WU SHUQI
Organization
Institute for Materials Chemistry and Engineering Department of Fundamental Organic Chemistry Assistant Professor
Title
Assistant Professor
Contact information
Profile
新規光機能性物質の開発と教育
External link
ORCID
Degree
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Bachelor of Science Tsinghua University (China)
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Master of Science Tsinghua University (China)
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Doctor of Science
Research Interests・Research Keywords
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Research theme：With the trend of miniaturization of electronic devices, molecular materials with multifunctionality are generally regarded as potential candidates for next-generation information technology. Controlling the magnetic and electronic states by external stimuli will play a central role in this aspect. In our study, we design and synthesize molecular crystals with the electronic structures lying at the boundary of different local minima on the potential energy surfaces, aiming at realizing the controllable switching behavior and synergistic electric and magnetic field effects. Currently, the pyroelectric effect from the pure molecular origin (e.g. intramolecular electron transfer) has been observed in polar valence tautomerism crystals. Future work involves the development of light- and field-responsive dynamic polar crystalline materials.
Keyword：Molecular Magnetism; Molecular Pyroelectricity; Magneto-electric Coupling; Electronic Structure
Research period： 2021.2 - 2025.1
Papers
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Quenching and Restoration of Orbital Angular Momentum through a Dynamic Bond in a Cobalt(II) Complex Reviewed
Sheng-Qun Su, Shu-Qi Wu, Michael L. Baker, Peter Bencok, Nobuaki Azuma, Yuji Miyazaki, Motohiro Nakano, Soonchul Kang, Yoshihito Shiota, Kazunari Yoshizawa, Shinji Kanegawa, Osamu Sato
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 142 ( 26 ) 11434 - 11441 2020.7
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Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex Reviewed
Shu-Qi Wu, Meijiao Liu, Kaige Gao, Shinji Kanegawa, Yusuke Horie, Genki Aoyama, Hajime Okajima, Akira Sakamoto, Michael L. Baker, Myron S. Huzan, Peter Bencok, Tsukasa Abe, Yoshihito Shiota, Kazunari Yoshizawa, Wenhuang Xu, Hui-Zhong Kou, Osamu Sato
NATURE COMMUNICATIONS 11 ( 1 ) 2020.4
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Temperature dependence of spherical electron transfer in a nanosized [Fe-14] complex
Wei Huang, Shuqi Wu, Xiangwei Gu, Yao Li, Atsushi Okazawa, Norimichi Kojima, Shinya Hayami, Michael L. Baker, Peter Bencok, Mariko Noguchi, Yuji Miyazaki, Motohiro Nakano, Takumi Nakanishi, Shinji Kanegawa, Yuji Inagaki, Tatsuya Kawae, Gui-Lin Zhuang, Yoshihito Shiota, Kazunari Yoshizawa, Dayu Wu, Osamu Sato
NATURE COMMUNICATIONS 10 2019.12
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Electron-Transfer Activity in a Cyanide-Bridged Fe-42 Nanomagnet
Michael L. Baker, Shu-Qi Wu, Soonchul Kang, Satoshi Matsuzawa, Marie-Anne Arrio, Yasuo Narumi, Takumi Kihara, Tetsuya Nakamura, Yoshinori Kotani, Osamu Sato, Hiroyuki Nojiri
INORGANIC CHEMISTRY 58 ( 15 ) 10160 - 10166 2019.8
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Rhodamine 6G-Labeled Pyridyl Aroylhydrazone Fe(II) Complex Exhibiting Synergetic Spin Crossover and Fluorescence
Juan Yuan, Shu-Qi Wu, Mei-Jiao Liu, Osamu Sato, Hui-Zhong Kou
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140 ( 30 ) 9426 - 9433 2018.8
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Slow Magnetic Relaxation in a Mononuclear Ruthenium(III) Complex
Shu-Qi Wu, Yuji Miyazaki, Motohiro Nakano, Sheng-Qun Su, Zi-Shuo Yao, Hui-Zhong Kou, Osamu Sato
CHEMISTRY-A EUROPEAN JOURNAL 23 ( 42 ) 10028 - 10033 2017.7
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Anisotropic Change in the Magnetic Susceptibility of a Dynamic Single Crystal of a Cobalt(II) Complex
Zi-Shuo Yao, Shu-Qi Wu, Yasutaka Kitagawa, Sheng-Qun Su, You-Gui Huang, Guo-Ling Li, Zhong-Hai Ni, Hiroyuki Nojiri, Yoshihito Shiota, Kazunari Yoshizawa, Soonchul Kang, Shinji Kanegawa, Osamu Sato
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56 ( 3 ) 717 - 721 2017.1
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Development of an FeII Complex Exhibiting Intermolecular Proton Shifting Coupled Spin Transition. Reviewed International journal
Tianchi Ji, Shengqun Su, Shuqi Wu, Yuta Hori, Yasuteru Shigeta, Yubo Huang, Wenwei Zheng, Wenhuang Xu, Xiaopeng Zhang, Ryoji Kiyanagi, Koji Munakata, Takashi Ohhara, Takumi Nakanishi, Osamu Sato
Angewandte Chemie (International ed. in English) e202404843 2024.4
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Polar Crystals Using Molecular Chirality: Pseudosymmetric Crystallization toward Polarization Switching Materials Reviewed
Shinji Kanegawa, Shu-Qi Wu, Ziqi Zhou, Yoshihito Shiota, Takumi Nakanishi, Kazunari Yoshizawa, Osamu Sato
Journal of the American Chemical Society 2024.4
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Electrically Detectable Photoinduced Polarization Switching in a Molecular Prussian Blue Analogue. Reviewed International journal
Yu-Bo Huang, Jun-Qiu Li, Wen-Huang Xu, Wenwei Zheng, Xiaopeng Zhang, Kai-Ge Gao, Tianchi Ji, Taisuke Ikeda, Takumi Nakanishi, Shinji Kanegawa, Shu-Qi Wu, Sheng-Qun Su, Osamu Sato
Journal of the American Chemical Society 146 ( 1 ) 201 - 209 2024.1
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Magnetoelectricity Enhanced by Electron Redistribution in a Spin Crossover [FeCo] Complex Reviewed
Xiaopeng Zhang, Wen-Huang Xu, Wenwei Zheng, Sheng-Qun Su, Yu-Bo Huang, Qirui Shui, Tianchi Ji, Mikoto Uematsu, Qian Chen, Masashi Tokunaga, Kaige Gao, Atsushi Okazawa, Shinji Kanegawa, Shu-Qi Wu, Osamu Sato
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 145 ( 29 ) 15647 - 15651 2023.7
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Energy conversion and storage via photoinduced polarization change in non-ferroelectric molecular [CoGa] crystals Reviewed
Pritam Sadhukhan, Shu-Qi Wu, Shinji Kanegawa, Sheng-Qun Su, Xiaopeng Zhang, Takumi Nakanishi, Jeremy Ian Long, Kaige Gao, Rintaro Shimada, Hajime Okajima, Akira Sakamoto, Joy G. Chiappella, Myron S. Huzan, Thomas Kroll, Dimosthenis Sokaras, Michael L. Baker, Osamu Sato
Nature Communications 14 ( 1 ) 3394 2023.6
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Aggregation-induced emission meets magnetic bistability: Synergy between spin crossover and fluorescence in iron(II) complexes Reviewed
Yao Li, Mohammad Khurram Javed, Shu-Qi Wu, Arshia Sulaiman, Ying-Ying Wu, Zhao-Yang Li, Osamu Sato, Xian-He Bu
Chinese Chemical Letters 34 ( 4 ) 107492 - 107492 2023.4
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Macroscopic Polarization Change of Mononuclear Valence Tautomeric Cobalt Complexes Through the Use of Enantiopure Ligand Reviewed
Feng Cheng, Shuqi Wu, Wenwei Zheng, Shengqun Su, Takumi Nakanishi, Wenhuang Xu, Pritam Sadhukhan, Hibiki Sejima, Shimon Ikenaga, Kaoru Yamamoto, Kaige Gao, Shinji Kanegawa, Osamu Sato
28 ( 59 ) 2022.8
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Fluorescence emission modulation in cyanido-bridged Fe(II) spin crossover coordination polymers Reviewed
Xue-Ru Wu, Zhi-Kun Liu, Min Zeng, Ming-Xing Chen, Jun Tao, Shu-Qi Wu, Hui-Zhong Kou
Science China Chemistry 65 ( 8 ) 1569 - 1576 2022.7
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Photoinduced Persistent Polarization Change in a Spin Transition Crystal. Reviewed International journal
Sheng-Qun Su, Shu-Qi Wu, Yu-Bo Huang, Wen-Huang Xu, Kai-Ge Gao, Atsushi Okazawa, Hajime Okajima, Akira Sakamoto, Shinji Kanegawa, Osamu Sato
Angewandte Chemie (International ed. in English) e202208771 2022.7
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Tuning of spin-crossover behavior in two cyano-bridged mixed-valence (Fe2FeII)-Fe-III trinuctear complexes based on a Tp(R) tigand
Arshia Sulaiman, Yi-Zhan Jiang, Mohammad Khurram Javed, Shu-Qi Wu, Zhao-Yang Li, Xian-He Bu
INORGANIC CHEMISTRY FRONTIERS 9 ( 2 ) 241 - 248 2022.1
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A Molecular Crystal Shows Multiple Correlated Magnetic and Ferroelectric Switchings Reviewed
Yun Li, Shu-Qi Wu, Jin-Peng Xue, Xiao-Lei Wang, Osamu Sato, Zi-Shuo Yao, Jun Tao
CCS Chemistry 3 ( 9 ) 2464 - 2472 2021.9
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Manipulating electron redistribution to achieve electronic pyroelectricity in molecular [FeCo] crystals. International journal
Pritam Sadhukhan, Shu-Qi Wu, Jeremy Ian Long, Takumi Nakanishi, Shinji Kanegawa, Kaige Gao, Kaoru Yamamoto, Hajime Okajima, Akira Sakamoto, Michael L Baker, Thomas Kroll, Dimosthenis Sokaras, Atsushi Okazawa, Norimichi Kojima, Yoshihito Shiota, Kazunari Yoshizawa, Osamu Sato
Nature communications 12 ( 1 ) 4836 - 4836 2021.8
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Adjusting Rotational Behavior of Molecular Rotors by a Rational Tuning of Molecular Structure
Hui-Miao Li, Gui-Ming Zhong, Shu-Qi Wu, Osamu Sato, Xiao-Yan Zheng, Zi-Shuo Yao, Jun Tao
INORGANIC CHEMISTRY 60 ( 11 ) 8042 - 8048 2021.6
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Water-oriented magnetic anisotropy transition Invited Reviewed International journal
Sheng-Qun Su, Shu-Qi Wu, #Masato Hagihala, #Ping Miao, #Zhijian Tan, #Shuki Torii, #Takashi Kamiyama, #Tongtong Xiao, #Zhenxing Wang, #Zhongwen Ouyang, #Yuji Miyazaki, #Motohiro Nakano, Takumi Nakanishi, @Jun-Qiu Li, Shinji Kanegawa, Osamu Sato,
Nat. Commun. 2021.5
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Water-oriented magnetic anisotropy transition. Reviewed International journal
Sheng-Qun Su, Shu-Qi Wu, Masato Hagihala, Ping Miao, Zhijian Tan, Shuki Torii, Takashi Kamiyama, Tongtong Xiao, Zhenxing Wang, Zhongwen Ouyang, Yuji Miyazaki, Motohiro Nakano, Takumi Nakanishi, Jun-Qiu Li, Shinji Kanegawa, Osamu Sato
Nature communications 12 ( 1 ) 2738 - 2738 2021.5
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Three-Step Spin State Transition and Hysteretic Proton Transfer in the Crystal of an Iron(II) Hydrazone Complex Reviewed
Takumi Nakanishi, Yuta Hori, Shuqi Wu, Hiroyasu Sato, Atsushi Okazawa, Norimichi Kojima, Yusuke Horie, Hajime Okajima, Akira Sakamoto, Yoshihito Shiota, Kazunari Yoshizawa, Osamu Sato
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 59 ( 35 ) 14781 - 14787 2020.8
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Giant Single-Crystal Shape Transformation with Wide Thermal Hysteresis Actuated by Synergistic Motions of Molecular Cations and Anions Reviewed
Xiao-Lei Wang, Jin-Peng Xue, Xiao-Peng Sun, Yan-Xin Zhao, Shu-Qi Wu, Zi-Shuo Yao, Jun Tao
CHEMISTRY-A EUROPEAN JOURNAL 26 ( 30 ) 6778 - 6783 2020.5
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Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex Invited Reviewed International journal
Shu-Qi Wu, @Meijiao Liu, @Kaige Gao, Shinji Kanegawa, @Yusuke Horie, @Genki Aoyama, @Hajime Okajima, @Akira Sakamoto, @Michael L. Baker, @Myron S. Huzan, @Peter Bencok, Tsukasa Abe, Yoshihito Shiota, Kazunari Yoshizawa, #Wenhuang Xu, @Hui-Zhong Kou, Osamu Sato
Nature Communications 2020.4
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Effect of Axial Ligands on Easy-Axis Anisotropy and Field-Induced Slow Magnetic Relaxation in Heptacoordinated Fe-II Complexes
Arpan Mondal, Shu-Qi Wu, Osamu Sato, Sanjit Konar
CHEMISTRY-A EUROPEAN JOURNAL 26 ( 21 ) 4780 - 4789 2020.4
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Manipulating Slow Magnetic Relaxation by Light in a Charge Transfer {Fe2Co} Complex
Junqiu Li, Shuqi Wu, Shengqun Su, ShinjShinji Kanegawa, Osamu Sato
CHEMISTRY-A EUROPEAN JOURNAL 26 ( 15 ) 3259 - 3263 2020.3
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Structural Modulation of Fluorescent Rhodamine-Based Dysprosium(III) Single-Molecule Magnets
Mei-Jiao Liu, Shu-Qi Wu, Jia-Xin Li, Yi-Quan Zhang, Osamu Sato, Hui-Zhong Kou
INORGANIC CHEMISTRY 59 ( 4 ) 2308 - 2315 2020.2
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Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal
Zi-Shuo Yao, Hanxi Guan, Yoshihito Shiota, Chun-Ting He, Xiao-Lei Wang, Shu-Qi Wu, Xiaoyan Zheng, Sheng-Qun Su, Kazunari Yoshizawa, Xueqian Kong, Osamu Sato, Jun Tao
NATURE COMMUNICATIONS 10 2019.10
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Observation of Proton Transfer Coupled Spin Transition and Trapping of Photoinduced Metastable Proton Transfer State in an Fe(II) Complex
Takumi Nakanishi, Yuta Hori, Hirorsu Sato, Shu-Qi Wu, Atsushi Okazawa, Norimichi Kojima, Takashi Yamamoto, Yasuaki Einaga, Shinya Hayami, Yusuke Horie, Hajime Okajima, Akira Sakamoto, Yoshihito Shiota, Kazunari Yoshizawa, Osamu Sato
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 141 ( 36 ) 14384 - 14393 2019.9
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Substituent effects on the fluorescent spin-crossover Fe(ii) complexes of rhodamine 6G hydrazones
Juan Yuan, Mei-Jiao Liu, Shu-Qi Wu, Xin Zhu, Nan Zhang, Osamu Sato, Hui-Zhong Kou
INORGANIC CHEMISTRY FRONTIERS 6 ( 5 ) 1170 - 1176 2019.5
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Selective CO2 Capture and High Proton Conductivity of a Functional Star-of-David Catenane Metal-Organic Framework
You-Gui Huang, Shu-Qi Wu, Wei-Hua Deng, Gang Xu, Fa-Lu Hu, Jonathan P. Hill, Wei Wei, Sheng-Qun Su, Lok Kumar Shrestha, Osamu Sato, Ming-Yan Wu, Mao-Chun Hong, Katsuhiko Ariga
ADVANCED MATERIALS 29 ( 42 ) 2017.11
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Field-Induced Slow Magnetic Relaxation in an Octacoordinated Fe(II) Complex with Pseudo-D-2d Symmetry: Magnetic, HF-EPR, and Theoretical Investigations
Guo-Ling Li, Shu-Qi Wu, Li-Fang Zhang, Zhenxing Wang, Zhong-Wen Ouyang, Zhong-Hai Ni, Sheng-Qun Su, Zi-Shuo Yao, Jun-Qiu Li, Osamu Sato
INORGANIC CHEMISTRY 56 ( 14 ) 8018 - 8025 2017.7
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Influence of Intermolecular Interactions on Valence Tautomeric Behaviors in Two Polymorphic Dinuclear Cobalt Complexes
Guo-Ling Li, Shinji Kanegawa, Zi-Shuo Yao, Sheng-Qun Su, Shu-Qi Wu, You-Gui Huang, Soonchul Kang, Osamu Sato
CHEMISTRY-A EUROPEAN JOURNAL 22 ( 48 ) 17130 - 17135 2016.11
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Thermally Induced Intra-Carboxyl Proton Shuttle in a Molecular Rack-and-Pinion Cascade Achieving Macroscopic Crystal Deformation
You-Gui Huang, Yoshihito Shiota, Sheng-Qun Su, Shu-Qi Wu, Zi-Shuo Yao, Guo-Ling Li, Shinji Kanegawa, Soonchul Kang, Takashi Kamachi, Kazunari Yoshizawa, Katsuhiko Ariga, Osamu Sato
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55 ( 47 ) 14628 - 14632 2016.11
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Metallogrid Single-Molecule Magnet: Solvent-Induced Nuclearity Transformation and Magnetic Hysteresis at 16 K
Wei Huang, Fu-Xing Shen, Shu-Qi Wu, Li Liu, Dayu Wu, Zhe Zheng, Jun Xu, Ming Zhang, Xing-Cai Huang, Jun Jiang, Feifei Pan, Yao Li, Kun Zhu, Osamu Sato
INORGANIC CHEMISTRY 55 ( 11 ) 5476 - 5484 2016.6
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Superior thermoelasticity and shape-memory nanopores in a porous supramolecular organic framework
You-Gui Huang, Yoshihito Shiota, Ming-Yan Wu, Sheng-Qun Su, Zi-Shuo Yao, Soonchul Kang, Shinji Kanegawa, Guo-Ling Li, Shu-Qi Wu, Takashi Kamachi, Kazunari Yoshizawa, Katsuhiko Ariga, Mao-Chun Hong, Osamu Sato
NATURE COMMUNICATIONS 7 2016.5
Presentations
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Giant Magnetic Field-Induced Polarization Switching in a Heterometallic Spin Crossover Complexes International conference
Shu-Qi Wu, Xiaopeng Zhang, Wen-Huang Xu, Wenwei Zheng, Shinji Kanegawa and Osamu Sato
18th International Conference on Molecule-Based Magnets 2023.10
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Electronic pyroelectricity in valence tautomeric complexes International conference
@Shu-Qi Wu, @Pritam Sadhukhan, @Shinji Kanegawa, @Osamu Sato
8th Asian Conference on Coordination Chemistry 2022.8
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Molecular Pyroelectricity via Directional Electron Transfer in Valence Tautomeric Complexes International conference
Shu-Qi Wua, Pritam Sadhukhana, Shinji Kanegawaa, Osamu Sato
17th International Conference on Molecule Based Magnets 2021.6
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Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex International conference
Shu-Qi Wu, Shinji Kanegawa, Osamu Sato
4th IRCCS International Symposium 2021.3
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Macroscopic Polarization Change via Electron Transfer in a Valence Tautomeric Cobalt Complex International conference
Shu-Qi Wu, Shinji Kanegawa, Osamu Sato
1st Asian Conference on Molecular Magnetism 2021.3
Research Projects
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Achieving large polarization change induced by magnetic field in molecular crystals
Grant number：24K17698 2024 - 2026
Japan Society for the Promotion of Science Grants-in-Aid for Scientific Research Early-Career Scientists
Authorship：Principal investigator Grant type：Scientific research funding
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Photoelectric Energy Conversion and Controlled Energy Release via Intramolecular Electron Transfer in Polar Materials
Grant number：0351039-A 2023 - 2024
Grants-in-Aid for Scientific Research
Authorship：Principal investigator Grant type：Competitive funding other than Grants-in-Aid for Scientific Research
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Magnetic Field-Induced Polarization Change in Molecular Crystals
Grant number：22K14694 2022 - 2024
Japan Society for the Promotion of Science Grants-in-Aid for Scientific Research Early-Career Scientists
Authorship：Principal investigator Grant type：Scientific research funding
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統合物質創製化学研究推進機構「融合創発研究」研究費 Control of Polarization in Molecular Materials by External Stimuli
2021
科学研究費助成事業
Grant type：Competitive funding other than Grants-in-Aid for Scientific Research
Educational Activities
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Teaching the physical concepts in molecular magnetism and theoretical calculations; discussing experimental plans and providing suggestions and comments to students.
FD Participation
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2020.4 Title：FD Conference
Organizer：[Undergraduate school/graduate school/graduate faculty]