Updated on 2024/10/01

Information

 

写真a

 
ONO TOSHIKAZU
 
Organization
Faculty of Engineering Department of Applied Chemistry Associate Professor
School of Engineering （Joint Appointment）
Graduate School of Engineering （Joint Appointment）
Title
Associate Professor
Contact information
メールアドレス
Tel
0928022830
Profile
分子システム科学センター（CMS）の准教授として、主に応用化学部門 生体機能化学講座において、学部学生および大学院生の卒業研究に関する指導を行っている。
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Research Areas

  • Nanotechnology/Materials / Polymer materials

  • Nanotechnology/Materials / Inorganic compounds and inorganic materials chemistry

  • Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry

  • Nanotechnology/Materials / Synthetic organic chemistry

Degree

  • Ph.D

Research History

  • Kyushu University Department of Applied Chemistry, Graduate School of Engineering Associate Professor

    2021.1 - Present

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  • Kyushu University Department of Applied Chemistry, Graduate School of Engineering Assistant Professor

    2012.8 - Present

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Research Interests・Research Keywords

  • Research theme：Preparation of circularly polarized emissive materials using hinge molecules

    Keyword：circularly polarized luminescence

    Research period： 2021.4

  • Research theme：Development of salt-cocrystal continuum for photofunction materials

    Keyword：salt-cocrystal continuum

    Research period： 2017.4

  • Research theme：Preparation of organic solid-state emissive materials based on multicomponent reactions

    Keyword：Multicomponent reactions

    Research period： 2017.4

  • Research theme：Development of helical metal complexes for circular polarized luminescent materials

    Keyword：circular polarized luminescence, helical metal complexes

    Research period： 2016.4

  • Research theme：Synthesis and characterization of novel porphycene derivatives

    Keyword：porphycene, solid-state emission, solid-state catalyst

    Research period： 2015.4

  • Research theme：Construction of Innovative Light Conversion Materials by Porous Organic Crystals

    Keyword：fluorescence, phosphorescence, emission lifetime, organic inclusion crystals

    Research period： 2014.10

  • Research theme：Development of novel radical transfer catalysis based on hydrophobic Vitamin B12.

    Keyword：organometallic chemistry, catalytic chemistry, photochemistry

    Research period： 2013.4 - 2020.9

  • Research theme：Development of functional soft matters based on dameged bases

    Keyword：chemical biology, DNA repair, hydro gel

    Research period： 2013.4 - 2016.3

  • Research theme：Supramolecular Composite Materials based on π-conjugated Molecules

    Keyword：supramolecular chemistry, πconjugated molecules, lewis pair, inclusion crystals, solid state emissions

    Research period： 2012.8

  • Research theme：Preparation of Protein-polymer Conjugates using apoprotein-Heme Supramolecular Interactions.

    Keyword：polymer chemistry, supramolecular chemistry, bioinorganic chemistry, hemoprotein, bionanomaterial

    Research period： 2010.4 - 2012.8

  • Research theme：Direct Fluorescence Monitoring of DNA Base Excision Repairs

    Keyword：chemical biology, DNA repair, fluorescence probe

    Research period： 2010.4 - 2011.12

  • Research theme：Preparation of Thickening Agents for Organic Solvents using Associative Polyelectrolyes

    Keyword：polymer chemistry, supramolecular chemistry, thickener

    Research period： 2008.4 - 2010.3

  • Research theme：Lipophilic Polyelectrolyte Gels as Super Absorbent Polymers for Organic Solvents

    Keyword：polymer chemistry, supramolecular chemistry, supar absorbent polymers, polymer gels

    Research period： 2005.4 - 2010.3

Awards

  • SHGSC Japan Award of Excellence 2023

    2023.6  

  • 令和五年度 文部科学大臣表彰 若手科学者賞

    2023.4   文部科学省   分子集積化技術と立体構造制御に基づく機能性色素の開拓研究

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    (1)成果の内容
    ・分子集積化技術を利用することで、従来困難であった３成分以上の分子を構成成分とした自己組織化発光材料（機能性色素）とセンサー素子の開拓研究を行った。
    ・赤色・近赤外発光を示す環状テトラピロール系色素（ポルフィセン）の新規合成法と光機能開拓研究を行った。
    ・キラルな螺旋錯体、軸不斉錯体（機能性色素）の合成と強発光・大きなストークスシフト・円偏光発光特性を示す材料の開拓研究を行った。

    (2)特徴、従来技術との相違等
    ・複数成分の分子（二成分、三成分、それ以上）の組み合わせによる自己組織化発光材料（機能性色素）に取り組み、複合材料とすることではじめて取得可能な新物質（機能性色素）の創製法を提案した。
    ・合成手法の簡略化、有機溶剤の低減、省エネルギー、重金属フリー、安価で豊富な汎用元素の活用による高機能かつ新物質（機能性色素）の創製法を提案した。

    (3)成果による社会的効果・実施効果
    ・高付加価値、高効率エネルギー変換材料による省エネ・創エネ・蓄エネへの貢献につながる
    ・有機化合物センサ、各種ガスセンサへの応用による安全安心な社会構築に貢献につながる
    ・希少資源・不足資源に変わる汎用元素活用による持続可能な社会の実現に貢献につながる
    ・医療診断、光線力学療法への適用によるヘルスケア事業や先進治療による健康寿命の延伸に貢献につながる

  • 2020年度 有機合成化学協会 九州山口支部　奨励賞

    2020.11   有機合成化学協会 九州山口支部   多成分系分子集積化技術に基づく光機能材料の創製

  • 日本化学会　第34回若い世代の特別講演会

    2020.3   日本化学会   多成分系分子の自己組織化を利用した発光材料とセンサー素子の開発

  • 平成28年度 有機合成化学協会九州山口支部 優秀論文賞

    2016.11   有機合成化学協会九州山口支部   Multicomponent Molecular Puzzles for Photofunction Design: Emission Color Variation in Lewis Acid–Base Pair Crystals Coupled with Guest-to-Host Charge Transfer Excitation

Papers

  • Advanced Molecular Design for Efficient Multicolor Electrochemiluminescence and Amplified Spontaneous Emission Based on Tetra‐BF<sub>2</sub> Complexes

    Luxia Cui, Ami Horioka, Ryoichi Ishimatsu, Masashi Mamada, Chihaya Adachi, Keishiro Tahara, Yu Hoshino, Toshikazu Ono

    Advanced Optical Materials   12 ( 14 )   2024.1   （ ISSN:2195-1071 eISSN:2195-1071 ）

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    Language：English   Publishing type：Research paper (scientific journal)   Publisher：Wiley  

    Abstract

    Advanced organoboron dyes, incorporating tetra‐boron difluoride (tetra‐BF<sub>2</sub>) moieties, are developed, demonstrating efficient electrochemiluminescence (ECL) emissions in the green to orange regions through direct ion annihilation. By introducing diverse alkyl modifications in the molecules, luminescence color tuning is achieved via alterations in conjugation and bending angle. A photoluminescence quantum yield of 100% in dilute solutions is successfully achieved. Notably, the introduction of alkyl groups to the methine side stabilizes the radical ionic state, resulting in a high ECL efficiency of 74% through an efficient radical‐ion annihilation pathway. The key factor is that the energy of the annihilation reaction exceeds the S<sub>1</sub> energy required for luminescence. Spin density calculations further elucidate the substituent effects on the radical ions of complexes. Moreover, the lasing properties of these materials in the solution‐processed blend films are investigated, revealing a low amplified spontaneous emission (ASE) threshold (E<sub>th</sub>) of 6.40 ± 0.24 µJ cm<sup>−2</sup>, which is notably lower among organic laser materials. This is attributed to their large Stokes shifts and high quantum yield. The excellent ECL and ASE performances establish these materials as a valuable addition to the existing library of organoboron dyes, offering fresh insights into the development of organic solid‐state lasers.

    DOI： 10.1002/adom.202302803

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  • Multicomponent Crystals with Competing Intermolecular Interactions: In Situ X-ray Diffraction and Luminescent Features Reveal Multimolecular Assembly of Mechanochemical Conditions. International journal

    Yoshio Yano, Hidetaka Kasai, Yanyan Zheng, Eiji Nishibori, Yoshio Hisaeda, Toshikazu Ono

    Angewandte Chemie (International ed. in English)   61 ( 35 )   e202203853   2022.6   （ ISSN:1433-7851 eISSN:1521-3773 ）

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    Language：English   Publishing type：Research paper (scientific journal)  

    Supramolecular chemistry under mechanochemical conditions has drawn attention because it can induce low-solubility molecules to self-assemble, although most of the reported examples have been limited to two-component systems. We applied mechanochemical synthesis to achieve multimolecular self-assembly in more challenging three-component systems. The produced crystals showed multicolor solid-state luminescence depending on the components when exposed to UV light.  Optical outputs and X-ray diffraction studies were used to examine the self-assembling behavior in greater depth. Using synchrotron radiation, in situ X-ray diffraction permitted direct observation of the milling process, which started the self-assembly process within 1 min. This research emphasizes the importance of multicomponent molecules with optical functions and self-assembling behavior and offers the possibility of developing more complicated multicomponent crystals and organic solid solutions for advanced materials.

    DOI： 10.1002/anie.202203853

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  • Optical Property Control by the Interligand Charge Transfer Excited State in Brominated Homoleptic and Heteroleptic Aluminum Dinuclear Triple-Stranded Helicates

    Konishi, Y; Ehara, T; Cui, LX; Ueno, K; Ishigaki, Y; Harada, T; Konta, T; Onda, K; Hoshino, Y; Miyata, K; Ono, T

    INORGANIC CHEMISTRY   63 ( 25 )   11716 - 11725   2024.6   （ ISSN:0020-1669 eISSN:1520-510X ）

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    Language：English   Publisher：Inorganic Chemistry  

    The utilization of aluminum, an abundant and inexpensive element, for the synthesis of novel functional complexes is extremely important, but the design and control of photofunctionality are still unexplored. In this study, we focused on our previously developed dinuclear triple-stranded helicates incorporating two aluminum ions (ALPHY) to synthesize both homoleptic and heteroleptic complexes with bromine atoms at the 3-position of the pyrrole moiety in the Schiff base ligands. The brominated Schiff base ligands were reacted with AlCl3 to synthesize homoleptic complexes, while different ligands were mixed to prepare heteroleptic complexes. Single-crystal X-ray structural analysis revealed the structures of these novel complexes. We found that increasing the degree of bromination resulted in a tunable emission color, shifting progressively from 550 (yellow) to 566 nm (orange). Optical resolution of the complexes facilitated the observation of mirror-image circular dichroism and circularly polarized luminescence. Furthermore, employing ultrafast spectroscopy techniques, we have elucidated that the optical properties are governed by the interligand charge transfer (ILCT) among the three ligands. The formation of heteroleptic complexes induces the ILCT state even in nonpolar environments, thereby accelerating nonradiative decay and intersystem crossing. These findings mark significant advancements in photofunctional materials based on multinuclear complexes.

    DOI： 10.1021/acs.inorgchem.4c01214

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  • Simultaneous discovery of chiral and achiral dyes: elucidating the optical functions of helical and flag-hinged boron tetradentate complexes

    Cui, LX; Furuta, R; Harada, T; Konta, T; Hoshino, Y; Ono, T

    DALTON TRANSACTIONS   53 ( 21 )   9183 - 9191   2024.5   （ ISSN:1477-9226 eISSN:1477-9234 ）

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    Language：English   Publisher：Dalton Transactions  

    The construction of novel complexes can lead to the manifestation of unexpected structures and properties, thereby making chemical exploration in experiments a potential source for novel discoveries. In this study, by reacting 6,6′-dihydrazineyl-2,2′-bipyridine with acyl chlorides and subsequently coordinating with boron trifluoride, two different boron-tetradentate ligand complexes were simultaneously generated. One of these complexes exhibited a unique structure in which tetra-BF2 moieties coordinated to all four coordination sites of the ligand molecule, forming a flag-hinged structure around the bipyridine part. The second complex featured a helical structure formed by the hybridization of two BF2 and one B-O-B moieties, representing a highly unusual form of the complex. The structures of these two boron complexes were consistently observed when various substituted acyl chlorides were employed. Furthermore, it was found that enhancing electron-donor properties could induce a redshift in emissions. Utilizing the dimethylamino group as the proton receptor promoted a yellow-to-blue fluorescence switch in the tetra-BF2 complex and an OFF/ON fluorescence in the B-O-B bridged complex upon protonation. The helical chirality observed in the latter complex resulted in stable (P)/(M)-enantiomers after optical resolution. This complex exhibited circular dichroism with a |gabs| of up to 1.2 × 10−2 and circularly polarized luminescence with a |glum| on the order of 10−3 in solution and polymer film.

    DOI： 10.1039/d4dt01172d

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  • Creation of photofunctional materials through supramolecular complex formation and host-guest chemistry

    Ono, T

    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY   2024.4   （ ISSN:1388-3127 eISSN:1573-1111 ）

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    Publisher：Journal of Inclusion Phenomena and Macrocyclic Chemistry  

    Functional dyes can interconvert energies, such as light, heat, and electricity, and they have broad applications in various fields. This review highlights our endeavors in the creation of novel photofunctional materials in solution and solid states via molecular assemblies, linkage, and distortion and the integration of supramolecular complex formation and host–guest chemistry. One approach involves the synthesis of solid-state luminescent materials with the use of cocrystals comprising host molecules with dye backbones and guest molecules derived from aromatic compounds. Cocrystal formation is tuned via intermolecular interactions, such as hydrogen bonding, charge-transfer interactions, π-π stacking, and inclusion phenomena of the crystal engineering approach. This state leads to the emergence of properties such as fluorescence, room-temperature phosphorescence, and the potential for applications in optical sensors. In the second approach, functional dyes comprising multidentate ligands with various elements, which results in photofunctional properties in solution and solid states. This method delves into structural characteristics affected by the distortion and torsional angles of multinuclear complexes and their resulting photophysical properties. Multinuclear complexes encompass helical and axial chirality. Here, we discuss the isolation of enantiomers through optical resolution and their subsequent circular dichroism and circularly polarized luminescence characteristics. The position and nature of substituents considerably affected the ground and excited states of the complexes, which led to the formation of unique photofunctional materials. These methodologies offer insightful and effective avenues for the further improvement of the functionality and device applicability of functional dyes.

    DOI： 10.1007/s10847-024-01243-3

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  • Water Solubilization and Guest Molecule‐Induced Fluorescence Changes of Porous Host Molecules via Complexing with Polysaccharide or Polypeptide

    Sota Umezane, Toshikazu Ono, Riku Kawasaki, Atsushi Ikeda

    Chemistry – An Asian Journal   19 ( 8 )   e202301015   2024.4   （ ISSN:1861-4728 eISSN:1861-471X ）

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    Language：English   Publishing type：Research paper (scientific journal)   Publisher：Wiley  

    Abstract

    To detect small aromatic molecules in water, we prepared functional host molecules based on water‐soluble N,N’‐bis(2‐aminobenzophenone)‐1,4,5,8‐naphthalenetetracarboxylic diimide (1) and a solubilizing agent using a high‐speed vibration milling apparatus. The fluorescence response of host 1‐solubilizing agent complexes before and after extraction of small aromatic guest molecules was large and the fluorescence maxima were dependent on the small aromatic guest molecules.

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  • Self-Inclusion Complexation of Electron-Accepting Guest into Electron-Donating Cyclic Host by Photoexcitation. International journal

    Keisuke Wada, Yuuya Nagata, Luxia Cui, Toshikazu Ono, Shigehisa Akine, Shunsuke Ohtani, Kenichi Kato, Shixin Fa, Tomoki Ogoshi

    Angewandte Chemie (International ed. in English)   63 ( 26 )   e202404409   2024.4   （ ISSN:1433-7851 eISSN:1521-3773 ）

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    Language：English   Publishing type：Research paper (scientific journal)  

    Self-inclusion complexes consisting of host-guest conjugates are one of the unique supramolecular structures because they form in-state and out-state depending on the external stimuli. Despite many reports of the stimuli-responsive self-inclusion complex formation, study of the structural relaxation from out-state to in-state by photoexcitation has been unexplored. Herein, we report that an electron-donating host and an electron-accepting guest conjugate exhibits the structural relaxation from out-state to in-state by photoexcitation. Formation of the in-state in the excited state resulted in exciplex emission along with the locally excited emission from the out-state. Moreover, this structural relaxation by photoexcitation was suppressed not only by temperature, but also by the presence of guest molecules, resulting in changes in the ratio of the dual emission intensities.

    DOI： 10.1002/anie.202404409

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  • Unraveling the Remarkable Influence of Substituents on the Emission Variation and Circularly Polarized Luminescence of Dinuclear Aluminum Triple-Stranded Helicates. International journal

    Kodai Ueno, Yuto Konishi, Luxia Cui, Takunori Harada, Kohei Ishibashi, Takeru Konta, Atsuya Muranaka, Yoshio Hisaeda, Yu Hoshino, Toshikazu Ono

    Inorganic chemistry   63 ( 14 )   6296 - 6304   2024.3   （ ISSN:0020-1669 eISSN:1520-510X ）

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    Language：English   Publishing type：Research paper (scientific journal)  

    This study explored the development of functional dyes using aluminum, focusing on aluminum-based dinuclear triple-stranded helicates, and examined the effects of substituent variations on their structural and optical properties. Key findings revealed that the modification of methyl groups to the pyrrole positions significantly extended the conjugation system, resulting in a red shift in the absorption and emission spectra. Conversely, the modification of methyl groups at the methine positions due to steric hindrances increased the torsion angle of the ligands, leading to a blue shift in the absorption and emission spectra. A common feature across all complexes was that in the excited state, one of the three ligands underwent significant structural relaxation. This led to a pronounced Stokes shift and minimal spectra overlap with high photoluminescence behaviors. Moreover, our research extended to the optical resolution of the newly synthesized complexes by analyzing the chiroptical properties of the resulting enantiomers, including their circular dichroism and circularly polarized luminescence. These insights offer valuable contributions to the design and application of novel aluminum-based functional dyes, potentially influencing a range of fields, from materials science to optoelectronics.

    DOI： 10.1021/acs.inorgchem.4c00045

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  • Influence of structural isomers of naphthalene diimides on photophysical and electrochemical properties

    Yusei Yamamoto, Ami Horioka, Luxia Cui, Yusuke Ishigaki, Yu Hoshino, Toshikazu Ono

    Chemistry Letters   53 ( 2 )   2024.2   （ ISSN:0366-7022 eISSN:1348-0715 ）

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    Three structural isomers of naphthalene diimides were synthesized. In all compounds, the electron-withdrawing diimide group exhibits a stable two-step reduction behavior under electrochemical conditions, and it was revealed that their reduction potentials vary significantly depending on the position of the diimide group relative to the naphthalene ring.

    DOI： 10.1093/chemle/upad022

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  • Role of Halobenzene Guest Molecules in Modulating Room Temperature Phosphorescence of Benzophenone–Naphthalene Diimide Inclusion Crystals

    Yoshifumi Tsukiyama, Yusei Yamamoto, Daiki Koga, Luxia Cui, Yu Hoshino, Yoshio Hisaeda, Toshikazu Ono

    Chemistry – An Asian Journal   19 ( 5 )   e202301114   2024.2   （ ISSN:1861-4728 eISSN:1861-471X ）

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    Language：Others   Publishing type：Research paper (scientific journal)   Publisher：Wiley  

    Abstract

    Materials exhibiting room temperature phosphorescence (RTP) have recently emerged as a subject of significant interest. In this study, we successfully created inclusion crystals by introducing halobenzenes as guests into a host molecule combining benzophenone with naphthalene diimide. This approach led to the creation of fascinating fluorescence and RTP properties dependent on the guest molecules. Notably, crystals containing chlorobenzene showed cyan fluorescence, while those with iodobenzene displayed red RTP. This difference highlights the impact of the guest molecule on the luminescent properties, with the significant external heavy‐atom effect of iodobenzene playing a key role in promoting efficient intersystem crossing between the excited singlet and triplet states. Crystals with bromobenzene exhibited a unique blend of fluorescence and RTP, both from benzophenone and naphthalene diimide, highlighting the moderate heavy‐atom effect. These findings reveal composite materials with remarkably diverse and interesting optical characteristics.

    DOI： 10.1002/asia.202301114

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  • Lewis-Pairing-Induced Electrochemiluminescence Enhancement from Electron Donor-Acceptor Diads Decorated with Tris(pentafluorophenyl)borane as an Electrochemical Protector

    Ikeda, T; Tahara, K; Ishimatsu, R; Ono, T; Cui, LX; Maeda, M; Ozawa, Y; Abe, M

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   62 ( 21 )   e202301109   2023.5   （ ISSN:1433-7851 eISSN:1521-3773 ）

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    Language：English   Publisher：Angewandte Chemie - International Edition  

    This study reports an effective peripheral decoration of organic donor-acceptor diads with B(C6F5)3 for stabilizing electrogenerated radical ions. By employing a common p-type organic semiconductor benzothienobenzothiophene (BTBT) as the donor, tetracoordinate boron complexes showed improved solution electrochemiluminescence (ECL) intensity, reaching a 156-fold increase compared to that of the parent diad. The unprecedented Lewis-pairing-induced ECL enhancement is attributed to the multiple roles of B(C6F5)3: 1) redistributing frontier orbitals, 2) facilitating electrochemical excitation, and 3) restricting molecular motions. Furthermore, B(C6F5)3 converted the molecular arrangement of BTBT from conventional 2D herringbones into 1D π-stacks. This robust, highly ordered columnar nanostructure allowed red-shifting of the crystalline film ECL with electrochemical doping through the electronic coupling pathways of BTBT. Our approach will facilitate the development of elaborate metal-free ECL systems.

    DOI： 10.1002/anie.202301109

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  • Exceptionally flexible quinodimethanes with multiple conformations: polymorph-dependent colour tone and emission of crystals

    Kazuma Sugawara, Toshikazu Ono, Yoshio Yano, Takanori Suzuki, Yusuke Ishigaki

    Materials Chemistry Frontiers   7 ( 8 )   1591 - 1598   2023.4   （ eISSN:2052-1537 ）

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    Publishing type：Research paper (scientific journal)   Publisher：Royal Society of Chemistry (RSC)  

    Tetraazaanthraquinodimethanes can exhibit various colours and emissions depending on their multiple conformations, such as not only folded and twisted forms but also intermediate structures, e.g., planar and twisted-folded forms, in pseudopolymorphs.

    DOI： 10.1039/d2qm01199a

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  • Lewis Pairing‐Induced Electrochemiluminescence Enhancement from Electron Donor‐Acceptor Diads Decorated with Tris(pentafluorophenyl)borane as an Electrochemical Protector

    Takashi Ikeda, Keishiro Tahara, Ryoichi Ishimatsu, Toshikazu Ono, Luxia Cui, Momoka Maeda, Yoshiki Ozawa, Masaaki Abe

    Angewandte Chemie   2023.3   （ ISSN:0044-8249 eISSN:1521-3757 ）

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    Language：Others   Publishing type：Research paper (scientific journal)   Publisher：Wiley  

    DOI： 10.1002/ange.202301109

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  • Fluorescence sensor using porous host molecules deposited on filter paper with vapochromic and mechanochromic properties

    Sota Umezane, Satoshi Fukutomi, Toshikazu Ono, Yoshio Hisaeda, Tomoki Nishimura, Riku Kawasaki, Atsushi Ikeda

    New Journal of Chemistry   47 ( 9 )   4166 - 4171   2023.2   （ ISSN:1144-0546 eISSN:1369-9261 ）

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    Publishing type：Research paper (scientific journal)   Publisher：Royal Society of Chemistry (RSC)  

    Naphthalenediimide derivative-absorbed papers had fluorescence intensity and maximum depending on the type of guest aromatic molecules after exposure to vapors of small 10 guest molecules. Furthermore, the papers showed a mechanochromic property.

    DOI： 10.1039/d2nj04929e

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  • Color-tuning and boosting circularly polarized luminescence performance of axially chiral tetra-BF<sub>2</sub>complexes by post-modifications

    Luxia Cui, Koichi Deyama, Takafumi Ichiki, Yuto Konishi, Ami Horioka, Takunori Harada, Kohei Ishibashi, Yoshio Hisaeda, Toshikazu Ono

    Journal of Materials Chemistry C   11 ( 7 )   2574 - 2581   2023.2   （ ISSN:2050-7526 eISSN:2050-7534 ）

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    Publishing type：Research paper (scientific journal)   Publisher：Royal Society of Chemistry (RSC)  

    Multicolored fluorescence, high Φ<sub>PL</sub>reaching 59%, and an efficientg<sub>lum</sub>up to 0.01 with the brightness for circularly polarized luminescence (125.2 M<sup>−1</sup> cm<sup>−1</sup>), were achieved in axially chiral tetra-BF<sub>2</sub> complexes by substituent engineering.

    DOI： 10.1039/d2tc04636a

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  • Aqueous solutions with information on solids: room-temperature phosphorescence of polysaccharide–benzophenone complexes

    Masafumi Okuno, Keita Yamana, Riku Kawasaki, Yuto Konishi, Toshikazu Ono, Tsutomu Ishi-i, Atsushi Ikeda

    RSC Advances   13 ( 6 )   3528 - 3533   2023.1   （ eISSN:2046-2069 ）

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    Water-soluble λ-carrageenan–benzophenone complexes retained their properties of crystallization-induced phosphorescence of benzophenones at room temperature in aqueous solutions.

    DOI： 10.1039/d2ra08205e

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  • Functions of bioinspired pyrrole cobalt complexes-recently developed catalytic systems of vitamin B-12 related complexes and porphycene complexes

    Taro Koide, Toshikazu Ono, Hisashi Shimakoshi, Yoshio Hisaeda

    COORDINATION CHEMISTRY REVIEWS   470   2022.11   （ ISSN:0010-8545 eISSN:1873-3840 ）

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    Language：English   Publisher：ELSEVIER SCIENCE SA  

    Pyrrole-containing metal complexes widely exist in nature, for example, vitamin B-12, heme, chlorophyll, and their derivatives. Each of them shows significant functions, which are essential for life. To mimic their important functions and substance conversion reactions, numerous pyrrole-containing metal complexes have been synthesized and investigated. This review mainly focuses on cobalt complexes having pyrrolecontaining ligands and the recent progress of molecular transformations catalyzed by the complexes, especially the vitamin B-12-related cobalt complexes and porphycene cobalt complexes. A variety of reaction systems, which enable a number of molecular transformations under mild conditions is described. The construction of new reaction systems and a combination of the materials inspired by natural systems is a promising and effective approach to realizing eco-friendly and cost-effective reaction systems. (C) 2022 Elsevier B.V. All rights reserved.

    DOI： 10.1016/j.ccr.2022.214690

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  • Unsymmetric Molecular Hinges Showing Intramolecular Charge Transfer Excitation: Strong Photoluminescence Properties in the Red to Near-Infrared Region Exhibited by Tri-BF2 Complexes br

    Cui, LX; Maeda, M; Hisaeda, Y; Ono, T

    JOURNAL OF PHYSICAL CHEMISTRY C   126 ( 42 )   18152 - 18158   2022.10   （ ISSN:1932-7447 eISSN:1932-7455 ）

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    Rationally designed unsymmetric tri-BF2red to near-infrared (NIR) emitters were first reported in this study via a facile one-pot synthetic approach. The single-crystal structures and density functional theory calculations suggest their tunable conformation change around the bipyrrole part and unsymmetric structures in which three boron atoms are coordinated with the existing four different bidentate binding pockets, leaving two of the uncoordinated nitrogens in the pyrrole part. These novel tri-BF2emitters in the red to NIR region demonstrated ca. 30% of photoluminescence quantum yield (φPL) in toluene at room temperature and highly intense fluorescence at 77 K (up to 89% of φPLin 2-MeTHF), which is attributed to increased molecular flexibility and enhanced intramolecular charge transfer interactions resulting from symmetry breaking. The photophysical modulation in multi-BF2complexes was achieved by the coordinated number of BF2units, providing a step forward to understanding and guiding the design of the most efficient versatile emissive organoboron compounds.

    DOI： 10.1021/acs.jpcc.2c05511

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  • Aqueous Solutions of a Porous Host–Poly‐L‐lysine Complex with Information on Solids as Different Fluorescence by Guests

    Katsuya Takahashi, Sota Umezane, Toshikazu Ono, Satoshi Fukutomi, Megumi Ihara, Yoshio Hisaeda, Riku Kawasaki, Atsushi Ikeda

    Chemistry – An Asian Journal   17 ( 23 )   e202200879   2022.10   （ ISSN:1861-4728 eISSN:1861-471X ）

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    Language：Others   Publishing type：Research paper (scientific journal)   Publisher：Wiley  

    DOI： 10.1002/asia.202200879

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    Other Link： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/asia.202200879

  • Electrochemical approach to trifluoroacetamide synthesis from 1,1,1-trichloro-2,2,2-trifluoroethane (CFC-113a) catalyzed by B<sub>12</sub> complex

    Moniruzzaman, M; Yano, Y; Ono, T; Hisaeda, Y; Shimakoshi, H

    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES   26 ( 06N07 )   419 - 426   2022.6   （ ISSN:1088-4246 eISSN:1099-1409 ）

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    Publisher：Journal of Porphyrins and Phthalocyanines  

    One-pot synthetic approach to produce trifluoroacetamide has been developed using an electrochemical method with the B12 complex as a catalyst under mild conditions, in open air at room temperature. Thirty examples of trifluoroacetamide were synthesized from 1,1,1-trichloro-2,2,2-trifluoroethane (CFC-113a) in moderate to good yields. This user-friendly strategy is compatible with a broad range of trifluoroacetamide syntheses.

    DOI： 10.1142/S1088424621500292

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  • Highly Fluorescent Bipyrrole-Based Tetra-BF2 Flag-Hinge Chromophores: Achieving Multicolor and Circularly Polarized Luminescence. International journal

    Luxia Cui, Hyuga Shinjo, Takafumi Ichiki, Koichi Deyama, Takunori Harada, Kohei Ishibashi, Takumi Ehara, Kiyoshi Miyata, Ken Onda, Yoshio Hisaeda, Toshikazu Ono

    Angewandte Chemie (International ed. in English)   61 ( 27 )   e202204358   2022.5   （ ISSN:1433-7851 eISSN:1521-3773 ）

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    This study reports the facile syntheses of tetra-boron difluoride (tetra-BF2 ) complexes, flag-hinge-like molecules that exhibit intense green-to-orange luminescence in solution and yellow-to-red emission in the solid states. Single-crystal structure analysis and density functional theory calculations suggested a bent structure of this series of compounds. The complexes also exhibited excellent optical properties, with quantum yields reaching 100 % and a large Stokes shift. These properties were attributed to the altered bending angle of the molecule in the S1 excited state. As the rotational motion was suppressed around the 2,2'-bipyrrole axis, atropisomers with axial chirality were formed, which are optically resolvable into (R) and (S)-enantiomers through a chiral column. The atropisomers thus function as circularly polarized luminescent (CPL) materials, in which the color (green, green-yellow, and yellow) can be varied by controlling the aggregation state. This rational design of multi-BF2 complexes can potentially realize novel photofunctional materials.

    DOI： 10.1002/anie.202204358

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  • Synthesis, redox properties, and catalytic hydrogen gas generation of porphycene cobalt complexes

    Zihan Zhou, Taro Koide, Yoshihito Shiota, Yoshio Yano, Ning Xu, Toshikazu Ono, Hisashi Shimakoshi, Kazunari Yoshizawa, Yoshio Hisaeda

    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES   26 ( 03 )   263 - 272   2022.3   （ ISSN:1088-4246 eISSN:1099-1409 ）

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    Language：English   Publishing type：Research paper (scientific journal)   Publisher：WORLD SCIENTIFIC PUBL CO PTE LTD  

    A new meso-tetrakis(3,5-di-tert-butylphenyl) substituted porphycene and its cobalt complex were synthesized and characterized. Several meso-tetraarylporphycene cobalt complexes having different substituents showed catalytic activity for the hydrogen gas evolution reaction (HER) in the presence of trifluoroacetic acid (TFA) under electrochemical reductive conditions. The electrochemical potential of the HER was -1.50V vs. Ag/AgCl in THF. The active species of this reaction were determined to be the ligand reduced species of Co(II) porphycenes. The catalytic efficiencies of the cobalt complexes of meso-aryl substituted porphycenes and meso-tetraphenylporphyrin were compared and meso-tetraphenyl porphycene cobalt complex exhibited the best current efficiency of 72%. Based on these experimental results and theoretical calculations, we proposed a possible HER mechanism of this system.A new porphycene having four 3,5-di-tert-butylphenyl groups at the meso-positions and its cobalt complex were synthesized and characterized. The electrocatalytic hydrogen evolution reaction via the ligand-centered reduction of porphycene cobalt complexes was investigated. The reaction process was revealed by experimental results and theoretical calculations and was clearly different from the system via metal-centered reduction using porphyrin cobalt complex.

    DOI： 10.1142/S108842462250016X

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  • Design of Dimeric Dinuclear Boron Complexes with Flexible Linkers: Aggregation-induced White-light Emission via Molecular Engineering

    Ihara, M; Cui, LX; Konishi, Y; Hisaeda, Y; Ono, T

    CHEMISTRY LETTERS   51 ( 3 )   300 - 302   2022.3   （ ISSN:0366-7022 eISSN:1348-0715 ）

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    Publisher：Chemistry Letters  

    The aggregation state of two new covalently bonded dinuclear boron-based dye complexes was controlled to fabricate white-light-emitting materials. The materials exhibit blue and orange emission, with a photoluminescence quantum yield of 16% for one of the complexes in the solid state. This study highlights the importance of molecular engineering through the control of dye aggregation as a fundamental technology for creating novel functional materials with interesting optical properties.

    DOI： 10.1246/cl.210794

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  • Insights into Proton Dynamics in a Photofunctional Salt-Cocrystal Continuum: Single-Crystal X-ray, Neutron Diffraction, and Hirshfeld Atom Refinement. International journal

    Yoshio Yano, Toshikazu Ono, Takashi Ohhara, Yoshio Hisaeda

    Chemistry (Weinheim an der Bergstrasse, Germany)   27 ( 71 )   17802 - 17807   2021.12

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    DOI： 10.1002/chem.202103044

  • Solid-State Structures and Photoluminescence of Lamellar Architectures of Cu(I) and Ag(I) Paddlewheel Clusters with Hydrogen-Bonded Polar Guests. International journal

    Haruki Inoue, Yuga Yamashita, Yoshiki Ozawa, Toshikazu Ono, Masaaki Abe

    Molecules (Basel, Switzerland)   26 ( 21 )   2021.11

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    DOI： 10.3390/molecules26216731

  • Aerobic Electrochemical Transformations of DDT to Oxygen-Incorporated Products Catalyzed by a B-12 Derivative

    Mohammad Moniruzzaman, Yoshio Yano, Toshikazu Ono, Yoshio Hisaeda, Hisashi Shimakoshi

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   94 ( 11 )   2784 - 2791   2021.11

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    DOI： 10.1246/bcsj.20210316

  • Hydrogen Bond Engineering Visualized by Picometer-Level Distortion of Planar Porphyrin Isomers. International journal

    Daiki Koga, Toshikazu Ono, Hyuga Shinjo, Yoshio Hisaeda

    The journal of physical chemistry letters   12 ( 42 )   10429 - 10436   2021.10

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    DOI： 10.1021/acs.jpclett.1c03020

  • Synthesis of First Antimony Porphycene and Electrocatalytic Hydrogen Evolution Driven by Ligand-Centered Reduction

    Zhi Zhang, Taro Fujioka, Taro Koide, Yoshio Yano, Toshikazu Ono, Yoshio Hisaeda

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   94 ( 8 )   2048 - 2053   2021.8

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    DOI： 10.1246/bcsj.20210177

  • Room-Temperature Phosphorescence Emitters Exhibiting Red to Near-Infrared Emission Derived from Intermolecular Charge-Transfer Triplet States of Naphthalenediimide-Halobenzoate Triad Molecules. International journal

    Toshikazu Ono, Kazuki Kimura, Megumi Ihara, Yuri Yamanaka, Miori Sasaki, Hirotoshi Mori, Yoshio Hisaeda

    Chemistry (Weinheim an der Bergstrasse, Germany)   27 ( 37 )   9465 - 9465   2021.7

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    DOI： 10.1002/chem.202101685

  • Room-temperature Phosphorescence Emitters Exhibiting Red to Near-infrared Emission Derived from Intermolecular Charge-transfer Triplet States of Naphthalenediimide-Halobenzoate Triad Molecules. International journal

    Toshikazu Ono, Kazuki Kimura, Megumi Ihara, Yuri Yamanaka, Miori Sasaki, Hirotoshi Mori, Yoshio Hisaeda

    Chemistry (Weinheim an der Bergstrasse, Germany)   2021.3

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    DOI： 10.1002/chem.202100906

  • Dinuclear Triple-Stranded Helicates Composed of Tetradentate Ligands with Aluminum(III) Chromophores: Optical Resolution and Multi-color Circularly Polarized Luminescence Properties International journal

    Toshikazu Ono, Kohei Ishihama, Ai Taema, Takunori Harada, Kiyonao Furusho, Masashi Hasegawa, Yuki Nojima, Masaaki Abe, Yoshio Hisaeda

    Angewandte Chemie - International Edition   60 ( 5 )   2614 - 2618   2021.2

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    DOI： 10.1002/anie.202011450

  • A Cuboidal Cu4S4 Cluster Supported by Bulky Iminothiolate Ligands: Synthesis, Solid-State Structure, and Solution Study

    Yoshiki Ozawa, Hiroki Iida, Hidetoshi Kiyooka, Kazutaka Nobori, Keishiro Tahara, Toshikazu Ono, Masaaki Abe

    Bulletin of the Chemical Society of Japan   94 ( 2 )   616 - 622   2021.2

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    DOI： 10.1246/bcsj.20200295

  • Rectangular Holes in Porphyrin Isomers Act As Mono- And Binucleating Ligands: Stereochemistry of Mono- And Diboron Porphycenes and Their Protonation Behaviors

    Ning Xu, Toshikazu Ono, Yoshitsugu Morita, Teruyuki Komatsu, Yoshio Hisaeda

    Inorganic Chemistry   60 ( 2 )   2021.1

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    DOI： 10.1021/acs.inorgchem.0c01266

  • Tetra- and Hexanuclear Copper(I) Iminothiolate Complexes: Synthesis, Structures, and Solid-State Thermochromic Dual Emission in Visible and Near-Infrared Regions Invited Reviewed International journal

    Yoshiki Ozawa, Marino Mori, Hidetoshi Kiyooka, Yuumi Sugata, @Toshikazu Ono, Masaaki Abe

    Chemical Papars   2020.11

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  • Vapoluminescence Behavior Triggered by Crystal-State Complexation between Host Crystals and Guest Vapors Exhibiting No Visible Fluorescence

    Tomoki Ogoshi, Yukie Hamada, Ryuta Sueto, Ryosuke Kojima, Fumiyasu Sakakibara, Yuuya Nagata, Yoko Sakata, Shigehisa Akine, Toshikazu Ono, Takahiro Kakuta, Tada Aki Yamagishi

    Crystal Growth and Design   20 ( 11 )   7087 - 7092   2020.11

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    DOI： 10.1021/acs.cgd.0c00982

  • Tetra- and hexanuclear copper(I) iminothiolate complexes: synthesis, structures, and solid-state thermochromic dual emission in visible and near-infrared regions

    Yoshiki Ozawa, Marino Mori, Hidetoshi Kiyooka, Yuumi Sugata, Toshikazu Ono, Masaaki Abe

    CHEMICAL PAPERS   74 ( 11 )   3717 - 3725   2020.11

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    DOI： 10.1007/s11696-020-01251-w

  • Electrochemically driven, cobalt-carbon bond-mediated direct intramolecular cyclic and acyclic perfluoroalkylation of (hetero)arenes using X(CF<inf>2</inf>)<inf>4</inf>X

    Luxia Cui, Toshikazu Ono, Md Jakir Hossain, Yoshio Hisaeda

    RSC Advances   10 ( 42 )   24862 - 24866   2020.6

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    DOI： 10.1039/d0ra05295g

  • Mechanistic Study on Ring-Contracting Skeletal Rearrangement from Porphycene to Isocorrole by Experimental and Theoretical Methods Reviewed

    Taro Koide, Takafumi Maeda, Tsukasa Abe, Yoshihito Shiota, Yoshio Yano, Toshikazu Ono, Kazunari Yoshizawa, Yoshio Hisaeda

    European Journal of Organic Chemistry   2020 ( 12 )   1811 - 1816   2020.3

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    DOI： 10.1002/ejoc.201901659

  • Cover Feature: Mechanistic Study on Ring-Contracting Skeletal Rearrangement from Porphycene to Isocorrole by Experimental and Theoretical Methods (Eur. J. Org. Chem. 12/2020) Reviewed

    Taro Koide, Takafumi Maeda, Tsukasa Abe, Yoshihito Shiota, Yoshio Yano, Toshikazu Ono, Kazunari Yoshizawa, Yoshio Hisaeda

    European Journal of Organic Chemistry   2020 ( 12 )   1783 - 1783   2020.3

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    DOI： 10.1002/ejoc.202000226

  • Electrochemical properties and catalytic reactivity of cobalt complexes with redox-active meso -substituted porphycene ligands Reviewed

    Taro Koide, Zihan Zhou, Ning Xu, Yoshio Yano, Toshikazu Ono, Zhongli Luo, Hisashi Shimakoshi, Yoshio Hisaeda

    Journal of Porphyrins and Phthalocyanines   24 ( 1-3 )   90 - 97   2020.1

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    DOI： 10.1142/S1088424619500780

  • Synthesis of a meso-Tetraalkylporphycene Bearing Reactive Sites Toward Porphycene–Polydimethylsiloxane Hybrids with Enhanced Photophysical Properties Reviewed

    2019 ( 46 )   7578 - 7583   2019.12

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    meso-Tetraalkyl porphycenes exhibit unique optical properties with wide potential applications. The very fact that incorporation of porphycenes into polymeric materials is rare, make this approach a particularly attractive one. In this work, meso-tetrakis(3-butenyl)porphycene bearing four terminal olefin groups is prepared via two synthetic strategies: 1) the McMurry reaction using 5,5′-diacyl-2,2′-bipyrroles as precursors and 2) the oxidative coupling of dipyrroethenes. The newly obtained porphycene has been characterized by single X-ray crystallography. A porphycene–polydimethylsiloxane hybrid film is successfully prepared by a platinum-catalyzed hydrosilylation reaction. The hybrid film can be anchored with tweezers, showing a weak red emission with a quantum yield of 0.4 % at room temperature, whose intensity drastically increases reaching a quantum yield of 6.7 % in liquid nitrogen (77 K). This report represents the first example of porphycene-containing elastomeric films for potential application in various fields.

    DOI： 10.1002/ejoc.201901497

  • Mechanistic Study on Ring Contracting Skeletal Rearrangement from Porphycene to Isocorrole by the Combination of Experimental and Theoretical Studies Reviewed

    Taro Koide, Takafumi Maeda, Tsukasa Abe, Yoshihito Shiota, Yoshio Yano, Toshikazu Ono, Kazunari Yoshizawa, Yoshio Hisaeda

    European Journal of Organic Chemistry   2019.12

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    Mechanistic Study on Ring Contracting Skeletal Rearrangement from Porphycene to Isocorrole by the Combination of Experimental and Theoretical Studies

  • Bipolar thianthrene derivatives exhibiting room temperature phosphorescence for oxygen sensing Reviewed

    Dyes and Pigments   170   2019.11

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    DOI： 10.1016/j.dyepig.2019.107605

  • Bipolar thianthrene derivatives exhibiting room temperature phosphorescence for oxygen sensing Reviewed

    Tomkeviciene Ausra, Dabuliene Asta, Matulaitis Tomas, Guzauskas Matas, Andruleviciene Viktorija, Grazulevicius Juozas Vidas, Yamanaka Yuri, Yano Yoshio, Ono Toshikazu

    DYES AND PIGMENTS   170   2019.11

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    Bipolar thianthrene derivatives exhibiting room temperature phosphorescence for oxygen sensing

    DOI： 10.1016/j.dyepig.2019.107605

  • Symmetry Reduction of Porphycenes with Finely Tuned Optical and Electronic Properties through Oxidative Cyclization of E/Z-Mixed Dipyrroethenes Reviewed

    Ning Xu, Toshikazu Ono, Yoshio Hisaeda

    Chemistry - A European Journal   25 ( 50 )   11680 - 11687   2019.9

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    DOI： 10.1002/chem.201902080

  • Inclusion crystals as vapochromic chemosensors: fabrication of a mini-sensor array for discrimination of small aromatic molecules based on side-chain engineering of naphthalenediimide derivatives Reviewed

    Toshikazu Ono, Yoshifumi Tsukiyama, Sou Hatanaka, Yuma Sakatsume, Tomoki Ogoshi, Yoshio Hisaeda

    JOURNAL OF MATERIALS CHEMISTRY C   7 ( 31 )   9726 - 9734   2019.8

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    DOI： 10.1039/c9tc03140e

  • Salt-cocrystal continuum for photofunction modulation: stimuli-responsive fluorescence color-tuning of pyridine-modified intramolecular charge-transfer dyes and acid complexes Reviewed

    Yano Yoshio, Ono Toshikazu, Hatanaka Sou, Gryko Daniel T, Hisaeda Yoshio

    JOURNAL OF MATERIALS CHEMISTRY C   7 ( 29 )   8847 - 8854   2019.8

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    Salt-cocrystal continuum for photofunction modulation: stimuli-responsive fluorescence color-tuning of pyridine-modified intramolecular charge-transfer dyes and acid complexes

    DOI： 10.1039/c9tc02524c

  • Symmetry Reduction of Porphycenes with Finely Tuned Optical and Electronic Properties through Oxidative Cyclization of E/Z-Mixed Dipyrroethenes Reviewed

    Xu Ning, Ono Toshikazu, Hisaeda Yoshio

    CHEMISTRY-A EUROPEAN JOURNAL   2019.7

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    Symmetry Reduction of Porphycenes with Finely Tuned Optical and Electronic Properties through Oxidative Cyclization of E/Z-Mixed Dipyrroethenes

    DOI： 10.1002/chem.201902080

  • Highly malleable haem-binding site of the haemoprotein HasA permits stable accommodation of bulky tetraphenylporphycenes Reviewed

    Sakakibara Erika, Shisaka Yuma, Onoda Hiroki, Koga Daiki, Xu Ning, Ono Toshikazu, Hisaeda Yoshio, Sugimoto Hiroshi, Shiro Yoshitsugu, Watanabe Yoshihito, Shoji Osami

    RSC ADVANCES   9 ( 32 )   18697 - 18702   2019.6

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    Highly malleable haem-binding site of the haemoprotein HasA permits stable accommodation of bulky tetraphenylporphycenes

    DOI： 10.1039/c9ra02872b

  • Electrochemical properties and catalytic reactivity of cobalt complexes with redox-active meso-substituted porphycene ligands Reviewed

    Taro Koide, Zihan Zhou, Ning Xu, Yoshio Yano, Toshikazu Ono, Zhongli Luo, Hisashi Shimakoshi, Yoshio Hisaeda

    Journal of Porphyrins and Phthalocyanines   2019.4

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    Electrochemical properties and catalytic reactivity of cobalt complexes with redox-active meso-substituted porphycene ligands

  • Visible Light-Driven, One-pot Amide Synthesis Catalyzed by the B 12 Model Complex under Aerobic Conditions Reviewed

    Hui Tian, Hisashi Shimakoshi, Toshikazu Ono, Yoshio Hisaeda

    ChemPlusChem   84 ( 3 )   237 - 240   2019.3

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    DOI： 10.1002/cplu.201800522

  • Front Cover: Visible Light‐Driven, One‐pot Amide Synthesis Catalyzed by the B 12 Model Complex under Aerobic Conditions (ChemPlusChem 3/2019) Reviewed

    84 ( 3 )   233   2019.3

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    DOI： 10.1002/cplu.201800587

  • Visible Light-Driven, One-pot Amide Synthesis Catalyzed by the B-12 Model Complex under Aerobic Conditions Reviewed

    Tian Hui, Shimakoshi Hisashi, Ono Toshikazu, Hisaeda Yoshio

    CHEMPLUSCHEM   84 ( 3 )   237 - 240   2019.3

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    Visible Light-Driven, One-pot Amide Synthesis Catalyzed by the B-12 Model Complex under Aerobic Conditions

    DOI： 10.1002/cplu.201800522

  • Flexible-color tuning and white-light emission in three-, four-, and five-component host/guest co-crystals by charge-transfer emissions as well as effective energy transfers Reviewed

    Ono Toshikazu, Hisaeda Yoshio

    JOURNAL OF MATERIALS CHEMISTRY C   7 ( 10 )   2829 - 2842   2019.3

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    Flexible-color tuning and white-light emission in three-, four-, and five-component host/guest co-crystals by charge-transfer emissions as well as effective energy transfers

    DOI： 10.1039/c8tc06165c

  • Visible-Light-Driven, One-pot Amide Synthesis Catalyzed by the B 12 Model Complex under Aerobic Conditions Reviewed

    Hui Tian, Hisashi Shimakoshi, Toshikazu Ono, Yoshio Hisaeda

    ChemPlusChem   84 ( 3 )   2019.3

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    DOI： 10.1002/cplu.201800586

  • Flexible-color tuning and white-light emission in three-, four-, and five-component host/guest co-crystals by charge-transfer emissions as well as effective energy transfers Reviewed

    Toshikazu Ono, Yoshio Hisaeda

    Journal of Materials Chemistry C   7 ( 10 )   2829 - 2842   2019.1

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    DOI： 10.1039/c8tc06165c

  • Salt-cocrystal continuum for photofunction modulation Stimuli-responsive fluorescence color-tuning of pyridine-modified intramolecular charge-transfer dyes and acid complexes Reviewed

    Yoshio Yano, Toshikazu Ono, Sou Hatanaka, Daniel T. Gryko, Yoshio Hisaeda

    Journal of Materials Chemistry C   7 ( 29 )   8847 - 8854   2019.1

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    DOI： 10.1039/c9tc02524c

  • Learning From Vitamin B 12 -Mediated Reactions Cobalt(III)−Carbon-Assisted Catalytic C−H Difluoroacylation of (Hetero)Arenes through Controlled-Potential Electrolysis Reviewed

    2019.1

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    The synthesis of difluoromethylated (CF 2 R) (R=H, alkyl/aryl, CO 2 R, etc.) compounds has received considerable attention in recent years. In this study, the cobalt(III)−carbon-mediated catalytic C−H difluoroacylation of unactivated arenes and heteroarenes using BrCF 2 CO 2 Et is reported. This catalytic cycle is based on a valence change of the cobalt catalyst, a naturally derived vitamin B 12 derivative, driven by controlled-potential electrolysis at −0.8 V vs. Ag/AgCl under visible-light irradiation in dimethyl sulfoxide. A broad substrate scope is demonstrated, and two compounds were characterized according to their X-ray crystal structures. Mechanistic studies showed that the reaction proceeds through a radical pathway mediated by homolytic cleavage of the cobalt(III)–carbon bond. A turnover number of more than 100 was observed, owing to the inherent stability of the vitamin B 12 framework. This naturally derived catalytic system has potential applications in medicinal chemistry and materials science.

    DOI： 10.1002/celc.201900164

  • Inclusion crystals as vapochromic chemosensors Fabrication of a mini-sensor array for discrimination of small aromatic molecules based on side-chain engineering of naphthalenediimide derivatives Reviewed

    Toshikazu Ono, Yoshifumi Tsukiyama, Sou Hatanaka, Yuma Sakatsume, Tomoki Ogoshi, Yoshio Hisaeda

    Journal of Materials Chemistry C   7 ( 31 )   9726 - 9734   2019.1

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    DOI： 10.1039/c9tc03140e

  • Highly malleable haem-binding site of the haemoprotein HasA permits stable accommodation of bulky tetraphenylporphycenes Reviewed

    Erika Sakakibara, Yuma Shisaka, Hiroki Onoda, Daiki Koga, Ning Xu, Toshikazu Ono, Yoshio Hisaeda, Hiroshi Sugimoto, Yoshitsugu Shiro, Yoshihito Watanabe, Osami Shoji

    RSC Advances   9 ( 32 )   18697 - 18702   2019.1

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    DOI： 10.1039/c9ra02872b

  • Switching of Monomer Fluorescence, Charge-Transfer Fluorescence, and Room-Temperature Phosphorescence Induced by Aromatic Guest Inclusion in a Supramolecular Host Reviewed

    Ono Toshikazu, Taema Ai, Goto Aiko, Hisaeda Yoshio

    CHEMISTRY-A EUROPEAN JOURNAL   24 ( 66 )   17487 - 17496   2018.11

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    Switching of Monomer Fluorescence, Charge-Transfer Fluorescence, and Room-Temperature Phosphorescence Induced by Aromatic Guest Inclusion in a Supramolecular Host

    DOI： 10.1002/chem.201804349

  • Learning from B-12 enzymes: biomimetic and bioinspired catalysts for eco-friendly organic synthesis Reviewed

    Tahara Keishiro, Pan Ling, Ono Toshikazu, Hisaeda Yoshio

    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY   14   2553 - 2567   2018.10

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    Learning from B-12 enzymes: biomimetic and bioinspired catalysts for eco-friendly organic synthesis

    DOI： 10.3762/bjoc.14.232

  • Synthesis of Trifluoromethylated B-12 Derivative and Photolysis of Cobalt(III)-Trifluoromethyl Bond Reviewed

    Ono Toshikazu, Wakiya Kosuke, Hossain Md. Jakir, Shimakoshi Hisashi, Hisaeda Yoshio

    CHEMISTRY LETTERS   47 ( 8 )   979 - 981   2018.8

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    Synthesis of Trifluoromethylated B-12 Derivative and Photolysis of Cobalt(III)-Trifluoromethyl Bond

    DOI： 10.1246/cl.180355

  • Piezofluorochromism in Charge-Transfer Inclusion Crystals: The Influence of High Pressure versus Mechanical Grinding Reviewed

    Ono Toshikazu, Tsukiyama Yoshifumi, Taema Ai, Sato Hiroyasu, Kiyooka Hidetoshi, Yamaguchi Yuma, Nagahashi Ayumi, Nishiyama Manami, Akahama Yuichi, Ozawa Yoshiki, Abe Masaaki, Hisaeda Yoshio

    CHEMPHOTOCHEM   2 ( 5 )   416 - 420   2018.5

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    Language：Others  

    Piezofluorochromism in Charge-Transfer Inclusion Crystals: The Influence of High Pressure versus Mechanical Grinding

    DOI： 10.1002/cptc.201700227

  • Ultralong Room-Temperature Phosphorescence from Amorphous Polymer Poly(Styrene Sulfonic Acid) in Air in the Dry Solid State Reviewed

    Tomoki Ogoshi, Hiromu Tsuchida, Takahiro Kakuta, Tada-Aki Yamagishi, Ai Taema, Toshikazu Ono, Manabu Sugimoto, Motohiro Mizuno

    Advanced Functional Materials   28 ( 16 )   2018.4

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/adfm.201707369

  • The first synthesis of meso-dicycloalkylporphycenes: ring strain effects on structural and optical properties of isomeric porphyrins Reviewed

    Toshikazu Ono, Daiki Koga, Kenji Yoza, Yoshio Hisaeda

    CHEMICAL COMMUNICATIONS   53 ( 91 )   12258 - 12261   2017.11

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/c7cc07170a

  • A vitamin B-12 derivative catalyzed electrochemical trifluoromethylation and perfluoroalkylation of arenes and heteroarenes in organic media Reviewed

    Md. Jakir Hossain, Toshikazu Ono, Kosuke Wakiya, Yoshio Hisaeda

    CHEMICAL COMMUNICATIONS   53 ( 79 )   10878 - 10881   2017.10

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/c7cc06221d

  • Thermoresponsivity of polymer solution derived from a self-attractive urea unit and a self-repulsive lipophilic ion unit Reviewed

    Shogo Amemori, Kazuya Iseda, Shizuka Anan, Toshikazu Ono, Kenta Kokado, Kazuki Sada

    POLYMER CHEMISTRY   8 ( 26 )   3921 - 3925   2017.7

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/c7py00591a

  • Inclusion Crystal Growth and Optical Properties of Organic Charge-transfer Complexes Built from Small Aromatic Guest Molecules and Naphthalenediimide Derivatives Reviewed

    Toshikazu Ono, Yoshifumi Tsukiyama, Ai Taema, Yoshio Hisaeda

    CHEMISTRY LETTERS   46 ( 6 )   801 - 804   2017.6

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1246/cl.170122

  • Facile Synthesis of 9,10,19,20-Tetraalkylporphycenes Reviewed

    Toshikazu Ono, Daiki Koga, Yoshio Hisaeda

    CHEMISTRY LETTERS   46 ( 2 )   260 - 262   2017.2

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1246/cl.161019

  • Turn-On Fluorogenic and Chromogenic Detection of Small Aromatic Hydrocarbon Vapors by a Porous Supramolecular Host Reviewed

    Sou Hatanaka, Toshikazu Ono, Yoshiio Hisaeda

    CHEMISTRY-A EUROPEAN JOURNAL   22 ( 30 )   10346 - 10350   2016.7

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/chem.201601812

  • Oxygen-binding Protein Fiber and Microgel: Supramolecular Myoglobin-Poly(acrylate) Conjugates Reviewed

    Toshikazu Ono, Yasushi Hisaoka, Akira Onoda, Koji Oohora, Takashi Hayashi

    CHEMISTRY-AN ASIAN JOURNAL   11 ( 7 )   1036 - 1042   2016.4

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/asia.201501415

  • Lipophilic Ionomers with Bulky Ion-Pairs and Effect of Counterion on Miscibility of the Ionomer Blends Reviewed

    Masahiko Ohta, Toshikazu Ono, Kenta Kokado, Akira Kakugo, Kazuki Sada

    MACROMOLECULAR CHEMISTRY AND PHYSICS   217 ( 3 )   433 - 444   2016.2

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/macp.201500281

  • An Electropolymerized Crystalline Film Incorporating Axially-Bound Metalloporphycenes: Remarkable Reversibility, Reproducibility, and Coloration Efficiency of Ruthenium(II/III)-Based Electrochromism Reviewed

    Abe, Masaaki, Futagawa, Hiroki, Ono, Toshikazu, Yamada, Teppei, Kimizuka, Nobuo, Hisaeda, Yoshio

    Inorganic Chemistry   54 ( 23 )   11061 - 11063   2015.12

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    Language：Others   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.inorgchem.5b02129

  • Multicomponent Molecular Puzzles for Photofunction Design: Emission Color Variation in Lewis Acid-Base Pair Crystals Coupled with Guest-to-Host Charge Transfer Excitation Reviewed

    Toshikazu Ono, Manabu Sugimoto, Yoshio Hisaeda

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   137 ( 30 )   9519 - 9522   2015.8

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/jacs.5b04178

  • In Vitro Fluorogenic Real-Time Assay of the Repair of Oxidative DNA Damage Reviewed

    Sarah K. Edwards, Toshikazu Ono, Shenliang Wang, Wei Jiang, Raphael M. Franzini, Jong Wha Jung, Ke Min Chan, Eric T. Kool

    CHEMBIOCHEM   16 ( 11 )   1637 - 1646   2015.7

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/cbic.201500184

  • Synthesis and X-ray crystallography of bipyrroles: impacts of a CO-pi interaction on their structure Reviewed

    Toru Okawara, Akane Doi, Toshikazu Ono, Masaaki Abe, Kenji Takehara, Yoshio Hisaeda, Shigenori Matsushima

    TETRAHEDRON LETTERS   56 ( 11 )   1407 - 1410   2015.3

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1016/j.tetlet.2015.01.159

  • Myoglobin-based non-precious metal carbon catalysts for an oxygen reduction reaction Reviewed

    Akira Onoda, Yuta Tanaka, Toshikazu Ono, Shotaro Takeuchi, Akira Sakai, Takashi Hayashi

    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES   19 ( 1-3 )   510 - 516   2015.1

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1142/S108842461550039X

  • Monitoring eukaryotic and bacterial UDG repair activity with DNA-multifluorophore sensors Reviewed

    Toshikazu Ono, Sarah K. Edwards, Shenliang Wang, Wei Jiang, Eric T. Kool

    NUCLEIC ACIDS RESEARCH   41 ( 12 )   2013.7

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1093/nar/gkt309

  • Ionic Polymers Act as Polyelectrolytes in Nonpolar Media Reviewed

    Toshikazu Ono, Masahiko Ohta, Kazuki Sada

    ACS MACRO LETTERS   1 ( 11 )   1270 - 1273   2012.11

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/mz3002879

  • Layer-by-layer Deposition of Ionomers with Lipophilic Ion-pairs Dissociated in Less-polar Media Reviewed

    Masahiko Ohta, Toshikazu Ono, Kazuki Sada

    CHEMISTRY LETTERS   40 ( 6 )   648 - 650   2011.6

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1246/cl.2011.648

  • Molecular Design of Superabsorbent Polymers for Organic Solvents by Crosslinked Lipophilic Polyelectrolytes Reviewed

    Toshikazu Ono, Takahiro Sugimoto, Seiji Shinkai, Kazuki Sada

    ADVANCED FUNCTIONAL MATERIALS   18 ( 24 )   3936 - 3940   2008.12

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/adfm.200801221

  • Lipophilic polyelectrolyte gels as super-absorbent polymers for nonpolar organic solvents Reviewed

    Toshikazu Ono, Takahiro Sugimoto, Seiji Shinkai, Kazuki Sada

    NATURE MATERIALS   6 ( 6 )   429 - 433   2007.6

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    Language：English   Publishing type：Research paper (scientific journal)  

    DOI： 10.1038/nmat1904

▼display all

Presentations

  • Design of Multicomponent Molecular Crystals for Light-emitting Materials and Optical Sensors

    @Toshikazu Ono

    2020.3 

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    Event date： 2020.3

    Language：English   Presentation type：Oral presentation (general)  

    Country：Japan  

  • Design of Multicomponent Crystals for Novel Photofunction Design Invited

    @Toshikazu Ono

    2020.3 

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    Event date： 2020.3

    Language：English   Presentation type：Oral presentation (general)  

    Country：Japan  

  • 有機結晶を利用した発光寿命可変材料の創製

    小野 利和, 福田 有貴, 多惠馬 愛, Yoshio Hisaeda

    第40回有機電子移動化学討論会  2017.6 

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    Event date： 2017.6

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：新潟   Country：Japan  

  • Color-tunable Solid-state Emission of Multicomponent Crystals by Cooperative Electron Donor-Acceptor Complexation International conference

    Toshikazu Ono, Yoshio Hisaeda

    Pacifichem 2015  2016.12 

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    Event date： 2016.12

    Language：English   Presentation type：Oral presentation (general)  

    Country：United States  

  • Preparation of Organic Inclusion Crystals with Tunable Properties of Fluorescence and Phosphorescence Emission International conference

    9th Asian Photochemistry Conference (APC2016)  2016.12 

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    Event date： 2016.12

    Language：English   Presentation type：Oral presentation (general)  

    Country：Singapore  

  • 多孔性有機結晶をホストとした発光色の自在制御可能な固体発光材料の創製

    第24回有機結晶シンポジウム  2015.11 

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    Event date： 2015.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：広島大学霞キャンパス   Country：Japan  

  • 電荷移動錯体を利用した強発光性室温リン光発光材料の創製

    小野 利和, 福田 有貴, 嶌越 恒, 久枝 良雄

    錯体化学会第65回討論会  2015.9 

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    Event date： 2015.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：奈良女子大学   Country：Japan  

  • ビタミンB１２誘導体を触媒とする電解トリフルオロメチル化反応

    脇谷 航介, 小野 利和, 嶌越 恒, 久枝 良雄

    錯体化学会第65回討論会  2015.9 

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    Event date： 2015.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：奈良女子大学   Country：Japan  

  • ビタミンB１２誘導体を利用したラジカル的フルオロアルキル化反応の開拓

    小野 利和, 脇谷 航介, 久枝 良雄

    第９回バイオ関連化学シンポジウム  2015.9 

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    Event date： 2015.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：熊本大学黒髪キャンパス   Country：Japan  

  • ヘテロ分子集積化技術を用いた革新的有機固体発光材料の創製

    小野 利和

    新学術領域「元素ブロック高分子材料の創出」第７回合同班会議  2015.7 

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    Event date： 2015.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：メルパルク京都   Country：Japan  

  • 多孔性有機結晶のナノ空間を利用した芳香族炭化水素の高感度蛍光検出

    畠中　創, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    日本化学会第95春季年会  2015.3 

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    Event date： 2015.3

    Language：Japanese  

    Venue：千葉県船橋市・日本大学理工学部船橋キャンパス   Country：Japan  

  • 多孔性有機結晶のナノ空間を利用した強発光性室温リン光材料の創製

    福田 有貴, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    日本化学会第95春季年会  2015.3 

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    Event date： 2015.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉県船橋市・日本大学理工学部船橋キャンパス   Country：Japan  

  • ヘテロ分子集積化技術を用いた有機固体発光特性の自在チューニング Invited

    小野 利和

    高分子学会九州支部 有機材料研究会  2015.3 

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    Event date： 2015.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：九州大学 伊都キャンパス   Country：Japan  

  • ヘテロ分子集積化技術を用いた有機固体発光材料の創製 Invited

    小野 利和

    元素ブロックミニ講演会  2014.12 

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    Event date： 2014.12

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：広島大学 東広島キャンパス   Country：Japan  

  • ビタミンB12誘導体を触媒とするトリフルオロメチル化反応

    脇谷 航介, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    第47回酸化反応討論会  2014.11 

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    Event date： 2014.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：熊本県熊本市中央区・市民会館崇城大学ホール   Country：Japan  

  • ルイスペア包接結晶の分子デザインによる固体蛍光・リン光発光材料の創製

    小野 利和, 久枝 良雄

    2014年光化学討論会  2014.10 

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    Event date： 2014.10

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北海道札幌市・北海道大学   Country：Japan  

  • ルイスペア包接結晶の固相合成法の検討と発光特性

    畠中 創, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    2014年光化学討論会  2014.10 

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    Event date： 2014.10

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北海道札幌市・北海道大学   Country：Japan  

  • 固相合成法による発光性包接結晶の創製

    畠中 創, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    第51回化学関連支部合同九州大会  2014.6 

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    Event date： 2014.6

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：福岡県北九州市・北九州国際会議場   Country：Japan  

  • ビタミンB12誘導体を触媒とするラジカル的トリフルオロメチル化反応の開発

    脇谷 航介, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    第38回有機電子移動化学討論会  2014.6 

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    Event date： 2014.6

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：岐阜県岐阜市・長良川国際会議場   Country：Japan  

  • 発光性包接結晶の分子設計-固相合成法の検討

    畠中 創, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    日本化学会第94春季年会  2014.3 

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    Event date： 2014.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋大学 東山キャンパス   Country：Japan  

  • トリフルオロメチル基を軸配位子とするビタミンB12誘導体の合成と性質

    脇谷 航介, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    日本化学会第94春季年会  2014.3 

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    Event date： 2014.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋大学 東山キャンパス   Country：Japan  

  • 発光性包接結晶の分子設計-多色、白色、室温リン光材料へのアプローチ

    小野 利和, 畠中 創, 嶌越 恒, 阿部 正明, 久枝 良雄

    日本化学会第94春季年会  2014.3 

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    Event date： 2014.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋大学 東山キャンパス   Country：Japan  

  • ホウ素-窒素錯形成を利用した超分子複合体の固相合成法の構築と固体発光特性の評価

    畠中 創, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    錯体化学会第63回討論会  2013.11 

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    Event date： 2013.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：琉球大学千原キャンパス   Country：Japan  

  • 嵩高いルイス酸-塩基形成を活用したナフタレンジイミド誘導体の会合制御と超分子複合材料の創製

    小野 利和, 池上 篤志, 久枝 良雄

    日本化学会第93春季年会  2013.3 

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    Event date： 2013.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：立命館大学、BKC   Country：Japan  

  • ゲスト包接を利用した発光性包接結晶の創製と有機化合物センサーの開発

    築山佳史、小野利和、小出太郎、嶌越恒、久枝良雄

    日本化学会第98春季年会  2018.3 

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    Event date： 2018.3

    Language：Japanese  

    Venue：日本大学理工学部船橋キャンパス   Country：Japan  

  • 酸塩基反応を利用したピロロピロール誘導体の固体発光チューニング

    矢野喜男、小野利和、小出太郎、嶌越恒、久枝良雄

    日本化学会第98春季年会  2018.3 

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    Event date： 2018.3

    Language：Japanese  

    Venue：日本大学理工学部船橋キャンパス   Country：Japan  

  • Muticomponent Molecular Puzzles for Photofunction Design: Flexible Color Tuning and Photofunction and White Light Emission in Cooperative Donor-Acceptor Molecular Crystals International conference

    Toshikazu ONO, Yoshio Hisaeda

    26th IUPAC Symposium on Photochemistry  2017.4 

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    Event date： 2017.4

    Language：English   Presentation type：Oral presentation (general)  

    Country：Japan  

  • 超分子ホスト分子と芳香族ゲスト分子から構成される発光性包接結晶の調製とメカノクロミズム発光特性

    Toshikazu ONo, 築山 佳史, 多惠馬 愛, Yoshio Hisaeda

    日本化学会 第97春季年会  2017.3 

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    Event date： 2017.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：神奈川　慶應義塾大学 日吉キャンパス   Country：Japan  

  • ナフタレンジイミド誘導体と芳香族ゲスト分子から構成される包接結晶の調製と有機化合物センサーへの応用

    Toshikazu ONo, 築山 佳史, 多惠馬 愛, Yoshio Hisaeda

    日本化学会 第97春季年会  2017.3 

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    Event date： 2017.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：神奈川　慶應義塾大学 日吉キャンパス   Country：Japan  

  • Creation of Fluorogenic Sensors for Aromatic Hydrocarbons by Supramolecular Porous Hosts International conference

    Toshikazu Ono, Sou Hatanaka, Yoshio Hisaeda

    Pacifichem 2015  2016.12 

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    Event date： 2016.12

    Language：English  

    Country：Japan  

  • Crystal Engineering of Multicomponent Molecular Puzzles for Novel Photofunction Design International conference

    Toshikazu ONo, Ai Taema, Yuki Fukuda, Sou Hatanaka, Yoshio Hisaeda

    9th Asian Photochemistry Conference (APC2016)  2016.12 

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    Event date： 2016.12

    Language：English  

    Country：Singapore  

  • 結晶工学を利用した発光色の制御可能な有機固体発光材料の創製

    福田 有貴, 小野 利和, 小出 太郎, 嶌越 恒, Yoshio Hisaeda

    第53回化学関連支部合同九州大会  2016.7 

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    Event date： 2016.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：福岡   Country：Japan  

  • 蛍光、燐光発光のチューニングを目的とした有機包接結晶の創製

    小野 利和, 多惠馬 愛, 小出 太郎, 嶌越 恒, Yoshio Hisaeda

    第53回化学関連支部合同九州大会  2016.7 

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    Event date： 2016.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：福岡   Country：Japan  

  • 発光色と発光寿命の自在制御を可能とする有機結晶空間内ホスト-ゲストケミストリー

    第96回日本化学会春季年会  2016.3 

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    Event date： 2016.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Country：Japan  

  • 芳香族炭化水素の高感度蛍光検出を目的とした多孔性有機結晶材料の創製

    第24回有機結晶シンポジウム  2015.11 

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    Event date： 2015.11

    Language：Japanese  

    Venue：広島大学霞キャンパス   Country：Japan  

  • 自己組織化を利用した多核金属錯体のメゾスコピック超分子構造体形成とその特性

    藤岡 太郎, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    錯体化学会第65回討論会  2015.9 

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    Event date： 2015.9

    Language：Japanese  

    Venue：奈良女子大学   Country：Japan  

  • ポルフィリン構造異性体を集積化した電解重合薄膜の創製及びそのエレクトロクロミック特性

    二川 裕紀, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    錯体化学会第65回討論会  2015.9 

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    Event date： 2015.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：奈良女子大学   Country：Japan  

  • 新規オキシム型二核錯体の合成とその特性

    橋本 将司, 嶌越 恒, 小野 利和, 久枝 良雄

    錯体化学会第65回討論会  2015.9 

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    Event date： 2015.9

    Language：Japanese  

    Venue：奈良女子大学   Country：Japan  

  • 多核錯体を集積化した環状構造体への修飾基導入法の開拓

    清水 遥加, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    錯体化学会第65回討論会  2015.9 

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    Event date： 2015.9

    Language：Japanese  

    Venue：奈良女子大学   Country：Japan  

  • 多核クラスターユニットの事前修飾による 機能性高分子錯体

    清水 遥加, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    日本化学会第95春季年会  2015.3 

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    Event date： 2015.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉県船橋市・日本大学理工学部船橋キャンパス   Country：Japan  

  • ポルフィリン構造異性体を集積化した電解重合薄膜の作製とそのエレクトロクロミック特性

    二川 裕紀, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    日本化学会第95春季年会  2015.3 

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    Event date： 2015.3

    Language：Japanese  

    Venue：千葉県船橋市・日本大学理工学部船橋キャンパス   Country：Japan  

  • 新規メソ位イミダゾール修飾ポルフィセンの合成

    金子和弘, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    日本化学会第95春季年会  2015.3 

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    Event date： 2015.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉県船橋市・日本大学理工学部船橋キャンパス   Country：Japan  

  • 自己組織化を利用した多核金属錯体のメゾスコピック超分子構造体形成とその特性

    藤岡 太郎, 阿部 正明, 小野 利和, 嶌越 恒, 山田 淳, 米村 弘明, 久枝 良雄

    日本化学会第95春季年会  2015.3 

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    Event date： 2015.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉県船橋市・日本大学理工学部船橋キャンパス   Country：Japan  

  • ビタミンB12誘導体のコバルト-ヒドリド錯体を用いた有機合成反応の開拓

    高橋 洸洋, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    日本化学会第95春季年会  2015.3 

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    Event date： 2015.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉県船橋市・日本大学理工学部船橋キャンパス   Country：Japan  

  • 新規オキシム型二核コバルト錯体の合成とその性質

    橋本 将司, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    日本化学会第95春季年会  2015.3 

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    Event date： 2015.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：千葉県船橋市・日本大学理工学部船橋キャンパス   Country：Japan  

  • 界面錯体形成を利用した可視光応答型ビタミンB12-TiO2触媒による物質変換反応

    米村俊佑, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    2014年光化学討論会  2014.10 

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    Event date： 2014.10

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北海道札幌市・北海道大学   Country：Japan  

  • 新規リンポルフィセンの合成と発光特性

    向高 寛人, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    2014年光化学討論会  2014.10 

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    Event date： 2014.10

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北海道札幌市・北海道大学   Country：Japan  

  • ルテニウムポルフィセン重合薄膜の合成及びそのエレクトロクロミック特性

    二川 裕紀, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    錯体化学会第64回討論会  2014.9 

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    Event date： 2014.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：東京都文京区・中央大学   Country：Japan  

  • ポルフィリン環を含むRu十二核錯箱型クラスターの合成、構造および溶液内挙動

    友田 満, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    錯体化学会第64回討論会  2014.9 

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    Event date： 2014.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：東京都文京区・中央大学   Country：Japan  

  • Highly Emitting Lattice Inclusion Crystals by Supramolecular Approach

    Toshikazu Ono, Yoshio Hisaeda

    2014.9 

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    Event date： 2014.9

    Language：English   Presentation type：Oral presentation (general)  

    Country：Japan  

  • コバルトポルフィセン錯体の配位還元体を活性種とした反応とその機構

    佐伯 達也, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    錯体化学会第64回討論会  2014.9 

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    Event date： 2014.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：東京都文京区・中央大学   Country：Japan  

  • Bioinspired Catalytic Reactions:Lessons from Vitamin B12 Enzymes

    Yoshio Hisaeda, Shunsuke Yonemura, Kosuke Wakiya, Toshikazu Ono, Hisashi Shimakoshi, Takahiro Masuki

    ICOMC 2014  2014.7 

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    Event date： 2014.7

    Language：English   Presentation type：Oral presentation (general)  

    Country：Japan  

  • Synthesis and Characterizations of a New Metalloporphycene with Axially-Coordunated Electropolymerizable Functionalities International conference

    Hiroki Futagawa, Masaaki Abe, Toshikazu Ono, Hisashi Shimakoshi, Yoshio Hisaeda

    ICOMC 2014  2014.7 

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    Event date： 2014.7

    Language：English  

    Country：Japan  

  • Redox-Active Supramolecular Clusters through Tridenate Coordination Linkage:Solid-State Characterisscs and Reactivity

    Haruka Shimizu, Masaaki Abe, Toshikazu Ono, Hisashi Shimakoshi, Yoshio Hisaeda

    ICOMC 2014  2014.7 

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    Event date： 2014.7

    Language：English   Presentation type：Oral presentation (general)  

    Country：Japan  

  • コバルトポルフィセンの酸化還元挙動と配位子還元体を利用した触媒反応

    佐伯 達也, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    第51回化学関連支部合同九州大会  2014.6 

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    Event date： 2014.6

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：福岡県北九州市・北九州国際会議場   Country：Japan  

  • 多角錯体を集積化したメタロ超分子ポリマーの創製とレドックス特性

    清水 遥加, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    第51回化学関連支部合同九州大会  2014.6 

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    Event date： 2014.6

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：福岡県北九州市・北九州国際会議場   Country：Japan  

  • 界面錯体形成により可視光応答化したビタミンB12-TiO2触媒の作製と反応評価

    米村 俊佑, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    第51回化学関連支部合同九州大会  2014.6 

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    Event date： 2014.6

    Language：Japanese  

    Venue：福岡県北九州市・北九州国際会議場   Country：Japan  

  • 電子メディエーターの導入による高効率なビタミンB12-Ru光増感剤系の構築

    法福 紀之, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    第51回化学関連支部合同九州大会  2014.6 

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    Event date： 2014.6

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：福岡県北九州市・北九州国際会議場   Country：Japan  

  • 多角箱形クラスターの合成と溶液内ホストゲスト相互作用のDOSYによる解析

    友田 満, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    第51回化学関連支部合同九州大会  2014.6 

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    Event date： 2014.6

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：福岡県北九州市・北九州国際会議場   Country：Japan  

  • ビタミンB12誘導体を用いたラジカル的トリフルオロメチル化反応

    脇谷 航介, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    第7回分子活性化公開シンポジウム  2014.6 

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    Event date： 2014.6

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北海道札幌市・北海道大学   Country：Japan  

  • 非金属ポルフィセンの化学：新規リンポルフィセンの合成と発光挙動

    向高 寛人, 阿部 正明, 大川原 徹, 小野 利和, 嶌越 恒, 久枝 良雄

    日本化学会第94春季年会  2014.3 

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    Event date： 2014.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋大学 東山キャンパス   Country：Japan  

  • 界面錯体形成により可視光応答化したビタミンB12-TiO2触媒の創製と反応特性

    米村 俊佑, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    日本化学会第94春季年会  2014.3 

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    Event date： 2014.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋大学 東山キャンパス   Country：Japan  

  • ビタミンB12誘導体を用いた有機ハロゲン化合物からの電気化学的物質変換

    稲葉 卓也, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    日本化学会第94春季年会  2014.3 

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    Event date： 2014.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋大学 東山キャンパス   Country：Japan  

  • ビタミンB12-Ru光増感剤系への電子メディエーターの導入とその応用

    法福 紀之, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    日本化学会第94春季年会  2014.3 

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    Event date： 2014.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋大学 東山キャンパス   Country：Japan  

  • Ru三核錯体とポルフィリンを含む多核箱型クラスターの合成と溶液内ホストゲスト相互作用

    友田 満, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    日本化学会第94春季年会  2014.3 

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    Event date： 2014.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋大学 東山キャンパス   Country：Japan  

  • 多座配位子を末端に有する多核金属錯体の合成と物性

    清水 遥加, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    日本化学会第94春季年会  2014.3 

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    Event date： 2014.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋大学 東山キャンパス   Country：Japan  

  • Preparation and Reactivity of Visible-light Responsive B12-TiO2 Catalyst Composed of Interfacial Complexartion International conference

    Korea-Japan Symposium on Frontier Photoscience (KJFP-2013)  2013.11 

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    Event date： 2013.11

    Language：English   Presentation type：Oral presentation (general)  

    Country：Japan  

  • Synthesis and Photoluminescent Property of Lanthanide Complexes bearing Ruthenium Porphyrin linked by Coordination bond International conference

    Korea-Japan Symposium on Frontier Photoscience (KJFP-2013)  2013.11 

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    Event date： 2013.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Country：Japan  

  • Synthesis of Vitamin B12-Ru(bby)3 Polymer as Visible Light Driving Catalyst International conference

    Korea-Japan Symposium on Frontier Photoscience (KJFP-2013)  2013.11 

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    Event date： 2013.11

    Language：English   Presentation type：Oral presentation (general)  

    Country：Japan  

  • コバルトポルフィセン錯体類の酸化還元挙動と酸化的付加反応

    久枝 良雄, 佐伯 達也, 橋本 浩一, 小野 利和, 嶌越 恒, 阿部 正明

    第46回酸化反応討論会  2013.11 

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    Event date： 2013.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：筑波大学大学会館   Country：Japan  

  • 非金属ポルフィセンの化学：新規リンポルフィセンの合成

    向高 寛人, 阿部 正明, 大川原 徹, 小野 利和, 嶌越 恒, 久枝 良雄

    錯体化学会第63回討論会  2013.11 

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    Event date： 2013.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：琉球大学千原キャンパス   Country：Japan  

  • Synthesis of Oxo-Centered Heterometalic Clucters Decorated by Four Porphyrincarboxylato Ligands

    2013.11 

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    Event date： 2013.11

    Language：English   Presentation type：Oral presentation (general)  

    Country：Japan  

  • 長鎖アルキル修飾ルテニウム三核錯体の合成とその自己集合特性

    中西 太郎, 小野 利和, 阿部 正明, 嶌越 恒, 久枝 良雄

    錯体化学会第63回討論会  2013.11 

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    Event date： 2013.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：琉球大学千原キャンパス   Country：Japan  

  • 水素化ポルフィセン金属錯体の合成と酸化還元特性

    橋本 浩一, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    錯体化学会第63回討論会  2013.11 

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    Event date： 2013.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：琉球大学千原キャンパス   Country：Japan  

  • コバルト錯体とバイオマスを用いた光駆動型水素発生触媒系の構築

    藤田 勇祐, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    錯体化学会第63回討論会  2013.11 

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    Event date： 2013.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：琉球大学千原キャンパス   Country：Japan  

  • 軸位連結型ルテニウム(II)ポルフィリン-ランタノイド(III)二核錯体の合成と発光特性

    満生 健太, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    錯体化学会第63回討論会  2013.11 

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    Event date： 2013.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：琉球大学千原キャンパス   Country：Japan  

  • コバルトポルフィセンの配位子レドックスを利用した触媒的脱ハロゲン化反応

    佐伯 達也, 有留 功, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    錯体化学会第63回討論会  2013.11 

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    Event date： 2013.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：琉球大学千原キャンパス   Country：Japan  

  • ポルフィリンとルテニウム三核錯体をユニットとする多核箱形クラスターの構築とホストゲスト相互作用

    谷口 直毅, 友田 満, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    錯体化学会第63回討論会  2013.11 

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    Event date： 2013.11

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：琉球大学千原キャンパス   Country：Japan  

  • ホウ素-窒素結合を活用したナフタレンジイミド誘導体の会合制御と固体発光特性の評価

    小野 利和, 久枝 良雄

    第7回バイオ関連化学シンポジウム  2013.9 

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    Event date： 2013.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：名古屋大学 東山キャンパス   Country：Japan  

  • 可視光駆動型ビタミンB12高分子触媒の開発と物質変換反応への応用

    法福 紀之, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    2013年光化学討論会  2013.9 

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    Event date： 2013.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：愛媛大学 城北キャンパス   Country：Japan  

  • 嵩高いルイスペアを利用したナフタレンジイミド誘導体の会合制御と固体発光材料への応用

    小野 利和, 久枝 良雄

    2013年光化学討論会  2013.9 

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    Event date： 2013.9

    Language：Japanese   Presentation type：Oral presentation (general)  

    Country：Japan  

  • 嵩高いルイスペアを活用したπ共役分子の会合制御と固体発光材料の開発

    小野 利和, 久枝 良雄

    第25回配位化合物の光化学討論会  2013.8 

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    Event date： 2013.8

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：唐津ロイヤルホテル   Country：Japan  

  • 非金属ポルフィセンの化学：新規リンポルフィセン錯体の合成と発光特性

    向高 寛人, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    第50回化学関連支部合同九州大会  2013.7 

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    Event date： 2013.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北九州国際会議場・北九州市小倉北区   Country：Japan  

  • ポルフィリン集積型混合金属錯体の合成と機能特性

    池上 篤志, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    第50回化学関連支部合同九州大会  2013.7 

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    Event date： 2013.7

    Language：Japanese  

    Venue：北九州国際会議場・北九州市小倉北区   Country：Japan  

  • オキソカルボキシレート架橋ルテニウム三核錯体に対するクリックケミストリーの 検討

    中西 太郎, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    第50回化学関連支部合同九州大会  2013.7 

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    Event date： 2013.7

    Language：Japanese  

    Venue：北九州国際会議場・北九州市小倉北区   Country：Japan  

  • 水素化ポルフィセンコバルト錯体の合成と機能特性

    橋本 浩一, 大川原 徹, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    第50回化学関連支部合同九州大会  2013.7 

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    Event date： 2013.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北九州国際会議場・北九州市小倉北区   Country：Japan  

  • バイオマスを電子源とした非貴金属系光駆動型水素発生

    藤田 勇祐, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    第50回化学関連支部合同九州大会  2013.7 

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    Event date： 2013.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北九州国際会議場・北九州市小倉北区   Country：Japan  

  • ランタノイド錯体配位子を軸位に持つRuポルフィリン錯体の合成と発光特性

    満生 健太, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    第50回化学関連支部合同九州大会  2013.7 

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    Event date： 2013.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北九州国際会議場・北九州市小倉北区   Country：Japan  

  • コバルトポルフィセンの配位子還元を利用した脱ハロゲン的触媒反応

    佐伯 達也, 有留 功, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    第50回化学関連支部合同九州大会  2013.7 

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    Event date： 2013.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北九州国際会議場・北九州市小倉北区   Country：Japan  

  • ルテニウム三核錯体をユニットとする箱型クラスターの合成と溶液内ホストゲスト相互作用

    友田 満, 池上 篤志, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    第50回化学関連支部合同九州大会  2013.7 

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    Event date： 2013.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北九州国際会議場・北九州市小倉北区   Country：Japan  

  • 光増感部位を利用したビタミンB12触媒システムの開発

    法福 紀之, 嶌越 恒, 小野 利和, 阿部 正明, 久枝 良雄

    第50回化学関連支部合同九州大会  2013.7 

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    Event date： 2013.7

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：北九州国際会議場・北九州市小倉北区   Country：Japan  

  • 嵩高いルイス酸-塩基形成を活用したナフタレンジイミド誘導体の包接結晶の創製とゲスト分子に依存した固体発行特性の評価

    小野 利和, 久枝 良雄

    第62回高分子学会年次大会  2013.5 

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    Event date： 2013.5

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：京都国際会館   Country：Japan  

  • 非金属ポルフィセン化学の開拓：新規リンポルフィセンの合成

    向高 寛人, 阿部 正明, 大川原 徹, 小野 利和, 嶌越 恒, 久枝 良雄

    日本化学会第93春季年会  2013.3 

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    Event date： 2013.3

    Language：Japanese  

    Venue：立命館大学BKC、滋賀   Country：Japan  

  • ミオグロビンを用いた燃料電池カソード触媒の調製と評価

    田中 雄大, 小野 利和, 小野田 晃, 林 高史

    日本化学会第93春季年会  2013.3 

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    Event date： 2013.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：立命館大学KBC、滋賀   Country：Japan  

  • コバルトポルフィセンの配位子還元を利用したCO-C結合の形成反応

    佐伯 達也, 有留 功, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    日本化学会第93春季年会  2013.3 

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    Event date： 2013.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：立命館大学BKC、滋賀   Country：Japan  

  • ポルフィリン環を含む多核箱形クラスターの合成と溶液内ホストゲスト相互作用

    友田 満, 阿部 正明, 谷口 直毅, 稲富 敦, 小野 利和, 嶌越 恒, 久枝 良雄

    日本化学会第93春季年会  2013.3 

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    Event date： 2013.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：立命館大学BKC、滋賀   Country：Japan  

  • メタロセン集積型金属クラスターの合成と電子特性

    池上 篤志, 阿部 正明, 小野 利和, 嶌越 恒, 久枝 良雄

    日本化学会第93春季年会  2013.3 

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    Event date： 2013.3

    Language：Japanese   Presentation type：Oral presentation (general)  

    Venue：立命館大学BKC、滋賀   Country：Japan  

  • コバルトポルフィセンの配位子レドックスを利用した酸化的付加反応

    佐伯 達也, 有留 功, 小野 利和, 嶌越 恒, 阿部 正明, 久枝 良雄

    第37回有機電子移動化学討論会 

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    Venue：岡山大学創立50周年記念館   Country：Japan  

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MISC

  • パズルの要領で分子を並べ、新しい機能性色素を作る技術 -宝石のように光る有機発光体-

    小野 利和, 久枝 良雄

    科学と工業、大阪工研協会   2016.6

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  • ベンゾチエノベンゾチオフェン誘導体と有機ホウ素化合物のルイス対形成を利用した電気化学発光の増強

    田原圭志朗, 田原圭志朗, 池田貴志, 石松亮一, 小野利和, 小澤芳樹, 阿部正明

    有機電子移動化学討論会講演要旨集   47th (CD-ROM)   2023

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  • 分子性レニウム(I)錯体の柔軟結晶が示す構造ダイナミクスと放射光粉末回折その場観測

    松田雄貴, 中村瞭汰, 小澤芳樹, 田原圭志朗, 小野利和, 吉成信人, 今野巧, 杉本邦久, 小林慎太郎, 河口彰吾, 阿部正明

    日本結晶学会年会講演要旨集   2023   2023

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  • Reversible Conversion of Multiple Non-Covalent Interactions in Vapochromic Gate-Open-Close Crystals of a Rhenium(I) Complex: In-Situ Observation of the Guest-Induced Structural Transformation Dynamics

    MATSUDA Yuki, NAKAMURA Ryota, OZAWA Yoshiki, TAHARA Keishiro, ONO Toshikazu, YOSHINARI Nobuto, KONNO Takumi, SUGIMOTO Kunihisa, KOBAYASHI Shintaro, KAWAGUCHI Shogo, ABE Masaaki

    錯体化学会討論会講演要旨集   72nd (CD-ROM)   2022

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  • Novel tricarbonylrhenium(I) vapochromic molecular crystals: gate-opening solvent-inclusion behavior and vapor-induced emission enhancement

    松田雄貴, 小澤芳樹, 田原圭志朗, 小野利和, 吉成信人, 今野巧, 杉本邦久, 小林慎太郎, 河口彰吾, 阿部正明

    ホスト-ゲスト・超分子化学シンポジウム講演要旨集   19th   2022

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  • Vapochromism of organic crystals based on macrocyclic compounds and inclusion complexes

    Toshikazu Ono, Yoshio Hisaeda

    Symmetry   2020.11

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    DOI： 10.3390/sym12111903

  • Synthesis of a meso-Tetraalkylporphycene Bearing Reactive Sites: Toward Porphycene–Polydimethylsiloxane Hybrids with Enhanced Photophysical Properties

    2019.12

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    © 2019 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim meso-Tetraalkyl porphycenes exhibit unique optical properties with wide potential applications. The very fact that incorporation of porphycenes into polymeric materials is rare, make this approach a particularly attractive one. In this work, meso-tetrakis(3-butenyl)porphycene bearing four terminal olefin groups is prepared via two synthetic strategies: 1) the McMurry reaction using 5,5′-diacyl-2,2′-bipyrroles as precursors and 2) the oxidative coupling of dipyrroethenes. The newly obtained porphycene has been characterized by single X-ray crystallography. A porphycene–polydimethylsiloxane hybrid film is successfully prepared by a platinum-catalyzed hydrosilylation reaction. The hybrid film can be anchored with tweezers, showing a weak red emission with a quantum yield of 0.4 &#37; at room temperature, whose intensity drastically increases reaching a quantum yield of 6.7 &#37; in liquid nitrogen (77 K). This report represents the first example of porphycene-containing elastomeric films for potential application in various fields.

    DOI： 10.1002/ejoc.201901497

  • Visible-Light-Driven, One-pot Amide Synthesis Catalyzed by the B <inf>12</inf> Model Complex under Aerobic Conditions

    Hui Tian, Hisashi Shimakoshi, Toshikazu Ono, Yoshio Hisaeda

    ChemPlusChem   2019.3

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    Visible-Light-Driven, One-pot Amide Synthesis Catalyzed by the B <inf>12</inf> Model Complex under Aerobic Conditions
    © 2019 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim Invited for this month&#039;s cover is the group of Prof. Dr. Hisashi Shimakoshi at Kyushu University, Japan. The front cover shows “le mariage” of an iridium complex and a vitamin B 12 derivative with two wedding rings in the background. This collaboration of two complexes is induced by visible light in the presence of air to achieve green molecular transformations. This protocol was applied to the synthesis of amides from a wide range of trichlorinated organic compounds. Read the full text of the article at 10.1002/cplu.201800522.

    DOI： 10.1002/cplu.201800586

  • Learning From Vitamin B<inf>12</inf>-Mediated Reactions: Cobalt(III)–Carbon-Assisted Catalytic C−H Difluoroacylation of (Hetero)Arenes through Controlled-Potential Electrolysis

    2019.1

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    © 2019 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim Invited for this month&#039;s cover picture is the group of Yoshio Hisaeda at Kyushu University (Japan). The cover picture shows the electrochemical activation of a vitamin B12 derivative and the obtained difluoroacylated products. Read the full text of the Article at 10.1002/celc.201900164.

    DOI： 10.1002/celc.201901155

  • Learning From Vitamin B <inf>12</inf> -Mediated Reactions: Cobalt(III)−Carbon-Assisted Catalytic C−H Difluoroacylation of (Hetero)Arenes through Controlled-Potential Electrolysis

    2019.1

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    © 2019 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim The synthesis of difluoromethylated (CF 2 R) (R=H, alkyl/aryl, CO 2 R, etc.) compounds has received considerable attention in recent years. In this study, the cobalt(III)−carbon-mediated catalytic C−H difluoroacylation of unactivated arenes and heteroarenes using BrCF 2 CO 2 Et is reported. This catalytic cycle is based on a valence change of the cobalt catalyst, a naturally derived vitamin B 12 derivative, driven by controlled-potential electrolysis at −0.8 V vs. Ag/AgCl under visible-light irradiation in dimethyl sulfoxide. A broad substrate scope is demonstrated, and two compounds were characterized according to their X-ray crystal structures. Mechanistic studies showed that the reaction proceeds through a radical pathway mediated by homolytic cleavage of the cobalt(III)–carbon bond. A turnover number of more than 100 was observed, owing to the inherent stability of the vitamin B 12 framework. This naturally derived catalytic system has potential applications in medicinal chemistry and materials science.

    DOI： 10.1002/celc.201900164

  • Learning from b12 enzymes Biomimetic and bioinspired catalysts for eco-friendly organic synthesis

    Keishiro Tahara, Ling Pan, Toshikazu Ono, Yoshio Hisaeda

    Beilstein Journal of Organic Chemistry   2018.10

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    Language：English   Publishing type：Article, review, commentary, editorial, etc. (scientific journal)  

    DOI： 10.3762/bjoc.14.232

  • 新規なポルフィセンリン錯体の合成とその酸化還元挙動

    藤岡太郎, 向高寛人, 阿部正明, 小出太郎, 小野利和, 小野利和, 嶌越恒, 久枝良雄, 久枝良雄

    電気化学秋季大会講演要旨集(CD‐ROM)   2017.8

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  • 新規なアンチモンポルフィセン錯体の合成と性質

    藤岡太郎, 向高寛人, 阿部正明, 小出太郎, 小野利和, 嶌越恒, 久枝良雄

    化学関連支部合同九州大会・外国人研究者交流国際シンポジウム講演予稿集   2017.7

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  • ルテニウム三核錯体とポルフィリンから成る箱型クラスターの光・電子物性評価

    中川貴博, 小澤芳樹, 友田満, 小野利和, 久枝良雄, 阿部正明

    日本化学会春季年会講演予稿集(CD-ROM)   2017.3

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  • オキソ‐プロピオン酸架橋ルテニウム三核環状四量体への修飾基導入と電気化学的性質

    大長継大, 小澤芳樹, 小澤芳樹, 清水遥加, 小野利和, 久枝良雄, 阿部正明, 阿部正明

    日本化学会春季年会講演予稿集(CD-ROM)   2017.3

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  • 新規なポルフィセン15族元素錯体の合成とその電気化学的特性について

    藤岡太郎, 向高寛人, 阿部正明, 小出太郎, 小野利和, 小野利和, 嶌越恒, 久枝良雄, 久枝良雄

    酸化反応討論会講演要旨集   2016.11

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  • ポルフィセンリン錯体の合成と光・電気化学物性

    小出太郎, 藤岡太郎, 向高寛人, 阿部正明, 小野利和, 小野利和, 嶌越恒, 久枝良雄

    酸化反応討論会講演要旨集   2016.11

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  • 新規なリンポルフィセン錯体の合成と構造および酸化還元挙動

    藤岡太郎, 向高寛人, 阿部正明, 小出太郎, 小野利和, 小野利和, 嶌越恒, 久枝良雄, 久枝良雄

    錯体化学会討論会講演要旨集   2016.8

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  • N‐ヘテロ四員環二座配位子を用いたハーフランタン型白金(II)二核錯体の構造と発光挙動

    松岡秀典, 小澤芳樹, 小澤芳樹, 鳥海幸四郎, 鳥海幸四郎, 小野利和, 久枝良雄, 阿部正明, 阿部正明

    錯体化学会討論会講演要旨集   2016.8

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  • 新規なポルフィセン15族元素錯体の合成とその物性

    藤岡太郎, 向高寛人, 阿部正明, 小出太郎, 小野利和, 嶌越恒, 久枝良雄

    化学関連支部合同九州大会・外国人研究者交流国際シンポジウム講演予稿集   2016.7

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  • 自己組織化を利用した多核金属錯体のメゾスコピック超分子構造体形成とその特性

    藤岡太郎, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    錯体化学会討論会講演要旨集   2015.9

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  • ポルフィリン構造異性体を集積化した電解重合薄膜の創製及びそのエレクトロクロミック特性

    二川裕紀, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    錯体化学会討論会講演要旨集   2015.9

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  • 多核錯体を集積化した環状構造体への修飾基導入法の開拓

    清水遥加, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    錯体化学会討論会講演要旨集   2015.9

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  • 自己組織化を利用した多核金属錯体のメゾスコピック超分子構造体形成とその特性

    藤岡太郎, 阿部正明, 中西太郎, 小野利和, 嶌越恒, 久枝良雄

    化学関連支部合同九州大会・外国人研究者交流国際シンポジウム講演予稿集   2015.6

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  • ポルフィリン構造異性体を集積化した電解重合薄膜の作製とそのエレクトロクロミック特性

    二川裕紀, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    化学関連支部合同九州大会・外国人研究者交流国際シンポジウム講演予稿集   2015.6

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  • 多核クラスターユニットの事前修飾による機能性高分子錯体の合成

    清水遥加, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    化学関連支部合同九州大会・外国人研究者交流国際シンポジウム講演予稿集   2015.6

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  • ポルフィリン構造異性体を集積化した電解重合薄膜の作製とそのエレクトロクロミック特性

    二川裕紀, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    万有生命科学振興国際交流財団福岡シンポジウム   2015.5

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  • 自己組織化を利用した多核金属錯体のメゾスコピック超分子構造体形成とその特性

    藤岡太郎, 阿部正明, 小野利和, 嶌越恒, 米村弘明, 山田淳, 久枝良雄

    日本化学会講演予稿集   2015.3

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  • ビタミンB12誘導体のコバルト‐ヒドリド錯体を用いた有機合成反応の開拓

    高橋洸洋, 嶌越恒, 小野利和, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2015.3

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  • ビタミンB12誘導体を触媒とした電解トリフルオロメチル化触媒反応

    脇谷航介, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2015.3

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  • ポルフィリン構造異性体を集積化した電解重合薄膜の作製とそのエレクトロクロミック特性

    二川裕紀, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    日本化学会講演予稿集   2015.3

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  • 多孔性有機結晶のナノ空間を利用した芳香族炭化水素の高感度蛍光検出

    畠中創, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2015.3

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  • 多孔性有機結晶のナノ空間を利用した強発光性室温リン光材料の創製

    福田有貴, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2015.3

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  • 多核クラスターユニットの事前修飾による機能性高分子錯体の合成

    清水遥加, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    日本化学会講演予稿集   2015.3

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  • 新規イミダゾール修飾ポルフィセンの合成

    金子和弘, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    日本化学会講演予稿集   2015.3

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  • 新規オキシム型二核コバルト錯体の合成とその性質

    橋本将司, 嶌越恒, 小野利和, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2015.3

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  • ビタミンB12誘導体を触媒とするトリフルオロメチル化反応

    脇谷航介, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    酸化反応討論会講演要旨集   2014.11

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  • 多核錯体を集積化したメタロ超分子ポリマーの創製とレドックス特性

    清水遥加, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    錯体化学会討論会講演要旨集   2014.9

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  • コバルトポルフィセン錯体の配位子還元体を活性種とした反応とその機構

    佐伯達也, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    錯体化学会討論会講演要旨集   2014.9

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  • ポルフィリン環を含むRu十二核箱型クラスターの合成,構造および溶液内挙動

    友田満, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    錯体化学会討論会講演要旨集   2014.9

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    Language：Japanese  

  • ルテニウムポルフィセン重合薄膜の合成及びそのエレクトロクロミック特性

    二川裕紀, 阿部正明, 大川原徹, 小野利和, 嶌越恒, 久枝良雄

    錯体化学会討論会講演要旨集   2014.9

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    Language：Japanese  

  • ビタミンB12誘導体を触媒とするラジカル的トリフルオロメチル化反応の開発

    脇谷航介, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    有機電子移動化学討論会講演要旨集   2014.6

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    Language：Japanese  

  • Ru三核錯体とポルフィリンを含む多核箱形クラスターの合成とホストゲスト相互作用

    友田満, 阿部正明, 谷口直毅, 稲富敦, 小野利和, 嶌越恒, 久枝良雄

    日本化学会講演予稿集   2014.3

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    Language：Japanese  

  • トリフルオロメチル基を軸配位子とするビタミンB12誘導体の合成と性質

    脇谷航介, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2014.3

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    Language：Japanese  

  • ビタミンB12誘導体を用いた有機ハロゲン化合物からの電気化学的物質変換反応

    稲葉卓也, 嶌越恒, 小野利和, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2014.3

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    Language：Japanese  

  • ビタミンB12‐Ru光増感剤系への電子メディエーターの導入とその応用

    法福紀之, 嶌越恒, 小野利和, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2014.3

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    Language：Japanese  

  • 多座配位子を末端に有する多核金属錯体の合成と物性

    清水遥加, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    日本化学会講演予稿集   2014.3

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    Language：Japanese  

  • 発光性包接結晶の分子設計:多色,白色,室温リン光材料へのアプローチ

    小野利和, 畠中創, 嶌越恒, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2014.3

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    Language：Japanese  

  • 発光性包接結晶の分子設計:固相合成法の適用

    畠中創, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2014.3

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    Language：Japanese  

  • 重合部位を有する新規ポルフィセン金属錯体の合成

    二川裕紀, 阿部正明, 大川原徹, 小野利和, 嶌越恒, 久枝良雄

    日本化学会講演予稿集   2014.3

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    Language：Japanese  

  • 非金属ポルフィセンの化学:新規リンポルフィセンの合成と発光挙動

    向高寛人, 阿部正明, 大川原徹, 小野利和, 嶌越恒, 久枝良雄

    日本化学会講演予稿集   2014.3

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    Language：Japanese  

  • コバルトポルフィセン錯体類の酸化還元挙動と酸化的付加反応

    久枝良雄, 佐伯達也, 橋本浩一, 小野利和, 嶌越恒, 阿部正明

    酸化反応討論会講演要旨集   2013.11

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    Language：Japanese  

  • 非金属ポルフィセンの化学:新規リンポルフィセンの合成

    向高寛人, 阿部正明, 大川原徹, 小野利和, 嶌越恒, 久枝良雄

    錯体化学会討論会講演要旨集   2013.10

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    Language：Japanese  

  • コバルトポルフィセンの配位子レドックスを利用した触媒的脱ハロゲン化反応

    佐伯達也, 有留功, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    錯体化学会討論会講演要旨集   2013.10

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    Language：Japanese  

  • コバルト錯体とバイオマスを用いた光駆動型水素発生触媒系の構築

    藤田勇祐, 嶌越恒, 小野利和, 阿部正明, 久枝良雄

    錯体化学会討論会講演要旨集   2013.10

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    Language：Japanese  

  • ホウ素‐窒素錯形成を利用した超分子複合体の固相合成法の構築と固体発光特性の評価

    畠中創, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    錯体化学会討論会講演要旨集   2013.10

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    Language：Japanese  

  • ポルフィリンとルテニウム三核錯体をユニットとする多核箱型クラスターの構築とホストゲスト相互作用

    友田満, 阿部正明, 谷口直毅, 稲富敦, 小野利和, 嶌越恒, 久枝良雄

    錯体化学会討論会講演要旨集   2013.10

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    Language：Japanese  

  • 水素化ポルフィセン金属錯体の合成と酸化還元特性

    橋本浩一, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    錯体化学会討論会講演要旨集   2013.10

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    Language：Japanese  

  • 軸位連結型ルテニウム(II)ポルフィリン‐ランタノイド(III)二核錯体の合成と発光特性

    満生健太, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    錯体化学会討論会講演要旨集   2013.10

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    Language：Japanese  

  • 長鎖アルキル修飾ルテニウム三核錯体の合成とその自己集合特性

    中西太郎, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    錯体化学会討論会講演要旨集   2013.10

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    Language：Japanese  

  • 可視光駆動型ビタミンB12高分子触媒の開発と物質変換反応への応用

    法福紀之, 嶌越恒, 小野利和, 阿部正明, 久枝良雄

    光化学討論会講演要旨集   2013.9

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    Language：Japanese  

  • コバルトポルフィセンの配位子レドックスを利用した酸化的付加反応

    佐伯達也, 有留功, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    有機電子移動化学討論会講演要旨集   2013.6

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    Language：Japanese  

  • 非金属ポルフィセン化学の開拓:新規リンポルフィセンの合成

    向高寛人, 阿部正明, 大川原徹, 小野利和, 嶌越恒, 久枝良雄

    日本化学会講演予稿集   2013.3

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    Language：Japanese  

  • コバルトポルフィセンの配位子還元を利用したCo‐C結合の形成反応

    佐伯達也, 有留功, 小野利和, 嶌越恒, 阿部正明, 久枝良雄

    日本化学会講演予稿集   2013.3

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    Language：Japanese  

  • ポルフィリン環を含む多核箱形クラスターの合成と溶液内ホストゲスト相互作用

    友田満, 阿部正明, 谷口直毅, 稲富敦, 小野利和, 嶌越恒, 久枝良雄

    日本化学会講演予稿集   2013.3

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    Language：Japanese  

  • メタロセン集積型金属クラスターの合成と電子特性

    池上篤志, 阿部正明, 小野利和, 嶌越恒, 久枝良雄

    日本化学会講演予稿集   2013.3

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    Language：Japanese  

  • Swelling behavior of super-absorbent polymer gels

    Toshikazu Ono, Takahiro Sugimoto, Seiji Shinkai, Kazuki Sada

    Polymer Preprints, Japan   2006.12

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    Language：Others  

    Swelling behavior of super-absorbent polymer gels
    We previously report development of a new class of ionic polymer gels having lipophilic ion-pairs that consist of a lipophilic tetraphenylborate anion and a quaternary ammonium cation with long alkyl chains. They swelled largely in the less polar solvents as &#039;super-absorbent&#039; ionic polymer gels. The driving force of the large swelling was osmotic pressure induced by dissociation of lipophilic ion-pairs in these solvents. Here we wish to present discontinuous volume phase transition of &#039;super-absorbent&#039; ionic polymer gels the by change of solvent polarity even in low dielectric media. Moreover, we investigated the effect of neutral comonomers to swelling behaviours in various organic solvents by changing the length of their alkyl chains. The ionic polymer gels with longer alkyl chain swelled in a large magnitude in the less polar solvents and those with shorter alkyl one did in more polar solvents.

  • Molecular design of super-absorbent polymer gels

    Toshikazu Ono, Takahiro Sugimoto, Seiji Shinkai, Kazuki Sada

    Polymer Preprints, Japan   2006.12

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    Language：Others  

    Molecular design of super-absorbent polymer gels
    Ionic polymer gels with the ability to absorb several hundreds times as much water as their dry weights have been used as &#039;super-absorbent polymers&#039; in wide range of biomedical and agricultural applications. However, in the low dielectric media (ε < 10), common ions form tightly bound ion-pairs or multiplet aggregates, and incompatibilities between the polymer chain and the solvents greatly diminish the swelling power. Here we report development of a new class of ionic polymer gels having lipophilic ion-pairs that consist of a lipophilic tetraphenylborate anion and a quaternary ammonium cation with long alkyl chains. They swelled largely in the less polar solvents such as tetrahydrofuran and chloroform as &#039;super-absorbent&#039; ionic polymer gels.

  • Preparation and function of polymer gels with hydrophobic ion pairs

    Toshikazu Ono, Takahiro Sugimoto, Kazuki Sada, Seiji Shinkai

    Polymer Preprints, Japan   2006.10

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    Language：Others  

    Preparation and function of polymer gels with hydrophobic ion pairs
    Molecular design of polymer gels with high swelling properties in non polar solvents lays on compatibility of the polymer chain with oil. In this study, we demonstrate new polymer gels based on the hydrophobic ion pairs in the polymer chain. They provided the high swelling degrees in polar solvents. In the mixtures of water and acetonitrile, the polymer gels exhibited volume phase transition.

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Industrial property rights

Patent   Number of applications: 6   Number of registrations: 0
Utility model   Number of applications: 0   Number of registrations: 0
Design   Number of applications: 0   Number of registrations: 0
Trademark   Number of applications: 0   Number of registrations: 0

Professional Memberships

  • The Chemical Society of Japan

  • The Society of Polymer Science, Japan

  • Japan Society of Coordination Chemistry

  • Japanese Photochemistry Association

  • The Society of Synthetic Organic Chemistry, Japan

  • The Society of Physical Organic Chemistry, Japan

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Academic Activities

  • Screening of academic papers

    Role(s)： Peer review

    2022

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    Type：Peer review 

    Number of peer-reviewed articles in foreign language journals：14

  • Screening of academic papers

    Role(s)： Peer review

    2021

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    Type：Peer review 

    Number of peer-reviewed articles in foreign language journals：11

  • NISTEP専門調査員

    Role(s)： Review, evaluation

    文部科学省　科学技術・学術政策研究所  2020.4 - 2021.3

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    Type：Scientific advice/Review 

  • Screening of academic papers

    Role(s)： Peer review

    2020

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    Type：Peer review 

    Number of peer-reviewed articles in foreign language journals：14

  • Screening of academic papers

    Role(s)： Peer review

    2019

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    Type：Peer review 

    Number of peer-reviewed articles in foreign language journals：17

  • Screening of academic papers

    Role(s)： Peer review

    2018

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    Type：Peer review 

    Number of peer-reviewed articles in foreign language journals：10

  • 世話人

    第38回光化学若手の会  （ 休暇村志賀島（福岡市東区勝馬1803-1） ） 2017.6

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    Type：Competition, symposium, etc. 

    Number of participants：87

  • 座長（Chairmanship）

    日本化学会第97春季年会  （ 慶應義塾大学　日吉キャンパス ） 2017.3

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    Type：Competition, symposium, etc. 

  • Screening of academic papers

    Role(s)： Peer review

    2017

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    Type：Peer review 

    Number of peer-reviewed articles in foreign language journals：3

  • 座長（Chairmanship）

    第64回高分子討論会  （ 東北大学川内キャンパス ） 2015.9

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    Type：Competition, symposium, etc. 

  • 世話人 補佐 International contribution

    第2回CMS国際シンポジウム  （ 九州大学 伊都キャンパス ） 2015.1

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    Type：Competition, symposium, etc. 

    Number of participants：50

  • 座長（Chairmanship）

    日本化学会第94春季年会  （ 愛知、名古屋大学東山キャンパス ） 2014.3

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    Type：Competition, symposium, etc. 

  • 世話人

    第2回 錯体化学若手の会 九州・沖縄支部 勉強会  （ 福岡、九州大学箱崎キャンパス ） 2013.11

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    Type：Competition, symposium, etc. 

  • 事務局

    第24回万有福岡シンポジウム  （ 福岡、九州大学馬出キャンパス 百年講堂 ） 2013.9 - Present

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    Type：Competition, symposium, etc. 

    Number of participants：500

  • 座長（Chairmanship）

    日本化学会第93春季年会  （ 滋賀、立命館大学びわこ・くさつキャンパス ） 2013.3

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    Type：Competition, symposium, etc. 

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Research Projects

  • Creation of Photofunctional Materials Based on Chiral Multinuclear Complexes of Typical Elements

    Grant number：24K01471  2024 - 2026

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

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    Authorship：Principal investigator  Grant type：Scientific research funding

    CiNii Research

  • 公益財団法人 旭硝子財団 2024年度研究助成／剛性と柔軟性を両立する三重螺旋錯体を用いた有 機固体レーザー材料の開発

    2024

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    Grant type：Donation

  • 公益財団法人　徳山科学技術振興財団 2024年度 第36回 研究助成／キラル螺旋錯体が拓く革新的光エネルギー変換材料の創製

    2024

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    Grant type：Donation

  • Development of a chemical sensor for characterization of biodegradable polymers

    Grant number：23K04815  2023 - 2025

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (C)

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    Authorship：Coinvestigator(s)  Grant type：Scientific research funding

    CiNii Research

  • 2023年度 豊田理研スカラー共同研究／高ひずみ化合物の精密分子合成に基づくメカノクロミックポリマーの開発

    2023

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    Grant type：Donation

  • Creation of axially chiral metal complexes for dynamic excitons

    Grant number：21H05400  2021 - 2022

    Japan Society for the Promotion of Science・Ministry of Education, Culture, Sports, Science and Technology  Grants-in-Aid for Scientific Research  Grant-in-Aid for Transformative Research Areas (A)

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    Authorship：Principal investigator  Grant type：Scientific research funding

    CiNii Research

  • 202１年度 豊田理研スカラー／精密分子合成を基盤とする革新的多孔質有機結晶の創製と機能評価

    2021

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    Grant type：Donation

  • 蝶番分子を利用した応力感知材料の開発

    2021

    QRプログラム／わかばチャレンジ

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    Authorship：Principal investigator  Grant type：On-campus funds, funds, etc.

  • 理論と実験の協同に基づく可視・近赤外円偏光発光材料の創出

    2021

    理研-九大科技ハブ共同研究プログラム

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    Authorship：Principal investigator  Grant type：On-campus funds, funds, etc.

  • 二核三重らせん錯体をモチーフとした円偏光発光材料の創製と応用

    Grant number：20K21212  2020 - 2021

    日本学術振興会  科学研究費助成事業  挑戦的研究（萌芽）

    小野 利和

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    Authorship：Principal investigator  Grant type：Scientific research funding

    本研究では、多種多様の配位子と金属イオンの組み合わせによる発光性二核三重らせん錯体の網羅的合成を進め、らせん構造のサイズ・ピッチ・歪みに伴うキラルな光学特性の評価を目的とする。続いてらせん錯体をモチーフとした、イオン・分子・バイオ分子（DNA、タンパク質、糖鎖）に対する高感度・選択的なセンサーの開発や、多孔性配位高分子への展開など、新物質群の創製に挑戦する。

    CiNii Research

  • 塩－共結晶連続体を利用した有機準安定結晶の計画的創出と機能開拓

    Grant number：20H04675  2020 - 2021

    日本学術振興会・文部科学省  科学研究費助成事業  新学術領域研究（研究領域提案型）

    小野 利和

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    Authorship：Principal investigator  Grant type：Scientific research funding

    ソフトクリスタルは、規則正しい結晶構造や周期構造を持つ安定な構造体でありながら、特定の弱い刺激で容易に構造変化や相転移を起こす。これは作成に困難を伴う準安定結晶の１種 であろう。本研究では、酸ー塩基複合体の中で部分的なプロトン移動を伴う塩―共結晶連続体が準安定結晶であることに着目した。酸と塩基のpKaデータベース先導型のソフトクリスタルの創製に取組み、新たな固体発光材料やセンサへの応用を実施する。

    CiNii Research

  • 2020年度 第4回サムコ科学技術振興財団　研究助成金／「匂い分子」を選別・可視化する人工嗅覚受容体の創製

    2020

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    Grant type：Donation

  • 2020年度 豊田理研スカラー／らせんキラリティを持つ多核金属錯体の創製と円偏光発光材料への応用

    2020

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    Grant type：Donation

  • データベースとpKa予測に基づく有機準安定結晶の計画的創出

    2020

    数理・データサイエンスに関する教育・研究支援プログラム

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    Authorship：Principal investigator  Grant type：On-campus funds, funds, etc.

  • アシンメトリック超分子クラスター相の創出と構造・集積制御に基づく機能開発

    Grant number：16H06514  2019 - 2020

    日本学術振興会・文部科学省  科学研究費助成事業  新学術領域研究

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    Authorship：Coinvestigator(s)  Grant type：Scientific research funding

  • 機能性架橋剤を利用したメカノフルオロクロミックエラストマーの開発

    2019 - 2020

    工学研究新分野開拓助成

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    Authorship：Principal investigator  Grant type：On-campus funds, funds, etc.

  • 公益財団法人　泉科学技術振興財団２０１９年度研究助成／機能性架橋剤を利用した応力感知メカノクロミックエラストマーの開発

    2019

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    Grant type：Donation

  • 一般財団法人　中村治四郎育英会／可視光駆動型フラストレイテッドルイスペア触媒

    2019

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    Grant type：Donation

  • 公益財団法人　マツダ財団／分子内水素結合の切断を鍵とする応力感知メカノクロミックエラストマーの創製

    2018

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    Grant type：Donation

  • 多成分系分子の自己組織化を利用した発光寿命可変材料の開発

    Grant number：17H04875  2017 - 2020

    科学研究費助成事業  若手研究(A)

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    Authorship：Principal investigator  Grant type：Scientific research funding

  • 理論化学と実験化学が拓くテトラピロール系色素の簡便合成法の開拓と機能創成

    2017 - 2018

    工学研究新分野開拓助成

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    Authorship：Principal investigator  Grant type：On-campus funds, funds, etc.

  • ヘテロ分子集積化技術を基盤としたπ造形光科学の開拓

    Grant number：17H05161  2017

    日本学術振興会・文部科学省  科学研究費助成事業  新学術領域研究

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    Authorship：Principal investigator  Grant type：Scientific research funding

  • 野口遵研究助成金／多成分分子の自己組織化を利用した有機蓄光材料の創製

    2017

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    Grant type：Donation

  • 公益財団法人 東燃ゼネラル石油研究奨励･奨学財団 第36回(平成28年度)研究助成／分子の自己組織化を利用した発光現象の時間軸可変材料の創製

    2017

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    Grant type：Donation

  • 革新的光エネルギー変換材料の創出を目的とした多成分系分子の自己組織化材料の開発

    2016

    平成28年度エネルギー研究教育機構　若手研究者・博士課程学生支援プログラム

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    Authorship：Principal investigator  Grant type：On-campus funds, funds, etc.

  • 嵩高いルイスペア、イオンペアを元素ブロックとした光機能性材料の開発

    Grant number：15H00757  2015 - 2016

    日本学術振興会・文部科学省  科学研究費助成事業  新学術領域研究

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    Authorship：Principal investigator  Grant type：Scientific research funding

  • 公益財団法人　村田学術振興財団／高効率エネルギー変換デバイスへ向けた強発光性室温リン光有機結晶の創製

    2015

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    Grant type：Donation

  • 一般財団法人　イオン工学振興財団／有機イオン結晶を基盤とした強発光性室温リン光発光材料の創製

    2015

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    Grant type：Donation

  • 多孔性有機結晶の閉塞空間を活用した革新的光エネルギー変換材料の創製

    2014.10 - 2017.3

    受託研究

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    Authorship：Principal investigator  Grant type：Other funds from industry-academia collaboration

  • 多孔性有機結晶の閉塞空間を活用した革新的光エネルギー変換材料の創製

    2014.10 - 2017.3

    独立行政法人科学技術振興機構(JST) 、さきがけ 

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    Authorship：Principal investigator 

    多孔性有機結晶のナノ空間に分子を閉じ込める技術を利用して、①分子間相互作用の向上、②分子運動(並進・回転・振動)の凍結、③酸素ブロックを達成し、有機化合物からの強リン光発光現象を室温下(25ºC)で実現します。固体発光デバイス(波長変換材料、バイオイメージング材料、照明材料、有機EL材料)への展開を目指した革新的光エネルギー変換材料を創製し、基礎研究から材料化につながる一連の研究を推進します

  • DNAアナログとして損傷塩基を活用した機能性ソフトマターの開発

    Grant number：25810102  2013 - 2015

    科学研究費助成事業  若手研究(B)

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    Authorship：Principal investigator  Grant type：Scientific research funding

  • 嵩高いルイスペアを元素ブロックとしたπ共役分子の会合制御と機能性材料の開発

    Grant number：25102534  2013 - 2014

    日本学術振興会・文部科学省  科学研究費助成事業  新学術領域研究

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    Authorship：Principal investigator  Grant type：Scientific research funding

▼display all

Class subject

  • 有機物質化学Ⅰ

    2024.10 - 2024.12   Fall quarter

  • 有機物質化学Ⅰ

    2024.10 - 2024.12   Fall quarter

  • 分子生命工学演習第十二

    2024.4 - 2025.3   Full year

  • 分子生命工学演習第十二

    2024.4 - 2025.3   Full year

  • 無機化学第二

    2023.12 - 2024.2   Winter quarter

  • 無機化学第二

    2023.12 - 2024.2   Winter quarter

  • 無機化学第二

    2023.12 - 2024.2   Winter quarter

  • 無機化学第二

    2023.12 - 2024.2   Winter quarter

  • 有機物質化学Ⅰ

    2023.10 - 2023.12   Fall quarter

  • 有機物質化学Ⅰ

    2023.10 - 2023.12   Fall quarter

  • 分子生命工学演習第十二

    2023.4 - 2024.3   Full year

  • 分子生命工学演習第十二

    2023.4 - 2024.3   Full year

  • 生物無機化学

    2023.4 - 2023.9   First semester

  • 生物無機化学

    2023.4 - 2023.9   First semester

  • 生物無機化学

    2023.4 - 2023.9   First semester

  • 無機化学第二

    2022.12 - 2023.2   Winter quarter

  • 無機化学第二

    2022.12 - 2023.2   Winter quarter

  • 無機化学第二

    2022.12 - 2023.2   Winter quarter

  • 無機化学第二

    2022.12 - 2023.2   Winter quarter

  • 有機物質化学Ⅰ

    2022.10 - 2023.3   Second semester

  • 有機物質化学Ⅰ

    2022.10 - 2022.12   Fall quarter

  • 有機物質化学Ⅰ

    2022.10 - 2022.12   Fall quarter

  • 分子生命工学演習第十二

    2022.4 - 2023.3   Full year

  • 無機化学第二

    2021.12 - 2022.2   Winter quarter

  • 有機物質化学Ⅱ

    2021.12 - 2022.2   Winter quarter

  • 有機物質化学Ⅰ

    2021.10 - 2022.3   Second semester

  • 無機化学第二

    2021.10 - 2022.3   Second semester

  • 有機物質化学Ⅰ

    2021.10 - 2021.12   Fall quarter

  • 生物無機化学

    2021.4 - 2021.9   First semester

  • Coordination Chemistry

    2021.4 - 2021.9   First semester

  • 物質科学工学実験第一

    2020.10 - 2021.3   Second semester

  • 物質科学工学実験第三

    2020.10 - 2021.3   Second semester

  • 物質科学工学実験第一

    2019.10 - 2020.3   Second semester

  • 物質科学工学実験第三

    2019.10 - 2020.3   Second semester

  • 物質科学工学実験第一

    2018.10 - 2019.3   Second semester

  • 物質科学工学実験第三

    2018.10 - 2019.3   Second semester

  • 物質科学工学実験第一

    2017.10 - 2018.3   Second semester

  • 物質科学工学実験第三

    2017.10 - 2018.3   Second semester

  • 物質科学工学実験第三

    2016.10 - 2017.3   Second semester

  • 物質科学工学実験第一

    2016.10 - 2017.3   Second semester

  • 物質科学工学実験第三

    2015.10 - 2016.3   Second semester

  • 物質科学工学実験第一

    2015.10 - 2016.3   Second semester

  • 物質科学工学実験第一

    2014.10 - 2015.3   Second semester

  • 物質科学工学実験第三

    2014.10 - 2015.3   Second semester

  • 物質科学工学実験第三

    2013.10 - 2014.3   Second semester

  • 物質科学工学実験第一

    2013.10 - 2014.3   Second semester

  • 物質科学工学実験第一

    2012.10 - 2013.3   Second semester

  • 物質科学工学実験第三

    2012.10 - 2013.3   Second semester

▼display all

FD Participation

  • 2014.3   Role：Participation   Title：『学生のメンタルヘルス-キャンパスライフ・健康支援センターから見た工学部の現状-』

    Organizer：[Undergraduate school/graduate school/graduate faculty]

  • 2013.2   Role：Participation   Title：平成24年度第1回工学部（府）FD

    Organizer：[Undergraduate school/graduate school/graduate faculty]

Social Activities

  • みらいの教室「化学」／目で見てわかる化学「吸水ポリマーのひみつ」

    体験型子ども科学館O-Lab  大分県大分市府内町　体験型子ども科学館 O-Labo  2023.11

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    Audience： General,　Scientific,　Company,　Civic organization,　Governmental agency

    Type：Lecture

  • みらいの教室「化学」／目で見てわかる化学「吸水ポリマーのひみつ」

    2023.11

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    Audience： Infants,　Schoolchildren,　Junior students,　High school students

    Type：Seminar, workshop

  • 令和5年度舞プラン／光で楽しむ化学

    福岡舞鶴高校  福岡舞鶴高校  2023.7

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    Audience： General,　Scientific,　Company,　Civic organization,　Governmental agency

    Type：Seminar, workshop

  • サイエンスカフェ 「現代の錬金術を考える！　〜周期表を利用した新素材づくり〜」

    「第３３回サイエンスカフェ＠ふくおか」  BIZCOLI交流ラウンジ　福岡市天神  2015.10

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    Audience： General,　Scientific,　Company,　Civic organization,　Governmental agency

    Type：Lecture

Media Coverage

  • 有機分子から結晶９種　北大九大　ねじれ溶媒分子で制御 Newspaper, magazine

    日刊工業新聞  2023.3

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    有機分子から結晶９種　北大九大　ねじれ溶媒分子で制御

  • 薄膜技術研究　5人に助成金　サムコ振興財団 Newspaper, magazine

    京都新聞  2020.7

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    薄膜技術研究　5人に助成金　サムコ振興財団

  • パズルの要領で分子を並べ機能性色素を作る技術開発　ー九大の研究グループなどが成功ー Newspaper, magazine

    科学新聞  2015.9

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    パズルの要領で分子を並べ機能性色素を作る技術開発　ー九大の研究グループなどが成功ー

  • 九大など、有機分子組み換えで七色に光る色素結晶を開発－白色発光も実現 Newspaper, magazine

    日刊工業新聞  2015.8

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    九大など、有機分子組み換えで七色に光る色素結晶を開発－白色発光も実現

  • 色自在の発光材料開発　九州大　照明向け、安価に合成 Newspaper, magazine

    日経産業新聞  2015.8

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    色自在の発光材料開発　九州大　照明向け、安価に合成

Travel Abroad

  • 2016.12

    Staying countory name 1：Singapore   Staying institution name 1：Nanyang technological university

    Staying countory name 2：Australia   Staying institution name 2：Monash university

  • 2016.8

    Staying countory name 1：Poland   Staying institution name 1：Polish Academy of Sciences

  • 2013.2

    Staying countory name 1：United Kingdom   Staying institution name 1：Southampton University

    Staying countory name 2：United States   Staying institution name 2：University of Bath

    Staying institution name 3：Oxford University

    Staying institution name (Other)：Lucite International, Kyushu University California Office, Stanford University