Faculty Profiles - KUNINOBU YOICHIRO

Information

写真a

KUNINOBU YOICHIRO

Organization

Institute for Materials Chemistry and Engineering Department of Fundamental Organic Chemistry Professor
Kyushu University Platform of Inter/Transdisciplinary Energy Research （Joint Appointment）
Interdisciplinary Graduate School of Engineering Sciences Department of Interdisciplinary Engineering Sciences（Joint Appointment）

Contact information

Tel

0925838855

Profile

In our laboratory, we are trying to solve energy and environmental problems through creation of high performance catalysts, development of practical organic synthesis reactions, and creation of high-performance organic functional materials.

Homepage

https://kuninobu-lab-english.weebly.com/
Homepage of Kuninobu Lab, Institute for Materials Chemistry and Engineering (Department of Molecular and Material Sciences, Interdisciplinary Graduate School of Engineering Sciences)

External link

Degree

Doctor of Science

Research History

2003年11月　岡山大学工学部物質応用化学科　助手 2005年4月　岡山大学大学院自然科学研究科機能分子化学専攻　助手（改組による） 2007年4月　岡山大学大学院自然科学研究科機能分子化学専攻　助教（職名変更による） 2012年4月東京大学大学院薬学系研究科　ERATOプロジェクト　グループリーダー（准教授相当） 2015年9月　ミュンスター大学（ドイツ）　客員教授

Research Interests・Research Keywords

Research theme：We create novel transition metal catalysts which can realize high activity and selectivity, and develop highly efficient and practical synthetic organic reactions, such as C-H transformations. We also create high-performance organic functional materials, such as pi-conjugated molecules and polymers. We aim to solve energy and environmental problems through these projects.

Keyword：Catalytic Reaction, Catalyst Design, C-H Bond Transformation, pi-Conjugated System, Polymer

Research period： 2017.2

Awards

日産化学・有機合成新反応／手法賞

2023.12 有機合成化学協会非共有結合性相互作用を活用する位置選択的な炭素－水素結合変換反応の開発
2018 Albert Nelson Marquis Lifetime Achievement Award

2018.4 Marquis Who's Who
2017 Albert Nelson Marquis Lifetime Achievement Award

2017.4 Marquis Who's Who

Papers

Control of Multicolor and White Emissions by Tuning Equilibrium Between Fluorophores, Lewis Acids, and Their Complexes Using Polymers Reviewed International journal

Mori, T.; Yoshigoe, Y.; Kuninobu, Y.

Angew. Chem. Int. Ed. 58 ( 41 ) 14457 - 14461 2019.10

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1002/anie.201903408

Other Link： https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201903408
Hydrogen Bond-Accelerated meta-Selective C-H Borylation of Aromatic Compounds and Expression of Functional Group and Substrate Specificities Reviewed

Xu Lu, Yusuke Yoshigoe, Haruka Ida, Mitsumi Nishi, Motomu Kanai, Yoichiro Kuninobu

ACS Catalysis 9 ( 3 ) 1705 - 1709 2019.3

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/acscatal.8b05005
Palladium-catalyzed synthesis of diaryl ketones from aldehydes and (hetero)aryl halides via C-H bond activation Reviewed

Takayuki Wakaki, Takaya Togo, Daisuke Yoshidome, Yoichiro Kuninobu, Motomu Kanai

ACS Catalysis 8 ( 4 ) 3123 - 3128 2018.4

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DOI： 10.1021/acscatal.8b00440
Lewis Acid-Base Interaction-Controlled ortho-Selective C-H Borylation of Aryl Sulfides Reviewed International journal

@Li, H.-L.; Kuninobu, Y.; @Kanai, M.

Angew. Chem. Int. Ed. 56 ( 6 ) 1495 - 1499 2017.2

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1002/anie.201610041
4-Position-Selective C-H Perfluoroalkylation and Perfluoroarylation of Six-Membered Heteroaromatic Compounds Reviewed

Masahiro Nagase, Yoichiro Kuninobu, Motomu Kanai

Journal of the American Chemical Society 138 ( 19 ) 6103 - 6106 2016.5

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DOI： 10.1021/jacs.6b01753
Erratum Rhodium-catalyzed asymmetric synthesis of spirosilabifluorene derivatives (Angewandte Chemie - International Edition (2013) (52) DOI: 10.1002/anie.201207723) Reviewed

Yoichiro Kuninobu, Kanae Yamauchi, Naoya Tamura, Takayuki Seiki, Kazuhiko Takai

Angewandte Chemie - International Edition 55 ( 6 ) 1948 2016.2

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DOI： 10.1002/anie.201511117
A meta-selective C-H borylation directed by a secondary interaction between ligand and substrate Reviewed

Yoichiro Kuninobu, Haruka Ida, Mitsumi Nishi, Motomu Kanai

Nature Chemistry 7 ( 9 ) 712 - 717 2015.9

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DOI： 10.1038/nchem.2322
Benzylic C(sp³)-H Perfluoroalkylation of Six-Membered Heteroaromatic Compounds Reviewed

Yoichiro Kuninobu, Masahiro Nagase, Motomu Kanai

Angewandte Chemie - International Edition 54 ( 35 ) 10263 - 10266 2015.8

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DOI： 10.1002/anie.201505335
Palladium-catalyzed oxirane-opening reaction with arenes via C-H bond activation Reviewed

Zhen Wang, Yoichiro Kuninobu, Motomu Kanai

Journal of the American Chemical Society 137 ( 19 ) 6140 - 6143 2015.5

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DOI： 10.1021/jacs.5b02435
Copper-catalyzed intramolecular C(sp3)-H and C(sp2)-H amidation by oxidative cyclization Reviewed

Zhen Wang, Jizhi Ni, Yoichiro Kuninobu, Motomu Kanai

Angewandte Chemie - International Edition 53 ( 13 ) 3496 - 3499 2014.3

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DOI： 10.1002/anie.201311105
Regioselective trifluoromethylation of N-heteroaromatic compounds using trifluoromethyldifluoroborane activator Reviewed

Tomoaki Nishida, Haruka Ida, Yoichiro Kuninobu, Motomu Kanai

Nature communications 5 2014.3

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DOI： 10.1038/ncomms4387
Palladium-catalyzed Ci-H fluorosilylation of 2-phenylpyridines Synthesis of silafluorene equivalents Reviewed

Qing Xiao, Xiangtai Meng, Motomu Kanai, Yoichiro Kuninobu

Angewandte Chemie - International Edition 53 ( 12 ) 3168 - 3172 2014.3

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DOI： 10.1002/anie.201310293
Rhenium-catalyzed synthesis of 3-imino-1-isoindolinones by C-H bond activation Application to the synthesis of polyimide derivatives Reviewed

Shunsuke Sueki, Yuanfang Guo, Motomu Kanai, Yoichiro Kuninobu

Angewandte Chemie - International Edition 52 ( 45 ) 11879 - 11883 2013.11

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DOI： 10.1002/anie.201306360
Palladium-catalyzed ortho-selective C-H borylation of 2-phenylpyridine and its derivatives at room temperature Reviewed

Yoichiro Kuninobu, Takashi Iwanaga, Tetsuya Omura, Kazuhiko Takai

Angewandte Chemie - International Edition 52 ( 16 ) 4431 - 4434 2013.4

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DOI： 10.1002/anie.201210328
Rhodium-catalyzed asymmetric synthesis of spirosilabifluorene derivatives Reviewed

Yoichiro Kuninobu, Kanae Yamauchi, Naoya Tamura, Takayuki Seiki, Kazuhiko Takai

Angewandte Chemie - International Edition 52 ( 5 ) 1520 - 1522 2013.1

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DOI： 10.1002/anie.201207723
Manganese-catalyzed cleavage of a carbon-carbon single bond between carbonyl carbon and α-carbon atoms of ketones Reviewed

50 ( 44 ) 10406 - 10408 2011.10

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Singled out: Treatment of ketones with carbodiimides in the presence of a catalytic amount of either [{HMn(CO)₄}₃] or [Mn ₂(CO)₁₀] gave amides in good to excellent yields. In this reaction, the carbon-carbon single bond of a ketone is cleaved efficiently. The reaction also proceeded by using isocyanates instead of carbodiimides.

DOI： 10.1002/anie.201104704
Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds Reviewed

Tomonari Ureshino, Takuya Yoshida, Yoichiro Kuninobu, Kazuhiko Takai

Journal of the American Chemical Society 132 ( 41 ) 14324 - 14326 2010.10

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DOI： 10.1021/ja107698p
Rhenium-catalyzed regioselective alkylation of phenols Reviewed

Yoichiro Kuninobu, Takashi Matsuki, Kazuhiko Takai

Journal of the American Chemical Society 131 ( 29 ) 9914 - 9915 2009.7

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DOI： 10.1021/ja904360k
Rhenium-catalyzed synthesis of stereodefined cyclopentenes from β-ketoesters and aliphatic allenes Reviewed

47 ( 48 ) 9318 - 9321 2008.11

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(Chemical Equation Presented) Come on allene: Commercially available [Re₂(CO)₁₀] as a catalyst provides five-membered carbocycles in moderate to excellent yields with high stereoselectivity (see scheme). The configuration at each of the three sp³ carbon centers of the ring is defined. The reaction proceeds at the β, γ, and adjacent methylene positions of the allene; previously, similar reactions usually occurred at the α, β, and γ positions of the allene.

DOI： 10.1002/anie.200803350
Synthesis of Cp-Re complexes via olefinic C-H activation and successive formation of cyclopentadienes Reviewed

Yoichiro Kuninobu, Yuta Nishina, Takashi Matsuki, Kazuhiko Takai

Journal of the American Chemical Society 130 ( 43 ) 14062 - 14063 2008.10

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DOI： 10.1021/ja805921f
Indium-catalyzed retro-claisen condensation Reviewed

Atsushi Kawata, Kazumi Takata, Yoichiro Kuninobu, Kazuhiko Takai

Angewandte Chemie - International Edition 46 ( 41 ) 7793 - 7795 2007.10

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DOI： 10.1002/anie.200702798
Manganese-catalyzed insertion of aldehydes into a C-H bond Reviewed

Yoichiro Kuninobu, Yuta Nishina, Takahiro Takeuchi, Kazuhiko Takai

Angewandte Chemie - International Edition 46 ( 34 ) 6518 - 6520 2007.9

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DOI： 10.1002/anie.200702256
Rhenium- and gold-catalyzed coupling of aromatic aldehydes with trimethyl(phenylethynyl)silane Synthesis of diethynylmethanes Reviewed

Yoichiro Kuninobu, Eri Ishii, Kazuhiko Takai

Angewandte Chemie - International Edition 46 ( 18 ) 3296 - 3299 2007.6

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DOI： 10.1002/anie.200700183
Efficient catalytic insertion of acetylenes into a carbon-carbon single bond of nonstrained cyclic compounds under mild conditions Reviewed

Yoichiro Kuninobu, Atsushi Kawata, Kazuhiko Takai

Journal of the American Chemical Society 128 ( 35 ) 11368 - 11369 2006.9

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DOI： 10.1021/ja064022i
Rhenium-catalyzed insertion of aldehyde into a C-H bond Synthesis of isobenzofuran derivatives Reviewed

Yoichiro Kuninobu, Yuta Nishina, Chie Nakagawa, Kazuhiko Takai

Journal of the American Chemical Society 128 ( 38 ) 12376 - 12377 2006.9

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DOI： 10.1021/ja065643e
Rhenium- and aniline-catalyzed one-pot annulation of aromatic ketones and α,β-unsaturated esters initiated by C-H bond activation Reviewed

45 ( 17 ) 2766 - 2768 2006.4

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(Chemical Equation Presented) Several reaction steps, including C-H activation, lead to indene derivatives in good yields in the rhenium-catalyzed reaction of aromatic ketimines and ethyl acrylate. Indene derivatives can also be obtained by the reactions of aromatic ketones with α,β-unsaturated esters in the presence of a catalytic rhenium complex and p-anisidine (see scheme).

DOI： 10.1002/anie.200503627
Insertion of polar and nonpolar unsaturated molecules into carbon-rhenium bonds generated by C-H bond activation Synthesis of phthalimidine and indene derivatives Reviewed

Yoichiro Kuninobu, Yukimi Tokunaga, Atsushi Kawata, Kazuhiko Takai

Journal of the American Chemical Society 128 ( 1 ) 202 - 209 2006.1

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DOI： 10.1021/ja054216i
Rhenium-catalyzed formation of indene frameworks via C-H bond activation [3+2] Annulation of aromatic aldimines and acetylenes Reviewed

Yoichiro Kuninobu, Atsushi Kawata, Kazuhiko Takai

Journal of the American Chemical Society 127 ( 39 ) 13498 - 13499 2005.10

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DOI： 10.1021/ja0528174
Carbamoylarylation of Alkenes with N-Aryl Oxamic Acids Involving 1,4-Aryl Migration Via C(aryl)–N Bond Cleavage Reviewed International journal

14 5972 - 5977 2024.4

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DOI： acscatal.4c00523

Other Link： https://pubs.acs.org/doi/10.1021/acscatal.4c00523
5-Ammonium-4,4-dimethylvaleryl (Amv) Group: Generation from Acryloyl Group through Decatungstate-Catalyzed C(sp3)–H Addition and Removal by Base-Triggered Cyclization Reviewed International journal

2023 e202301015 2023.12

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1002/ejoc.202301015

Other Link： https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202301015
Site-selective Direct Intermolecular C(sp3)–H Alkylation of Saccharides and Switching of Reaction Sites by Changing Photocatalysts Reviewed International journal

365 ( 15 ) 2577 - 2587 2023.7

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1002/adsc.202300329

Other Link： https://onlinelibrary.wiley.com/doi/10.1002/adsc.202300329
Decatungstate-Catalyzed C(sp3)–H Alkylation of a Val Residue Proximal to the N-Terminus Controlled by an Electrostatic Interaction Reviewed International journal

25 ( 20 ) 3708 - 3712 2023.5

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Language：Japanese Publishing type：Research paper (scientific journal)

DOI： 10.1021/acs.orglett.3c01154
Bifunctional 1-Hydroxypyrene-Photocatalyst for Hydrodesulfurization via Reductive C(Aryl)–S Bond Cleavage Reviewed International journal

25 ( 18 ) 3293 - 3297 2023.4

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/acs.orglett.3c01061
3-Position-Selective C–H Trifluoromethylation of Pyridine Rings Based on Nucleophilic Activation Reviewed International journal

2022.11

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DOI： 10.1021/acs.orglett.2c03327

Other Link： https://pubs.acs.org/doi/10.1021/acs.orglett.2c03327
Near-Infrared and Dual Emissions of Diphenylamino Group-Substituted Malachite Green Derivatives Reviewed International journal

Mori, T.; Sekine, K.; Kawashima, K.; Mori, T.; Kuninobu, Y.*

Eur. J. Org. Chem. 2022 e202200873 2022.7

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1002/ejoc.202200873

Other Link： https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202200873
Photoinduced Divergent Deaminative Borylation and Hydrodeamination of Primary Aromatic Amines Reviewed International journal

Shiozuka, A.; Sekine, K.*; Toki, T.; Kawashima, K.; Mori, T.*; Kuninobu, Y.*

Org. Lett. 24 4281 - 4285 2022.6

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DOI： 10.1021/acs.orglett.2c01663

Other Link： https://pubs.acs.org/doi/10.1021/acs.orglett.2c01663
Iridium-catalyzed C(sp3)–H Borylation Using Silyl-Bipyridine Pincer Ligands Reviewed International journal

61 e202202327 2022.5

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1002/anie.202202327

Other Link： https://onlinelibrary.wiley.com/doi/10.1002/anie.202202327
Creation of Transition Metal Catalysts with Substrate Recognition Moiety and Development of Regioselective and Substrate Specific Reactions. Invited Reviewed

Kuninobu, Y.*

J. Synth. Org. Chem. Jpn. 80 ( 5 ) 421 - 430 2022.5

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Language：Japanese Publishing type：Research paper (scientific journal)

DOI： 10.5059/yukigoseikyokaishi.80.421
Photoinduced Organic Reactions by Employing Pyrene Catalysts Invited Reviewed International journal

Shiozuka, A.; Sekine, K.*; Kuninobu, Y.*

Synthesis 54 2330 - 2339 2022.2

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1055/a-1739-4793

Other Link： https://www.thieme-connect.com/products/ejournals/abstract/10.1055/a-1739-4793
Palladium-Catalyzed Enantioselective C(sp3)–H Arylation of 2-Propyl Azaaryls Enabled by Amino Acid Ligand. Reviewed International journal

24 ( 6 ) 1286 - 1291 2022.2

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DOI： 10.1021/acs.orglett.1c04215
Control of Site-Selectivity in Hydrogen Atom Transfer by Noncovalent Interactions: Proximal-Selective C(sp3)–H Alkylation of 2-Methylanilinium Salts Using a Decatungstate Photocatalyst. Reviewed International journal

12 ( 5 ) 3058 - 3062 2022.2

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/acscatal.2c00278
Synthesis of Fluorenes and Their Related Compounds from Biaryls and Meldrum’s Acid Derivatives. Reviewed International journal

58 ( 6 ) 843 - 846 2021.12

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DOI： 10.1039/d1cc06212c
Facile Synthesis of Tribenzosilepins from Terphenyls and Dihydrosilanes by Electrophilic Double Silylation Invited Reviewed International journal

Dong, Y.; Sekine, K.; Kuninobu, Y.*

Chem. Commun. 57 ( 57 ) 7007 - 7010 2021.6

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DOI： 10.1039/D1CC02326H
Photoinduced Deaminative Borylation of Unactivated Aromatic Amines Enhanced by CO2 Invited Reviewed International journal

Shiozuka, A.; Sekine, K.*; Kuninobu, Y.*

Org. Lett. 23 ( 12 ) 4774 - 4778 2021.6

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DOI： 10.1021/acs.orglett.1c01503
Regioselective C-H Trifluoromethylation of Aromatic Compounds by Inclusion in Cyclodextrins Reviewed International journal

23 ( 11 ) 4327 - 4331 2021.5

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/acs.orglett.1c01259
Manganese/Bipyridine-catalyzed Non-directed C(sp3)–H Bromination Using NBS and TMSN3. Invited Reviewed International journal

17 885 - 890 2021.4

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.3762/bjoc.17.74

Other Link： https://www.beilstein-journals.org/bjoc/articles/17/74
Urea-accelerated Iridium-catalyzed 2-Position-selective C-H Borylation of Indole Derivatives. Reviewed International journal

Wang, J.; Torigoe, T.; Kuninobu, Y.*

Chem. Lett. 50 808 - 811 2021.4

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DOI： 10.1246/cl.200939

Other Link： https://www.journal.csj.jp/doi/full/10.1246/cl.200939
Regioselective C(sp3)–H Alkylation of Fructopyranose Derivative by 1,6 HAT. Reviewed International journal

19 3124 - 3127 2021.4

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1039/d1ob00326g

Other Link： https://pubs.rsc.org/en/Content/ArticleLanding/2021/OB/D1OB00326G#!divAbstract
C–N and C–O Bond Formation in Copper-Catalyzed/Mediated sp3 C–H Activation: Mechanistic Studies from Experimental and Computational Aspects Reviewed International journal

85 ( 15 ) 9713 - 9726 2020.7

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/acs.joc.0c01038

Other Link： https://pubs.acs.org/doi/10.1021/acs.joc.0c01038
Palladium-catalyzed Secondary C(sp3)-H Arylation of 2-Alkylpyridines Reviewed International journal

Li, H.-L.: Kuninobu, Y.*; Antilla, J. C.*

Adv. Synth. Catal. 362 ( 13 ) 2637 - 2641 2020.5

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DOI： 10.1002/adsc.202000306

Other Link： https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.202000306
Iridium-Catalyzed ortho-C–H Borylation of Thioanisole Derivatives Using Bipyridine-Type Ligand Reviewed International journal

22 ( 9 ) 3485 - 3489 2020.4

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/acs.orglett.0c00946

Other Link： https://pubs.acs.org/doi/10.1021/acs.orglett.0c00946
Synthesis, Structures and Photophysical Properties of Hexacoordinated Organosilicon Compounds with 2-(2-Pyridyl)phenyl Groups Invited Reviewed International journal

Furuta, S.; Mori, T.; Yoshigoe, Y.; Sekine, K.; Kuninobu, Y.*

Org. Biomol. Chem. 18 3239 - 3242 2020.3

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DOI： 10.1039/D0OB00484G

Other Link： https://pubs.rsc.org/en/content/articlelanding/2020/ob/d0ob00484g#!divAbstract
Synthesis of six-membered silacycles by borane-catalyzed double sila-Friedel–Crafts reaction Invited Reviewed International journal

16 409 - 414 2020.3

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DOI： 10.3762/bjoc.16.39

Other Link： https://www.beilstein-journals.org/bjoc/articles/16/39
Copper-Catalyzed Tertiary Alkylative Cyanation for the Synthesis of Cyanated Peptide Building Blocks Reviewed International journal

Miwa, N.; Tanaka, C.; Ishida, S.; Hirata, G.; Song, J.; Torigoe, T.; Kuninobu, Y.*; Nishikata, T.*

J. Am. Chem. Soc. 142 ( 4 ) 1692 - 1697 2020.1

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/jacs.9b113497

Other Link： https://pubs.acs.org/doi/10.1021/jacs.9b11349
Donor–Acceptor π-Conjugated Enamines: Functional Group-Compatible Synthesis from Amides and Their Photoabsorption and Photoluminescence Properties Reviewed International journal

84 ( 23 ) 15236 - 15254 2019.12

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/acs.joc.9b02267
Synthesis of Silafluorene Derivatives from Biphenyls and Dihydrosilanes via Double Sila-Friedel-Crafts Reaction Reviewed International journal

Dong, Y.; Takata, Y.; Yoshigoe, Y.; Sekine, K.; Kuninobu, Y.

Chem. Commun. 55 ( 88 ) 13303 - 13306 2019.11

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Language：Others Publishing type：Research paper (scientific journal)

DOI： 10.1039/c9cc07692a
2-Position-Selective Trifluoromethylthiolation of Six-Membered Heteroaromatic Compounds Reviewed International journal

Muta, R.; Torigoe, T.; Kuninobu, Y.

Org. Lett. 21 ( 11 ) 4289 - 4292 2019.6

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/acs.orglett.9b01474
Palladium-Catalyzed C–H Heteroarylation of 2,5-Disubstituted Imidazoles Invited Reviewed

67 ( 3 ) 196 - 198 2019.3

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1248/cpb.c18-00586
Hydrogen-Bond-Controlled Formal Meta-Selective C-H Transformations and Regioselective Synthesis of Multisubstituted Aromatic Compounds Reviewed

Jie Wang, Takeru Torigoe, Yoichiro Kuninobu

Organic Letters 21 ( 5 ) 1342 - 1346 2019.3

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/acs.orglett.9b00030
Hydrogen-Bond-Controlled Formal Meta-Selective C-H Transformations and Regioselective Synthesis of Multisubstituted Aromatic Compounds Reviewed International journal

Wang, J.; Torigoe, T.; Kuninobu, Y.

Org. Lett. 21 ( 5 ) 1342 - 1346 2019.3

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DOI： 10.1021/acs.orglett.9b00030

Other Link： https://pubs.acs.org/doi/10.1021/acs.orglett.9b00030
Palladium-catalyzed C–H heteroarylation of 2,5-disubstituted imidazoles Reviewed

196 - 198 2019.1

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We developed a palladium-catalyzed C–H N-heteroarylation of N-protected-2,5-disubstituted imidazoles at the C4-position using N-heteroaryl halides as a coupling partner. Intensive reaction condition screening led us to identify fluo-rinated bathophenanthroline 7 as the optimum ligand for the palladium catalyst. This reaction will enhance lead optimization of drug candidates by facilitating the synthesis of hetero-biaryl compounds containing an imidazole ring.

DOI： 10.1248/cpb.c18-00586
Rhenium-catalyzed ortho-alkylation of phenols Reviewed

Yoichiro Kuninobu, Masaki Yamamoto, Mitsumi Nishi, Tomoyuki Yamamoto, Takashi Matsuki, Masahito Murai, Kazuhiko Takai

Organic Syntheses 94 2018.6

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DOI： 10.1002/0471264229.os094.20
Near-Infrared Photoactivatable Oxygenation Catalysts of Amyloid Peptide Reviewed

Jizhi Ni, Atsuhiko Taniguchi, Shuta Ozawa, Yukiko Hori, Yoichiro Kuninobu, Takashi Saito, Takaomi C. Saido, Taisuke Tomita, Youhei Sohma, Motomu Kanai

Chem 4 ( 4 ) 807 - 820 2018.4

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1016/j.chempr.2018.02.008
2-Position-Selective C-H Perfluoroalkylation of Quinoline Derivatives Reviewed

Takahiro Shirai, Motomu Kanai, Yoichiro Kuninobu

Organic Letters 20 ( 6 ) 1593 - 1596 2018.3

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DOI： 10.1021/acs.orglett.8b00339
Preparation of solid-state luminescent materials by complexation between π-conjugated molecules and activators Reviewed

47 ( 11 ) 1391 - 1394 2018.1

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A combination of simple π-conjugated molecules bearing a lone pair on heteroatom(s) and activators afforded new solidstate fluorescent materials. A solid-state red-emitting material that exhibits aggregation-induced emission was also synthesized by the present method.

DOI： 10.1246/cl.180735
Preparation of solid-state luminescent materials by complexation between π-conjugated molecules and activators Reviewed

47 ( 11 ) 1391 - 1394 2018.1

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A combination of simple π-conjugated molecules bearing a lone pair on heteroatom(s) and activators afforded new solidstate fluorescent materials. A solid-state red-emitting material that exhibits aggregation-induced emission was also synthesized by the present method.

DOI： 10.1246/cl.180735
Development of Novel C-H Bond Transformations and Their Application to the Synthesis of Organic Functional Molecules Reviewed

Yoichiro Kuninobu

Synlett 29 ( 16 ) 2093 - 2107 2018.1

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DOI： 10.1055/s-0037-1610531
Iridium/Bipyridine-Catalyzed ortho-Selective C-H Borylation of Phenol and Aniline Derivatives Reviewed

Hong Liang Li, Motomu Kanai, Yoichiro Kuninobu

Organic Letters 19 ( 21 ) 5944 - 5947 2017.11

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DOI： 10.1021/acs.orglett.7b02936
Iron-Catalyzed ortho-Selective C−H Borylation of 2-Phenylpyridines and Their Analogs Reviewed International journal

19 ( 13 ) 3450 - 3453 2017.6

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DOI： 10.1021/acs.orglett.7b01423
Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents Reviewed International journal

@Wang, Z.; @Kanai, M.; Kuninobu, Y.

Org. Lett. 19 ( 9 ) 2398 - 2401 2017.4

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DOI： 10.1021/acs.orglett.7b00923
Rhenium-Catalyzed Synthesis of 1,3-Diiminoisoindolines via Insertion of Carbodiimides into a C-H Bond of Aromatic and Heteroaromatic Imidates Reviewed

Zijia Wang, Shunsuke Sueki, Motomu Kanai, Yoichiro Kuninobu

Organic Letters 18 ( 10 ) 2459 - 2462 2016.5

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DOI： 10.1021/acs.orglett.6b01012
Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters Reviewed

Masahito Murai, Yutaro Takeuchi, Kanae Yamauchi, Yoichiro Kuninobu, Kazuhiko Takai

Chemistry - A European Journal 22 ( 17 ) 6048 - 6058 2016.4

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DOI： 10.1002/chem.201504718
5-Position-selective C-H trifluoromethylation of 8-aminoquinoline derivatives Reviewed

Yoichiro Kuninobu, Mitsumi Nishi, Motomu Kanai

Organic and Biomolecular Chemistry 14 ( 34 ) 8092 - 8100 2016.1

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DOI： 10.1039/c6ob01325b
The development of novel C-H bond transformations and their application to the synthesis of organic functional molecules Reviewed

Yoichiro Kuninobu

Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry 74 ( 11 ) 1058 - 1068 2016.1

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DOI： 10.5059/yukigoseikyokaishi.74.1058
Manganese- and Borane-Mediated Synthesis of Isobenzofuranones from Aromatic Esters and Oxiranes via C-H Bond Activation Reviewed

Shunsuke Sueki, Zijia Wang, Yoichiro Kuninobu

Organic Letters 18 ( 2 ) 304 - 307 2016.1

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DOI： 10.1021/acs.orglett.5b03474
C-H Bond Transformations Leading to the Synthesis of Organic Functional Materials Reviewed

Yoichiro Kuninobu, Shunsuke Sueki

Synthesis (Germany) 47 ( 24 ) 3823 - 3845 2015.12

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DOI： 10.1055/s-0035-1560346
Acceleration effects of phosphine ligands on the rhodium-catalyzed dehydrogenative silylation and germylation of unactivated C(sp³)-H bonds Reviewed

Masahito Murai, Hirotaka Takeshima, Haruka Morita, Yoichiro Kuninobu, Kazuhiko Takai

Journal of Organic Chemistry 80 ( 11 ) 5407 - 5414 2015.6

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DOI： 10.1021/acs.joc.5b00920
Palladium-catalyzed construction of heteroatom-containing π-conjugated systems by intramolecular oxidative C-H/C-H coupling reaction Reviewed

21 ( 23 ) 8365 - 8368 2015.6

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Synthesis of heteroatom-containing ladder-type π-conjugated molecules was successfully achieved via a palladium-catalyzed intramolecular oxidative C-H/C-H cross-coupling reaction. This reaction provides a variety of π-conjugated molecules bearing heteroatoms, such as nitrogen, oxygen, phosphorus, and sulfur atoms, and a carbonyl group. The π-conjugated molecules were synthesized efficiently, even in gram scale, and larger π-conjugated molecules were also obtained by a double C-H/C-H cross-coupling reaction and successive oxidative cycloaromatization.

DOI： 10.1002/chem.201501116
Copper-catalyzed intermolecular C(sp³)-H bond functionalization towards the synthesis of tertiary carbamates Reviewed

Prasanna Kumara Chikkade, Yoichiro Kuninobu, Motomu Kanai

Chemical Science 6 ( 5 ) 3195 - 3200 2015.5

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DOI： 10.1039/c5sc00238a
Rhodium-catalysed synthesis of multi-substituted silylindenes from aryl alkynes and hydrosilanes via C-H bond activation Reviewed

Shunsuke Sueki, Yoichiro Kuninobu

Chemical Communications 51 ( 36 ) 7685 - 7688 2015.5

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DOI： 10.1039/c5cc01569c
Iridium-catalyzed ortho -selective C-H silylation of aromatic compounds directed toward the synthesis of π-conjugated molecules with Lewis acid-base interaction Reviewed

17 ( 7 ) 1758 - 1761 2015.4

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We successfully developed an iridium-catalyzed ortho-selective C-H silylation of aromatic compounds. The reaction exhibited a wide substrate scope, and a variety of π-conjugated molecules were synthesized in good to excellent yields, even in gram scale. Several silyl groups could also be introduced into the products. The experimental results indicated that the regioselectivity could be controlled by a Lewis acid-base interaction between the Lewis acidic silicon atoms of fluorinated hydrosilanes and the Lewis basic nitrogen atoms of aromatic compounds.

DOI： 10.1021/acs.orglett.5b00529
Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp³)-H bonds adjacent to a nitrogen atom Reviewed

Masahito Murai, Tetsuya Omura, Yoichiro Kuninobu, Kazuhiko Takai

Chemical Communications 51 ( 22 ) 4583 - 4586 2015.3

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DOI： 10.1039/c4cc09508a
Copper-mediated direct C(sp³)-H and C(sp²)-H acetoxylation Reviewed

Zhen Wang, Yoichiro Kuninobu, Motomu Kanai

Organic Letters 16 ( 18 ) 4790 - 4793 2014.9

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DOI： 10.1021/ol5022542
Friedel-Crafts functionalization of the cyclopentadienyl ligand in buckymetallocenes Reviewed

Yutaka Matsuo, Yoichiro Kuninobu, Shingo Ito, Masaya Sawamura, Eiichi Nakamura

Dalton Transactions 43 ( 20 ) 7407 - 7412 2014.5

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DOI： 10.1039/c3dt52002a
Copper-catalyzed benzylic C(sp³)-H alkoxylation of heterocyclic compounds Reviewed

Noriaki Takemura, Yoichiro Kuninobu, Motomu Kanai

Organic and Biomolecular Chemistry 12 ( 16 ) 2528 - 2532 2014.4

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DOI： 10.1039/c4ob00215f
Palladium-catalyzed direct C-H silylation and germanylation of benzamides and carboxamides Reviewed

Kyalo Stephen Kanyiva, Yoichiro Kuninobu, Motomu Kanai

Organic Letters 16 ( 7 ) 1968 - 1971 2014.4

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DOI： 10.1021/ol500519y
Molybdenum-mediated desulfurization of dhiols and disulfides Reviewed

Zhen Wang, Yoichiro Kuninobu, Motomu Kanai

Synlett 25 ( 13 ) 1869 - 1872 2014.1

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DOI： 10.1055/s-0034-1378315
Synthesis of pyridine N-oxide-BF2CF3 complexes and their fluorescence properties Reviewed

Tomoaki Nishida, Aiko Fukazawa, Eriko Yamaguchi, Hiroya Oshima, Shigehiro Yamaguchi, Motomu Kanai, Yoichiro Kuninobu

Chemistry - An Asian Journal 9 ( 4 ) 1026 - 1030 2014

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DOI： 10.1002/asia.201301688
Copper-catalyzed intramolecular N-S bond formation by oxidative dehydrogenative cyclization Reviewed

Zhen Wang, Yoichiro Kuninobu, Motomu Kanai

Journal of Organic Chemistry 78 ( 14 ) 7337 - 7342 2013.7

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DOI： 10.1021/jo401056g
Transition metal-catalyzed highly efficient and novel transformations -Development of reactions using group 7 and other transition metal catalysts Reviewed

Yoichiro Kuninobu

Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry 71 ( 5 ) 425 - 432 2013.7

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DOI： 10.5059/yukigoseikyokaishi.71.425
Copper-catalyzed N- and O-alkylation of amines and phenols using alkylborane reagents Reviewed

Shunsuke Sueki, Yoichiro Kuninobu

Organic Letters 15 ( 7 ) 1544 - 1547 2013.4

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DOI： 10.1021/ol400323z
Copper-catalyzed C-H alkoxylation of azoles Reviewed

Noriaki Takemura, Yoichiro Kuninobu, Motomu Kanai

Organic Letters 15 ( 4 ) 844 - 847 2013.2

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DOI： 10.1021/ol303533z
Rhodium-catalyzed intramolecular silylation of unactivated C(sp ³)-H bonds Reviewed

Yoichiro Kuninobu, Takahiro Nakahara, Hirotaka Takeshima, Kazuhiko Takai

Organic Letters 15 ( 2 ) 426 - 428 2013.1

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DOI： 10.1021/ol303353m
Palladium-catalyzed synthesis of a phosphine oxide with a chiral phosphorus center via C-H phosphination Reviewed

Yoichiro Kuninobu, Kazuki Origuchi, Kazuhiko Takai

Heterocycles 85 ( 12 ) 3029 - 3034 2012.12

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DOI： 10.3987/COM-12-12595
Rhenium-catalyzed regio- and stereoselective synthesis of γ-thio-α,β-unsaturated ketones via insertion of terminal alkynes into the C-S bond Reviewed

14 ( 23 ) 6116 - 6118 2012.12

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The reaction of α-thioketones and alkynes in the presence of a rhenium catalyst, [HRe(CO)₄]_n, gave γ-thio-α, β-unsaturated ketones in excellent yields. The alkynes were inserted into the carbon-sulfur bond of the α-thioketones, and isomerization of a double bond provided the products with high regio- and stereoselectivities. This reaction also proceeded in an intramolecular fashion.

DOI： 10.1021/ol302810u
Erratum Correction to palladium-catalyzed synthesis of dibenzophosphole oxides via intramolecular dehydrogenative cyclization (Journal of Organic Chemistry (2011) 76 (7370-7376) DOI: 10.1021/jo201030j)) Reviewed

Yoichiro Kuninobu, Takuya Yoshida, Kazuhiko Takai

Journal of Organic Chemistry 77 ( 20 ) 2012.10

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DOI： 10.1021/jo3021506
Development of novel and highly efficient methods to construct carboncarbon bonds using group 7 transition-metal catalysts Reviewed

Yoichiro Kuninobu, Kazuhiko Takai

Bulletin of the Chemical Society of Japan 85 ( 6 ) 656 - 671 2012.7

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DOI： 10.1246/bcsj.20120015
Rhenium-catalyzed regioselective synthesis of multisubstituted pyridines from β-enamino ketones and alkynes via C-C bond cleavage Reviewed

14 ( 12 ) 3182 - 3185 2012.6

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A new method is described for the regioselective synthesis of multisubstituted pyridine derivatives. Treatment of N-acetyl β-enamino ketones with alkynes in the presence of the rhenium catalyst, Re ₂(CO) ₁₀, gives multisubstituted pyridines regioselectively. In this reaction, the N-acetyl moieties are important for the selective formation of the multisubstituted pyridines. This reaction proceeds via insertion of alkynes into a carbon-carbon single bond of β-enamino ketones, intramolecular nucleophilic cyclization, and elimination of acetic acid.

DOI： 10.1021/ol301273j
Rhenium-catalyzed allylation of C-H bonds of benzoic and acrylic acids Reviewed

Yoichiro Kuninobu, Kazuhiro Ohta, Kazuhiko Takai

Chemical Communications 47 ( 38 ) 10791 - 10793 2011.10

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DOI： 10.1039/c1cc12359a
Synthesis of multisubstituted cyclopentadienes from cyclopentenones prepared via catalytic double aldol condensation and nazarov reaction sequence Reviewed

Yuta Nishina, Tomohiro Tatsuzaki, Ayano Tsubakihara, Yoichiro Kuninobu, Kazuhiko Takai

Synlett ( 17 ) 2585 - 2589 2011.10

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DOI： 10.1055/s-0030-1260324
Indium-catalyzed construction of polycyclic aromatic hydrocarbon skeletons via dehydration Reviewed

Yoichiro Kuninobu, Tomohiro Tatsuzaki, Takashi Matsuki, Kazuhiko Takai

Journal of Organic Chemistry 76 ( 17 ) 7005 - 7009 2011.9

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DOI： 10.1021/jo200861s
Palladium-catalyzed synthesis of dibenzophosphole oxides via intramolecular dehydrogenative cyclization Reviewed

Yoichiro Kuninobu, Takuya Yoshida, Kazuhiko Takai

Journal of Organic Chemistry 76 ( 18 ) 7370 - 7376 2011.9

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DOI： 10.1021/jo201030j
Synthesis of meso-substituted tetraarylalkynylporphyrins via rhenium-catalyzed formation of naphthalene units Reviewed

Ali Samarat, Yoichiro Kuninobu, Kazuhiko Takai

Synlett ( 15 ) 2177 - 2180 2011.8

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DOI： 10.1055/s-0030-1261199
Rhenium-catalyzed regio- and stereoselective addition of two carbon units to terminal alkynes via carbon-carbon bond cleavage of β-keto sulfones Reviewed

13 ( 11 ) 2959 - 2961 2011.6

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Treatment of β-keto sulfones with terminal alkynes gave unsaturated δ-keto sulfones in good to excellent yields under rhenium catalysis. In this reaction, the insertion of the alkynes into the nonstrained carbon-carbon single bond between the α- and β-positions of the β-keto sulfones proceeded smoothly, and (Z)-isomers were produced with high regio- and stereoselectivities.

DOI： 10.1021/ol2008507
Organic reactions catalyzed by rhenium carbonyl complexes Reviewed

Yoichiro Kuninobu, Kazuhiko Takai

Chemical Reviews 111 ( 3 ) 1938 - 1953 2011.3

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DOI： 10.1021/cr100241u
Rhenium-catalyzed insertion of terminal alkenes into a C(sp²)-H bond and successive transfer hydrogenation Reviewed

Yoichiro Kuninobu, Takahiro Nakahara, Peng Yu, Kazuhiko Takai

Journal of Organometallic Chemistry 696 ( 1 ) 348 - 351 2011.1

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DOI： 10.1016/j.jorganchem.2010.09.064
Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate Reviewed

Yoichiro Kuninobu, Mitsumi Nishi, Kazuhiko Takai

Chemical Communications 46 ( 46 ) 8860 - 8862 2010.12

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DOI： 10.1039/c0cc03781h
Cross-coupling reactions between C(sp2)-H and C(sp 3)-H bonds via sequential dehydrogenation and C-H insertion Reviewed

Yoichiro Kuninobu, Daisuke Asanoma, Kazuhiko Takai

Synlett ( 19 ) 2883 - 2886 2010.11

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DOI： 10.1055/s-0030-1259040
Synthesis of functionalized pentacenes from isobenzofurans derived from C-H bond activation Reviewed

Yoichiro Kuninobu, Takayuki Seiki, Shunsuke Kanamaru, Yuta Nishina, Kazuhiko Takai

Organic Letters 12 ( 22 ) 5287 - 5289 2010.11

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DOI： 10.1021/ol102349r
Rhenium-catalyzed diastereoselective synthesis of aminoindanes via the insertion of allenes into a C-H bond Reviewed

Yoichiro Kuninobu, Peng Yu, Kazuhiko Takai

Organic Letters 12 ( 19 ) 4274 - 4276 2010.10

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DOI： 10.1021/ol101627x
Regioselective functionalization of alkanes by sequential dehydrogenation-hydrozirconation Reviewed

Yoichiro Kuninobu, Tomonari Ureshino, Shun Ichi Yamamoto, Kazuhiko Takai

Chemical Communications 46 ( 29 ) 5310 - 5312 2010.7

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DOI： 10.1039/c0cc00243g
Rhenium-catalyzed synthesis of indenones by novel dehydrative trimerization of aryl aldehydes via C-H bond activation Reviewed

Yoichiro Kuninobu, Takashi Matsuki, Kazuhiko Takai

Organic Letters 12 ( 13 ) 2948 - 2950 2010.7

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DOI： 10.1021/ol100947p
Rhenium-catalyzed regioselective synthesis of phenol derivatives from 1,3-diesters and terminal alkynes Reviewed

Yoichiro Kuninobu, Takashi Iwanaga, Mitsumi Nishi, Kazuhiko Takai

Chemistry Letters 39 ( 8 ) 894 - 895 2010.7

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DOI： 10.1246/cl.2010.894
Rhenium- and manganese-catalyzed carbon-carbon bond formation using 1,3-dicarbonyl compounds and alkynes Reviewed

Yoichiro Kuninobu, Atsushi Kawata, Salprima S. Yudha, Hisatsugu Takata, Mitsumi Nishi, Kazuhiko Takai

Pure and Applied Chemistry 82 ( 7 ) 1491 - 1501 2010.7

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DOI： 10.1351/PAC-CON-09-09-21
Indium-catalyzed synthesis of keto esters from cyclic 1,3-diketones and alcohols and application to the synthesis of seratrodast Reviewed

Yoichiro Kuninobu, Atsushi Kawata, Taihei Noborio, Syun Ichi Yamamoto, Takashi Matsuki, Kazumi Takata, Kazuhiko Takai

Chemistry - An Asian Journal 5 ( 4 ) 941 - 945 2010.4

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DOI： 10.1002/asia.200900553
Rhenium- and manganese-catalyzed synthesis of aromatic compounds from 1,3-dicarbonyl compounds and alkynes Reviewed

Yoichiro Kuninobu, Mitsumi Nishi, Atsushi Kawata, Hisatsugu Takata, Yumi Hanatani, S. Salprima Yudha, Aya Iwai, Kazuhiko Takai

Journal of Organic Chemistry 75 ( 2 ) 334 - 341 2010.1

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DOI： 10.1021/jo902072q
Rhenium-catalyzed addition of -enamino esters to allenes Reviewed

Yoichiro Kuninobu, Atsuhiro Yamashita, Shun Ichi Yamamoto, Salprima Yudha S., Kazuhiko Takai

Synlett ( 18 ) 3027 - 3031 2009.12

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DOI： 10.1055/s-0029-1218281
Rhenium- and manganese-catalyzed insertion of alkynes into a carbon-carbon single bond of cyclic and acyclic 1,3-dicarbonyl compounds Reviewed

Yoichiro Kuninobu, Atsushi Kawata, Mitsumi Nishi, Salprima Yudha S, Jingjin Chen, Kazuhiko Takai

Chemistry - An Asian Journal 4 ( 9 ) 1424 - 1433 2009.9

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DOI： 10.1002/asia.200900137
Rhenium-catalyzed formation of bicyclo[3.3.1]nonene frameworks by a reaction of cyclic β-keto esters with terminal alkynes Reviewed

11 ( 12 ) 2535 - 2537 2009.6

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Treatment of cyclic βKeto esters with terminal alkynes in the presence of a catalytic amount of a rhenium complex, [ReBr(CO)₃(thf)] ₂, gave bicyclo[3.3.1]nonene derivatives. The reaction conditions and yields of the bicyclo[3.3.1]nonenes were improved by the sequential use of tetrabutylammonium fluoride (TBAF) after the rhenium-catalyzed reactions.

DOI： 10.1021/ol900772h
Rhenium-catalyzed insertion of nonpolar and polar unsaturated molecules into an olefinic C-H bond Reviewed

Yoichiro Kuninobu, Yasuo Fujii, Takashi Matsuki, Yuta Nishina, Kazuhiko Takai

Organic Letters 11 ( 12 ) 2711 - 2714 2009.6

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DOI： 10.1021/ol900962v
Manganese-catalyzed construction of tetrasubstituted benzenes from 1,3-dicarbonyl compounds and terminal acetylenes Reviewed

Yoichiro Kuninobu, Mitsumi Nishi, Salprima S. Yudha, Kazuhiko Takai

Organic Letters 10 ( 14 ) 3009 - 3011 2008.12

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DOI： 10.1021/ol800969h
Rhenium-catalyzed synthesis of multisubstituted aromatic compounds via C-C single-bond cleavage Reviewed

Yoichiro Kuninobu, Hisatsugu Takata, Atsushi Kawata, Kazuhiko Takai

Organic Letters 10 ( 14 ) 3133 - 3135 2008.12

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DOI： 10.1021/ol801226t
Rhenium- and manganese-catalyzed insertion of acetylenes into β-keto esters Synthesis of 2-pyranones Reviewed

( 47 ) 6360 - 6362 2008.12

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Rhenium- and manganese-catalyzed reactions between β-keto esters and acetylenes, followed by treatment with tetrabutylammonium fluoride, gave 2-pyranone derivatives regioselectively.

DOI： 10.1039/b814694b
Reactions and mechanistic studies of rhenium-catalyzed insertion of α,β-unsaturated carbonyl compounds into a C-H bond Reviewed

81 ( 11 ) 1393 - 1401 2008.12

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A rhenium complex, [ReBr(CO)₃(thf)]₂, catalyzes the insertion of α, β-unsaturated carbonyl compounds into a C-H bond of aromatic compounds having nitrogen-containing directing groups. In this reaction, Re₂(CO)₁₀ can also be used as a catalyst. When imines are employed as the aromatic substrates, sequential cyclization proceeds and indene derivatives are obtained in good to excellent yields. This reactivity is in contrast to those of ruthenium and rhodium complexes, which are usually used as catalysts in the insertion reactions of unsaturated molecules into a C-H bond. Investigations on the reaction mechanism indicate that the rhenium catalyst promotes C-H bond activation of aromatic compounds, the insertion of α, β-unsaturated carbonyl compounds into a Re-C bond, and intramolecular nucleophilic cyclization followed by reductive elimination and the elimination of an amine.

DOI： 10.1246/bcsj.81.1393
Rhenium-catalyzed coupling of 2-propynyl alcohols and several nucleophiles via dehydration Reviewed

Yoichiro Kuninobu, Hirokazu Ueda, Kazuhiko Takai

Chemistry Letters 37 ( 8 ) 878 - 879 2008.8

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DOI： 10.1246/cl.2008.878
Manganese-catalyzed synthesis of hydantoin derivatives from terminal alkynes and isocyanates Reviewed

Yoichiro Kuninobu, Kou Kikuchi, Kazuhiko Takai

Chemistry Letters 37 ( 7 ) 740 - 741 2008.7

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DOI： 10.1246/cl.2008.740
Synthesis of metal fullerene complexes by the use of fullerene halides Reviewed

Yutaka Matsuo, Yoichiro Kuninobu, Ayako Muramatsu, Masaya Sawamura, Eiichi Nakamura

Organometallics 27 ( 14 ) 3403 - 3409 2008.7

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DOI： 10.1021/om8001262
Hydroarylation of acetylenes, acrylates, and isocyanates with heteroaromatic compounds under rhenium catalysis Reviewed

Yoichiro Kuninobu, Kou Kikuchi, Yukimi Tokunaga, Yuta Nishina, Kazuhiko Takai

Tetrahedron 64 ( 26 ) 5974 - 5981 2008.6

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DOI： 10.1016/j.tet.2008.01.145
Rhenium-catalyzed synthesis of indene derivatives via C-H bond activation Reviewed

Yoichiro Kuninobu, Yuta Nishina, Atsushi Kawata, Makoto Shouho, Kazuhiko Takai

Pure and Applied Chemistry 80 ( 5 ) 1149 - 1154 2008.5

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DOI： 10.1351/pac200880051149
Copper(I)- And gold(I)-catalyzed synthesis of 2,4-disubstituted quinoline derivatives from N-Aryl-2-propynylamines Reviewed

Yoichiro Kuninobu, Yuichi Inoue, Kazuhiko Takai

Chemistry Letters 36 ( 12 ) 1422 - 1423 2007.12

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DOI： 10.1246/cl.2007.1422
Rhenium-catalyzed hydroamidation of unactivated terminal alkynes Synthesis of (E)-enamides Reviewed

S. Salprima Yudha, Yoichiro Kuninobu, Kazuhiko Takai

Organic Letters 9 ( 26 ) 5609 - 5611 2007.12

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DOI： 10.1021/ol702564e
Rhenium-catalyzed [2 + 2] cycloadditions of norbornenes with internal and terminal acetylenes Reviewed

Yoichiro Kuninobu, Peng Yu, Kazuhiko Takai

Chemistry Letters 36 ( 9 ) 1162 - 1163 2007.9

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DOI： 10.1246/cl.2007.1162
Rearrangement of indene skeletons under mild conditions Reviewed

Yoichiro Kuninobu, Hirokazu Ueda, Atsushi Kawata, Kazuhiko Takai

Journal of Organic Chemistry 72 ( 18 ) 6749 - 6752 2007.8

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DOI： 10.1021/jo070537w
Rhenium-catalyzed synthesis of naphthalene derivatives via insertion of aldehydes into a C-H bond Reviewed

Yoichiro Kuninobu, Yuta Nishina, Kazuhiko Takai

Tetrahedron 63 ( 35 ) 8463 - 8468 2007.8

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DOI： 10.1016/j.tet.2007.05.083
Rhenium-catalyzed amidation of heteroaromatic compounds via C-H bond activation Reviewed

Yoichiro Kuninobu, Yukimi Tokunaga, Kazuhiko Takai

Chemistry Letters 36 ( 7 ) 872 - 873 2007.7

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1246/cl.2007.872
Rhenium-catalyzed addition of trimethylsilylacetylene to aldimines Reviewed

Yoichiro Kuninobu, Yuichi Inoue, Kazuhiko Takai

Chemistry Letters 35 ( 12 ) 1376 - 1377 2006.12

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DOI： 10.1246/cl.2006.1376
Sequential ruthenium-catalyzed hydroamination and rhenium-catalyzed C-H bond activation leading to indene derivatives Reviewed

Yoichiro Kuninobu, Yuta Nishina, Kazuhiko Takai

Organic Letters 8 ( 13 ) 2891 - 2893 2006.6

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DOI： 10.1021/ol0611292
Isocyanate acting as a carbonyl precursor Pyridyl group-assisted formation of 4H-pyrido[1,2-a]pyrimidin-4-ones from ketimines and isocyanates Reviewed

Yoichiro Kuninobu, Shuhei Nishimura, Kazuhiko Takai

Organic and Biomolecular Chemistry 4 ( 2 ) 203 - 205 2006.4

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DOI： 10.1039/b516916j
Rhenium-catalyzed insertion of terminal acetylenes into a C-H bond of active methylene compounds Reviewed

Yoichiro Kuninobu, Atsushi Kawata, Kazuhiko Takai

Organic Letters 7 ( 22 ) 4823 - 4825 2005.10

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DOI： 10.1021/ol0515208
Mössbauer spectroscopy of bucky ferrocenes Lattice dynamics and motional anisotropy of the metal atom Reviewed

44 ( 16 ) 5629 - 5635 2005.8

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Temperature-dependent ⁵⁷Fe Mössbauer effect spectroscopy has been used to elucidate the metal atom dynamics in three neutral and two cationic bucky ferrocenes. For the three diamagnetic complexes Fe(C ₆₀H₅)Cp (1), Fe(C₆₀Me₅)Cp (2), and Fe(C₆₀Ph₅)Cp (3), the metal atom motion is anisotropic and the temperature dependence of the mean-square amplitude of vibration of the metal atom at a number of temperatures is reported. The Mössbauer lattice temperatures have been determined and compared to the parent ferrocene (6). The synthesis and X-ray crystal structure of 3 have been determined at 153(2) K, and the ¹H and ¹³C NMR spectra have been recorded. The cationic complexes derived from 2 and 3 show spin-lattice relaxation. The relaxation rate appears insensitive to the nearest-neighbor environment of the metal atom in this pair.

DOI： 10.1021/ic050251e
Molecular orientation and electronic structure of epitaxial bucky ferrocene (Fe(C₆₀(CH₃)₅)C₅H ₅) thin films Reviewed

Toshihiko Kaji, Toshihiro Shimada, Hiroaki Inoue, Yoichiro Kuninobu, Yutaka Matsuo, Eiichi Nakamura, Koichiro Saiki

Journal of Physical Chemistry B 108 ( 28 ) 9914 - 9918 2004.7

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Nickel, palladium, and platinum complexes of η ⁵- cyclopentadienide C ₆₀R ₅ ligands. Kinetic and thermodynamic stabilization effects of the C ₆₀Ph ₅ ligand Reviewed

23 ( 13 ) 3259 - 3266 2004.6

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The nickel-, palladium-, and platinum-RFC _p complexes η ⁵-RFC _p)(η ³-allylic) (3b, RFC _p = C ₆₀R ₅, R = Me, allylic = methallyl; 4a, R = Ph, allylic = allyl; 4b, R = Ph, allylic = methallyl), Pd(η ⁵- RFC _p)(η ³-allylic) (7a, R = Me, allylic = allyl; 7b, R = Me, allylic = methallyl; 7c, R = Me, allylic = crotyl; 8a, R = Ph, allylic = allyl; 8b, R = Ph, allylic = methallyl; 8c, R = Ph, allylic = crotyl), and Pt(η ⁵-RFC _p)(η ³-methallyl) (9, R = Me; 10, R = Ph), were synthesized by transmetalation between K(RFC _p) (R = Me, Ph) and [Ni(allylic)Br] ₂, [Pd(allylic)Cl] ₂, or [Pt(methallyl)Cl] ₂ in THF at 25 °C for 10 min. The nickel-PhFC _p complexes 4a,b are unusually more stable toward molecular oxygen than the corresponding simple nickel cyclopentadienides and survive in air for many hours at elevated temperature. The crystal structures and the electrochemical properties of the palladium complexes suggest that the unusual stability of the PhFC _p complexes is due to the kinetic stabilization effect of the five Ph groups surrounding the metal atom and the thermodynamic stabilization effect of the electron-withdrawing fullerene moiety, hence suggesting new opportunities for the synthesis of otherwise unstable organometallic compounds.

DOI： 10.1021/om0499153
Synthesis and reactivity of bucky ruthenocene Ru(η5-C 60Me5)(η5-C5H5) Reviewed

33 ( 1 ) 68 - 69 2004.1

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Metathetical coupling of an η⁵-fullerene ruthenium complex Ru(η⁵-C₆₀Me₅)Cl(CO)₂ and sodium cyclopentadienide gives a molecular hybrid of ruthenocene and fullerene, Ru(η⁵-C₆₀Me₅)(η⁵-C ₅H₅) (bucky ruthenocene), the structure of which was determined by spectroscopic and crystallographic analyses. The molecule shows unique reactivity among known ferrocene and ruthenocene compounds.

DOI： 10.1246/cl.2004.68
Photoinduced change in the Raman spectrum of buckyferrocene ((Fe(C ₆₀(CH₃)₅)C₅H₅) Reviewed

Toshihiro Shimada, Yoshiro Yamamoto, Toshihiko Kaji, Kenji Itaka, Hideomi Koinuma, Yoichiro Kuninobu, Yutaka Matsuo, Eiichi Nakamura, Koichiro Saiki

Solid State Communications 132 ( 3-4 ) 197 - 201 2004.1

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1016/j.ssc.2004.07.046
Hybrid of ferrocene and fullerene Reviewed

Masaya Sawamura, Yoichiro Kuninobu, Motoki Toganoh, Yutaka Matsuo, Masahiro Yamanaka, Eiichi Nakamura

Journal of the American Chemical Society 124 ( 32 ) 9354 - 9355 2002.8

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DOI： 10.1021/ja026069j
Epitaxial growth and electronic structure of a C₆₀ derivative prepared by using a solution spray technique Reviewed

T. Shimada, H. Nakatani, K. Ueno, A. Koma, Yoichiro Kuninobu, M. Sawamura, E. Nakamura

Journal of Applied Physics 90 ( 1 ) 209 - 212 2001.7

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DOI： 10.1063/1.1379052
Half-sandwich metallocene embedded in a spherically extended π-conjugate system. Synthesis, structure, and electrochemistry of Rh(η⁵-C₆₀Me₅)(CO)₂ Reviewed

122 ( 49 ) 12407 - 12408 2000.12

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Language：English Publishing type：Research paper (scientific journal)

DOI： 10.1021/ja005564h
Synthesis of pentamethyl-monohydro[60]fullerene C₆₀Me₅H and its use as cyclopentadienyl-type ligand precursor Reviewed

Masaya Sawamura, Motoki Toganoh, Yoichiro Kuninobu, Seiichi Kato, Eiichi Nakamura

Chemistry Letters ( 3 ) 270 - 271 2000.1

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DOI： 10.1246/cl.2000.270

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Books

Handbook of CH-Functionalization

Yoichiro Kuninobu（ Role： Joint author）

Wiley 2022.10

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Catalyst with Earth-abundant Elements

Kuninobu, Y.; Sueki, S.; Kaplaneris, N.; Ackermann, L.（ Role： Joint author）

Royal Society of Chemistry 2020.10

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Language：English Book type：Scholarly book

DOI： 10.1039/9781788012775

Other Link： https://pubs.rsc.org/en/content/ebook/978-1-78801-118-1
錯体化合物事典

國信　洋一郎（ Role： Joint author）

朝倉書店 2019.9

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Language：Japanese Book type：Scholarly book
ファインケミカルシリーズ「有機フッ素化合物の最新動向」

國信　洋一郎（ Role： Joint author）

シーエムシー出版 2018.7

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Language：Japanese Book type：Scholarly book

Presentations

有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 Invited

國信　洋一郎

長崎大学工学部講演会 2020.2

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Event date： 2020.2

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：長崎大学文教キャンパス Country：Japan
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 Invited

國信　洋一郎

近畿化学協会有機金属部会第４回例会 2020.1

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Event date： 2020.1

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：大阪府立大学中百舌鳥キャンパス Country：Japan
Development of Regioselective C-H Bond Transformations Invited International conference

Yoichiro Kuninobu

NCL Pune-One Day Symposium 2020.1

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Event date： 2020.1

Language：English Presentation type：Oral presentation (invited, special)

Country：India
Development of Regioselective C-H Bond Transformations Invited International conference

Yoichiro Kuninobu

International Conference on Chemistry for Human Development (ICCHD-2020) 2020.1

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Event date： 2020.1

Language：English Presentation type：Oral presentation (invited, special)

Country：India
Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules Invited

Yoichiro Kuninobu

2019.12

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Event date： 2019.12

Language：English Presentation type：Oral presentation (invited, special)

Country：Japan
非共有結合性相互作用を利用する炭素－水素結合変換反応における位置選択性制御法の開発 Invited

國信　洋一郎

統合物質創製化学研究推進機構　第５回国内シンポジウム 2019.11

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Event date： 2019.11

Language：Japanese Presentation type：Oral presentation (general)

Venue：北海道大学 Country：Japan
位置選択的なフッ素系官能基化反応の開発 Invited

國信　洋一郎

第６回次世代の有機化学・広島シンポジウム 2019.10

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Event date： 2019.10

Language：Japanese Presentation type：Oral presentation (general)

Venue：広島大学 Country：Japan
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 Invited

國信　洋一郎

CRESTxIoLセンタージョイントシンポジウム 2019.7

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Event date： 2019.7

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：山口大学工学部 Country：Japan
Hydrogen Bond-Controlled meta-selective C-H Borylation and Its Applications Invited International conference

Yoichiro Kuninobu

2019.7

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Event date： 2019.7

Language：Japanese Presentation type：Oral presentation (general)

Country：Japan
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 Invited

國信洋一郎

北海道大学講演会 2019.6

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Event date： 2019.6

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：北海道大学薬学部 Country：Japan
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 Invited

國信　洋一郎

武蔵野大学講演会 2019.5

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Event date： 2019.5

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：武蔵野大学 Country：Japan
Noncovalent Bond-Controlled Regioselective C-H Transformations Invited

Yoichiro Kuninobu

2019.4

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Event date： 2019.4

Language：English Presentation type：Oral presentation (general)

Country：Japan
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 Invited

國信　洋一郎

富山大学講演会 2019.2

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Event date： 2019.2

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：富山大学工学部 Country：Japan
触媒配位子による基質認識を利用する位置選択的なC-H結合変換反応の開発 Invited

國信　洋一郎

新学術「ハイブリッド」第２回公開シンポジウム 2019.1

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Event date： 2019.1

Language：Japanese Presentation type：Oral presentation (general)

Venue：東北大学　理学研究科サイエンスホール Country：Japan
Noncovalent Bond-Controlled Regioselective C-H Transformations Invited International conference

Yoichiro Kuninobu

The 13th International Symposium on Organic Reactions 2018.11

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Event date： 2018.11

Language：English Presentation type：Oral presentation (general)

Country：Japan
Noncovalent Bond-Controlled Regioselective C-H Transformations Invited International conference

Yoichiro Kuninobu

18th Tateshina Conference 2018.11

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Event date： 2018.11

Language：English

Country：Japan
Noncovalent Bond-Controlled Regioselective C-H Transformations Invited International conference

Yoichiro Kuninobu

ICPAC Langkawi 2018 2018.10

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Event date： 2018.10 - 2018.11

Language：English Presentation type：Oral presentation (invited, special)

Country：Japan
非共有結合性相互作用を利用する位置選択的なC-H結合変換反応の開発 Invited

國信　洋一郎

第５回次世代の有機化学・広島シンポジウム 2018.10

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Event date： 2018.10

Language：Japanese Presentation type：Oral presentation (general)

Venue：広島大学 Country：Japan
遷移金属触媒による炭素－水素結合変換反応 Invited

國信　洋一郎

第１２回触媒道場 2018.9

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Event date： 2018.9

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：長崎 Country：Japan
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 Invited

國信　洋一郎

愛媛大学第２４９回応用化学科セミナーミニシンポジウム 2018.8

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Event date： 2018.8

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：愛媛大学 Country：Japan
Development of Regioselective C-H Bond Transformations Invited International conference

Yoichiro Kuninobu

2018.5

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Event date： 2018.5

Language：English Presentation type：Oral presentation (invited, special)

Country：Japan
Regioselective C-H Trifluoromethylation of 6-Membered Heteroaromatic Compounds Invited International conference

Yoichiro Kuninobu

ICPAC 2018 2018.3

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Event date： 2018.3

Language：English Presentation type：Oral presentation (invited, special)

Country：Cambodia
Regioselective C-H Trifluoromethylation of 6-Membered Heteroaromatic Compounds Invited International conference

Yoichiro Kuninobu

ICPAC 2018 2018.3

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Event date： 2018.3

Language：English Presentation type：Oral presentation (general)

Country：Japan
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 Invited

國信　洋一郎

第44回有機典型元素化学討論会 2017.12

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Event date： 2017.12

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：東京工業大学大岡山キャンパス Country：Japan
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 Invited

國信　洋一郎

第４回次世代の有機化学・広島シンポジウム 2017.10

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Event date： 2017.10

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：広島大学　東広島キャンパス Country：Japan
Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules Invited International conference

Yoichiro Kuninobu

Lecture at Institute of Chemistry, Chinese Academy of Sciences 2017.9

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Event date： 2017.9

Language：English Presentation type：Oral presentation (invited, special)

Country：China
Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules Invited International conference

Yoichiro Kuninobu

Lecture at Peking University 2017.9

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Event date： 2017.9

Language：English Presentation type：Oral presentation (invited, special)

Country：China
Development of C-H Bond Transformations Directed Towards the Synthesis of Organic Functional Molecules Invited International conference

Yoichiro Kuninobu

Lecture at Tsinghua University 2017.9

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Event date： 2017.9

Language：English Presentation type：Oral presentation (invited, special)

Country：China
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 Invited

國信　洋一郎

第29回若手研究者のためのセミナー 2017.8

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Event date： 2017.8

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：九州大学伊都キャンパス Country：Japan
Noncovalent Bond-Controlled Regioselective C-H Borylation Invited International conference

Yoichiro Kuninobu

ISPAC 2017 2017.6

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Event date： 2017.6 - 2018.6

Language：English Presentation type：Oral presentation (invited, special)

Country：Viet Nam
位置選択的なトリフルオロメチル化反応の開発 Invited

國信　洋一郎

第１４回フッ素相模セミナー 2017.6

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Event date： 2017.6

Language：Japanese Presentation type：Oral presentation (invited, special)

Venue：東ソー（株）東京研究所 Country：Japan
生物活性分子合成を志向した炭素－水素結合変換反応の開発 Invited

國信　洋一郎

日本薬学会第137年会 2017.3

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Event date： 2017.3 - 2018.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：仙台 Country：Japan
ビアリール化合物とメルドラム酸誘導体からのフルオレン類の合成

姜志彦、関根康平、國信洋一郎

第35回若手研究者のためのセミナー 2024.8

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Event date： 2024.8

Language：Japanese

Country：Japan
ロジウム触媒によるアルキンのシリル化を基盤とする含ケイ素環状化合物の選択的な合成

藤和人、関根康平、國信洋一郎

第50回有機典型元素化学討論会 2024.4

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Event date： 2024.4

Language：Japanese

Venue：市民会館おおみや Country：Japan
N－アリールオキサミン酸を二官能基化剤とするアルキンのカルバモイルアリール化反応

岳高帆、呉迪、塩塚朗、関根康平、國信洋一郎

日本化学会第104春季年会 2024.3

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Event date： 2024.3

Language：Japanese

Venue：日本大学船橋キャンパス Country：Japan
水素結合を用いたナフタレン誘導体の遠隔位での位置選択的C–Hボリル化反応の開発

吉野元規、猪股志帆、國信洋一郎

日本化学会第104春季年会 2024.3

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Event date： 2024.3

Language：Japanese

Venue：日本大学船橋キャンパス Country：Japan
二重Friedel-Crafts反応による環状ジラジカルジカチオンの合成とその性質

許潤杰、國信洋一郎

日本化学会第104春季年会 2024.3

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Event date： 2024.3

Language：English

Venue：日本大学船橋キャンパス Country：Japan
可視光駆動型カルバモイルアリール化反応を利用した環状イミドの合成

高汰佑、呉迪、関根康平、國信洋一郎

日本化学会第104春季年会 2024.3

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Event date： 2024.3

Language：Japanese

Venue：日本大学船橋キャンパス Country：Japan
金触媒を用いたアリールジイン化合物の環化反応による含ケイ素環状化合物の合成

藤和人、関根康平、國信洋一郎

日本化学会第104春季年会 2024.3

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Event date： 2024.3

Language：Japanese

Venue：日本大学船橋キャンパス Country：Japan
N-アリールオキサミン酸の芳香族炭素–窒素結合切断を鍵とするアルケンのカルバモイルアリール化反応

塩塚朗、呉迪、川島恭平、森俊文、関根康平、國信洋一郎

日本化学会第104春季年会 2024.3

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Event date： 2024.3

Language：Japanese

Country：Japan
二重Friedel-Crafts反応によるペンローズ階段型環状分子の合成と物性

姜志彦、國信洋一郎

日本化学会第104春季年会 2024.3

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Event date： 2024.3

Language：Japanese

Venue：日本大学船橋キャンパス Country：Japan
ロジウム触媒を用いた含ケイ素環状分子合成法の開発

藤和人、関根康平、國信洋一郎

第26回ケイ素化学協会シンポジウム 2023.11

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Event date： 2023.11

Language：Japanese

Venue：静岡県清水文化会館 Country：Japan
金触媒による含ケイ素環状化合物の合成

関根康平、藤和人、國信洋一郎

第27回ケイ素化学協会シンポジウム 2023.11

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Event date： 2023.11

Language：Japanese

Venue：ラフォーレ那須 Country：Japan
炭素－水素およびケイ素－水素結合変換に基づく含ケイ素π共役系分子の合成 Invited

國信　洋一郎

第27回ケイ素化学協会シンポジウム 2023.11

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Event date： 2023.11

Language：Japanese

Venue：リゾートホテル　ラフォーレ那須 Country：Japan
Hydrogen Bond-controlled Site-selective C-H Borylation of Naphthalene Derivatives at the Remote-position

2023.9

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Event date： 2023.9

Language：Japanese

Country：Japan
ヒドロキシピレンの特性を活かした光駆動型脱アルキルチオ化反応

関根康平・呉迪・塩塚朗・川島恭平・森俊文・國信洋一郎

第33回基礎有機化学討論会 2023.9

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Event date： 2023.9

Language：Japanese

Country：Japan
Synthesis of Cyclic Compounds and the Diradical Dication Species and Investigation of Their Properties

Runjie Xu, Yoichiro Kuninobu

2023.9

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Event date： 2023.9

Language：English

Country：Japan
二重Friedel-Crafts反応による新規環状π共役系分子の創製

姜志彦、國信洋一郎

第33回基礎有機化学討論会 2023.9

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Event date： 2023.9

Language：Japanese

Country：Japan
ロジウム触媒によるベンゾシロール誘導体の合成

藤和人、関根康平、國信洋一郎

第68回有機金属化学討論会 2023.9

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Event date： 2023.9

Language：Japanese

Venue：オンライン Country：Japan
LLX 型ピンサー配位子を用いるイリジウム触媒による C(sp3)‒H ボリル化

鳥越尊、河津稜平、峯海吏、國信洋一郎

第68回有機金属化学討論会 2023.9

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Event date： 2023.9

Language：Japanese

Venue：オンライン Country：Japan
LLX型PNSiピンサー配位子を用いたイリジウム触媒によるC(sp³)-Hボリル化

峯海吏、鳥越尊、國信洋一郎

第59回化学関連支部合同九州大会 2023.7

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Event date： 2023.7

Language：Japanese

Venue：第59回化学関連支部合同九州大会 Country：Japan
光誘起電子移動を鍵とする芳香族第一級アミンの脱アミノ化反応の開発

土岐拓未、塩塚朗、関根康平、國信洋一郎

第59回化学関連支部合同九州大会 2023.7

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Event date： 2023.7

Language：Japanese

Venue：北九州国際会議場 Country：Japan
ピリジン環の求核的活性化を経る３位選択的トリフルオロメチル化

牟田龍平、鳥越尊、國信洋一郎

第59回化学関連支部合同九州大会 2023.7

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Event date： 2023.7

Language：Japanese

Venue：第59回化学関連支部合同九州大会 Country：Japan
Synthesis of Cyclic Compounds and the Diradical Dication Species and Investigation of Their Properties

2023.7

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Event date： 2023.7

Language：English

Country：Japan
Bifunctional 1-Hydroxypyrene-Photocatalyst for Hydrodesulfurization via Reductive C(aryl)–S Bond Cleavage International conference

2023.6

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Event date： 2023.6

Language：English

Country：Japan
Deaminative Borylation and Hydrodeamination of Aromatic Amines via Radical/Radical Ion Intermediates International conference

Kohei Sekine, Akira Shiozuka, Takumi Toki, Kyohei Kawashima, Toshifumi Mori, Yoichiro Kuninobu

10th Pacific Synposium on Radical Chemistry (PSRC-10) 2023.6

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Event date： 2023.6

Language：English

Country：Japan
ビアリール化合物とメルドラム酸誘導体からのフルオレン類の合成

姜志彦、関根康平、國信洋一郎

第33回万有福岡シンポジウム 2023.6

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Event date： 2023.6

Language：Japanese

Country：Japan
紫外光照射によるSelectfluorを用いる２-メチルベンゼンスルホン酸塩誘導体のベンジル位ジフッ素化

曾嘉林、鳥越尊、國信洋一郎

2023.3

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Event date： 2023.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：東京理科大学野田キャンパス Country：Japan
ロジウム触媒を用いたアルキンの分子内および分子間ヒドロ官能基化による含ケイ素環状化合物の選択的な合成

藤和人、関根康平、國信洋一郎

日本化学会第103春季年会 2023.3

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Event date： 2023.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：東京理科大学野田キャンパス Country：Japan
Photoinduced Hydrodesulfurization of Alkylthio Group-substituted Aromatic Compounds via C(sp2)-S Bond Cleavage

Di Wu, Akira Shiozuka, Kohei Sekine, Yoichiro Kuninobu

2023.3

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Event date： 2023.3

Language：English Presentation type：Oral presentation (general)

Country：Japan
Hydrogen Bond-Accelerated Decatungstate-Catalyzed C(sp3)–H Alkylation of 2-Methylphenylboronic Acid Derivatives 日本化学会第103春季年会、K704-2am-03

日本化学会第103春季年会 2023.3

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Event date： 2023.3

Language：English Presentation type：Oral presentation (general)

Venue：東京理科大学野田キャンパス Country：Japan
ペプチド主鎖N末端アンモニウムとの静電相互作用を利用したデカタングステン酸塩光触媒によるバリン残基の選択的なC(sp3)–Hアルキル化

宋済舟、鳥越尊、國信洋一郎

120回有機合成シンポジウム 2022.6

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Event date： 2022.6

Language：Japanese Presentation type：Oral presentation (general)

Venue：オンライン Country：Japan
光誘起電子移動を鍵とする芳香族第一級アミンの炭素–窒素結合切断を伴うボリル化および脱アミノ化反応の開発

塩塚朗、関根康平、土岐拓未、川島恭平、森俊文、國信洋一郎

第46回有機電子移動化学討論会 2022.6

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Event date： 2022.6

Language：Japanese Presentation type：Oral presentation (general)

Venue：オンライン Country：Japan
静電相互作用を利用したデカタングステン酸塩光触媒による2-メチルアニリニウム塩の位置選択的C(sp3)-Hアルキル化

曾嘉林、鳥越尊、國信洋一郎

第32回万有福岡シンポジウム 2022.6

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Event date： 2022.6

Language：Japanese Presentation type：Symposium, workshop panel (public)

Venue：九州大学伊都キャンパス椎木講堂 Country：Japan
Decatungstate-catalyzed Site-selective C(sp3)–H Alkylation of 2-Methylanilinium Salts Controlled by Noncovalent Interactions

日本化学会第102春季年会 2022.3

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Event date： 2022.3

Language：English

Venue：オンライン Country：Japan
ビアリール化合物とメルドラム酸誘導体からのフルオレン類の合成

姜志彦、関根康平、國信洋一郎

日本化学会第102春季年会 2022.3

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Event date： 2022.3

Language：Japanese

Venue：オンライン Country：Japan
光誘起電子移動を鍵とする芳香族アミンのC–N結合切断を伴うボリル化反応の開発

塩塚朗、関根康平、國信洋一郎

日本化学会第102春季年会 2022.3

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Event date： 2022.3

Language：Japanese

Venue：オンライン Country：Japan
ヒドロシリル基を有するキノリン骨格トリアリールホスフィン配位子を用いたイリジウム触媒によるC¬–Hボリル化

峯海吏、鳥越尊、國信洋一郎

日本化学会第102春季年会 2022.3

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Event date： 2022.3

Language：Japanese

Venue：オンライン Country：Japan
光誘起電子移動を利用した芳香族第一級アミンの脱アミノ化反応の開発

土岐拓未、塩塚朗、関根康平、國信洋一郎

日本化学会第102春季年会 2022.3

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Event date： 2022.3

Language：Japanese

Venue：オンライン Country：Japan
ヒドロシリル基を有するビピリジン配位子を用いたイリジウム触媒によるC(sp3)–Hボリル化

河津稜平、鳥越尊、國信洋一郎

日本化学会第102春季年会 2022.3

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Event date： 2022.3

Language：Japanese

Venue：オンライン Country：Japan
3-Position-selective Trifluoromethylation of Pyridine Rings Using Nucleophilic Activation based on 1,4-Reduction

Ryuhei Muta, Takeru Torigoe, Yoichiro Kuninobu

2022.3

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Event date： 2022.3

Language：English

Country：Japan
ペプチド主鎖の末端アンモニウム基とデカタングステン酸塩光触媒との相互作用を利用した選択的なバリン残基のC(sp3)–H官能基化

宋済舟、鳥越尊、國信洋一郎

日本化学会第102春季年会 2022.3

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Event date： 2022.3

Language：Japanese

Venue：オンライン Country：Japan
ピリジン類の求核的活性化に基づく3位選択的トリフルオロメチル化

牟田龍平、鳥越尊、國信洋一郎

第44回フッ素化学討論会 2021.11

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Event date： 2021.11

Language：Japanese

Venue：オンライン Country：Japan
LLX型NNSiピンサー配位子を有するイリジウム触媒を用いたC(sp3)-Hボリル化

河津稜平, 鳥越尊, 國信洋一郎

第67回有機金属化学討論会 2021.9

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Event date： 2021.9

Language：Japanese

Venue：オンライン Country：Japan
ケイ素架橋スチルベン合成反応の開発

藤和人, 関根康平, 國信洋一郎

第67回有機金属化学討論会 2021.9

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Event date： 2021.9

Language：Japanese

Venue：オンライン Country：Japan
非共有結合性相互作用を利用したデカタングステン酸塩光触媒によるC(sp3)-H結合アルキル化の位置選択性制御

曾嘉林, 鳥越尊, 國信洋一郎

第67回有機金属化学討論会 2021.9

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Event date： 2021.9

Language：Japanese

Venue：オンライン Country：Japan
ロジウム触媒によるケイ素架橋スチルベンの新規合成反応の開発 International conference

藤和人, 関根康平, 國信洋一郎

第58回化学関連支部合同九州大会 2021.7

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Event date： 2021.7

Language：Japanese

Venue：オンライン Country：Japan
Regioselective C(sp3)–H Alkylation of Fructopyranose Derivative by 1,6 HAT International conference

李艷茹, 宮本翔太, 鳥越尊, 國信洋一郎

第58回化学関連支部合同九州大会 2021.7

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Event date： 2021.7

Language：English

Venue：オンライン Country：Japan
二重炭素―炭素結合形成によるフルオレン合成反応の開発 International conference

姜志彦, 関根康平, 國信洋一郎

第58回化学関連支部合同九州大会 2021.7

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Event date： 2021.7

Language：Japanese

Venue：オンライン Country：Japan
デカタングステン酸塩光触媒を用いたアニリニウム塩の位置選択的なC(sp3)–H結合官能基化反応 International conference

曾嘉林, 鳥越尊, 國信洋一郎

第58回化学関連支部合同九州大会 2021.7

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Event date： 2021.7

Language：Japanese

Venue：オンライン Country：Japan
デカタングステン酸塩光触媒を用いたアミノ酸残基の選択的C(sp3)-Hアルキル化 International conference

宋済舟, 鳥越尊, 國信洋一郎

第58回化学関連支部合同九州大会 2021.7

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Event date： 2021.7

Language：Japanese

Venue：オンライン Country：Japan
LLX型NNSiピンサー配位子を用いたC(sp3)–H結合ホウ素化 International conference

河津稜平, 鳥越尊, 國信洋一郎

第58回化学関連支部合同九州大会 2021.7

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Event date： 2021.7

Language：Japanese

Venue：オンライン Country：Japan
ロジウム触媒によるケイ素架橋スチルベン類の新規合成反応の開発

藤和人、関根康平、國信洋一郎

第118回有機合成シンポジウム 2021.6

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Event date： 2021.6

Language：Japanese

Venue：九州大学伊都キャンパス椎木講堂＋オンライン Country：Japan
二重炭素―炭素結合形成によるフルオレン合成反応の開発

姜志彦、関根康平、國信洋一郎

第118回有機合成シンポジウム 2021.6

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Event date： 2021.6

Language：Japanese

Venue：九州大学伊都キャンパス椎木講堂＋オンライン Country：Japan
光エネルギーを利用する不活性なC–N結合切断を伴う芳香族アミンのボリル化反応

塩塚朗、関根康平、國信洋一郎

第118回有機合成シンポジウム 2021.6

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Event date： 2021.6

Language：Japanese

Venue：九州大学伊都キャンパス椎木講堂 Country：Japan
2-Position-Selective C-H Trifluoromethylation of Quinoline Derivatives International conference

Takahiro SHIRAI, Motomu KANAI, Yoichiro KUNINOBU

ACS Publications Symposium: The Power of Chemical Transformations 2021.5

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Event date： 2021.5

Language：English

Country：Japan
ロジウム触媒によるケイ素架橋スチルベン類の新規合成反応の開発

藤和人、関根康平、國信洋一郎

日本化学会第101春季年会 2021.3

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Event date： 2021.3

Language：Japanese

Venue：オンライン Country：Japan
Regioselective C(sp3)–H Alkylation of Fructopyranose Derivative by 1,6-HAT

日本化学会第101春季年会 2021.3

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Event date： 2021.3

Language：English

Venue：オンライン Country：Japan
Borane-catalyzed Double C-H Silylation for the Synthesis of Silacyclic Compounds

Yafang Dong, Kohei Sekine, Yoichiro Kuninobu

2020.5

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Event date： 2020.5

Language：English

Country：Japan
ニッケル触媒を用いた分子内および分子間C-Hシリル化反応の開発

藤和人、関根康平、國信洋一郎

日本化学会第100春季年会 2020.3

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Event date： 2020.3

Language：Japanese

Venue：東京理科大学野田キャンパス Country：Japan
ホウ素触媒を用いる二重シラFriedel-Crafts反応による含ケイ素六員環化合物の合成

酒井優光、Yafang Dong、藤和人、関根康平、國信洋一郎

日本化学会第100春季年会 2020.3

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Event date： 2020.3

Language：Japanese

Venue：東京理科大学野田キャンパス Country：Japan
Synthesis of Silepins from Terphenyls and Dihydrosilanes via Double Sila-Friedel-Crafts Reaction

Yafang Dong, Kohei Sekine, Yoichiro Kuninobu

2020.3

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Event date： 2020.3

Language：English

Country：Japan
水素結合を利用したイリジウム触媒によるチオアニソール類のオルト位選択的なC-Hボリル化

曾嘉林、内藤森生、鳥越尊、山中正浩、國信洋一郎

日本化学会第100春季年会 2020.3

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Event date： 2020.3

Language：Japanese

Venue：東京理科大学野田キャンパス Country：Japan
含窒素六員環芳香族化合物への位置選択的な含フッ素官能基導入反応の開発

楢山光司、牟田龍平、鳥越尊、國信洋一郎

日本化学会第100春季年会 2020.3

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Event date： 2020.3

Language：Japanese

Country：Japan
アミノ酸側鎖の位置選択的なC-Hトリフルオロメチル化

宋済舟、鳥越尊、國信洋一郎

日本化学会第100春季年会 2020.3

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Event date： 2020.3

Language：Japanese

Venue：東京理科大学野田キャンパス Country：Japan
シクロデキストリンによる包接を利用した鉄触媒による芳香族化合物の位置選択的C-Hトリフルオロメチル化反応の開発

盧旭、鳥越尊、國信洋一郎

日本化学会第100春季年会 2020.3

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Event date： 2020.3

Language：Japanese

Venue：東京理科大学野田キャンパス Country：Japan
Manganese-catalyzed C(sp3)-H Bromination

Kumar Sneh, Takeru Torigoe, Yoichiro Kuninobu

2020.3

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Event date： 2020.3

Language：Japanese

Country：Japan
２－フェニルピリジン部位を有する六配位ケイ素化合物の合成とその光物性

森俊彰、古田翔平、吉越裕介、関根康平、國信洋一郎

日本化学会第100春季年会 2020.3

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Event date： 2020.3

Language：Japanese

Venue：東京理科大学野田キャンパス Country：Japan
デカタングステン酸塩光触媒によるC(sp3)-H結合官能基化反応の静電相互作用を用いた位置選択性制御

曾嘉林、鳥越尊、國信洋一郎

日本化学会第100春季年会 2020.3

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Event date： 2020.3

Language：Japanese

Venue：東京理科大学野田キャンパス Country：Japan
ホウ素触媒を用いる連続的なC-Hシリル化反応によるシラフルオレンの合成

関根康平、Yafang Dong、高田雄大、吉越裕介、國信　洋一郎

統合物質創製化学研究推進機構　第５回国内シンポジウム 2019.11

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Event date： 2019.11

Language：Japanese

Venue：北海道大学 Country：Japan
Lewis Acid-Catalyzed Synthesis of Silafluorenes from Biphenyls and Dihydrosilanes via Double Sila-Friedel-Crafts Reaction

Yafang Dong, Yuta Takata, Kohei Sekine, Yusuke Yoshigoe, Yoichiro Kuninobu

2019.11

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Event date： 2019.11

Language：English

Country：Japan
ルイス酸―塩基相互作用を利用した蛍光色素のマルチカラー発光とポリマー担持による固体発光特性の制御

森敏彰、吉越裕介、國信洋一郎

第30回基礎有機化学討論会 2019.9

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Event date： 2019.9 - 2019.12

Language：Japanese

Venue：大阪国際交流センター Country：Japan
ortho-Selective C–H Borylation of Thioanisole Derivatives Using Iridium Catalyst Bearing a Simple Bipyridine-Type Ligand

第66回有機金属化学討論会 2019.9

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Event date： 2019.9

Language：English

Venue：首都大学東京南大沢キャンパス Country：Japan
Double C-H Silylation for the Synthesis of Silafluorenes by Borane Catalyst

Yafang Dong, Yuta Takata, Kohei Sekine, Yusuke Yoshigoe, Yoichiro Kuninobu

2019.9

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Event date： 2019.9

Language：English

Country：Japan
単純なビピリジン系配位子をもつイリジウム触媒による芳香族イオウ化合物のオルト位選択的C-Hボリル化 Invited

曾嘉林、鳥越尊、國信　洋一郎

第31回若手研究者のためのセミナー 2019.8

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Event date： 2019.8

Language：Japanese

Venue：九州大学筑紫キャンパス Country：Japan
ポリマーを利用する蛍光色素-ルイス酸間での平衡の調整によるマルチカラーおよび白色発光 Invited

森敏彰、吉越裕介、國信洋一郎

第31回若手研究者のためのセミナー 2019.8

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Event date： 2019.8

Language：Japanese

Venue：九州大学筑紫キャンパス Country：Japan
六員環ヘテロ芳香族化合物の2位選択的C–Hトリフルオロメチルチオ化反応の開発 Invited

牟田龍平、鳥越尊、國信　洋一郎

第31回若手研究者のためのセミナー 2019.8

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Event date： 2019.8

Language：Japanese

Country：Japan
ヨウ素化合物をハロゲン結合ドナーとして用いる発光材料の開発

吉越裕介、山川健司、王子嘉、金井求、國信洋一郎

第22回ヨウ素学会シンポジウム 2019.8

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Event date： 2019.8

Language：Japanese

Venue：千葉大学西千葉キャンパス Country：Japan
Noncovalent Bond-Controlled Regioselective C-H Transformations International conference

Yoichiro Kuninobu

OMCOS 20 2019.7

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Event date： 2019.7

Language：English

Country：Germany
One-pot meta-Selective Functionalizations of Aromatic Compounds Utilizing Iridium-catalyzed C-H Borylated Products International conference

Jie Wang, Takeru Torigoe, Yoichiro Kuninobu

2019.7

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Event date： 2019.7

Language：English Presentation type：Symposium, workshop panel (public)

Country：Japan
単純なビピリジン系配位子をもつイリジウム触媒による芳香族イオウ化合物のオルト位選択的C-Hボリル化 International conference

曾嘉林、鳥越尊、國信　洋一郎

第56回化学関連支部合同九州大会・外国人研究者交流国際シンポジウム 2019.7

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Event date： 2019.7

Language：Japanese Presentation type：Symposium, workshop panel (public)

Venue：北九州国際会議場 Country：Japan
Hydrogen Bond-Accelerated meta-Selective C-H Borylation of Aromatic Compounds and Expression of Substrate Specificity International conference

Xu Lu, Yusuke Yoshigoe, Yoichiro Kuninobu

2019.7

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Event date： 2019.7

Language：English Presentation type：Symposium, workshop panel (public)

Country：Japan
六員環ヘテロ芳香族化合物の2位選択的C–Hトリフルオロメチルチオ化反応の開発 International conference

牟田龍平、鳥越尊、國信　洋一郎

第56回化学関連支部合同九州大会・外国人研究者交流国際シンポジウム 2019.7

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Event date： 2019.7

Language：Japanese Presentation type：Symposium, workshop panel (public)

Venue：北九州国際会議場 Country：Japan
ポリマーを利用する蛍光色素ｰルイス酸間での平衡の調整によるマルチカラーおよび白色発光 International conference

森　敏彰、吉越　裕介、國信　洋一郎

第56回化学関連支部合同九州大会・外国人研究者交流国際シンポジウム 2019.7

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Event date： 2019.7

Language：Japanese Presentation type：Symposium, workshop panel (public)

Venue：北九州国際会議場 Country：Japan
Double C-H Silylation for the Synthesis of Silafluorenes by Borane Catalyst International conference

Yafang Dong, Yuta Takata, Kohei Sekine, Yusuke Yoshigoe, Yoichiro Kuninobu

2019.7

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Event date： 2019.7

Language：English Presentation type：Symposium, workshop panel (public)

Country：Japan
Hydrogen Bond-Accelerated meta-Selective C-H Borylation of Aromatic Compounds and Expression of Substrate Specificity International conference

Xu Lu, Yusuke Yoshigoe, @Haruka Ida, @Mitsumi Nishi, @Motomu Kanai, Yoichiro Kuninobu

2019.5

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Event date： 2019.5

Language：Japanese Presentation type：Symposium, workshop panel (public)

Country：Japan
ポリマーを利用する蛍光色素－ルイス酸間での平衡の調整によるマルチカラーおよび白色発光の制御

森　敏彰、吉越裕介、國信　洋一郎

第29回万有福岡シンポジウム 2019.5

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Event date： 2019.5

Language：Japanese Presentation type：Symposium, workshop panel (public)

Venue：九州大学馬出キャンパス Country：Japan
ベンゾフェノン誘導体とLewis酸の錯形成による蛍光材料の開発とポリマー担持による固体発光特性の評価

森　敏彰、吉越裕介、國信　洋一郎

三地区交歓会 2019.5

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Event date： 2019.5

Language：Japanese Presentation type：Oral presentation (general)

Venue：九州大学馬出キャンパス Country：Japan
キノリン類に対するC2位選択的なトリフルオロメチル化反応の開発

@白井孝宏、國信洋一郎、@金井求

日本薬学会第139年会 2019.3

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Event date： 2019.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：千葉、幕張メッセ Country：Japan
パラジウム触媒を用いた2,5-に置換イミダゾールのアリール化反応の開発

藤後貴也、相馬洋平、國信洋一郎、金井求

日本薬学会第139年会 2019.3

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Event date： 2019.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：千葉、幕張メッセ Country：Japan
水素結合部位をもつ配位子の改良によるメタ位選択的なC-Hボリル化反応の加速および基質特異性の発現

盧旭、吉越裕介、井田悠、西光海、金井求、國信洋一郎

日本化学会第99春季年会 2019.3

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Event date： 2019.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：甲南大学岡本キャンパス Country：Japan
６員環ヘテロ芳香族化合物の位置選択的なC-Hトリフルオロメチルチオ化反応の開発 Invited

牟田龍平、鳥越尊、國信洋一郎

日本化学会第99春季年会 2019.3

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Event date： 2019.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：甲南大学岡本キャンパス Country：Japan
非共有結合性相互作用を利用した蛍光材料の開発

森俊彰、吉越裕介、國信洋一郎

日本化学会第99春季年会 2019.3

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Event date： 2019.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：甲南大学岡本キャンパス Country：Japan
ボラン触媒を用いた二重シラFriedel-Crafts反応によるシラフルオレンの合成

高田雄大、吉越裕介、國信洋一郎

日本化学会第99春季年会 2019.3

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Event date： 2019.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：甲南大学岡本キャンパス Country：Japan
meta-Selective Functionalizations of Aromatic Compounds via Iridium-catalyzed C-H Borylation

Jie Wang, Takeru Torigoe, Yoichiro Kuninobu

2019.3

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Event date： 2019.3

Language：Japanese Presentation type：Oral presentation (general)

Country：Japan
含窒素芳香族化合物の位置選択的なC-Hトリフルオロメチルチオ化反応の開発

牟田龍平、鳥越尊、國信洋一郎

第45回有機典型元素化学討論会 2018.12

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Event date： 2018.12

Language：Japanese Presentation type：Oral presentation (general)

Venue：朱鷺メッセ：新潟コンベンションセンター Country：Japan
イリジウム触媒によるC-Hボリル化に基づく形式的なメタ位選択的C-H変換

鳥越尊、王杰、國信洋一郎

統合物質創製科学研究推進機構　第４回国内シンポジウム 2018.10

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Event date： 2018.10

Language：Japanese Presentation type：Oral presentation (general)

Venue：九州大学筑紫キャンパス Country：Japan
メタ位選択的なC-Hボリル化反応における反応の加速と基質特異性の発現

盧旭、吉越裕介、井田悠、西光海、金井求、國信洋一郎

統合物質創製科学研究推進機構　第４回国内シンポジウム 2018.10

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Event date： 2018.10

Language：Japanese Presentation type：Oral presentation (general)

Venue：九州大学筑紫キャンパス Country：Japan
非共有結合性相互作用による分極制御を利用したマルチカラー蛍光分子の開発

森敏彰、吉越裕介、山川健司、金井求、國信洋一郎

統合物質創製科学研究推進機構　第４回国内シンポジウム 2018.10

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Event date： 2018.10

Language：Japanese Presentation type：Oral presentation (general)

Venue：九州大学筑紫キャンパス Country：Japan
Formal meta-C-H Functionalizations via Iridium-catalyzed C-H Borylation

Jie Wang, Takeru Torigoe, Yoichiro Kuninobu

2018.9

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Event date： 2018.9

Language：English Presentation type：Oral presentation (general)

Country：Japan
Improvement of Ligands For ⅿeta-Selective C-H Borylation and Their Kinetics

盧旭、吉越裕介、@井田悠、@西光海、@金井求、國信洋一郎

第65回有機金属化学討論会 2018.9

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Event date： 2018.9

Language：English Presentation type：Oral presentation (general)

Venue：同志社大学今出川キャンパス Country：Japan
非共有結合性相互作用を利用する蛍光性π共役系化合物の分極制御と高機能化 International conference

森　敏彰、吉越　裕介、@山川　健司、@金井　求、國信　洋一郎

第55回化学関連支部合同九州大会・外国人研究者交流国際シンポジウム 2018.6

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Event date： 2018.6

Language：Japanese Presentation type：Oral presentation (general)

Venue：北九州国際会議場 Country：Japan
非共有結合性相互作用が引き起こす蛍光性π共役系分子の発光挙動変化

吉越裕介、@山川健司、@金井求、國信洋一郎

第28回万有福岡シンポジウム 2018.5

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Event date： 2018.5

Language：Japanese Presentation type：Oral presentation (general)

Venue：九州大学馬出キャンパス Country：Japan
Control of Solid-state Fluorescent Properties of π-Conjugated Molecules by Non-covalent Bonding

2018.3

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Event date： 2018.3

Language：English Presentation type：Oral presentation (general)

Venue：Funabashi campus, Nihon University Country：Japan
Photo-induced Coloring of ortho-Borylated 2-Phenylpyridines International conference

Yusuke Yoshigoe, @Yuji Suzaki, @Kohtaro Osakada, Yoichiro Kuninobu

2018.1

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Event date： 2018.1

Language：English Presentation type：Oral presentation (general)

Country：Japan
ホウ素化2‐フェニルピリジン類の固相相転移とその機構解明

吉越裕介, @須崎裕司、@小坂田耕太郎、國信洋一郎

統合物質創製化学研究推進機構　第3回国内シンポジウム 2017.10

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Event date： 2017.10

Language：Japanese Presentation type：Oral presentation (general)

Venue：京都大学、宇治キャンパス Country：Japan
ピコリン酸アミド配位子をもつパラジウム触媒によるアルデヒドと有機ハロゲン化物からのヘテロアリールケトン合成

@若木貴行、@藤後貴也、@吉留大輔、國信洋一郎、@金井求

第64回有機金属化学討論会 2017.9

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Event date： 2017.9

Language：Japanese Presentation type：Oral presentation (general)

Venue：東北大学川内キャンパス Country：Japan
安価な鉄塩によって触媒される2-フェニルピリジンのオルト位選択的C-Hホウ素化

吉越裕介, 國信洋一郎

第２９回若手研究者のためのセミナー 2017.8

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Event date： 2017.8 - 2018.8

Language：Japanese Presentation type：Oral presentation (general)

Venue：九州大学、伊都キャンパス Country：Japan
Noncovalent Bond-Controlled Regioselective C-H Borylation International conference

Yoichiro Kuninobu, @Haruka Ida, @Hong-Liang Li, @Mitsumi Nishi, @Motomu Kanai

OMCOS19 2017.6

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Event date： 2017.6 - 2018.6

Language：English Presentation type：Oral presentation (general)

Country：Korea, Republic of
アミロイドβを標的とした近赤外光で活性化可能な酸素化触媒の開発

@倪積智, @谷口敦彦, @小澤柊太, @堀由起子, @富田泰輔, 國信洋一郎, @相馬洋平, @金井求

日本薬学会第137年会 2017.3

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Event date： 2017.3 - 2018.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：仙台 Country：Japan
Aβ凝集阻害剤の創出を支援するC-Hカップリング反応の開発

@藤後貴也, @新谷卓士, @相馬洋平, 國信洋一郎, @金井求

日本薬学会第137年会 2017.3

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Event date： 2017.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：仙台 Country：Japan
パラジウム触媒によるC-H結合活性化を伴うアルデヒドとハロゲン化物からのケトン合成

@若木貴行, @藤後貴也, @吉留大輔, 國信洋一郎, @金井求

日本薬学会第137年会 2017.3

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Event date： 2017.3 - 2018.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：仙台 Country：Japan
Iron-Catalyzed Oxyalkylation of Styrenes Using Hypervalent Iodine Reagents

#Zijia Wang, @Motomu Kanai, Yoichiro Kuninobu

2017.3

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Event date： 2017.3

Language：English Presentation type：Oral presentation (general)

Country：Japan
ortho-Selective C-H Borylation of Aromatic Compounds Using Distal Functional Group

@Hongliang Li, Yoichiro Kuninobu, @Motomu Kanai

2017.3

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Event date： 2017.3

Language：English Presentation type：Oral presentation (general)

Country：Japan
イリジウム触媒を用いるピリジン類の４位選択的なC-H ホウ素化

@山川健司、國信洋一郎、@金井求

日本化学会第97春季年会 2017.3

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Event date： 2017.3

Language：Japanese Presentation type：Oral presentation (general)

Venue：慶應義塾大学　日吉キャンパス Country：Japan
マンガン触媒を用いたC-H 結合活性化反応に関するDFT 計算

@飯島千景・@坂田健・@末木俊輔・國信洋一郎

日本化学会第97春季年会 2017.3

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Event date： 2017.3

Language：Japanese Presentation type：Oral presentation (general)

Country：Japan
Development of Iron-Catalyzed C－H Borylation of 2-Phenylpyridines and Their Analogues and Optical Properties of The Products

日本化学会第97春季年会 2017.3

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Event date： 2017.3

Language：English Presentation type：Oral presentation (general)

Venue：慶應義塾大学　日吉キャンパス Country：Japan

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MISC

Regioselective C–H Trifluoromethylation and Its Related Reactions of (Hetero)aromatic Compounds Reviewed

2023.9

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Language：English

DOI： 10.1002/tcr.202300003

Other Link： https://onlinelibrary.wiley.com/doi/10.1002/tcr.202300003

Repository Public URL： https://hdl.handle.net/2324/7177951
Non-covalent Interaction-Controlled Site-selective C–H Transformations Reviewed

2023.9

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Language：English

DOI： 10.1002/tcr.202300149

Other Link： https://onlinelibrary.wiley.com/doi/10.1002/tcr.202300149

Repository Public URL： https://hdl.handle.net/2324/7174488
Regioselective C-H Trifluoromethylation of Heteroaromatic Compounds. Reviewed

Kuninobu, Y.*; Torigoe, T.

Bull. Chem. Soc. Jpn. 2021.2

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Language：English Publishing type：Article, review, commentary, editorial, etc. (scientific journal)

DOI： 10.1246/bcsj.20200302

Other Link： https://www.journal.csj.jp/doi/full/10.1246/bcsj.20200302
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発～新しい位置選択性制御法の創出：非共有結合性相互作用の利用～ Reviewed

國信　洋一郎

2020.6

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Language：Japanese Publishing type：Article, review, commentary, editorial, etc. (scientific journal)
有機溶媒がいらない!? －固体状態での高効率クロスカップリング反応

鳥越　尊、國信　洋一郎

化学 2020.6

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Language：Japanese Publishing type：Article, review, commentary, editorial, etc. (scientific journal)
Resent Progress on Transition Metal-catalysed Regioselective C–H Transformations Based on Noncovalent Interactions Reviewed

2020.5

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Language：Japanese Publishing type：Article, review, commentary, editorial, etc. (scientific journal)

DOI： 10.1002/adsc.202000306

Other Link： https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.202000306
Development of Novel C-H Bond Transformations and Their Application to the Synthesis of Organic Functional Molecules

Yoichiro Kuninobu

Synlett 2018.1

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Language：English

DOI： 10.1055/s-0037-1610531
Rhenium-Catalyzed ortho-Alkylation of Phenols

Kuninobu, Y.; @Yamamoto, M.; @Nishi, M.; @Yamamoto, T.; @Matsuki, T.; @Murai, M.; @Takai, K.

Org. Synth. 2017.11

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Language：English

DOI： 10.15227/orgsyn.094.0280
Cy-Ubpyの開発物語

國信　洋一郎

2017.9

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Language：Japanese Publishing type：Article, review, commentary, editorial, etc. (scientific journal)

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Industrial property rights

Patent	Number of applications: 2	Number of registrations: 1
Utility model	Number of applications: 0	Number of registrations: 0
Design	Number of applications: 0	Number of registrations: 0
Trademark	Number of applications: 0	Number of registrations: 0

Professional Memberships

The Chemical Society of Japan
The Society of Synthetic Organic Chemistry, Japan
The Pharmaceutical Society of Japan
Kinka Chemical Society, Japan
The Society of Physical Organic Chemistry, Japan
The Society of Silicon Chemistry JAPAN
The Society of Fluorine Chemistry, Japan
SIS the Society of Iodine Science
American Chemical Society

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Committee Memberships

Organizer Domestic

2020.1 - 2023.12
Executive Domestic

2020.1 - 2023.12
近畿化学協会有機金属部会幹事 Domestic

2020.1 - 2023.12
ケイ素化学協会理事 Domestic

2020.1 - 2023.12
Organizer Domestic

2020.1 - 2020.12
有機合成化学協会九州山口支部庶務幹事 Domestic

2020.1 - 2020.12
Organizer Domestic

2019.1 - 2019.12
有機合成化学協会九州山口支部会計幹事 Domestic

2019.1 - 2019.12
Organizer Domestic

2018.1 - 2018.12

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Academic Activities

Screening of academic papers

Role(s)： Peer review

2023

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Type：Peer review

Number of peer-reviewed articles in foreign language journals：11
Screening of academic papers

Role(s)： Peer review

2022

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Type：Peer review

Number of peer-reviewed articles in foreign language journals：14

Number of peer-reviewed articles in Japanese journals：0

Proceedings of International Conference Number of peer-reviewed papers：0

Proceedings of domestic conference Number of peer-reviewed papers：0
Screening of academic papers

Role(s)： Peer review

2021

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Type：Peer review

Number of peer-reviewed articles in foreign language journals：30

Number of peer-reviewed articles in Japanese journals：0

Proceedings of International Conference Number of peer-reviewed papers：0

Proceedings of domestic conference Number of peer-reviewed papers：0
世話人

有機合成化学協会九州山口支部有機合成化学講演会（オンライン） 2020.11

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Type：Competition, symposium, etc.
実行委員

ケイ素化学協会シンポジウム（オンライン） 2020.11

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Type：Competition, symposium, etc.
実行委員

第117回有機合成シンポジウム（オンライン） 2020.10

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Type：Competition, symposium, etc.
世話人 International contribution

第57回化学関連支部合同九州大会（北九州国際会議場） 2020.6

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Type：Competition, symposium, etc.
Screening of academic papers

Role(s)： Peer review

2020

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Type：Peer review

Number of peer-reviewed articles in foreign language journals：39

Number of peer-reviewed articles in Japanese journals：0

Proceedings of International Conference Number of peer-reviewed papers：0

Proceedings of domestic conference Number of peer-reviewed papers：0
共同世話人

ケイ素化学協会シンポジウム（宮崎シーガイア） 2019.11

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Type：Competition, symposium, etc.
世話人

有機合成化学協会九州山口支部　第31回若手研究者のためのセミナー（九州大学筑紫キャンパス） 2019.8

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Type：Competition, symposium, etc.
主催者

第１回機能分子化学若手シンポジウム（九州大学筑紫キャンパス） 2019.6

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Type：Competition, symposium, etc.
科学技術予測センター　専門調査員

Role(s)： Review, evaluation

2019.6 - 2022.3

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Type：Scientific advice/Review
Co-Organizer

（ Japan ） 2019.5

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Type：Competition, symposium, etc.
Screening of academic papers

Role(s)： Peer review

2019

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Type：Peer review

Number of peer-reviewed articles in foreign language journals：84

Number of peer-reviewed articles in Japanese journals：0

Proceedings of International Conference Number of peer-reviewed papers：0

Proceedings of domestic conference Number of peer-reviewed papers：0
共同世話人

近畿化学協会有機金属部会平成30年度第3回例会（九州大学馬出キャンパス） 2018.10

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Type：Competition, symposium, etc.
事務局長 International contribution

IRCCS-JST CREST Joint Symposium “Chemical Sciences facing a difficult challenge” （九州大学筑紫キャンパス） 2018.1

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Type：Competition, symposium, etc.
Screening of academic papers

Role(s)： Peer review

2018

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Type：Peer review

Number of peer-reviewed articles in foreign language journals：70

Number of peer-reviewed articles in Japanese journals：0

Proceedings of International Conference Number of peer-reviewed papers：0

Proceedings of domestic conference Number of peer-reviewed papers：0
Screening of academic papers

Role(s)： Peer review

2017

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Type：Peer review

Number of peer-reviewed articles in foreign language journals：63

Number of peer-reviewed articles in Japanese journals：0

Proceedings of International Conference Number of peer-reviewed papers：0

Proceedings of domestic conference Number of peer-reviewed papers：0
Screening of academic papers

Role(s)： Peer review

2016

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Type：Peer review

Number of peer-reviewed articles in foreign language journals：8

Number of peer-reviewed articles in Japanese journals：0

Proceedings of International Conference Number of peer-reviewed papers：0

Proceedings of domestic conference Number of peer-reviewed papers：0

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Research Projects

非共有結合性相互作用に着目した触媒の創製と高選択的C-H結合変換反応の開発

Grant number：24K01489 2024 - 2026

日本学術振興会科学研究費助成事業基盤研究(B)

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Authorship：Principal investigator Grant type：Scientific research funding
データサイエンスを利用する位置選択的かつエナンチオ選択的変換反応の開発

Grant number：22H05370 2022 - 2023

日本学術振興会・文部科学省科学研究費助成事業学術変革領域研究(A)

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Authorship：Principal investigator Grant type：Scientific research funding
有機機能性材料への利用を志向した湾曲π共役系分子の開発

2022 - 2023

松籟科学技術振興財団　研究助成

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Authorship：Principal investigator Grant type：Contract research
炭素－水素結合変換反応における位置および立体選択性制御法の創出

Grant number：21H01941 2021 - 2023

日本学術振興会科学研究費助成事業基盤研究(B)

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Authorship：Principal investigator Grant type：Scientific research funding
湾曲したナノグラフェン類および含ヘテロ原子π共役系分子の創製

2021 - 2022

徳山科学技術振興財団　2021年度研究助成

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Authorship：Principal investigator Grant type：Contract research
合成・分解再利用が容易な糖・糖鎖ポリマーの合成

2021

糖業協会　糖類に関する調査研究活動に対する助成事業

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Authorship：Principal investigator Grant type：Contract research
波長変換材料の開発

2020.4 - 2023.3

共同研究

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Authorship：Principal investigator Grant type：Other funds from industry-academia collaboration
触媒と環状分子とのハイブリッドによる高選択的有機合成反応の開発

Grant number：20H04824 2020 - 2021

日本学術振興会・文部科学省科学研究費助成事業新学術領域研究

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Authorship：Principal investigator Grant type：Scientific research funding
炭素-水素結合変換反応における位置選択性制御法の確立

2019 - 2020

山田科学振興財団2019年度研究援助

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Authorship：Principal investigator Grant type：Contract research
金属錯体/ホスト分子ハイブリッド触媒系の創製と選択的C-H変換反応の開発

Grant number：18H04656 2018 - 2019

日本学術振興会・文部科学省科学研究費助成事業新学術領域研究

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Authorship：Principal investigator Grant type：Scientific research funding
農業施設用部材や太陽電池を志向する高性能波長変換材料の開発

2018 - 2019

国立研究開発法人科学技術振興機構研究成果展開事業　A-STEP機能検証フェーズ

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Authorship：Principal investigator Grant type：Contract research
動的共有結合を利用する位置選択的な炭素－水素結合変換反応の開発

2018 - 2019

平成30年度三菱財団助成

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Authorship：Principal investigator Grant type：Contract research
超分子相互作用を利用する位置選択的フッ素系官能基化反応の開発

2018 - 2019

武田科学振興財団ライフサイエンス研究助成

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Authorship：Principal investigator Grant type：Contract research
π共役系内にLewis酸－塩基相互作用をもつ新規π共役系分子の創製

2018 - 2019

2018年度住友財団基礎科学研究助成

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Authorship：Principal investigator Grant type：Contract research
タンパク質をターゲットとする水系溶媒中での位置選択的な酸化反応の開発

2018 - 2019

内藤記念科学振興財団研究助成

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Authorship：Principal investigator Grant type：Contract research
固体でも水溶液でも光る蛍光材料の開発

2018

2018年度池谷科学振興財団　研究助成

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Authorship：Principal investigator Grant type：Contract research
ハロゲン結合により機能発現する蛍光性化合物の開発

2018

2018年度ヨウ素研究助成

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Authorship：Principal investigator Grant type：Contract research
非共有結合性相互作用による炭素－水素結合変換反応の位置選択性制御法の確立

Grant number：17H03016 2017 - 2019

日本学術振興会科学研究費助成事業基盤研究(B)

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Authorship：Principal investigator Grant type：Scientific research funding
位置選択的なトリフルオロメチル化反応の開発

Grant number：16K13946 2016 - 2017

科学研究費助成事業挑戦的萌芽研究

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Authorship：Principal investigator Grant type：Scientific research funding
医薬品合成を志向するC-Hトリフルオロメチル化反応の開発

2016 - 2017

公益財団法人薬学振興会　平成27年度基礎的研究助成

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Authorship：Principal investigator Grant type：Contract research
非共有結合性相互作用を利用する炭素－水素結合変換反応の開発

Grant number：26288014 2014 - 2016

日本学術振興会科学研究費助成事業基盤研究(B)

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Authorship：Principal investigator Grant type：Scientific research funding

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Class subject

有機金属化学

2024.10 - 2025.3 Second semester
有機機器分析

2024.4 - 2024.6 Spring quarter
機能有機化学

2024.4 - 2024.6 Spring quarter
有機金属化学

2023.10 - 2024.3 Second semester
総合理工学修士実験

2023.4 - 2024.3 Full year
総合理工学修士実験

2023.4 - 2024.3 Full year
総合理工学修士演習

2023.4 - 2024.3 Full year
物質理工学修士実験

2023.4 - 2024.3 Full year
物質理工学修士演習

2023.4 - 2024.3 Full year
物質理工学第一特別講究

2023.4 - 2024.3 Full year
総合理工学修士演習

2023.4 - 2024.3 Full year
総合理工学修士実験

2023.4 - 2024.3 Full year
総合理工学修士演習

2023.4 - 2024.3 Full year
機能有機化学

2023.4 - 2023.6 Spring quarter
有機機器分析 ei

2023.4 - 2023.6 Spring quarter
有機金属化学

2022.10 - 2023.3 Second semester
総合理工学修士実験

2022.4 - 2023.3 Full year
総合理工学修士演習

2022.4 - 2023.3 Full year
機能有機化学

2022.4 - 2022.6 Spring quarter
有機機器分析 ei

2022.4 - 2022.6 Spring quarter
有機金属化学

2021.10 - 2022.3 Second semester
物質理工学修士演習第一

2021.4 - 2022.3 Full year
物質理工学第一特別講究

2021.4 - 2022.3 Full year
物質理工学第一特別講究

2021.4 - 2022.3 Full year
物質理工学修士実験第一

2021.4 - 2022.3 Full year
機能有機化学

2021.4 - 2021.6 Spring quarter
有機機器分析 ei

2021.4 - 2021.6 Spring quarter
機能有機化学

2020.10 - 2021.3 Second semester
機能有機化学

2020.10 - 2021.3 Second semester
有機元素化学

2020.6 - 2020.8 Summer quarter
有機元素化学

2020.6 - 2020.8 Summer quarter
生体有機化学

2020.4 - 2021.3 Full year
生体有機化学

2020.4 - 2021.3 Full year
物質理工学修士実験第一

2020.4 - 2021.3 Full year
物質理工学修士演習第一

2020.4 - 2021.3 Full year
Experiments on Molecular and Material Sciences

2020.4 - 2021.3 Full year
Exercises on Molecular and Material Sciences

2020.4 - 2021.3 Full year
物質理工学修士実験第一

2020.4 - 2021.3 Full year
物質理工学修士演習第一

2020.4 - 2021.3 Full year
有機構造物性論

2020.4 - 2020.6 Spring quarter
有機構造物性論

2020.4 - 2020.6 Spring quarter
機能有機化学

2019.10 - 2020.3 Second semester
立体制御合成論

2019.4 - 2020.3 Full year
物質理工学修士実験第一

2019.4 - 2020.3 Full year
物質理工学修士演習第一

2019.4 - 2020.3 Full year
機能有機化学

2018.10 - 2019.3 Second semester
立体制御合成論

2018.4 - 2019.3 Full year
物質理工学修士演習第一

2018.4 - 2019.3 Full year
物質理工学修士実験第一

2018.4 - 2019.3 Full year
機能有機化学

2017.10 - 2018.3 Second semester
異分野特別演習

2017.10 - 2018.3 Second semester
立体制御合成論

2017.4 - 2018.3 Full year
物質理工学修士演習第一

2017.4 - 2018.3 Full year
物質理工学修士実験第一

2017.4 - 2018.3 Full year

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FD Participation

2024.10 Role：Moderator Title：先導研FD

Organizer：[Undergraduate school/graduate school/graduate faculty]
2023.3 Role：Participation Title：先導研FD

Organizer：[Undergraduate school/graduate school/graduate faculty]
2022.1 Role：Participation Title：先導研FD

Organizer：[Undergraduate school/graduate school/graduate faculty]
2021.1 Role：Participation Title：先導研FD

Organizer：[Undergraduate school/graduate school/graduate faculty]
2020.1 Role：Participation Title：第２回先導研FD

Organizer：[Undergraduate school/graduate school/graduate faculty]
2019.5 Role：Participation Title：第１回先導研FD

Organizer：[Undergraduate school/graduate school/graduate faculty]
2019.1 Role：Participation Title：第２回先導研FD

Organizer：[Undergraduate school/graduate school/graduate faculty]
2018.7 Role：Participation Title：第１回先導研FD

Organizer：[Undergraduate school/graduate school/graduate faculty]
2018.1 Role：Participation Title：第２回先導研FD

Organizer：[Undergraduate school/graduate school/graduate faculty]
2017.5 Role：Participation Title：第１回先導研FD

Organizer：[Undergraduate school/graduate school/graduate faculty]
2017.4 Role：Participation Title：新任教員研修

Organizer：University-wide

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Visiting, concurrent, or part-time lecturers at other universities, institutions, etc.

2022 京都大学大学院工学研究科 Classification:Part-time lecturer Domestic/International Classification:Japan

Semester, Day Time or Duration：2022年10月14日（金）
2021 福岡大学大学院理学研究科 Classification:Part-time lecturer Domestic/International Classification:Japan

Semester, Day Time or Duration：2021年9月14日（火）－15日（水）
2020 名古屋大学大学院工学研究科 Classification:Part-time lecturer Domestic/International Classification:Japan

Semester, Day Time or Duration：2020年10月9日
2019 東京大学大学院理学系研究科 Classification:Part-time lecturer Domestic/International Classification:Japan

Semester, Day Time or Duration：2019年12月5-6日