硫黄化合物の選択的吸着

    ＃松川 一聖、＠徳永 信、＠村山 美乃、＠山本 英治、＃篠崎 貴旭、高 ヨハン1

    日本化学会第103春季年会  2023.3 

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    Event date： 2023.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉   Country：Japan  

  • 固体コバルト触媒を用いた水素、硫黄、アルケンを原料とするチオール類の新合成法開発

    ＃許 柯、＠山本 英治、＠村山 美乃、松枝 宏尚、坂田 浩、＠徳永 信

    日本化学会第103春季年会  2023.3 

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    Event date： 2023.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉   Country：Japan  

  • 金属酸化物担持金ナノ粒子触媒によるアリルエステル異性化の連続フロー反応

    ＃佐藤 一斗、＃黄 啓安、＠村山 美乃、＠山本 英治、鈴木 葉裕、＠徳永 信

    日本化学会第103春季年会  2023.3 

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    Event date： 2023.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉   Country：Japan  

  • 固体触媒を用いたジアルキルポリスルファン類の硫化水素フリーな新規合成法

    ＃髙城 悠太・河合 靖貴・高倉 慶・木村 萌水・松枝 宏尚・坂田 浩・大槻 周次郎・＠山本 英治・＠村山 美乃・＠徳永 信

    第12回CSJ化学フェスタ2022  2022.10 

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    Event date： 2022.10

    Language：Japanese  

    Venue：東京   Country：Japan  

  • ジルコニア担持金ナノ粒子触媒を用いたアリルエステルの異性化反応

    ＃佐藤一斗 、＃黄啓安 、＠村山美乃 、＠山本英治 、 石田玉青 、 鈴木葉裕 、 ＠徳永信

    第38回有機合成化学セミナー  2022.9 

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    Event date： 2022.9

    Language：Japanese  

    Venue：北九州   Country：Japan  

  • アリルエステルの異性化反応におけるジルコニア担持金ナノ粒子触媒の活性検討

    ＃黄 啓安 、＃佐藤 一斗 、＠村山 美乃 、＠山本 英治 、石田 玉青 、鈴木 葉裕 、＠徳永 信

    第130回触媒討論会  2022.9 

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    Event date： 2022.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：富山   Country：Japan  

  • メタクロレインの液相選択酸化反応におけるチタニア担持金触媒へのマンガン添加効果

    ＃邱逸飛 、＠山本 英治 、＠村山 美乃 、加藤 裕樹 、二宮 航 、＠徳永 信

    第130回触媒討論会  2022.9 

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    Event date： 2022.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：富山   Country：Japan  

  • ジルコニア担持パラジウム触媒を用いたカルボニル化によるエステルの合成

    ＃白倉那桜, シムジュヨン, ＠山本英治,＠ 村山美乃, 本間徹生, ＠徳永信

    XAFS夏の学校2022  2022.9 

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    Event date： 2022.9

    Language：Japanese  

    Venue：茨城   Country：Japan  

  • 実用的なアリルエステル異性化反応における担持Pt触媒の再利用性と構造解析

    ＃黄啓安，＠村山美乃，＠山本英治，本間徹生，＠徳永信

    第25回XAFS討論会  2022.8 

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    Event date： 2022.8

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：佐賀   Country：Japan  

  • Development of an efficient desulfurization method for aromatic organic sulfur compounds in fuel using ultraviolet light International conference

    #Taka-Aki Shinozaki, @Masahiko Suenaga, Yohan Ko, @Eiji Yamamoto, @Haruno Murayama, @Makoto Tokunaga

    12th International Conference on Environmental Catalysis (ICEC2022)  2022.8 

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    Event date： 2022.7 - 2022.8

    Language：Japanese  

    Country：Japan  

  • Na-salt-modified Au nanoparticles supported on metal oxides as catalysts for intramolecular cyclization of alkynoic acid International conference

    The 9th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT9)  2022.7 

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    Event date： 2022.7

    Language：Japanese  

    Country：Japan  

  • 担持金ナノ粒子による本格焼酎に含まれる硫黄化合物の吸着特性

    ＃福重智基, ＠村山美乃, 磯谷敦子, ＠山本英治, ＠徳永信

    第59回化学関連支部合同九州大会  2022.7 

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    Event date： 2022.7

    Language：Japanese  

    Venue：福岡   Country：Japan  

  • 担持金ナノ粒子前駆体としての金－アミノ酸錯体合成条件の検討

    ＃深江友博, ＠村山美乃, ＠山本英治, ＠徳永信

    第５９回化学関連支部合同九州大会  2022.7 

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    Event date： 2022.7

    Language：Japanese  

    Venue：福岡   Country：Japan  

  • 燃料中に含まれるジベンゾチオフェン誘導体の紫外線を用いた効率的な脱硫法の開発

    #篠﨑 貴旭，@末永 正彦，高 ヨハン，@山本 英治，@村山 美乃，@徳永 信

    第32回福岡万有シンポジウム  2022.6 

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    Event date： 2022.6

    Language：Japanese  

    Venue：福岡   Country：Japan  

  • ジルコニア担持パラジウムが触媒する位置選択的アルコキシカルボニル化反応

    #白倉 那桜1、@Joo Young Shim、#春口 一騎、森 陽暉、＠山本 英治、＠村山 美乃、本間 徹生、＠徳永 信

    日本化学会第102春季年会  2022.3 

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    Event date： 2022.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：オンライン   Country：Japan  

  • チタニア担持銀ナノ粒子を用いたジベンゾチオフェンの可視光酸化

    #山内 崇弘、#篠﨑 貴旭、高 ヨハン、@村山 美乃、@山本 英治、@徳永 信

    日本化学会第102春季年会  2022.3 

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    Event date： 2022.3

    Language：Japanese  

    Venue：オンライン   Country：Japan  

  • 担持0価金ナノ粒子触媒によるアルキニルカルボン酸の分子内環化反応におけるナトリウム塩添加効果

    @山本 英治、#黄 啓安、池田 孝明、川相 誓也、#春口 一騎、@村山 美乃、石田 玉青、本間 徹生、@徳永 信

    日本化学会第102春季年会  2022.3 

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    Event date： 2022.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：オンライン   Country：Japan  

  • 相間移動触媒によるアズラクトン類の不斉加アルコール分解反応

    #岩佐 颯起、#若藤 空大、#大内田 希奈、@山本 英治、蒲池 高志、@徳永 信

    日本化学会第102春季年会  2022.3 

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    Event date： 2022.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：オンライン   Country：Japan  

  • 担持パラジウム触媒を用いたアルコキシカルボニル化におけるホスフィン配位子の添加効果 （ｐ-11）

    #白倉 那桜, @シム ジュヨン, 森 陽暉, @山本 英治, @村山 美乃, 本間 徹生, @徳永 信

    第31回キャラクタリゼーション講習会「触媒および表面の解析に役立つキャラクタリゼーションの基礎と実際」  2022.1 

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    Event date： 2022.1

    Language：Japanese  

    Venue：熊本   Country：Japan  

  • ナトリウム修飾した担持金ナノ粒子触媒によるアルキニルカルボン酸の分子内環化反応

    #黄 啓安、川相 誓也、池田 孝明、@山本 英治、@村山 美乃、石田 玉青、@徳永 信

    第128回触媒討論会  2021.9 

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    Event date： 2021.9

    Language：Japanese  

    Venue：オンライン   Country：Japan  

  • 金属酸化物担持白金―ビスマス合金を触媒とした イソプレングリコールの空気酸化反応

    #河合 靖貴、隅川 佳星、#川田 真衣、@山本 英治、@村山 美乃、@徳永 信

    第128回触媒討論会  2021.9 

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    Event date： 2021.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：オンライン   Country：Japan  

  • 含浸法による活性炭担持金ナノ粒子の調製と硫黄化合物の選択的吸着

    @村山 美乃、高木 真由、本間 徹生、小林 康浩、磯谷 敦子、飯塚 幸子、@山本 英治、@徳永 信

    第128回触媒討論会  2021.9 

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    Event date： 2021.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：オンライン   Country：Japan  

  • チタニア担持鉛触媒による分子状酸素を酸化剤としたcis-シクロオクテンのエポキシ化

    #大内田希奈、@山本英治、木下義輝、隅川佳星、@村山美乃、本間徹生、@徳永信

    第33回若手研究者のためのセミナー  2021.8 

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    Event date： 2021.8

    Language：Japanese  

    Venue：WEB   Country：Japan  

  • 金ナノ粒子蒸着基板を用いた難脱硫性硫黄化合物の光分解

    ＃山内崇弘, ＠村山美乃, ＃篠崎貴旭, ＠山本英治, 徳永信

    第58回化学関連支部合同九州大会  2021.7 

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    Event date： 2021.7

    Language：Japanese  

    Venue：WEB   Country：Japan  

  • ジルコニア担持・チタニア担持白金ービスマス合金を触媒としたイソプレングリコールの空気酸化反応

    #河合靖貴, 隅川佳星, #川田真衣,@ 山本英治,@ 村山美乃, @徳永信

    第58回化学関連支部合同九州大会  2021.7 

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    Event date： 2021.7

    Language：Japanese  

    Venue：WEB   Country：Japan  

  • パラジウム触媒によるアルケン類のアルコキシカルボニル化反応

    ＃白倉那桜,＠ シムジュヨン, ＠山本英治, ＠村山美乃, ＠徳永信

    第58回化学関連支部合同九州大会  2021.7 

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    Event date： 2021.7

    Language：Japanese  

    Venue：WEB   Country：Japan  

  • 不斉相間移動触媒を用いたアズラクトン類の動的速度論分割型加アルコール分解

    ＃大内田希奈, ＃若藤空大, ＃岩佐颯起, チョヘミン, ＃土肥弘嗣, ＠山本英治, 蒲池高志, ＠徳永信

    第58回化学関連支部合同九州大会  2021.7 

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    Event date： 2021.7

    Language：Japanese  

    Venue：WEB   Country：Japan  

  • リチウムイオン電池正極における有機電解液の反応解析

    ＃川相誓也，＠村山美乃，日浅巧，三田洋樹，本橋一成，＠山本英治，＠徳永信

    2021.3 

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    Event date： 2021.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Country：Japan  

  • シリカ担持金ナノ粒子を用いた焼酎に含まれる硫黄化合物の吸着

    ＃八木 政俊・＠村山 美乃・＃高木 真由・磯谷 敦子・＠山本 英治・飯塚 幸子・＠徳永 信

    第10回CSJ化学フェスタ  2020.10 

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    Event date： 2020.10

    Language：Japanese  

    Venue：オンライン   Country：Japan  

  • 担持ルテニウム触媒による流通式オレフィン 不斉水素化反応

    ＃宮田 透子・村上 亜紀子・＠村山 美乃・＠山本 英治・＠徳永 信

    第10回CSJ化学フェスタ  2020.10 

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    Event date： 2020.10

    Language：Japanese  

    Venue：オンライン   Country：Japan  

  • 固体塩基触媒を用いたチオール-ジスルファン交換反応による非対称ジスルファン合成

    ＠山本英治・＃河合靖貴・木村萌水・高倉慶・＠村山美乃・松枝宏尚・大槻周次郎・坂田浩・＠徳永信

    第126回触媒討論会  2020.10 

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    Event date： 2020.10

    Language：Japanese  

    Venue：オンライン   Country：Japan  

  • 含浸法による担持金ナノ粒子調製における金―アミノ酸錯体分解過程の解析

    @村山美乃・#高木真由・本間徹生・小林康浩・磯谷敦子・飯塚幸子・奥村光隆・@山本英治・@徳永信

    第126回触媒討論会  2020.10 

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    Event date： 2020.10

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：オンライン   Country：Japan  

  • 金属酸化物担持白金-ビスマス触媒を用いたイソプレングリコールの空気酸化

    #河合靖貴・ 隅川佳星・#川田真衣・@山本英治・@村山美乃・@徳永信

    第126回触媒討論会  2020.10 

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    Event date： 2020.10

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：オンライン   Country：Japan  

  • Phase-Transfer Catalytic Dynamic Kinetic Resolution of Amino Acid Esters with Water and Alcohols as Nucleophiles

    2020.3 

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    Event date： 2020.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Country：Japan  

  • 分子状酸素を酸化剤とした固体鉛触媒によるアルケンのエポキシ化反応

    ＃隅川 佳星・木下 義輝・＃＠山本 英治・＠村山 美乃・＠徳永 信

    日本化学会第100春季年会  2020.3 

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    Event date： 2020.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉   Country：Japan  

  • 担持金ナノ粒子を用いたジメチルトリスルファンの流通循環式除去

    ＠村山 美乃・＃小宮 晋世・＠山本 英治・磯谷 敦子・飯塚 幸子・＠徳永 信

    日本化学会第100春季年会  2020.3 

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    Event date： 2020.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉   Country：Japan  

  • ジイミド官能基を有する金属有機構造体負極を用いた水系カリウムイオン電池特性

    ＃白珺文，中本康介，趙麗巍，坂本遼，岡田重人，＠山本英治，＠村山美乃，＠徳永信

    第60回電池討論会  2019.11 

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    Event date： 2019.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋   Country：Japan  

  • Halogen Effect in the Supported Platinum Catalysts for 1,3-Rearrangement of Allylic Esters Compounds

    2019.9 

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    Event date： 2019.9

    Language：Japanese  

    Country：Japan  

  • 種々のアミノ酸-金錯体を前駆とした含浸法による担持金ナノ粒子の調製

    @村山美乃・#高木真由・本間徹生・大橋弘範・小林康浩・@山本英治・@徳永信

    第124回触媒討論会  2019.9 

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    Event date： 2019.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：長崎   Country：Japan  

  • Removal of Aged Odor from Japanese Sake with Supported Gold and Silver Nanoparticles by Chemical Adsorption. International conference

    @Haruno Murayama, #Yusuke Yamamoto, #Takayuki Hasegawa, #Misaki Tone, @Eiji Yamamoto, @Tamao Ishida, @Atsuko Isogai, @Tsutomu Fujii, @Mitsutaka Okumura, @Tadahiro Fujitani, @Tetsuo Honma, @Makoto Tokunaga.

    Gold2018  2018.7 

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    Event date： 2019.7 - 2018.7

    Language：English   Presentation type：Oral presentation (general)  

    Country：France  

  • ジイミド官能基を有する有機構造体を⽤いた⽔系二次電池特性

    ＃白珺文, 中本康介, 趙麗巍, 坂本遼, 伊藤正人, 岡田重人, ＠山本英治, ＠村山美乃, ＠徳永信

    第５６回化学関連支部合同九州大会  2019.7 

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    Event date： 2019.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北九州   Country：Japan  

  • 金属酸化物担持0価金触媒を用いたアルキニルカルボン酸の分子内環化反応による不飽和ラクトン合成

    #川相誓也, 池田孝明, @山本英治, @村山美乃, @徳永信

    第５６回化学関連支部合同九州大  2019.7 

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    Event date： 2019.7

    Language：Japanese  

    Venue：北九州   Country：Japan  

  • 分子状酸素を酸化剤とした担持鉛触媒によるアルケンのエポキシ化反応

    ＃隅川佳星, 木下義輝, ＠山本英治,＠ 村山美乃, ＠徳永信

    第５６回化学関連支部合同九州大会  2019.7 

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    Event date： 2019.7

    Language：Japanese  

    Venue：北九州   Country：Japan  

  • セリア担持白金触媒によるアリルエステルの異性化反応

    ＃春田朝陽, ＃黄啓安, ＠村山美乃, ＠山本英治, 本間徹生, 井澤雄輔, 谷口翔平, ＠徳永信

    第５６回化学関連支部合同九州大会  2019.7 

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    Event date： 2019.7

    Language：Japanese  

    Venue：北九州   Country：Japan  

  • シリカ担持金ナノ粒子による日本酒劣化臭の流通式吸着除去

    ＃小宮晋世, ＠村山美乃, 磯谷敦子, ＠山本英治, 飯塚幸子, 藤井力, ＠徳永信

    第５６回化学関連支部合同九州大会  2019.7 

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    Event date： 2019.7

    Language：Japanese  

    Venue：北九州   Country：Japan  

  • 担体上への金ナノ粒子固定化法の最適化と前駆体としての金-アミノ酸錯体の構造解析

    ＃高木真由,＠ 村山美乃, 本間徹生, ＠山本英治, ＠徳永信

    第５６回化学関連支部合同九州大会  2019.7 

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    Event date： 2019.7

    Language：Japanese  

    Venue：北九州   Country：Japan  

  • Deep Desulfurization of Thiophene by Photooxidation Reaction with Supported Noble Metal Nanoparticles International conference

    #Yohan Ko, #Takaaki Shinozaki, @Haruno Murayama, @Eiji Yamamoto, and @Makoto Tokunaga

    24th Joint symposium between KB-CSJ and BB-KCS  2019.6 

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    Event date： 2019.6

    Language：English  

    Country：Japan  

  • Continuous-flow asymmetric hydrogenation of diethyl itaconate by supported Ru-BINAP catalysts International conference

    #Akiko Murakami, #Y. Ikutake, #Hiroshi Nakashima, @Haruno Murayama, @Tetsuo Honma, @Eiji Yamamoto, @Makoto Tokunaga

    3rd Edition of International Congress on Catalysis and Chemical Science  2019.3 

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    Event date： 2019.3

    Language：Japanese  

    Country：Singapore  

  • Structures analyses of supported ruthenium catalysts under asymmetric hydrogenation reaction International conference

    @Haruno Murayama, #Yuya Ikutake, #Hiroshi Nakashima, @Tetsuo Honma, @Eiji Yamamoto, @Makoto Tokunaga

    XAFS 2018  2018.7 

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    Event date： 2018.7

    Language：English   Presentation type：Oral presentation (general)  

    Country：Poland  

  • Structures of supported ruthenium catalysts for enantioselective hydrogenation of olefins International conference

    #Yuya Ikutake, #Hiroshi Nakashima, #Haruno Murayama, @Tetsuo Honma, @Eiji Yamamoto, @Makoto Tokunaga.

    NENCS UEC100  2017.10 

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    Event date： 2017.10

    Language：Japanese  

    Country：Japan  

  • Removal of Aged Odor from Japanese Sake with Supported Gold and Silver Nanoparticles by Chemical Adsorption. International conference

    @Haruno Murayama, #Yusuke Yamamoto, #Takayuki Hasegawa, #Misaki Tone, @Eiji Yamamoto, @Tamao Ishida, @Atsuko Isogai, @Tsutomu Fujii, @Mitsutaka Okumura, @Tadahiro Fujitani, @Tetsuo Honma, @Makoto Tokunaga.

    C&FC2016  2016.11 

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    Event date： 2016.11

    Language：English   Presentation type：Oral presentation (general)  

    Country：Taiwan, Province of China  

  • Bacteroides thetaiomicron VPI-5482由来Glycoside hydrolase family 66 様タンパク質の発現と精製および機能解析

    山本 英治, 金 泳民, 奥山 正幸, 森 春英, 千葉 誠哉, 木村 淳夫

    日本農芸化学会  2005.3 

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    Event date： 2016.9

    Language：Japanese  

    Country：Japan  

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MISC

  • キラル四級アンモニウム塩を触媒とする不斉塩基加水分解反応の開発

    山本 英治, 徳永 信

    月刊ファインケミカル   2014.6

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    Language：Japanese   Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

  • Formal Nucleophilic Boryl Substitution of Organic Halides with Silylborane/Alkoxy Base System

    Topics in Catalysis   2014.4

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    Language：English   Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

  • Recent Trends of Asymmetric Catalysis with Water as a Nucleophile.

    2012.10

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    Language：English   Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

  • 固体コバルト触媒を用いた、水素、硫黄、アルケンを原料とするポリスルファン合成

    山本英治、髙城悠太、河合靖貴、村山美乃、松枝宏尚、坂田浩、大槻周次郎、徳永信

    触媒討論会討論会A予稿集 132nd   2023.9

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  • Effect of Sodium Salt Additives on Intramolecular Cyclization of Alkynoic Acids Catalyzed by Au(0) Catalysts Supported on Metal Oxides

    山本英治, HUANG Qi-An, 池田孝明, 川相誓也, 春口一騎, 村山美乃, 石田玉青, 本間徹生, 徳永信

    日本化学会春季年会講演予稿集(Web)   102nd   2022

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  • Transition-Metal-Free Boryl Substitution Using Silylboranes and Alkoxy Bases

    Eiji Yamamoto, Satoshi Maeda, Tetsuya Taketsugu, Hajime Ito

    Synlett   2017.7

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    Language：English  

    DOI： 10.1055/s-0036-1588772

  • 銅(I)-ホスフィン錯体触媒を用いた有機ホウ素化合物の選択的合成法

    山本 英治, 竹ノ内 雄太, 久保田 浩司, 伊藤 肇

    有機合成化学協会誌   2014.7

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    Language：Japanese   Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

  • Highly Atom Efficient Catalytic Reactions Utilizing Water and Alcohols as Reagents

    J. Organomet. Chem.   2011.1

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    Language：Japanese   Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

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Industrial property rights

Patent   Number of applications: 3   Number of registrations: 0
Utility model   Number of applications: 0   Number of registrations: 0
Design   Number of applications: 0   Number of registrations: 0
Trademark   Number of applications: 0   Number of registrations: 0

Professional Memberships

  • 日本化学会

  • 触媒学会

  • 有機合成化学協会

Academic Activities

  • Screening of academic papers

    Role(s)： Peer review

    2017

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    Type：Peer review 

    Number of peer-reviewed articles in foreign language journals：1

  • ポスター審査員

    第53回化学関連支部合同九州大会  （ 北九州国際会議場 ） 2016.7

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    Type：Competition, symposium, etc. 

  • 運営補助

    万有福岡シンポジウム  （ 九州大学 ） 2016.4

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    Type：Competition, symposium, etc. 

Research Projects

  • 貴金属触媒を用いた酸化反応に関する研究

    2022.1 - 2023.1

    共同研究

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    Authorship：Principal investigator  Grant type：Other funds from industry-academia collaboration

  • 環状アセタールの水素化還元反応に関する研究

    2021.9 - 2022.8

    共同研究

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    Authorship：Principal investigator  Grant type：Other funds from industry-academia collaboration

  • Development of Stereoselective transformations of Ester Functional Group using Phase-Transfer Catalysts

    Grant number：20K05497  2020

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (C)

    Yamamoto Eiji

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    Authorship：Principal investigator  Grant type：Scientific research funding

    In this study, we investigated the development of asymmetric alcoholysis of amino acid esters and azlactones using phase-transfer catalysts and found that the reaction proceeds highly stereoselectively for substrates with a bulky substituent at the carbonyl α-position. We also proposed a detailed reaction mechanism. Furthermore, we found that the asymmetric ring-opening reaction of azlactone with a nitrogen nucleophile proceeded stereoselectively, and the product showed preferential enrichment phenomenon.

    CiNii Research

  • (メタ)アクリルモノマー合成のための新規反応およびその触媒の探索

    2019.4 - 2023.3

    共同研究

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    Authorship：Principal investigator  Grant type：Other funds from industry-academia collaboration

  • 低反応性ジスルフィドを用いる効率的な非対称S-S結合形成反応開発と生理活性化合物合成への応用

    2019

    2019年度 豊田理研スカラー

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    Authorship：Principal investigator  Grant type：Contract research

  • Development of Asymmetric Organic Catalysts Using Accurate and Efficient Conformational Analysis

    Grant number：18H01969  2018 - 2022

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

    Kamachi Takashi

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    Authorship：Coinvestigator(s)  Grant type：Scientific research funding

    Organocatalysts are ideal catalysts that are free from toxic heavy metal residues and can address the issues of rising rare metal prices and depletion. In this study, we have developed a variety of conformational analysis methods to elucidate the causes of enantioselectivity of organocatalysts. We used our own ConFinder program to perform fast and accurate conformational analysis. This program allows us to elucidate the specific conformations responsible for the high selectivity, providing hints for the analysis of reaction mechanisms and the design of catalysts. In collaboration with an experimental group developing organocatalysts, we conducted research on asymmetric hydrolysis reactions of esters.

    CiNii Research

  • アンモニウムヒドロキシド活性種の構造制御に基づく触媒的不斉加水分解反応の開発

    Grant number：18K14223  2018 - 2019

    日本学術振興会  科学研究費助成事業  若手研究

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    Authorship：Principal investigator  Grant type：Scientific research funding

  • 固体触媒を用いる有機合成反応の開発

    2016.4 - 2018.3

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    Authorship：Coinvestigator(s) 

  • 相間移動触媒を用いたエステル不斉塩基加水分解反応

    2016.4 - 2018.3

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    Authorship：Principal investigator 

  • 双性イオン型求核触媒活性種を活用するエステル不斉塩基加水分解反応の開発

    Grant number：16H07042  2016 - 2017

    日本学術振興会  科学研究費助成事業  研究活動スタート支援

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    Authorship：Principal investigator  Grant type：Scientific research funding

  • キラル四級アンモニウムアルコールを求核触媒とする不斉エステル加水分解反応の開発

    2016

    平成２８年度 QRプログラム 『わかばチャレンジ』

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    Authorship：Principal investigator  Grant type：Contract research

  • セリアおよびジルコニア担持貴金属触媒を用いる実用的合成反応

    Grant number：19H02755 

    徳永 信, 山本 英治, 村山 美乃

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    Grant type：Scientific research funding

    無機酸化物担持貴金属触媒は、自動車触媒などで汎用化されており、低コスト、優れた耐久性、大量生産可能、焼成で触媒再生が可能などの利点があるが、有機合成、有機反応への適用が不十分で、未開発の機能が埋もれている。そこで我々は、金、白金、パラジウム、ルテニウムなどの担持触媒の新機能開発を行う。担体として、高活性を示すことが多いセリア(CeO2) やジルコニア (ZrO2) を用い、酸化還元機能とソフトルイス酸機能の解明と応用を行う。ソフトルイス酸機能はアルケン、アルキン、芳香族などのπ電子を活性化するソフトな金属特有の機能であるが担持貴金属触媒では触媒設計指針が確立されておらず、それを目指す。

    CiNii Research

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Class subject

  • 基本操作法

    2023.10 - 2024.3   Second semester

  • 有機化学特論IIB

    2023.10 - 2024.3   Second semester

  • 有機化学学生実験

    2023.4 - 2023.9   First semester

Other educational activity and Special note

  • 2016  Special Affairs 

Travel Abroad

  • 2015.2 - 2016.2

    Staying countory name 1：United States   Staying institution name 1：ユタ大学