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写真a

セリャンチン ロマン
SELYANCHYN ROMAN
SELYANCHYN ROMAN
所属
エネルギー研究教育機構 准教授
職名
准教授
連絡先
メールアドレス
電話番号
0928026723
プロフィール
1)エネルギー分野に関連する教育・研究の企画、調整、支援。研究者、学生、一般市民を対象に、九州大学が行うエネルギー研究の推進を行う。[60%のエフォート] 2) 超薄膜を用いたガス分離に関する基礎的・応用的研究(主に産業混合物からの二酸化炭素回収(CCS)および大気からの直接回収(DAC)を対象とする。[40%のエフォート] 。
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学位

  • 修士(物理)、Uzhhorod National University (ウクライナ)

  • 博士(工学)、北九州市立大学

経歴

  • Assistant professor, International Institute for Carbon-Neutral Energy Research, Kyushu University, Japan /March 2019 - March 2022 WPI Researcher, International Institute for Carbon-Neutral Energy Research, Kyushu University, Japan /January 2014 - February 2019 Post-doctoral researcher, The University of Kitakyushu, Japan /April 2012 - December 2013/ Clinical Trial Site Study coordinator, Uzhgorod National University, Ukraine /August 2005 - December 2008/ Engineer, Uzhgorod National University, Ukraine /September 2002 - August 2005/   

研究テーマ・研究キーワード

  • 研究テーマ: 様々なエネルギー応用のため、再生可能で持続可能なナノバイオマテリアルを用いた膜の研究

    研究キーワード: イオン交換膜、燃料電池、プロトン交換膜、ナノセルロース

    研究期間: 2016年1月

  • 研究テーマ: 持続可能なエネルギーとサステイナブルな環境のためのガス分離膜の研究

    研究キーワード: 二酸化炭素、ガス分離膜、CO2選択制、ナノ界面、金属有機構造体

    研究期間: 2014年1月

論文

  • Continuous direct air capture and methanation using combined system of membrane-based CO2 capture and Ni-Ca based dual functional materials 査読 国際誌

    Lingcong Li, Shinta Miyazaki, Ziyang Wu, Takashi Toyao, Roman Selyanchyn, Zen Maeno, Shigenori Fujikawa, Ken-ichi Shimizu

    Applied Catalysis B: Environmental   ( 123151 )   2023年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    Direct CO2 capture from the air by membranes (membrane-based DAC, m-DAC) is a promising new technique to achieve CO2 net zero emissions. In addition, a continuous system for CO2 capture and its reduction by hydrogen using coupled reactors has scarcely been investigated. In this study, a new continuous system consisting of a m-DAC and a methanation process (m-DAC-M) was developed. For methanation, Ni nanoparticles supported on Ca-loaded Al2O3 (Ni-Ca/Al2O3; 10 wt% Ni and 6 wt% CaO) were utilized as a dual functional material (DFM). The Ni-Ca/Al2O3 exhibited high CH4 productivity and selectivity, good stability over 100 h, and high humidity resistance properties at a low reaction temperature of 350 °C. The catalytic properties of Ni-Ca/Al2O3 were elucidated using microscopic and spectroscopic techniques. The characterization results indicated that the CaO species not only served as CO2 adsorption sites to trap concentrated CO2 from the m-DAC system but also improved the reducibility of oxidized Ni species in the hydrogenation period, thereby promoting the reduction of surface carbonate species to CH4.

    DOI: 10.1016/j.apcatb.2023.123151

    その他リンク: https://www.sciencedirect.com/science/article/pii/S0926337323007944

  • A new strategy for membrane-based direct air capture. 招待 査読 国際誌

    Shigenori Fujikawa, Roman Selyanchyn, Toyoki Kunitake

    Polym. J. (Tokyo, Jpn.)   53 ( 1 )   219   2021年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    ABSTRACT: Direct CO2 capture from the air, so-called direct air capture (DAC), has become inevitable to reduce the concentration of CO2 in the atmosphere. Current DAC technologies consider only sorbent-based systems. Recently, there have been reports that show ultrahigh CO2 permeances in gas separation membranes and thus membrane separation could be a potential new technology for DAC in addition to sorbent-based CO2 capture. The simulation of chemical processes has been well established and is commonly used for the development and performance assessment of industrial chemical processes. These simulations offer a credible assessment of the feasibility of membrane-based DAC (m-DAC). In this paper, we discuss the potential of m-DAC considering the state-of-the-art performance of organic polymer membranes. The multistage membrane separation process was employed in process simulation to estimate the energy requirements for m-DAC. Based on the analysis, we propose the target membrane separation performance required for m-DAC with competitive energy expenses. Finally, we discuss the direction of future membrane development for DAC.

    DOI: 10.1038/s41428-020-00440-4

    その他リンク: https://www.nature.com/articles/s41428-020-00429-z

  • Critical role of the molecular interface in double-layered Pebax-1657/PDMS nanomembranes on highly efficient CO2/N2 gas separation 査読 国際誌

    #Olena Selyanchyn, Roman Selyanchyn, Shigenori Fujikawa

    ACS Applied Materials and Interfaces   2020年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    ABSTRACT: In this work, we deposited a CO2-selective block copolymer, Pebax-1657, as a selective layer with a thickness of 2–20 nm on the oxygen plasma-activated surface of poly(dimethylsiloxane) (PDMS) used as a gutter layer (thickness ∼400 nm). This double-layered structure was subsequently transferred onto the polyacrylonitrile (PAN) microporous support and studied for CO2/N2 separation. The effect of interfacial molecular arrangements between the selective and gutter layers on CO2 permeance and selectivity has been investigated. We have revealed that the gas permeance and selectivity do not follow the conventional theoretical predictions for the multilayer membrane (resistance in series transport model); specifically, more selective CO2/N2 separation membranes were achieved with ultrathin selective layers. Detailed characterization of the chemical structure of the outermost membrane surface suggests that nanoscale blending of the ultrathin Pebax-1657 layer with O2 plasma-activated PDMS chains on the surface takes place. This nanoblending at the interface between the selective and gutter layers played a critical role in enhancing the CO2/N2 selectivity. CO2 permeances in the developed thin-film composite membranes (TFCM) were between 1200 and 3500 gas permeance units (GPU) and the respective CO2/N2 selectivities were between 72 and 23, providing the gas separation performance suitable for CO2 capture in postcombustion processes. This interpenetrating polymer interface enhanced the overall selectivity of the membrane significantly, exceeding the separation ability of the pristine Pebax-1657 polymer.

    DOI: 10.1021/acsami.0c07344

    その他リンク: https://pubs.acs.org/doi/abs/10.1021/acsami.0c07344

  • Fabrication of novel mixed matrix polymer electrolyte membranes (PEMs) intended for renewable hydrogen production <i>via</i> electrolysis application

    Mokete, R; Miksik, F; Selyanchyn, R; Takata, N; Thu, K; Miyazaki, T

    ENERGY ADVANCES   3 ( 5 )   1019 - 1036   2024年5月   eISSN:2753-1457

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    出版者・発行元:Energy Advances  

    Hydrogen gas is among the sustainable energy forms that counteract the energy crisis. Polymer electrolyte membranes (PEMs) derived from biomass fillers and polyvinyl-based matrix blends have been fabricated and applied in H2 generation through electrolysis. Faradaic efficiencies ranging from 82.8 ± 1.9% to 88.9 ± 1.6% were exhibited when voltages of 6.5 V, 8 V and 10 V were applied; thus, proton conduction and hence H2 generation commenced at 2-2.5 V. The apparent morphology of the PEMs that verified the incorporation of pine bark (PB) and Chinese Tallow Seed Capsule (CT) fillers was visible as surface bumps and internal cavities within the PEMs. Although the proton conductivity of Nafion™ 115's (NF-M) was 23.94 mS cm−1, those of the fabricated PEMs (PB-M, CT-M and SSA-M) were 1.33, 0.46 and 0.48 mS cm−1, respectively. The PB-M exhibited good characteristics, including functional groups and water adsorption; thus, H2 production was achieved, but losses such as bubble production affected efficiency. This study presents a cost-effective alternative for H2 production that can be used in diverse applications.

    DOI: 10.1039/d3ya00503h

    Web of Science

    Scopus

  • Controlling Microstructure–Transport Interplay in Poly(ether-block-amide) Multiblock Copolymer Gas Separation Membranes 査読 国際誌

    Sinan Feng, Yokajaksusri Nutthon, Hiroyasu Masunaga, Sono Sasaki, Roman Selyanchyn, Shigenori Fujikawa, Shinichi Murata, and Atsushi Takahara

    Langmuir   39 ( 49 )   17879 - 17888   2023年11月

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    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

    In this study, we investigated the effect of morphology on the gas-transport properties of a poly(ether-block-amide) (PEBA) multiblock copolymer. We annealed the copolymer samples and varied the annealing temperature to evaluate the influence of changes in the microstructure on the gas transport properties of PEBA. In addition, we used time-resolved attenuated total reflection Fourier transform infrared spectroscopy to evaluate the diffusion coefficient of CO2 in PEBA based on the Fickian model. The effect of the annealing temperature on the microphase-separated structure of the multiblock copolymer is discussed in detail. Furthermore, the gas diffusivity was significantly affected by the purity of the soft domains. The annealed sample demonstrated a 38% increase in CO2 permeability while maintaining a high CO2/N2 permselectivity of approximately 53. The findings of this study provide valuable insight into the design and optimization of PEBA membranes for gas separation applications.

    DOI: 10.1021/acs.langmuir.3c02516

    その他リンク: https://pubs.acs.org/doi/full/10.1021/acs.langmuir.3c02516

  • Carbon molecular sieve membranes fabricated at low carbonization temperatures with novel polymeric acid porogen for light gas separation 招待 査読 国際誌

    Hongfang Guo, Jing Wei, Yulei Ma, Zikang Qin, Xiaohua Ma, Roman Selyanchyn, Bangda Wang, Xuezhong He, Bo Tang, Lin Yang, Lu Yao, Wenju Jiang, Yuanfa Zhuang, Dengguo Yin, Xue Li, Zhongde Dai

    SEPARATION AND PURIFICATION TECHNOLOGY   317   2023年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.seppur.2023.123883

    その他リンク: https://www.sciencedirect.com/science/article/pii/S1383586623007918

  • Cellulose Nanocrystals Crosslinked with Sulfosuccinic Acid as Sustainable Proton Exchange Membranes for Electrochemical Energy Applications 招待 査読 国際誌

    Olena Selyanchyn, Thomas Bayer, Dino Klotz, Roman Selyanchyn, Kazunari Sasaki, Stephen Matthew Lyth

    MEMBRANES   12 ( 7 )   2022年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    Nanocellulose is a sustainable material which holds promise for many energy-related applications. Here, nanocrystalline cellulose is used to prepare proton exchange membranes (PEMs). Normally, this nanomaterial is highly dispersible in water, preventing its use as an ionomer in many electrochemical applications. To solve this, we utilized a sulfonic acid crosslinker to simultaneously improve the mechanical robustness, water-stability, and proton conductivity (by introducing -SO3−H+ functional groups). The optimization of the proportion of crosslinker used and the crosslinking reaction time resulted in enhanced proton conductivity up to 15 mS/cm (in the fully hydrated state, at 120 °C). Considering the many advantages, we believe that nanocellulose can act as a sustainable and low-cost alternative to conventional, ecologically problematic, perfluorosulfonic acid ionomers for applications in, e. fuel cells and electrolyzers.

    DOI: 10.3390/membranes12070658

  • Direct air capture by membranes 招待 査読 国際誌

    Shigenori Fujikawa and Roman Selyanchyn

    MRS BULLETIN   2022年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1557/s43577-022-00313-6

  • Achieving a Carbon Neutral Future through Advanced Functional Materials and Technologies 査読 国際誌

    A. Chapman, E. Ertekin , M. Kubota, A. Nagao, K. Bertsch, A. Macadre, T. Tsuchiyama, T. Masamura, S. Takaki, R. Komoda, M. Dadfarnia, B. Somerday, A. Staykov, J. Sugimura, Y. Sawae, T. Morita, H. Tanaka, K. Yagi, V. Niste, P. Saravanan, S. Onitsuka, K.S. Yoon, S. Ogo, T. Matsushima, G. Tumen-Ulzii, Dino Klotz, D. H. Nguyen, G. Harrington, C. Adachi, H. Matsumoto, L. Kwati, Y. Takahashi, N. Kosem, T. Ishihara, M. Yamauchi, B. Saha, Md. A. Islam, J. Miyawaki, H. Sivasankaran, M. Kohno, S. Fujikawa, R. Selyanchyn, T. Tsuji, Y. Higashi, R. Kirchheim, and P.Sofronis

    Bulletin of the Chemical Society of Japan   95 ( 1 )   73 - 103   2022年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1246/bcsj.20210323

    その他リンク: https://www.journal.csj.jp/doi/full/10.1246/bcsj.20210323

  • Hydrogen sulfide removal from natural gas using membrane technology: a review 査読 国際誌

    Yulei Ma, Hongfang Guo, Roman Selyanchyn, Bangda Wang, Liyuan Deng, Zhongde Dai, Xia Jiang

    JOURNAL OF MATERIALS CHEMISTRY A   9 ( 36 )   20211 - 20240   2021年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    ABSTRACT: Natural gas, having a significantly lower CO2 emission factor than oil and coal when combusted, is accepted as an important transition fuel towards carbon net-zero society. To meet the calorific value requirements (≥34.0 MJ m−3) and reduce possible corrosion of transportation pipelines, acid gases such as CO2 and H2S must be removed from raw natural gas. Membrane separation is a promising alternative approach to removing acid gases from natural gas. This paper aims to review the development of various polymer-based membranes and membrane processes for H2S separation from natural gas. Progress in glassy polymer membranes, rubbery polymer membranes, hybrid membranes, and membrane contactors for H2S removal from natural gas are summarized and analyzed. The H2S separation performance of various membranes are plotted in one diagram and a new H2S/CH4 upper bound is proposed. Challenges of membranes for H2S separation and prospects of future development are thoroughly discussed.

    DOI: 10.1039/d1ta04693d

    その他リンク: https://pubs.rsc.org/en/content/articlehtml/2021/ta/d1ta04693d

  • Thermal and Gas Adsorption Properties of Troger's Base/Diaza-cyclooctane Hybrid Ladder Polymers. 招待 査読 国際誌

    Keiki Inoue, Roman Selyanchyn, Shigenori Fujikawa, Fumitaka Ishiwari, Takanori Fukushima

    ChemNanoMat   7 ( 7 )   824 - 830   2021年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    ABSTRACT: A polymer of intrinsic microporosity (PIM) consisting of Tröger's base (TB) undergoes ring-opening of the bicyclic amine upon N-methylation followed by alkaline hydrolysis, resulting in a hybrid ladder polymer that contains diazacyclooctane (DACO) units with tert- and sec-amino groups. The hybrid ladder polymers with various TB/DACO ratios can be prepared depending on the reaction conditions. Here we report a systematic study on the effect of DACO content on the thermal and gas adsorption properties of the hybrid ladder polymer. Using a PIM derived from 2,5-diamino-p-xylene, we prepared hybrid ladder polymers with a DACO content ranging from 19% to 55% while having a similar molecular weight. The thermal stability of the hybrid ladder polymers, evaluated by thermogravimetric analysis, is decreased with the increase in DACO content. Based on gas adsorption measurements, the increase in DACO content results in the decrease in the BET surface area but improves the gas adsorption selectivity for CO2 against N2, likely due to the high basicity of the sec-amino group of DACO unit. This result demonstrates that the partial TB-to-DACO conversion of the TB-based PIM may provide a simple but useful strategy to design polymer materials that enable selective CO2 capture and/or separation.

    DOI: 10.1002/cnma.202100151

    その他リンク: https://onlinelibrary.wiley.com/doi/full/10.1002/cnma.202100151

  • “Artificial Wood” Lignocellulosic Membranes: Influence of Kraft Lignin on the Properties and Gas Transport in Tunicate-Based Nanocellulose Composites 査読 国際誌

    Ievgen Pylypchuk, Roman Selyanchyn, Tetyana Budnyak,Yadong Zhao, Mikael Lindström, Shigenori Fujikawa, Olena Sevastyanova

    MEMBRANES   11 ( 3 )   2021年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    ABSTRACT: Nanocellulose membranes based on tunicate-derived cellulose nanofibers, starch, and ~5% wood-derived lignin were investigated using three different types of lignin. The addition of lignin into cellulose membranes increased the specific surface area (from 5 to ~50 m2/g), however, the fine porous geometry of the nanocellulose with characteristic pores below 10 nm in diameter remained similar for all membranes. The permeation of H2, CO2, N2, and O2 through the membranes was investigated and a characteristic Knudsen diffusion through the membranes was observed at a rate proportional to the inverse of their molecular sizes. Permeability values, however, varied significantly between samples containing different lignins, ranging from several to thousands of barrers (10−10 cm3 (STP) cm cm−2 s−1 cmHg −1), and were related to the observed morphology and lignin distribution inside the membranes. Additionally, the addition of ~5% lignin resulted in a significant increase in tensile strength from 3 GPa to ~6–7 GPa, but did not change thermal properties (glass transition or thermal stability). Overall, the combination of plant-derived lignin as a filler or binder in cellulose–starch composites with a sea-animal derived nanocellulose presents an interesting new approach for the fabrication of membranes from abundant bio-derived materials. Future studies should focus on the optimization of these types of membranes for the selective and fast transport of gases needed for a variety of industrial separation processes.

    DOI: 10.3390/membranes11030204

    その他リンク: https://www.mdpi.com/2077-0375/11/3/204

  • Spray deposition of sulfonated cellulose nanofibers as electrolyte membranes in fuel cells 査読 国際誌

    Thomas Bayer, Benjamin Vaughan Cunning, Břetislav Šmíd, Roman Selyanchyn, Shigenori Fujikawa, Kazunari Sasaki, Stephen Matthew Lyth

    CELLULOSE   28 ( 3 )   1355 - 1367   2021年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    ABSTRACT: Nanocellulose is a promising new membrane material for fuel cells, with a much lower cost and environmental impact compared with Nafion or Aquivion. It is mechanically strong, is an excellent hydrogen barrier, and has reasonable proton conductivity. Here, sulfonation of cellulose nanofibers is performed to enhance the conductivity (up to 2 × 10− 3 S cm− 1) without compromising the membrane integrity, and fuel cells are fabricated with 30 µm-thick “paper” membranes. The hydrogen crossover current is two orders of magnitude lower than for Nafion fuel cells with equivalent thickness, but the power density is rather low. Spray-coating is used to deposit 8 µm-thick membranes directly onto the electrocatalyst layer, in a process analogous to 3D printing or additive manufacturing. The resulting paper fuel cell has a high current density (> 0.8 A cm− 2) and power density (156 mW cm− 2) under standard measurement conditions (H2/air; 80°C; 95% RH; 0.1 MPa), attributed to decreased membrane resistance. The cost of the spray-painted cellulose membranes is calculated to be ~ 50 $ m− 2, which is much lower than that of Nafion, even without taking into consideration economies of scale. This new concept in electrochemical energy conversion paves the way for the mass production of affordable, recyclable fuel cells.

    DOI: 10.1007/s10570-020-03593-w

    その他リンク: https://link.springer.com/article/10.1007/s10570-020-03593-w

  • A Review of Proton Conductivity in Cellulosic Materials 招待 査読 国際誌

    #Olena Selyanchyn, Roman Selyanchyn, Stephen M. Lyth

    FRONTIERS IN ENERGY RESEARCH   8   2020年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    ABSTRACT: Cellulose is derived from biomass and is useful in a wide range of applications across society, most notably in paper and cardboard. Nanocellulose is a relatively newly discovered variant of cellulose with a much smaller fibril size, leading to unique properties such as high mechanical strength. Meanwhile, electrochemical energy conversion in fuel cells will be a key technology in the development of the hydrogen economy, but new lower-cost proton exchange membrane (PEM) materials are needed. Nanocellulose has emerged as a potential candidate for this important application. In this review, we summarize scientific developments in the area of cellulosic materials with special emphasis on the proton conductivity, which is the most important parameter for application in PEMs. We cover conventional cellulose and nanostructured cellulose materials, polymer composites or blends, and chemically modified cellulose. These developments are critically reviewed, and we identify interesting trends in the literature data. Finally, we speculate on future directions for this field.

    DOI: 10.3389/fenrg.2020.596164

  • Ultra-fast, selective CO2 permeation by free-standing siloxane nanomembranes 査読 国際誌

    Shigenori Fujikawa, Miho Ariyoshi, Roman Selyanchyn, Toyoki Kunitake

    Chemistry Letters   48 ( 11 )   1351 - 1354   2019年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    ABSTRACT: Fabrication and gas permselective behavior of free-standing polydimethylsiloxane (PDMS) nanomembranes is discussed. The largest CO2 permeance is close to 40,000 GPU (the highest one ever reported) at 34-nm membrane thickness without losing the CO2/N2 selectivity of 10-12, indicating the formation of pin-hole free nanomembranes.

    DOI: 10.1246/cl.190558

    その他リンク: https://doi.org/10.1246/cl.190558

  • The effect of oxygen on the tribology of (PEI/GO)15 multilayer solid lubricant coatings on steel substrates 査読

    Prabakaran Saravanan, Roman Selyanchyn, Hiroyoshi Tanaka, Shigenori Fujikawa, Stephen Matthew Lyth, Joichi Sugimura

    Wear   432-433   2019年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    ABSTRACT: Multilayers of polyethyleneimine and graphene oxide, (PEI/GO)15, were coated onto steel substrates via electrostatic layer-by-layer (LbL) deposition, and their tribological properties were investigated as solid lubricants. The coefficient of friction (COF) and specific wear rate (SWR) were measured against a poly(methyl methacrylate) (PMMA) counterface ball, in various gas environments with different oxygen concentrations. The COF and SWR both significantly decreased with decreasing oxygen content. Detailed surface characterization of the contact area of the counterface ball revealed that continuous transfer films were formed in oxygen-free environments, but not in oxygen-rich environments. This is attributed to an increased proportion of sp3 bonding in the wear debris in the presence of oxygen (as confirmed by Raman spectroscopy), as well as possible suppression of wear debris adhesion on the counterface ball due to oxygen adsorption on the surface.

    DOI: 10.1016/j.wear.2019.05.035

    その他リンク: https://doi.org/10.1016/j.wear.2019.05.035

  • Molecular Hybridization of Polydimethylsiloxane with Zirconia for Highly Gas Permeable Membranes 査読 国際誌

    Roman Selyanchyn, Shigenori Fujikawa

    ACS Applied Polymer Materials   1 ( 5 )   1165 - 1174   2019年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    ABSTRACT: Inorganic–organic nanocomposite hybrids containing zirconium dioxide (ZrO2) as inorganic cross-linker/filler and polydimethylsiloxane (PDMS) as a polymeric matrix have been synthesized using the in situ sol-gel reaction between silanol-terminated PDMS and zirconium normal butoxide (Zr(OC4H9)4). Hybrid materials were used to fabricate gas separation membranes which were characterized by scanning electron microscopy, dynamic scanning calorimetry, nanoindentation, ATR-FTIR, and XPS spectroscopies. The amorphous structure of incorporated ZrO2 fillers was verified by X-ray diffraction. Small gases (He, H2, O2, N2, and CO2) permeability experiments were carried out to study the effect of the inorganic component amount on the properties of the ZrO2@PDMS hybrids. The permeability of the developed hybrids considerably exceeded the permeability of conventional PDMS which is known as “gold standard” highly gas-permeable rubbery polymer. Depending on the ZrO2 content, fabricated hybrids demonstrated increased permeability for all gases with improvement inversely proportional to the kinetic diameter of gas molecules, that is, the highest permeability increase (relatively to PDMS) was observed for H2 and lowest for N2. Such behavior suggests the formation of the size-sieving amorphous zirconia domains within PDMS which do not impede gas transport due to the nanosize of the fillers. As a result, gas separation membranes prepared using the developed materials demonstrated better separation performance for CO2/N2, H2/N2, and O2/N2 pairs compared to the conventional PDMS.

    DOI: 10.1021/acsapm.9b00178

    その他リンク: https://pubs.acs.org/doi/10.1021/acsapm.9b00178

  • Study of Gases Permeation in Necklace-Shaped Dimethylsiloxane Polymers Bearing POSS Cages 査読

    Roman Selyanchyn, Shigenori Fujikawa, Naohiro Katsuta, Kazuya Suwa, Masashi Kunitake

    Membranes   9 ( 4 )   1   2019年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    The transport of small gases (H2, CO2, N2, O2) through a series of novel membranes based on necklace-shaped inorganic polymers (DMS@POSS), in which a polyhedral oligomeric silsesquioxane (POSS) cage unit and soft chains of oligo-dimethyl siloxane (DMS) were alternately connected, was investigated. The influence of the DMS chain length and crosslinking density of the DMS@POSS on membrane properties were studied. The membranes revealed characteristic structure-property relation towards both glass transition and gases transport. Specifically, a clear dependence of properties from the length of DMS units (or overall siloxane content) was revealed. Gas transport properties, when compared to state-of-art polydimethylsiloxane and commercial silicone rubber, demonstrated significantly higher selectivity of DMS@POSS for carbon dioxide (in CO2/N2), hydrogen (in H2/N2) and oxygen (in O2/N2) but lowered permeability, proportional to the amount of POSS in the material. With precise control over mechanical and thermal properties compared to conventional silicone rubbers, described materials could be considered as materials of choice in niche gas separation or other applications.

  • Thickness effect on CO2/N2 separation in double layer Pebax-1657®/PDMS membranes 招待 査読 国際誌

    Roman Selyanchyn, Miho Ariyoshi, Shigenori Fujikawa

    Membranes   8 ( 4 )   2018年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.3390/membranes8040121

    その他リンク: https://www.mdpi.com/2077-0375/8/4/121

  • Ultra-low friction of polyethylenimine / molybdenum disulfide (PEI/MoS2)15 thin films in dry nitrogen atmosphere and the effect of heat treatment 招待 査読 国際誌

    Prabakaran Saravanan, Roman Selyanchyn, Motonori Watanabe, Shigenori Fujikawa, Hiroyoshi Tanaka, Stephen Matthew Lyth, JoichiSugimura

    Tribology International   127   255 - 263   2018年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.triboint.2018.06.003

    その他リンク: https://www.sciencedirect.com/science/article/pii/S0301679X18302895

  • Porphyrin-nanoassembled fiber-optic gas sensor fabrication: Optimization of parameters for sensitive ammonia gas detection 招待 査読 国際誌

    Sergiy Korposh, Suguru Kodaira, Roman Selyanchyn, Francisco H. Ledezma, Stephen W. James, Seung-Woo Lee

    Optics & Laser Technology   101   1 - 10   2018年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.optlastec.2017.10.027

  • Development of polymer-polymer type charge-transfer blend membranes for fuel cell application 査読 国際誌

    Shiyan Feng, Shoichi Kondo, Takahiro Kaseyama, Taichi Nakazawa, Takamasa Kikuchi, Roman Selyanchyn, Shigenori Fujikawa, Liana Christiani, Kazunari Sasaki, Masamichi Nishihara

    Journal of Membrane Sciences   548   223 - 231   2018年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/j.memsci.2017.11.025

    その他リンク: https://www.sciencedirect.com/science/article/pii/S0376738817325140

  • Preparation of large, ultra-flexible and free-standing nanomembranes of metal oxide–polymer composite and their gas permeation properties 査読

    Anteneh Mersha, Roman Selyanchyn, Shigenori Fujikawa

    Clean Energy   1 ( 1 )   80 - 89   2017年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    In this work, fabrication of free-standing nanomembranes of metal oxide (MOx) and polymers by the simple spin-coating method is discussed. First, double-layer nanomembranes containing MOx and epoxy resin of polyethyleneimine and poly[(o-cresyl glycidyl ether)-co-formaldehyde] were prepared. Free-standing nanomembranes were successfully prepared, but defects formed in the metal oxide nanolayer during sharp bending of the nanomembrane. To overcome the fragility of MOx nanolayer, poly(vinyl alcohol) nanolayers were introduced between MOx nanolayers by layer-by-layer (LbL) assembly process. The LbL nanomembrane was also free-standing and was highly flexible during macroscopic membrane manipulations. Even after the transfer of the LbL nanomembrane onto a porous support, it did not have apparent cracks, confirmed by scanning electron microscopy (SEM). The LbL nanomembrane sustained low gas permeance, confirming the absence of significant defects, although it shows excellent flexibility. We believe that the presented LbL nanomembrane could be a platform useful for the design of molecular nanochannels, which is the next challenge for efficient gas separation.

  • Ultra-low friction between polymers and graphene oxide multilayers in nitrogen atmosphere, mediated by stable transfer film formation 査読

    Prabakaran Saravanan, Roman Selyanchyn, Hiroyoshi Tanaka, Shigenori Fujikawa, Stephen Matthew Lyth, Joichi Sugimura

    Carbon   122   395 - 403   2017年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    The efficiency and lifetime of mechanical devices is significantly decreased by friction and wear, significantly contributing to global energy consumption. We previously showed that multilayer polyethyleneimine/graphene oxide thin films, (PEI/GO)15, on steel display superlubricity against a steel counterface ball. Here, the coefficient of friction (COF) and wear of (PEI/GO)15 with six different counterface polymer balls is investigated in air and in nitrogen, with particular focus on the formation of tribological transfer films. The polymers polyoxymethylene (POM), polyetheretherketone (PEEK), polyethylene (PE), poly(methyl methacrylate) (PMMA), polycarbonate (PC), and polytetrafluoroethylene (PTFE) are utilized. The COF of (PEI/GO)15 vs steel is 0.35 in both air and nitrogen. In air, the COF ranges from 0.06 to 0.17 for all polymers. Significantly, in nitrogen, four polymers (POM, PEEK, PMMA and PC) display ultra-low friction (COF ∼0.02) whilst two do not (PTFE and PE). The wear tracks and transfer films are investigated using e.g. optical microscopy, electron microscopy, and Raman mapping, and the tribological behavior is correlated to the hydrophilicity and relative hardness of the polymer balls compared to GO.

    DOI: 10.1016/j.carbon.2017.06.090

  • Membrane thinning for efficient CO2 capture 招待 査読 国際誌

    Roman Selyanchyn, Shigenori Fujikawa

    Science and Technology of Advanced Materials   18 ( 1 )   816 - 827   2017年9月

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  • Spray-painted graphene oxide membrane fuel cells 査読 国際誌

    Thomas Bayer, Roman Selyanchyn, Shigenori Fujikawa, Kazunari Sasaki, Stephen M. Lyth

    Journal of Membrane Science   541   347 - 357   2017年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    Graphene oxide (GO) is potentially a useful electrolyte material for polymer electrolyte membrane fuel cells due to its high strength, excellent hydrogen gas barrier properties, hydrophilicity, and proton conducting acidic functional groups. Here, GO paper is prepared from aqueous dispersion by vacuum-filtration, and the hydrogen permeability (2 × 10−2 barrer) is measured to be 3 orders of magnitude lower than Nafion (30 barrer) at 30 °C. The in-plane and through-plane conductivities are measured to be 49.9 and 0.3 mS cm−1, respectively. This significant anisotropy is attributed to the lamellar structure of GO, and the physical anisotropy between the thickness and lateral size of the GO nanoplatelets. Interestingly, the in-plane conductivity of GO is comparable to the through-plane conductivity of Nafion. GO membrane fuel cells (GOMFCs) are fabricated. To compensate for the low in-plane conductivity of GO, whilst taking advantage of the excellent hydrogen gas barrier properties, extremely thin electrode-supported GOMFCs are prepared by spray painting GO directly onto the electrocatalyst layer. The effect of membrane thickness on cell performance is investigated. Decreasing membrane thickness by spray painting improves the power density from 3.7 mW cm−2 for a 50 μm-thick membrane-supported GOMFC, to 79 mW cm−2 for a 3 µm-thick, spray-painted membrane, electrode-supported GOMFC.

    DOI: 10.1016/j.memsci.2017.07.012

  • Macroscale Superlubricity of Multilayer Polyethylenimine/Graphene Oxide Coatings in Different Gas Environments 査読

    Prabakaran Saravanan, Roman Selyanchyn, Hiroyoshi Tanaka, Durgesh Darekar, Aleksandar Staykov, Shigenori Fujikawa, Stephen Matthew Lyth, Joichi Sugimura

    ACS Applied Materials and Interfaces   8 ( 40 )   27179 - 27187   2016年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    Friction and wear decrease the efficiency and lifetimes of mechanical devices. Solving this problem will potentially lead to a significant reduction in global energy consumption. We show that multilayer polyethylenimine/graphene oxide thin films, prepared via a highly scalable layer-by-layer (LbL) deposition technique, can be used as solid lubricants. The tribological properties are investigated in air, under vacuum, in hydrogen, and in nitrogen gas environments. In all cases the coefficient of friction (COF) significantly decreased after application of the coating, and the wear life was enhanced by increasing the film thickness. The COF was lower in dry environments than in more humid environments, in contrast to traditional graphite and diamond-like carbon films. Superlubricity (COF < 0.01) was achieved for the thickest films in dry N2. Microstructural analysis of the wear debris revealed that carbon nanoparticles were formed exclusively in dry conditions (i.e., N2, vacuum), and it is postulated that these act as rolling asperities, decreasing the contact area and the COF. Density functional theory (DFT) simulations were performed on graphene oxide sheets under pressure, showing that strong hydrogen bonding occurs in the presence of intercalated water molecules compared with weak repulsion in the absence of water. It is suggested that this mechanism prevents the separation graphene oxide layers and subsequent formation of nanostructures in humid conditions.

    DOI: 10.1021/acsami.6b06779

  • High temperature proton conduction in nanocellulose membranes Paper fuel cells 査読

    Thomas Bayer, Benjamin V. Cunning, Roman Selyanchyn, Masamichi Nishihara, Shigenori Fujikawa, Kazunari Sasaki, Stephen M. Lyth

    Chemistry of Materials   28 ( 13 )   4805 - 4814   2016年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    Polymer electrolyte membrane fuel cells are an efficient and clean alternative power source, but high cost impedes widespread commercialization. The fuel cell membrane, e.g., Nafion, contributes significantly to this cost, and therefore, novel alternatives are required. Temperature is also an important factor; high temperature operation leads to faster reaction kinetics, lower electrocatalyst loading, and improved water management, thereby further reducing cost. However, higher temperature puts greater demands on the membrane. Conductivity is related strongly to humidification, and therefore, this generally decreases above 100 °C. Nanocellulose membranes for fuel cells in which the proton conductivity increases up to 120 °C are reported here for the first time. The hydrogen barrier properties are far superior to conventional ionomer membranes. Fuel cells with nanocellulose membranes are successfully operated at 80 °C. Additionally, these membranes are environmentally friendly and biodegradable.

    DOI: 10.1021/acs.chemmater.6b01990

  • Alkaline anion exchange membranes based on KOH-treated multilayer graphene oxide 査読

    Thomas Bayer, Benjamin V. Cunning, Roman Selyanchyn, Takeshi Daio, Masamichi Nishihara, Shigenori Fujikawa, Kazunari Sasaki, Stephen M. Lyth

    Journal of Membrane Science   508   51 - 61   2016年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    A novel class of alkaline anion exchange membrane (AAEM) is presented, in the form of KOH-modified multilayer graphene oxide paper (GOKOH). Such membranes can be easily fabricated at large scale with varying thickness using conventional filtration techniques, and have high tensile strength (24.5 MPa). However, a large degree of swelling is observed. SEM investigations show that the morphology of GO changes after KOH-treatment, whilst XPS measurements and XRD analysis confirm successful chemical modification. The hydrogen gas permeability is several orders of magnitude lower than conventional polymer-based ionomer membranes. The maximum anion conductivity is 6.1 mS/cm at 70 °C, and the dominant charge carrier is confirmed to be OH- by utilization of anion and proton-conducting blocking layers. The ion exchange capacity is 6.1 mmol/g, measured by titration. A water-mediated reverse Grotthuss-like mechanism is proposed as the main diffusion mode of OH- ions. Finally, a prototype AAEM fuel cell is fabricated using a GOKOH membrane, confirming the applicability to real systems.

    DOI: 10.1016/j.memsci.2016.02.017

  • Incorporation of CO2 philic moieties into a TiO2 nanomembrane for preferential CO2 separation 査読 国際誌

    Roman Selyanchyn, Aleksandar Staykov, Shigenori Fujikawa

    RSC Advances   6 ( 91 )   88664 - 88667   2016年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    Here we report a preferential CO2 separation membrane consisting of a nanometer-thick TiO2 layer incorporated with phtalic acid (PA) molecules on polydimethylsiloxane (PDMS) (PA@TiO2/PDMS). Incorporated PAs in TiO2 act as CO2-philic pores for preferential CO-2 permeation over nitrogen. CO2 binding to the PA incorporated in TiO2 is confirmed by the density functional theory calculation (DFT). As a result, membranes with of PA@TiO2 layer demonstrated much higher selectivity to CO2 for mixed CO2/N2 gas separation compared to a conventional PDMS membrane. The exceptional selectivity of the composite layer alone (>150) was estimated by a resistance model.

    DOI: 10.1039/c6ra18419g

  • Detection of ammonia in human breath using quartz crystal microbalance sensors with functionalized mesoporous SiO2 nanoparticle films 査読

    Yusuke Ogimoto, Roman Selyanchyn, Naoki Takahara, Shunichi Wakamatsu, Seung Woo Lee

    Sensors and Actuators, B: Chemical   215   428 - 436   2015年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    Quartz crystal microbalance (QCM) sensors with porous films comprising silica nanoparticles and poly(allylamine hydrochloride) (PAH) were fabricated. The films were deposited via an electrostatic self-assembly method, and they exhibited considerable sensitivity to relative humidity. The infusion of poly(acrylic acid) (PAA) into multi-layer porous films (5 or 10 cycles) enabled the construction of a highly sensitive and selective QCM sensor device for the detection of gaseous ammonia. Two types of QCM sensors, with and without PAA, were used as sensors for the simultaneous quantitative detection of humidity and ammonia. A comprehensive Fourier transform infrared (FTIR) investigation of the fabricated films was conducted to elucidate the mechanism of the chemical interaction at the sensor device interface. Preliminary tests were conducted to detect low concentrations of ammonia in human breath, which are of clinical relevance. The results of these tests showed that the sensor can detect ammonia in human breath at pathological levels (greater than 3 ppm).

    DOI: 10.1016/j.snb.2015.03.103

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講演・口頭発表等

  • Gas separation membranes and membrane process for direct air capture of carbon dioxide 招待

    Roman Selyanchyn and Shigenori Fujikawa

    SCEJ 89th Annual Meeting  2024年3月 

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    開催年月日: 2024年3月

    記述言語:日本語  

    開催地:Osaka Metropolitan University (Nakamozu Campus)   国名:日本国  

    その他リンク: https://www4.scej.org/meeting/89a/en_index.html

  • Optimization of the gas separation nanomembrane device and separation process for the direct air capture of carbon dioxide 国際会議

    Roman Selyanchyn and Shigenori Fujikawa

    MRM2023/IUMRS-ICA2023  2023年12月 

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    開催年月日: 2023年12月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Kyoto International Conference Center   国名:日本国  

    その他リンク: https://mrm2023.jmru.org/

  • Exploring the feasibility of membrane technology for direct air capture 国際会議

    Roman Selyanchyn and Shigenori Fujikawa

    13th International Congress on Membranes and Membrane Processes  2023年7月 

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    開催年月日: 2023年7月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Makuhari Messe, Chiba   国名:日本国  

    その他リンク: https://icom2023.jp/index.html

  • CO2 preconcentration from air with the aid of membranes and its potential for distributed CO2 utilization systems 国際会議

    Roman Selyanchyn

    Mirai 2.0 Sweden-Japan joint workshop "Research and Innovation week"  2022年11月 

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    開催年月日: 2022年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Kyushu University, Japan   国名:日本国  

  • Development of the membranes for the CO2 separation from air based on the CO2 selective NbOFFIVE-1-Ni metal-organic framework 国際会議

    Roman Selyanchyn, Shigenori Fujikawa

    Material Research Society Fall meeting  2021年12月 

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    開催年月日: 2021年12月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Online   国名:アメリカ合衆国  

  • Utilization of molecular interface between polymer layers for better CO2/N2 separation by thin-film composite membranes 国際会議

    Roman Selyanchyn, Olena Selyanchyn and Shigenori Fujikawa

    Pacifichem 2021  2021年12月 

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    開催年月日: 2021年12月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Online   国名:アメリカ合衆国  

  • Efficient CO2 capture by free-standing polysiloxane nanomembranes 国際会議

    Shigenori Fujikawa, Roman Selyanchyn, Miho Ariyoshi, Toyoki Kunitake

    Pacifichem 2021  2021年12月 

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    開催年月日: 2021年12月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Online   国名:アメリカ合衆国  

  • A New Strategy of Negative Carbon Emissions by Nanomembranes for Ubiquitous CO2 Capture 招待 国際会議

    Shigenori Fujikawa, Roman Selyanchyn, Miho Ariyoshi, Toyoki Kunitake

    Material Research Society Fall meeting  2021年12月 

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    開催年月日: 2021年12月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Online   国名:アメリカ合衆国  

  • Interface-governed, highly efficient CO2/N2 gas separation in thin-film composite nanomembranes 国際会議

    Roman Selyanchyn, Olena Selyanchyn and Shigenori Fujikawa

    2020年12月 

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    開催年月日: 2021年10月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Online   国名:グレートブリテン・北アイルランド連合王国(英国)  

    Gas separation membranes suitable for economically feasible post-combustion CO2 capture should combine the moderate CO2/N2 selectivity (20-60) with a substantial values of CO2 permeances (>1000 GPU). Most the membranes tailored to have these properties are so-called thin-film composite membranes (TFCM) containing different layers it structure, each having a specific function (porous support, gutter, selective, protective layer). Due to the highest resistance towards gas transport, selective layers in TFCM are commonly fabricated with thicknesses below 100 nm. In this work, in order to achieve high CO2 permeances in TFCM we have fabricated ultra-thin selective layers (2-20 nm) composed of well-known hydrophilic and CO2-selective block-copolymer (Pebax MH-1657). It was deposited on the O2-plasma-activated surface of a much thicker (~400 nm) gutter layer composed of polydimethylsiloxane (PDMS). The structure was subsequently transferred on the polyacrylonitrile (PAN) microporous support to complete the TFCM. We have found that contrary to the theoretical predictions (resistance in the series model) for the layered membrane, highly selective CO2/N2 separation membrane was achieved in the TFCM with ultra-thin selective layer. The critical role to achieve this selectivity was attributed to the specific interface formed between selective and gutter layers which were controlled by the duration of oxygen plasma treatment (PDMS activation). Permeances of CO2 in the developed TFCM were between 1000-3000 GPU and CO2/N2 selectivities between 30-100, providing the gas separation parameters that are within the optimal range for cost-efficient CO2 capture in post-combustion processes. Detailed characterization of the interface revealed the chemical structure of the outermost membrane surface suggesting the blending of the ultra-thin Pebax-1657 layer with the activated surface of PDMS. This nano-thick blend layer contributed to the overall selectivity of the membrane significantly exceeding the selectivity that can be achieved by Pebax-1657 alone. The formed interface demonstrates stable gas separation with a moderate change of performance over one year.

  • Mixed matrix membranes containing highly CO2 selective ultramicroporous NbOFFIVE-1-Ni fillers: influence of particle size and content on CO2/N2 separation 国際会議

    Roman Selyanchyn

    International Congress on Membranes and Membrane Processes (ICOM-2020)  2020年12月 

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    開催年月日: 2020年12月

    記述言語:英語  

    開催地:Online   国名:グレートブリテン・北アイルランド連合王国(英国)  

  • Prussian blue nanomembranes on porous supports: growth mechanism and gas separation 国際会議

    Roman Selyanchyn, #Risa Okeda, #Keisuke Kanakogi, Shigenori Fujikawa, Nobuo Kimizuka

    2019年3月 

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    開催年月日: 2019年3月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Sixth International Conference of Multifunctional, Hybrid and Nanomaterials   国名:日本国  

    その他リンク: https://www.elsevier.com/events/conferences/international-conference-on-multifunctional-hybrid-and-nanomaterials

  • In-situ formation of molecularly dispersed ZrO2 in polydimethylsiloxane for highly gas permeable membranes 国際会議

    Roman Selyanchyn, Shigenori Fujikawa

    2019年3月 

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    開催年月日: 2019年3月

    記述言語:英語  

    開催地:Sixth International Conference of Multifunctional, Hybrid and Nanomaterials   国名:スペイン  

    その他リンク: https://www.elsevier.com/events/conferences/international-conference-on-multifunctional-hybrid-and-nanomaterials

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産業財産権

特許権   出願件数: 1件   登録件数: 1件
実用新案権   出願件数: 0件   登録件数: 0件
意匠権   出願件数: 0件   登録件数: 0件
商標権   出願件数: 0件   登録件数: 0件

所属学協会

  • Materials Research Society (MRS)

  • American Chemical Society (ACS)

学術貢献活動

  • 学術論文等の審査

    役割:査読

    2023年

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    種別:査読等 

    外国語雑誌 査読論文数:10

    日本語雑誌 査読論文数:0

    国際会議録 査読論文数:0

    国内会議録 査読論文数:0

  • 学術論文等の審査

    役割:査読

    2022年

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    種別:査読等 

    外国語雑誌 査読論文数:10

  • 学術論文等の審査

    役割:査読

    2021年

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    種別:査読等 

    外国語雑誌 査読論文数:8

  • 学術論文等の審査

    役割:査読

    2020年

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    種別:査読等 

    外国語雑誌 査読論文数:7

  • 学術論文等の審査

    役割:査読

    2019年

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    種別:査読等 

    外国語雑誌 査読論文数:7

共同研究・競争的資金等の研究課題

  • Study of molecular interfaces in polymer thin-film composite membranes for the efficient gas separations

    研究課題/領域番号:22K04806  2022年 - 2025年

    日本学術振興会  科学研究費助成事業  基盤研究(C)

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    担当区分:研究代表者  資金種別:科研費

  • 施設園芸農業におけるスマートCO2回収・利用の実現に向けたスタートアップ共創研究

    2022年 - 2024年

    Q-PIT module research collaborative projects

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    担当区分:研究分担者  資金種別:学内資金・基金等

  • CO2分離の高効率化を目指した混合マトリックス膜中の多孔質金属有機構造体の微細化.

    2021年 - 2022年

    岩谷科学技術研究助成

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    担当区分:研究代表者  資金種別:受託研究

  • Development of Global CO2 Recycling Technology towards “Beyond-Zero” Emission

    2020年8月

    NEDO (Japan) 

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    担当区分:研究分担者 

    - Development of CO2 capture unit using innovative separation nano-membranes with unparalleled CO2 permeability
    - Development of conversion unit that converts CO2 into carbon fuel with high efficiency
    - Scalable system for use in small-sized homes and medium-sized buildings

  • MOF-based polycrystalline nanomembranes directly grown on microporous polymeric supports for advanced post-combustion CO2 separation

    研究課題/領域番号:19K15342  2019年 - 2021年

    日本学術振興会  科学研究費助成事業  若手研究

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    担当区分:研究代表者  資金種別:科研費

  • Ultra-thin metal oxide films for gas separation

    研究課題/領域番号:26889045  2014年 - 2016年

    科学研究費助成事業  若手研究(スタートアップ)

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    担当区分:研究代表者  資金種別:科研費

▼全件表示

教育活動概要

  • 1. Responsible instructor of the KIKAN Education course - 脱炭素エネルギー概論 (Spring Quarter, course code KED-GES1221J), 2023 ~ ongoing
    2. Instructor in the (IUPE) Fundamental Organic Chemistry class (Autumn/Winter quarters), 2022 ~ ongoing
    3. Co-instructor in the KIKAN Education Class - 脱炭素エネルギー技術と社会デザイン (Winter Quarter, course code KED-SSD5211J), 2022 ~ ongoing
    4. Co-instructor in the Automotive Advanced Science class, Department of Automotive Science, Graduate School of Integrated Frontier Sciences (Spring Semester, class code 22692117 ) 2019 ~ ongoing
    5. Co-instructor in the AMS International Communication seminar, Department of Automotive Science, Graduate School of Integrated Frontier Sciences (Summer/Winter Quarters) 2019 ~ ongoing
    6. Co-instructor in the KIKAN Education Class - Introduction to Carbon Dioxide: Emissions, Capture, Storage and Utilization (Autumn Semester) 2020, course code 20892233

担当授業科目

  • Fundamental Organic Chemistry Ⅱ

    2023年12月 - 2024年2月   冬学期

  • 脱炭素エネルギー技術と社会デザイン

    2023年12月 - 2024年2月   冬学期

  • Fundamental Organic Chemistry Ⅰ

    2023年10月 - 2023年12月   秋学期

  • 脱炭素エネルギー概論

    2023年4月 - 2023年6月   春学期

  • Fundamental Organic Chemistry Ⅱ

    2022年12月 - 2023年2月   冬学期

  • 脱炭素エネルギー技術と社会デザイン

    2022年12月 - 2023年2月   冬学期

  • International Communication Seminar

    2022年10月 - 2023年3月   後期

  • Fundamental Organic Chemistry Ⅰ

    2022年10月 - 2022年12月   秋学期

  • Automotive Advanced Science

    2022年4月 - 2022年9月   前期

  • International Communication Seminar

    2022年4月 - 2022年9月   前期

  • Automotive Advanced Science

    2022年4月 - 2022年9月   前期

  • International Communication Seminar

    2021年10月 - 2022年3月   後期

  • Automotive Advanced Science

    2021年4月 - 2021年9月   前期

  • International Communication Seminar

    2021年4月 - 2021年9月   前期

  • Automotive Advanced Science

    2020年4月 - 2020年9月   前期

  • Automotive Advanced Science

    2019年4月 - 2019年9月   前期

▼全件表示

FD参加状況

  • 2023年9月   役割:参加   名称:Succeeding in academic careers in Japan (FD in English)

    主催組織:全学

  • 2023年6月   役割:参加   名称:Navigating the Undergraduate Classroom Strategies, Tips & Lessons from the Field

    主催組織:全学

  • 2022年9月   役割:参加   名称:Understanding the Faculty Evaluation Systems at Kyushu University

    主催組織:全学

  • 2021年9月   役割:参加   名称:Financial Planning in Japan: Medical System, Insurance and Loans

    主催組織:全学

その他教育活動及び特記事項

  • 2023年  学友会・同好会等の指導  Joint Ph.D. students and teachers summer retreat, team activity session on achieving the carbon-neutral campus in Kyushu University.

     詳細を見る

    Guidance, coordinator, and moderation.

  • 2022年  学友会・同好会等の指導  脱炭素エネルギー先導人材育成フェローシップ、夏合宿セミナー

     詳細を見る

    Organizer and moderator of the joint student-teachers discussion, brainstorming session on building future decarbonized society of Japan.

外国人研究者等の受け入れ状況

  • Linnaeus University (Vaxjo, Sweden)

    受入れ期間: 2023年11月 - 2024年11月   (期間):2週間未満

    国籍:中華人民共和国

    専業主体:外国政府・外国研究機関・国際機関

海外渡航歴

  • 2023年3月

    滞在国名1:スウェーデン王国   滞在機関名1:KTH Royal Institute of Technology

    滞在機関名2:Uppsala University

    滞在機関名3:Linnaeus University