Updated on 2024/12/24

Information

 

写真a

 
MOTOYAMA MUNEKAZU
 
Organization
Kyushu University Platform of Inter/Transdisciplinary Energy Research Associate Professor
Kyushu University Platform of Inter/Transdisciplinary Energy Research (Concurrent)
Title
Associate Professor
Contact information
メールアドレス
Tel
0925837798
Profile
エネルギー研究教育機構、研究推進部門のサブコーディネーターとして、コーディネーター等と協力しながら、クラスターならびにモジュールを跨ぐ学際的研究、教育、産学官連携の企画、調整、支援に取り組んでいます。
External link

Research Areas

  • Nanotechnology/Materials / Nanomaterials

  • Nanotechnology/Materials / Composite materials and interfaces

Degree

  • Dr. (Energy Science)

Research History

  • Kyushu University Platform of Inter/Transdisciplinary Energy Research Associate Professor 

    2022.4 - Present

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  • Nagoya University Graduate School of Engineering Materials Design Innovation Engineering Lecturer 

    2015.4 - 2022.3

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  • 名古屋大学(2013.1〜2022.3)   

Education

  • Kyoto University   Graduate School of Energy Science   Department of Fundamental Energy Science

    - 2006.9

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    Country:Japan

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Research Interests・Research Keywords

  • Research theme: Developments of Energy Conversion Devices Based on Materials Science, Electrochemistry, and Nanotechnology

    Keyword: Electrochemistry, Crystal Growth, Surface and Interface Science, All-Solid-State Battery, Nanomaterial Science

    Research period: 2022.4

Awards

  • 2018年電池技術委員会賞

    2018.11   電池技術委員会  

  • Best Oral Presentation Award for Symposium A02 "Challenges in Advanced Analytical Tools and Techniques for Batteries: in Honor of Prof. Zempachi Ogumi" (PRiME2016, Honolulu, HI)

    2016.10   The Electrochemical Society  

  • 2015年電気化学会東海支部若手研究者特別賞

    2015.2   電気化学会東海支部  

  • Best Poster Award for the "4th International Symposium on Electrochemical Processing of Tailored Materials" (Kyoto, Japan)

    2005.10   Organizing Committee of the "4th International Symposium on EPTM"  

Papers

  • Electrochemical lithium-ion insertion/extraction reactions of multilayered graphene with random twist angles Reviewed

    Satoshi Yamamoto, Ryotaro Sakakibara, Soichi Shima, Shinsuke Matsuura, Takeshi Yajima, Munekazu Motoyama, Wataru Norimatsu, Yuta Kimura, Koji Amezawa, Yasutoshi Iriyama

    Chemical Communications   60 ( 99 )   14790 - 14793   2024.12   ISSN:1359-7345 eISSN:1364-548X

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    A multilayer graphene film with random twist angles between layers (TAGr) on SiC(0001̄) shows six pairs of redox peaks for Li<sup>+</sup> insertion/extraction reaction.

    DOI: 10.1039/d4cc04441j

    DOI: 10.1039/d4cc04441j

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    Other Link: https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=kikir2023&SrcAuth=WosAPI&KeyUT=WOS:001362010500001&DestLinkType=FullRecord&DestApp=WOS_CPL

  • Uncovering the Dynamics of Li-Au Alloying and Li Nucleation at the Au/LiPON Interface with In Situ Z Contrast and Surface Roughness Contrast Imaging via Scanning Electron Microscopy Reviewed

    Motoyama, M; Shimizu, K; Kimura, T; Yamamoto, T; Watanabe, S; Iriyama, Y

    JACS Au   4 ( 12 )   4700 - 4714   2024.12   eISSN:2691-3704

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:JACS Au  

    Controlling the nucleation, growth, and dissolution of Li is crucial for the high cycling stability in rechargeable Li metal batteries. The overpotential for Li nucleation (ηnc) on Li alloys such as Li-Au is generally lower than that on metal current collectors (CCs) with very limited Li solubility like Cu. However, the alloying process of CC and its impact on the Li nucleation kinetics remain unclear. Herein, we experimentally investigate the Li nucleation mechanism on Li-Au alloys using scanning electron microscopy with multiple detectors to distinguish the atomic number and topography contrast. Nonequilibrium processes near the Au CC film/lithium phosphorus oxynitride (LiPON) glass electrolyte interface were observed. Local dissolution of Li occurs concurrently with the Li plating process. This phenomenon indicates that Li nucleates as a metastable phase in Li-Au alloy CC films during Li plating due to the substantially lower interfacial energy of Li with the alloy phase. This low interfacial energy also leads to a low ηnc. Moreover, the local Li redissolution process results in a nonrandom spatial distribution of Li growth sites. Consequently, the alloy layer acts as a buffer, facilitating a more uniform distribution of the reaction sites.

    DOI: 10.1021/jacsau.4c00530

    DOI: 10.1021/jacsau.4c00530

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  • Synergistic Impact of Alloying with Ni on Cu Cathode Interfaces for Fluoride Batteries Reviewed

    Motoyama, M.; Sakurai, K.; Nakagawa, T.; Nakatani, T.; Kiuchi, H.; Nakanishi, K.; Fujinami, S.; Yamamoto, T.; Ogumi, Z.; Abe, T.

    ACS Applied Materials & Interfaces   16 ( 40 )   53631 - 53642   2024.9   ISSN:1944-8244 eISSN:1944-8252

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:ACS Applied Materials and Interfaces  

    All-solid-state fluoride batteries have the potential to achieve energy densities significantly higher than those of lithium-ion batteries. A common cathode material for fluoride batteries is Cu. Cu has a low polarization, but its rapid capacity degradation due to grain growth and subsequent delamination from the solid-state electrolyte are critical issues. To enhance the performance of Cu-based cathodes in all-solid-state fluoride batteries, we explore alloying of Cu with Ni to create metastable solid solution phases (CuxNi1-x with x = 0, 0.32, 0.52, 0.72, 0.89, and 1.0). Compared to Cu, Ni has a higher polarization but exhibits superior capacity retention. The Cu0.72Ni0.28 alloy demonstrates a polarization as low as Cu, but it has a significantly improved capacity retention, which is comparable to Ni. Transmission electron microscopy observations demonstrate that the thin Ni-rich region formed near the interface inhibits Cu grain growth and delamination from the LaF3 electrolyte. By incorporating an appropriate amount of Ni into Cu, Cu-Ni alloy films combine the advantages of both metals, improving the performance of fluoride batteries.

    DOI: 10.1021/acsami.4c06502

    DOI: 10.1021/acsami.4c06502

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  • Electrochemical Lithium-Ion Insertion/Extraction Reactions of Multilayered Graphene with Random Twist Angles Reviewed

    Satoshi Yamamoto, Ryotaro Sakakibara, Soichi Shima, Shinsuke Matsuura, Takeshi Yajima, Munekazu Motoyama, Yuta Kimura, Koji Amezawa, Wataru Norimatsu, and Yasutoshi Iriyama

    Chemical Communications   2024

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    Language:English   Publishing type:Research paper (scientific journal)  

  • "<it>In situ</it> microscopy techniques for understanding Li plating and stripping in solid-state batteries" Invited Reviewed International journal

    Motoyama, M.

    Microscopy   73 ( 2 )   184 - 195   2023.12   ISSN:2050-5698 eISSN:2050-5701

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Microscopy  

    Solid-state batteries have potential to realize a rechargeable Li-metal anode. However, several challenges persist in the charging and discharging processes of the Li-metal anode, which require a fundamental understanding of Li plating and stripping across the interface of solid-state electrolytes (SEs) to address. This review overviews studies on Li-metal anodes in solid-state batteries using in situ observation techniques with an emphasis on Li electrodeposition and dissolution using scanning electron microscopy and SEs such as lithium phosphorus oxynitride and garnet-type compounds such as Li7La3Zr2O12. The previous research is categorized into three topics: (i) Li nucleation, growth and dissolution at the anode-free interface, (ii) electrochemical reduction of SE and (iii) short-circuit phenomena in SE. The current trends of each topic are summarized.

    DOI: 10.1093/jmicro/dfad058

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  • "Electrochemical Li+ insertion/extraction reactions at LiPON/epitaxial graphene interfaces" Reviewed International journal

    Yamamoto, S.; @#BMotoyama, M.#BR; Suzuki, M.; Sakakibara, R.; Ishigaki, N.; Kumatani, A.; Norimatsu, W.; Iriyama, Y.

    ACS Nano   17 ( 17 )   16448 - 16460   2023.8   ISSN:1936-0851 eISSN:1936-086X

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    Redox reactions of the Li+ insertion/extraction from one to two interlayers of graphene (Gr) on area-defined single-crystalline SiC substrates are investigated using lithium phosphorus oxynitride glass (LiPON) as the solid-state electrolyte. Unlike an organic liquid electrolyte, this glassy electrolyte does not induce a reduction current and excludes the desolvation reaction of Li+. Gr electrodes with less than two Gr layers show a single reduction peak and one or two oxidation peaks below +0.21 V (vs Li+/Li), differing distinctly from those of graphite and multilayer Gr, which display multiple peaks (multiple stage transitions). However, this finding aligns with the conventional understanding that graphite stage structure transitions proceed with stepwise increases or decreases in the number of Gr layers between adjacent Li-inserted interlayers. Cyclic voltammetry measurements indicate the presence of surface capacity due to Li+ adsorption/desorption at the LiPON/Gr interface. Moreover, Li+ insertion and extraction induce different charge transfer resistances at the level of a single interlayer. These sensitive measurements are achieved using high-quality epitaxial Gr and LiPON electrolyte, which prevent the formation of a solid electrolyte interphase and the desolvation reaction of Li+. Similar measurements using bilayer Gr produced by chemical vapor deposition coupled with a Gr transfer method and an ethylene carbonate/dimethyl carbonate liquid electrolyte are not reliable. Thus, the proposed method is effective for electrochemical measurement of Gr electrodes with a controlled number of layers.

    DOI: 10.1021/acsnano.3c00158

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  • "Mechanical failure of Cu current collector films affecting Li plating/stripping cycles at Cu/LiPON interfaces" Reviewed International journal

    Motoyama, M.; Ejiri, M.; Nakajima, H.; Iriyama, Y.

    Journal of The Electrochemical Society   170 ( 1 )   012503 - 012503   2023.1   ISSN:0013-4651 eISSN:1945-7111

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    Herein an electro-chemo-mechanical theory, which states that mechanical work to deform a Cu current collector (CC) film influences the nucleation overpotential (η<sub>nc</sub>) for Li nucleation at the Cu CC film/lithium phosphorus oxynitride (LiPON) electrolyte interface, is examined. The finite element method (FEM) simulated the mechanical pressure that the CC film exerted on the Li nuclei at the Cu/LiPON interface, and the results agreed with the trends in our previous study. In situ scanning electron microscopy (SEM) observations for cycling of Li plating/stripping showed that Li repeatedly nucleated and grew at positions where the CC film was locally fractured, and η<sub>nc</sub> decreased with repeated Li plating/stripping because the mechanical pressure to the Li nuclei was no longer applied at locations where the CC film was fractured. On the other hand, for thicker CC films that did not crack, η<sub>nc</sub> exhibited nearly consistent values in the Li plating/stripping cycles. Consequently, the experimental results in this study supported our nucleation theory for a metal/solid-state-electrolyte interfacial system.

    DOI: 10.1149/1945-7111/aca79d

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    Other Link: https://iopscience.iop.org/article/10.1149/1945-7111/aca79d/pdf

  • "Preparation of Li-excess and Li-deficient antiperovskite structured Li2+xOH1-xBr and their effects on total ionic conductivity" Reviewed International journal

    Sugumar, M. K.; Yamamoto, T.; Ikeda, K.; @#BMotoyama, M.#BR; Iriyama, Y.

    Inorganic Chemistry   61 ( 11 )   4655 - 4659   2022.3   ISSN:00201669

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Inorganic Chemistry  

    This paper describes about the effect of Li-H exchange amount on total lithium-ion (Li+) conductivity of Li2+xOH1-xBr (x = -0.5 to +0.4). These samples are systematically prepared at room temperature by a dry ball-milling process using LiOH, LiOH·H2O, Li2O, and LiBr as starting materials. Synchrotron X-ray diffraction analysis reveals that single-phase Li2+xOH1-xBr samples are formed within x = -0.5 to +0.35. For improving total Li+conductivity (σt), a larger x value increases both the Li carrier density and lattice constant as positive factors, while that decreases both the crystallite size and OH rotational unit possibly assisting Li+conduction as negative factors. This trade-off provides an optimized σtof 3.6 × 10-6S cm-1at the Li-excess Li2.2OH0.8Br composition, which is ca. 3 times higher than pristine Li2OHBr (1.1 × 10-6S cm-1). The hydrogen incorporation into the lattice is confirmed by neutron diffraction analysis, and the refined composition is almost consistent with the prepared composition.

    DOI: 10.1021/acs.inorgchem.1c03657

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  • "Atomic layer deposition for thin film solid-state battery and capacitor" Invited Reviewed International journal

    Go, D.; Shin, J. W.; Lee, S.; Lee, J.; Yang, B. C.; Won, Y.; @#BMotoyama, M.#BR; An, J.

    International Journal of Precision Engineering and Manufacturing-Green Technology   10 ( 3 )   1 - 23   2022.1   ISSN:22886206

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:International Journal of Precision Engineering and Manufacturing - Green Technology  

    The demand for electrical power management has increased in recent years, owing partly to increasing contribution of intermittent renewable energy resources to the overall electricity generation. Electrical energy storage systems, such as batteries and capacitors, are core technologies for effective power management. Recent significant technological developments for these energy storage devices include the use of thin film components, which result in increased capacity and reliability. Specifically, thin films with high integrity and uniformity are required in the electrolytes of solid-state Li batteries (SSLBs) and the dielectrics of electrostatic capacitors (ECs), even at extremely thin length scale (< 100 nm) and on complex nanostructures. In this regard, atomic layer deposition (ALD), which can deposit uniform and dense thin films over 3-dimensional (3D) structures, has demonstrated its efficiency in increasing device performance, particularly when applied to the electrolytes and dielectrics of SSLBs and ECs. As a result, the applications of ALD techniques to SSLB electrolytes and EC dielectrics will be examined in this study, with a particular emphasis on research instances that used high aspect ratio structures with conformal ALD coating. Finally, we will discuss how recent advances in innovative ALD processes and equipment with better controllability, versatility, throughput, and economy may further contribute to the development of SSLBs and ECs, especially at scaled-up level.

    DOI: 10.1007/s40684-022-00419-x

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  • "Control of chemical structure and lithium-ion conductivity of amorphous lithium phosphate thin film deposited by pulsed laser deposition" Reviewed International journal

    Yamamoto, T.; Takeuchi, A.; Ohnishi, J.; Yasuno, S.; @#BMotoyama, M.#BR; Iriyama, Y.

    Chemistry Letters   51 ( 1 )   34 - 37   2021.10   ISSN:03667022

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Chemistry Letters  

    Effects of target-substrate (TS) distance during pulsed laser deposition process on the chemical structure and lithium-ion conductivity of amorphous lithium phosphate (LPO) thin films are investigated. The shorter TS distance results in lower Li concentration, longer phosphate chain, and higher ionic conductivity. The ionic conductivity of 2.7 10 7 S/cm is obtained at 25 °C in the LPO thin film with short TS distance.

    DOI: 10.1246/cl.210529

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  • "Charge/discharge reactions via LiPON/multilayer-graphene interfaces without Li+ desolvation/solvation processes" Reviewed International journal

    @#BMotoyama, M.#BR; Miyoshi, K.; Yamamoto, S.; Sakakibara, R.; Yamamoto, Y.; Yamamoto, T.; Norimatsu, W.; Iriyama, Y.

    ACS Applied Energy Materials   4 ( 10 )   10442 - 10450   2021.10

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    DOI: 10.1021/acsaem.1c00628

  • "An appropriate reference and counter electrode in an all-solid-state battery using NASICON-structured solid electrolyte" Reviewed International journal

    Kee, Y.; Suzuki, Y.; Ishigaki, N.; @#BMotoyama, M.#BR; Kimura, Y.; Amezawa, K.; Iriyama, Y.

    Electrochemistry Communications   130   107108   2021.8

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    DOI: 10.1016/j.elecom.2021.107108

  • "Room temperature operation and high cycle stability of an all-solid-state lithium battery fabricated by cold pressing using soft Li2OHBr solid electrolyte" Reviewed International journal

    Yoshikawa, K.; Yamamoto, T.; Sugumar, M. K.; @#BMotoyama, M.#BR; Iriyama, Y.

    Energy & Fuels   35 ( 15 )   12581 - 12587   2021.7

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    DOI: 10.1021/acs.energyfuels.1c01190

  • "Low‐resistive LiCoO2/Li1.3Al0.3Ti2(PO4)3 interface formation by low‐temperature annealing using aerosol deposition" Reviewed International journal

    Sakakura, M.; Suzuki, Y.; Yamamoto, T.; Yamamoto, Y.; @#BMotoyama, M.#BR; Iriyama, Y.

    Energy Technology   9   2001059   2021.3

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    DOI: 10.1002/ente.202001059

  • "Synthesis of LiCoO2 particles with tunable sizes by a urea-based-homogeneous-precipitation method" Reviewed International journal

    @#BMotoyama, M.#BR; Iwasaki, H.; Sakakura, M.; Yamamoto, T.; Iriyarria, Y.

    International Journal of Materials Research   111 ( 4 )   347 - 355   2021.2

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    DOI: 10.3139/146.111892

  • "Tailoring the lithium-ion conductivity of Li2OHBr by substitution of bromine with other halogens" Reviewed International journal

    Sugumar, M. K.; Yamamoto, T.; @#BMotoyama, M.#BR; Iriyama, Y.

    Chemistry Letters   50 ( 3 )   448 - 451   2020.12

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    DOI: 10.1246/cl.200778

  • "Synthesis of the metastable cubic phase of Li2OHCl by a mechanochemical method" Reviewed International journal

    Yamamoto, T.; Shiba, H.; Mitsukuchi, N.; Sugumar, M. K.; @#BMotoyama, M.#BR; Iriyama, Y.

    Inorganic Chemistry   59 ( 17 )   11901 - 11904   2020.8

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    DOI: 10.1021/acs.inorgchem.0c01631

  • "Temperature effects on Li nucleation at Cu/LiPON interfaces" Reviewed International journal

    @#BMotoyama, M.#BR; Hirota, M.; Yamamoto, T.; Iriyama, Y.

    ACS Applied Materials & Interfaces   12 ( 34 )   38045 - 38053   2020.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.0c02354

  • "Room temperature synthesis of anti-perovskite structured Li2OHBr" Reviewed International journal

    Sugumar, M. K.; Yamamoto, T.; @#BMotoyama, M.#BR; Iriyama, Y.

    Solid State Ionics   349   115298   2020.4

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    DOI: 10.1016/j.ssi.2020.115298

  • "The active interface of Ta-doped Li7La3Zr2O12 for Li plating/stripping revealed by acid aqueous etching" Reviewed International journal

    @#BMotoyama, M.#BR; Tanaka, Y.; Yamamoto, T.; Tsuchimine, N.; Kobayashi, S.; Iriyama, Y.

    ACS Applied Energy Materials   2 ( 9 )   6720 - 6731   2019.8

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    DOI: 10.1021/acsaem.9b01193

  • "A Li-free inverted-stack all-solid-state thin film battery using crystalline cathode material" Reviewed International journal

    Yamamoto, T.; Iwasaki, H.; Suzuki, Y.; Sakakura, M.; Fujii, Y.; @#BMotoyama, M.#BR; Iriyama, Y.

    Electrochemistry Communications   105   106494   2019.7

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    DOI: 10.1016/j.elecom.2019.106494

  • "In situ direct lithium distribution analysis around interfaces in an all‐solid‐state rechargeable lithium battery by combined ion‐beam method" Reviewed International journal

    Tsuchiya, B.; Ohnishi, J.; Sasaki, Y.; Yamamoto, T.; Yamamoto, Y.; @#BMotoyama, M.#BR; Iriyama, Y.; Morita, K.

    Advanced Materials Interfaces   6   1900100   2019.4

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  • "Freestanding all-solid-state rechargeable lithium batteries with in-situ formed positive electrodes" Reviewed International journal

    Yamamoto, T.; Sugiura, Y.; Iwasaki, H.; @#BMotoyama, M.#BR; Iriyama, Y.

    Solid State Ionics   337   19 - 23   2019.4

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    DOI: 10.1016/j.ssi.2019.04.003

  • "In situ scanning electron microscope observations of Li plating/stripping reactions with Pt current collectors on LiPON electrolyte" Reviewed International journal

    @#BMotoyama, M.#BR; Ejiri, M.; Yamamoto, T.; Iriyama, Y.

    Journal of The Electrochemical Society   165 ( 7 )   A1338 - A1347   2018.5

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    DOI: 10.1149/2.0411807jes

  • "5V-class bulk-type all-solid-state rechargeable lithium batteries with electrode-solid electrolyte composite electrodes prepared by aerosol deposition" Reviewed International journal

    Iriyama, Y.; Wadaguchi, M.; Yoshida, K.; Yamamoto, Y.; @#BMotoyama, M.#BR; Yamamoto, T.

    Journal of Power Sources   385   55 - 61   2018.3

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    DOI: 10.1016/j.jpowsour.2018.03.017

  • "In-situ electronic conductivity measurements of LiNi0.45Mn1.485Cr0.05O4 thin films using all-solid-state thin-film batteries" Reviewed International journal

    Sato, M.; Yamamoto, T.; @#BMotoyama, M.#BR; Iriyama, Y.

    Electrochemistry Communications   87   31 - 34   2017.12

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    DOI: 10.1016/j.elecom.2017.12.021

  • "Temperature effects on cycling stability of Li plating/stripping on Ta-doped Li7La3Zr2O12" Reviewed International journal

    Yonemoto, F.; Nishimura, A.; @#BMotoyama, M.#BR; Tsuchimine, N.; Kobayashi, S.; Iriyama, Y.

    Journal of Power Sources   343   207 - 215   2017.1

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    DOI: 10.1016/j.jpowsour.2017.01.009

  • "Deep-discharged LiCoMnO4 lithium-ion cathodes with high rate capability and long cycle life" Reviewed International journal

    Li, H.; West, W. C.; @#BMotoyama, M.#BR; Iriyama, Y.

    Thin Solid Films   615   210 - 214   2016.7

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    DOI: 10.1016/j.tsf.2016.07.023

  • "Effects of sintering temperature on interfacial structure and interfacial resistance for all-solid-state rechargeable lithium batteries" Reviewed International journal

    Kato, T.; Yoshida, R.; Yamamoto, K.; Hirayama, T.; @#BMotoyama, M.#BR; West, W. C.; Iriyama, Y.

    Journal of Power Sources   325   584 - 590   2016.6

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    DOI: 10.1016/j.jpowsour.2016.06.068

  • "Reduction of charge-transfer resistance at the solid electrolyte–electrode interface by pulsed laser deposition of films from a crystalline Li2PO2N source" Reviewed International journal

    West, W. C.; Hood, Z. D.; Adhikari, S. P.; Liang, C.; Lachgar, A.; @#BMotoyama, M.#BR; Iriyama, Y.

    Journal of Power Sources   312   116 - 122   2016.2

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    DOI: 10.1016/j.jpowsour.2016.02.034

  • "Li+ conduction in Li–Nb–O films deposited by a sol–gel method" Reviewed International journal

    Niinomi, H.; @#BMotoyama, M.#BR; Iriyama, Y.

    Solid State Ionics   285   13 - 18   2015.11

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    DOI: 10.1016/j.ssi.2015.10.010

  • "Preparation of thick-film electrode-solid electrolyte composites on Li7La3Zr2O12 and their electrochemical properties" Reviewed International journal

    Kato, T.; Iwasaki, S.; Ishii, Y.; @#BMotoyama, M.#BR; West, W. C.; Yamamoto, Y.; Iriyama, Y.

    Journal of Power Sources   303   65 - 72   2015.11

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    DOI: 10.1016/j.jpowsour.2015.10.101

  • "Modeling the nucleation and growth of Li at metal current collector/LiPON interfaces" Reviewed International journal

    @#BMotoyama, M.#BR; Ejiri, M.; Iriyama, Y.

    Journal of The Electrochemical Society   162 ( 13 )   A7067 - A7071   2015.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1149/2.0051513jes

  • "In-situ scanning electron microscope observations of strain-confined lithium nucleation at electrode/electrolyte interfaces in all-solid-state-lithium battery" Reviewed

    @#BMotoyama, M.#BR; Ejiri, M.; Iriyama, Y.

    MRS Online Proceedings Library   1754   25 - 30   2015.6

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    Publishing type:Research paper (other academic)  

    DOI: 10.1557/opl.2015.584

  • "Thermal conduction in nanoporous copper inverse opal films" Reviewed International journal

    Barako, M. T.; Weisse, J. M.; Roy, S.; Kodama, T.; Dusseault, T. J.; @#BMotoyama, M.#BR; Asheghi, M.; Prinz, F. B.; Zheng, X.; Goodson, K. E.

    2014 IEEE Intersociety Conference on Thermal and Thermochemical Phenomena in Electronic Systems (ITherm)   736 - 743   2014.9

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  • "Preparation of thick-film LiNi1/3Co1/3Mn1/3O2 electrodes by aerosol deposition and its application to all-solid-state batteries" Reviewed International journal

    Iwasaki, S.; Hamanaka, T.; Yamakawa, T.; West, W. C.; Yamamoto, K.; @#BMotoyama, M.#BR; Hirayama, T.; Iriyama, Y.

    Journal of Power Sources   272   1086 - 1090   2014.9

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    DOI: 10.1016/j.jpowsour.2014.09.038

  • "Deep discharge and elevated temperature cycling of LiMn1.485Ni0.45Cr0.05O4 spinel cathodes: solid-state cell studies" Reviewed International journal

    West, W. C.; Ishii, Y.; Kaneko, M.; @#BMotoyama, M.#BR; Iriyama, Y.

    ECS Electrochemistry Letters   3 ( 10 )   A99 - A101   2014.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1149/2.0051410eel

  • "In-situ electron microscope observations of electrochemical Li deposition/dissolution with a LiPON electrolyte" Reviewed International journal

    @#BMotoyama, M.#BR; Ejiri, M.; Iriyama, Y.

    Electrochemistry   82 ( 5 )   364 - 368   2014.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.5796/electrochemistry.82.364

  • "In-situ Li7La3Zr2O12/LiCoO2 interface modification for advanced all-solid-state battery" Reviewed International journal

    Kato, T.; Hamanaka, T.; Yamamoto, K.; Hirayama, T.; Sagane, F.; @#BMotoyama, M.#BR; Iriyama, Y.

    Journal of Power Sources   260   292 - 298   2014.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.jpowsour.2014.02.102

  • "Electrodeposition and behavior of single metal nanowire probes" Reviewed International journal

    @#BMotoyama, M.#BR; Prinz, F. B.

    ACS Nano   8 ( 4 )   3556 - 3566   2014.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/nn4066582

  • "Nanotubular array solid oxide fuel cell" Reviewed International journal

    @#BMotoyama, M.#BR; Chao, C.-C.; An, J.; Jung, H. J.; G&uuml;r, T. M.; Prinz, F. B.

    ACS Nano   8 ( 1 )   340 - 351   2013.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/nn4042305

  • "Electrochemical properties of an all-solid-state lithium-ion battery with an in-situ formed electrode material grown from a lithium conductive glass ceramics sheet" Reviewed International journal

    Amiki, Y.; Sagane, F.; Yamamoto, K.; Hirayama, T.; Sudoh, M.; @#BMotoyama, M.#BR; Iriyama, Y.

    Journal of Power Sources   241   583 - 588   2013.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.jpowsour.2013.05.006

  • "Nanoscale conformable coatings for enhanced thermal conduction of carbon nanotube films" Reviewed International journal

    Marconnet, A. M.; @#BMotoyama, M.#BR; Barako, M. T.; Gao, Y.; Pozder, S.; Fowler, B.; Ramakrishna, K.; Mortland, G.; Asheghi, M.; Goodson, K. E.

    2012 IEEE Intersociety Conference on Thermal and Thermochemical Phenomena in Electronic Systems (ITherm)   15 - 19   2012.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1109/ITHERM.2012.6231408

  • "Nanostructured platinum catalysts by atomic-layer deposition for solid-oxide fuel cells" Reviewed International journal

    Chao, C.-C.; @#BMotoyama, M.#BR; Prinz, F. B.

    Advanced Energy Materials   2 ( 6 )   651 - 654   2012.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/aenm.201200002

  • "Effect of high surface area Pd electrodes on SOFC performance at 350 °C" Reviewed International journal

    Komadina, J.; @#BMotoyama, M.#BR; Kim, Y. B.; Prinz, F. B.

    ECS Transactions   41 ( 46 )   35 - 41   2012.5

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    Language:English   Publishing type:Research paper (international conference proceedings)  

    DOI: 10.1149/1.4729180

  • "Fabrication of nanotubular membrane electrode assembly for a solid oxide fuel cell" Reviewed International journal

    @#BMotoyama, M.#BR; Chao, C.-C.; G&uuml;r, T.; Prinz, F. B.

    ECS Transactions   33 ( 40 )   129 - 139   2011.1

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    Language:English   Publishing type:Research paper (international conference proceedings)  

    DOI: 10.1149/1.3589191

  • "Electrodeposited metallic nanowires as a scanning probe tip" Reviewed International journal

    @#BMotoyama, M.#BR; Prinz, F. B.

    MRS Online Proceedings Library   1206   M18-03   2011.1

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    Language:English   Publishing type:Research paper (international conference proceedings)  

    DOI: 10.1557/PROC-1206-M18-03

  • "Electrodeposited metallic nanowires as a scanning probe tip" Reviewed International journal

    @#BMotoyama, M.#BR; Prinz, F. B.

    ECS Transactions   33 ( 16 )   101 - 108   2010.11

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    Language:English   Publishing type:Research paper (international conference proceedings)  

    DOI: 10.1149/1.3553161

  • "Impact of accompanying hydrogen generation on metal nanotube electrodeposition" Reviewed International journal

    @#BMotoyama, M.#BR; Fukunaka, Y.; Ogata, Y. H.; Prinz, F. B.

    Journal of The Electrochemical Society   157 ( 6 )   D357 - D369   2010.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1149/1.3365038

  • "Electrochemical deposition of metallic nanowires as a scanning probe tip" Reviewed International journal

    @#BMotoyama, M.#BR; Dasgupta, N. P.; Prinz, F. B.

    ECS Transactions   16 ( 46 )   3 - 12   2009.11

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    Language:English   Publishing type:Research paper (international conference proceedings)  

    DOI: 10.1149/1.3169314

  • "Nanoscale topography measurements with a metal nanowire AFM tip" Reviewed International journal

    @#BMotoyama, M.#BR; Prinz, F. B.

    ECS Transactions   19 ( 24 )   85 - 96   2009.11

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    Language:Japanese   Publishing type:Research paper (international conference proceedings)  

    DOI: 10.1149/1.3246601

  • "Electrochemical deposition of metallic nanowires as a scanning probe tip" Reviewed International journal

    @#BMotoyama, M.#BR; Dasgupta, N. P.; Prinz, F. B.

    Journal of The Electrochemical Society   156 ( 10 )   D431 - D438   2009.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1149/1.3187215

  • "Initial stages of electrodeposition of metal nanowires in nanoporous templates" Reviewed International journal

    @#BMotoyama, M.#BR; Fukunaka, Y.; Sakka, T.; Ogata, Y. H.

    Electrochimica Acta   53 ( 1 )   205 - 212   2007.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.electacta.2007.04.122

  • "Electrochemical metal deposition on silicon" Invited Reviewed International journal

    Ogata, Y. H.; Kobayashi, K.; @#BMotoyama, M.#BR

    Current Opinion in Solid State and Materials Science   10 ( 3-4 )   163 - 172   2007.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.cossms.2007.02.001

  • "Nickel electrodeposition under magnetic field" Reviewed International journal

    @#BMotoyama, M.#BR; Fukunaka, Y.; Sakka, T.; Ogata, Y. H.; Kikuchi, S.

    ECS Transactions   3   3 - 13   2007.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1149/1.2753235

  • "Effect of hydrogen generation on electrochemical processing of Ni nanowires and nanotubes" Reviewed International journal

    Fukunaka, Y.; @#BMotoyama, M.#BR; Sakka, T.; Ogata, Y.

    ECS Transactions   2   389 - 397   2007.2

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1149/1.2408892

  • "Effect of surface pH on electrodeposited Ni films" Reviewed International journal

    @#BMotoyama, M.#BR; Fukunaka, Y.; Sakka, T.; Ogata, Y. H.

    Journal of The Electrochemical Society   153 ( 7 )   C502 - C508   2006.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1149/1.2196672

  • "Effects of gravitational level & magnetic field flux on electrochemical processing" International journal

    Wakatsuki, T.; Osaki, H.; Kawai, S.; @#BMotoyama, M.#BR; Kusaka, E.; Fukunaka, Y.; Kuribayashi, K.

    Space Utilization Research: Proceedings of Space Utilization Symposium   22   2006.3

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    Language:Japanese   Publishing type:Research paper (international conference proceedings)  

  • "Producing shape-controlled metal nanowires and nanotubes by an electrochemical method" Reviewed International journal

    Fukunaka, Y.; @#BMotoyama, M.#BR; Konishi, Y.; Ishii, R.

    Electrochemical and Solid State Letters   9 ( 3 )   C62 - C64   2006.1

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1149/1.2165711

  • "Electrochemical processing for Cu and Ni nanowire arrays" International journal

    @#BMotoyama, M.#BR; Fukunaka, Y.; Sakka, T.; Ogata, Y. H.; Kikuchi, S.

    3rd International Symposium on Pits and Pores III: Formation, Properties, and Significance for Advanced Materials (206th ECS Meeting)   99 - 108   2006.1

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    Language:Japanese   Publishing type:Research paper (international conference proceedings)  

  • "Electrochemical processing of Cu and Ni nanowire arrays" Reviewed International journal

    @#BMotoyama, M.#BR; Fukunaka, Y.; Sakka, T.; Ogata, Y. H.; Kikuchi, S.

    Journal of Electroanalytical Chemistry   584 ( 2 )   84 - 91   2005.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.jelechem.2005.07.023

  • "Bi electrodeposition under magnetic field" Reviewed International journal

    @#BMotoyama, M.#BR; Fukunaka, Y.; Kikuchi, S.

    Electrochimica Acta   51 ( 5 )   897 - 905   2005.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.electacta.2005.05.059

  • "Electrodeposition of Cu nanowire arrays with a template" Reviewed International journal

    Konishi, Y.; @#BMotoyama, M.#BR; Matsushima, H.; Fukunaka, Y.; Ishii, R.; Ito, Y.

    Journal of Electroanalytical Chemistry   559   149 - 153   2003.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0022-0728(03)00157-8

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Books

  • 「全固体リチウム電池の開発動向と応用展望」(辰巳砂昌弘,林晃敏監修)第5章 酸化物系無機固体電解質を介したLi金属の析出溶解機構

    @#B本山宗主#BR,入山恭寿(Role:Joint author)

    シーエムシー出版  2019.6 

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    Responsible for pages:pp. 167-178   Language:Japanese   Book type:Scholarly book

  • 「エアロゾルデポジション法の新展開 −常温衝撃固化現象活用の最前線−」(明渡純監修)第18章 酸化物全固体リチウム二次電池の開発

    入山恭寿,@#B本山宗主#BR,山本貴之(Role:Joint author)

    シーエムシー出版  2019.2 

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    Responsible for pages:pp. 248-259   Language:Japanese   Book type:Scholarly book

  • 「全固体電池の基礎理論と開発最前線」(菅野了次監修)第8章 無機固体電解質上のLiの析出溶解反応のin-situ SEM観察

    @#B本山宗主#BR,入山恭寿(Role:Joint author)

    シーエムシー・リサーチ  2018.7 

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    Responsible for pages:pp. 106-118   Language:Japanese   Book type:Scholarly book

  • 「全固体電池のイオン伝導性向上技術と材料、製造プロセスの開発」第11章 LiPONガラス電解質上で起こるLiの核生成・成長過程のその場走査型電子顕微鏡観察

    @#B本山宗主#BR(Role:Sole author)

    技術情報協会  2017.2 

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    Responsible for pages:pp. 459-465   Language:Japanese   Book type:Scholarly book

Presentations

  • "(Invited) Critical current densities for short-circuiting of solid-state electrolytes" Invited International conference

    Kurose, R.; Iriyama, Y.; @#BMotoyama, M.#BR

    2024 MRS Spring Meeting & Exhibit  2024.5 

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    Event date: 2024.5

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Seattle, WA   Country:United States  

  • "(Invited) Critical current densities for short-circuiting of solid-state electrolytes" Invited International conference

    Kurose, R.; Iriyama, Y.; <b>Motoyama, M.</b>

    <i>2024 MRS Spring Meeting & Exhibit</i>  2024.5 

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    Event date: 2024.5

    Language:English  

    Venue:Seattle, WA   Country:United States  

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  • "Electrochemical performance of Cu-Alloy cathodes for thin-film-all-solid-state-fluoride batteries" International conference

    @#BMotoyama, M.#BR; Nakagawa, T.; Ogumi, Z.; Abe, T.

    3rd Nucleation and Growth Research Conference  2023.11 

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    Event date: 2023.11

    Language:English   Presentation type:Oral presentation (general)  

    Venue:関西セミナーハウス、京都市   Country:Japan  

  • "Electrochemical performance of Cu-Alloy cathodes for thin-film-all-solid-state-fluoride batteries" International conference

    <b>Motoyama, M.</b>; Nakagawa, T.; Ogumi, Z.; Abe, T.

    <i>3rd Nucleation and Growth Research Conference</i>  2023.11 

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    Event date: 2023.11

    Language:English  

    Venue:関西セミナーハウス、京都市   Country:Japan  

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  • “(招待)フッ化物電池のための高機能正極活物質の開発” Invited

    @#B本山宗主#BR,中川 嵩士,小久見 善八,安部 武志

    電気化学会九州支部・令和5年度秋季講演会  2023.10 

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    Event date: 2023.10

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:長崎大学   Country:Japan  

  • “(招待)フッ化物電池のための高機能正極活物質の開発” Invited

    <b>本山宗主</b>, 中川 嵩士, 小久見 善八, 安部 武志

    <i>電気化学会九州支部・令和5年度秋季講演会</i>  2023.10 

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    Event date: 2023.10

    Language:Japanese  

    Venue:長崎大学   Country:Japan  

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  • "(Invited) Effects of the alloy composition on cycling performance of Cu-Ni alloy cathodes in all-solid-state-fluoride-shuttle batteries" Invited International conference

    @#BMotoyama, M.#BR; Sakurai, K.; Kiuchi, H.; Nakatani, T.; Nakagawa, T.; Iriyama, Y.; Ogumi, Z.; Abe, T.

    242nd ECS Meeting  2022.10 

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    Event date: 2022.10

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Atlanta, GA   Country:United States  

  • "(Invited) Effects of the Alloy Composition on Cycling Performance of Cu-Ni Alloy Cathodes in All-Solid-State-Fluoride-Shuttle Batteries" Invited International conference

    <b>Motoyama, M.</b>; Sakurai, K.; Kiuchi, H.; Nakatani, T.; Nakagawa, T.; Iriyama, Y.; Ogumi, Z.; Abe, T.

    <i>242nd ECS Meeting</i>  2022.10 

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    Event date: 2022.10

    Language:English  

    Venue:Atlanta, GA   Country:United States  

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  • “(招待)酸化物系固体電解質を介したLi金属の電析と溶解について” Invited

    @#B本山宗主#BR

    化学電池材料研究会 第48回講演会・夏の学校  2022.8 

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    Event date: 2022.8

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  • “(招待)酸化物系固体電解質を介したLi金属の電析と溶解について” Invited

    <b>本山宗主</b>

    <i>化学電池材料研究会 第48回講演会・夏の学校</i>  2022.8 

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    Event date: 2022.8

    Language:Japanese  

    Venue:オンライン   Country:Japan  

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  • "(Invited) Temperature effects on Li nucleation at Cu/LiPON interfaces" Invited International conference

    @#BMotoyama, M.#BR; Hirota, M.; Iriyama, Y.

    241st ECS Meeting  2022.6 

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    Event date: 2022.5 - 2022.6

    Language:English   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  • "(Invited) Temperature effects on Li nucleation at Cu/LiPON interfaces" Invited International conference

    <b>Motoyama, M.</b>; Hirota, M.; Iriyama, Y.

    <i>241st ECS Meeting</i>  2022.6 

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    Event date: 2022.5 - 2022.6

    Language:English  

    Venue:オンライン   Country:Japan  

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  • "(Invited) The influence of temperature on Li plating/stripping at metal/oxide solid electrolyte interfaces" Invited International conference

    @#BMotoyama, M.#BR; Iriyama, Y.

    2022 MRS Spring Meeting & Exhibit  2022.5 

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    Event date: 2022.5

    Language:English   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  • "(Invited) The influence of temperature on Li plating/stripping at metal/oxide solid electrolyte interfaces" Invited International conference

    <b>Motoyama, M.</b>; Iriyama, Y.

    <i>2022 MRS Spring Meeting & Exhibit</i>  2022.5 

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    Event date: 2022.5

    Language:English  

    Venue:オンライン   Country:Japan  

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  • "(Invited) Short-circuiting of Li6.6La3Zr1.6Ta0.4O12 caused by Li plating" Invited International conference

    @#BMotoyama, M.#BR

    Interface IONICS Online Symposium 2021 Spring  2021.3 

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    Event date: 2021.3

    Language:English   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  • “(招待)酸化物系無機固体電解質を介したLi金属の析出溶解機構” Invited

    @#B本山宗主#BR

    東北イオニクス研究会・講演会  2020.12 

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    Event date: 2020.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:宮城・東北大学   Country:Japan  

  • “(招待)酸化物系無機固体電解質を介したLiの析出溶解反応について” Invited

    @#B本山宗主#BR

    第60回電気化学セミナー「高性能次世代電池開発の最前線 −新規コンセプトによる産学官の取り組み−」  2020.11 

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    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  • “(招待)酸化物系無機固体電解質を介したLi析出溶解反応のその場SEM観察” Invited

    @#B本山宗主#BR

    日本顕微鏡学会 その場観察分科会 2020年研究討論会  2020.10 

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    Event date: 2020.10

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  • "(Invited) Electrochemical Li nucleation, growth, and dissolution in oxide solid electrolyte systems" Invited International conference

    @#BMotoyama, M.#BR; Kitagawa, M.; Hirota, M.; Yamamoto, T.; Iriyama, Y.

    Pacific Meeting on Electrochemical and Solid State Science 2020 (PRiME 2020)  2020.10 

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    Event date: 2020.10

    Language:English   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:United States  

  • "(Invited) Understanding Li plating/stripping behaviors on oxide solid electrolytes using the in-situ SEM technique" Invited International conference

    @#BMotoyama, M.#BR; Iriyama, Y.

    44th International Conference and Expo and Advanced Ceramics and Composites (ICACC 2020)  2020.1 

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    Event date: 2020.1

    Language:English   Presentation type:Oral presentation (general)  

    Venue:米国・フロリダ   Country:United States  

  • "(Invited) In-situ SEM studies on Li plating/stripping reactions on oxide solid electrolytes" Invited International conference

    @#BMotoyama, M.#BR; Yamamoto, T.; Iriyama, Y.

    2nd World Conference on Solid Electrolytes for Advanced Applications: Garnets and Competitors  2019.9 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  • “(招待)酸化物系無機固体電解質上で起こるLi金属の析出溶解反応に及ぼす温度と圧力の影響” Invited

    @#B本山宗主#BR,入山恭寿

    第397回電池技術委員会  2019.9 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  • “(招待)酸化物系無機固体電解質を介したリチウム金属の析出溶解機構” Invited

    @#B本山宗主#BR,入山恭寿

    日本金属学会・日本鉄鋼協会東海支部 学術討論会  2019.1 

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    Event date: 2019.1

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  • “(招待)酸化物系無機固体電解質上で起こるLi金属の析出溶解反応” Invited

    @#B本山宗主#BR

    第75回日本金属学会・日本鉄鋼協会 東海支部若手材料研究会  2019.1 

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    Event date: 2019.1

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  • "(Invited) In situ scanning electron microscope observations of Li plating/stripping reactions on oxide solid electrolytes" Invited International conference

    @#BMotoyama, M.#BR

    2018 MRS Fall Meeting & Exhibit  2018.11 

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    Event date: 2018.11

    Language:English   Presentation type:Oral presentation (general)  

    Venue:米国・ボストン   Country:United States  

  • “(招待)酸化物系全固体リチウム電池のためのリチウム金属負極に関する研究” Invited

    @#B本山宗主#BR

    平成30年度日本鉄鋼協会・日本金属学会両北海道支部合同サマーセッション  2018.7 

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    Event date: 2018.7

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:北海道・札幌市教育文化会館   Country:Japan  

  • “(招待)酸化物系固体電解質上におけるLi金属の析出溶解反応” Invited

    @#B本山宗主#BR

    第387回電池技術委員会  2017.9 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:愛知・安保ホール   Country:Japan  

  • “(依頼)酸化物系固体電解質上におけるLi金属の析出溶解反応”

    @#B本山宗主#BR

    公益社団法人日本セラミックス協会 第30回秋季シンポジウム  2017.9 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:兵庫・神戸大学   Country:Japan  

  • “(招待)酸化物系ガラス電解質/金属集電体界面におけるLi析出溶解反応のin-situ SEM観察” Invited

    @#B本山宗主#BR

    日本金属学会東海支部・日本鉄鋼協会東海支部学術討論会  2017.2 

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    Event date: 2017.2

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:愛知・名古屋大学   Country:Japan  

  • “(招待)リン酸リチウムオキシナイトライドガラス/金属界面におけるリチウムの核生成・成長過程のその場電子顕微鏡観察” Invited

    @#B本山宗主#BR,木村俊雄,入山恭寿

    第26回東海地区光電気化学研究会・2015年東海地区ヤングエレクトロケミスト研究会合同講演会  2015.9 

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    Event date: 2015.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:愛知・名古屋大学   Country:Japan  

  • "(Invited) In-situ electron microscope observations of electrochemical Li deposition/dissolution with a LiPON electrolyte" Invited International conference

    @#BMotoyama, M.#BR; Ejiri, M.; Iriyama, Y.

    ISPlasma2015/IC-PLANTS2015  2015.3 

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    Event date: 2015.3

    Language:English   Presentation type:Oral presentation (general)  

    Venue:日本・名古屋   Country:Japan  

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MISC

  • “アンチペロブスカイト型結晶構造を有する低融点固体電解質の研究開発” Reviewed

    山本貴之,@#B本山宗主#BR,入山恭寿

    月刊 車載テクノロジー 2021年3月号   2021.3

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

  • “エアロゾルデポジションを活用した酸化物全固体電池の研究開発” Reviewed

    山本貴之,@#B本山宗主#BR,入山恭寿

    粉体および粉末冶金   2020.4

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

    DOI: 10.2497/jjspm.67.200

  • “酸化物系全固体Li 電池におけるLi金属負極の課題” Reviewed

    @#B本山宗主#BR,山本貴之,入山恭寿

    工業材料   2020.4

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

  • “全固体Li 電池の高性能化に向けた固体電解質の短絡機構の解明” Reviewed

    @#B本山宗主#BR,山本貴之,入山恭寿

    応用物理   2020.4

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

    DOI: 10.11470/oubutsu.89.4_213

  • “酸化物系無機固体電解質を介したLi金属の析出溶解機構” Reviewed

    @#B本山宗主#BR,入山恭寿

    電気化学   2018.12

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

    DOI: 10.5796/denkikagaku.18-FE0028

  • “界面制御に基づく酸化物系全固体電池の高性能化” Reviewed

    入山恭寿,William C. West,@#B本山宗主#BR,石井陽祐

    電池技術   2015.10

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

  • “不燃性ガラス電解質上で起こるリチウム析出溶解反応” Reviewed

    @#B本山宗主#BR,入山恭寿

    化学工業   2014.10

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

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Industrial property rights

Patent   Number of applications: 1   Number of registrations: 1
Utility model   Number of applications: 0   Number of registrations: 0
Design   Number of applications: 0   Number of registrations: 0
Trademark   Number of applications: 0   Number of registrations: 0

Professional Memberships

  • Materials Research Society (MRS)

  • The Electrochemical Society (ECS)

  • Japan Society of Applied Physics

  • The Electrochemical Society of Japan

  • Materials Research Society

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  • Materials Research Society (MRS)

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  • The Electrochemical Society

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  • The Electrochemical Society (ECS)

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  • Japan Society of Applied Physics

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  • The Electrochemical Society of Japan

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  • 応用物理学会

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  • 電気化学会

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  • 電池技術委員会

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Committee Memberships

  • 九州大学   九州脱炭素化研究会(Q-DeCS)運営委員  

    2023.2   

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    Committee type:Other

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  • 九州大学   研究推進部門サブコーディネーター  

    2022.4   

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    Committee type:Other

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Academic Activities

  • 電気化学

    2023.4 - Present

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    Type:Academic society, research group, etc. 

  • <i>電気化学</i>

    Role(s): Review, evaluation

    2023.4

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    Type:Peer review 

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  • Ionics International contribution

    2023.2 - Present

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    Type:Academic society, research group, etc. 

  • <i>Ionics</i> International contribution

    Role(s): Review, evaluation

    2023.2

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    Type:Peer review 

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  • Screening of academic papers

    Role(s): Peer review

    2023

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    Type:Peer review 

    Number of peer-reviewed articles in foreign language journals:19

    Number of peer-reviewed articles in Japanese journals:0

    Proceedings of International Conference Number of peer-reviewed papers:0

    Proceedings of domestic conference Number of peer-reviewed papers:0

  • Screening of academic papers

    Role(s): Peer review

    2022

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    Type:Peer review 

    Number of peer-reviewed articles in foreign language journals:12

    Number of peer-reviewed articles in Japanese journals:0

    Proceedings of International Conference Number of peer-reviewed papers:0

    Proceedings of domestic conference Number of peer-reviewed papers:0

  • 実行委員 International contribution

    第62回電池討論会  ( Japan ) 2021.11 - 2021.12

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    Type:Competition, symposium, etc. 

  • Screening of academic papers

    Role(s): Peer review

    2021

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    Type:Peer review 

    Number of peer-reviewed articles in foreign language journals:6

    Number of peer-reviewed articles in Japanese journals:0

    Proceedings of International Conference Number of peer-reviewed papers:0

    Proceedings of domestic conference Number of peer-reviewed papers:0

  • 実行委員会事務局長 International contribution

    第61回電池討論会  ( Japan ) 2020.11

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    Type:Competition, symposium, etc. 

  • Screening of academic papers

    Role(s): Peer review

    2020

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    Type:Peer review 

    Number of peer-reviewed articles in foreign language journals:6

    Number of peer-reviewed articles in Japanese journals:0

    Proceedings of International Conference Number of peer-reviewed papers:0

    Proceedings of domestic conference Number of peer-reviewed papers:0

  • 実行委員 International contribution

    第60回電池討論会  ( Japan ) 2019.11

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    Type:Competition, symposium, etc. 

  • Conference Secretary International contribution

    2nd World Conference on Solid Electrolytes for Advanced Applications: Garnets and Competitors  ( Japan ) 2019.9

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    Type:Competition, symposium, etc. 

  • Screening of academic papers

    Role(s): Peer review

    2019

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    Type:Peer review 

    Number of peer-reviewed articles in foreign language journals:5

    Number of peer-reviewed articles in Japanese journals:0

    Proceedings of International Conference Number of peer-reviewed papers:0

    Proceedings of domestic conference Number of peer-reviewed papers:0

  • Screening of academic papers

    Role(s): Peer review

    2018

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    Type:Peer review 

    Number of peer-reviewed articles in foreign language journals:4

    Number of peer-reviewed articles in Japanese journals:0

    Proceedings of International Conference Number of peer-reviewed papers:0

    Proceedings of domestic conference Number of peer-reviewed papers:0

  • Screening of academic papers

    Role(s): Peer review

    2017

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    Type:Peer review 

    Number of peer-reviewed articles in foreign language journals:1

    Number of peer-reviewed articles in Japanese journals:0

    Proceedings of International Conference Number of peer-reviewed papers:0

    Proceedings of domestic conference Number of peer-reviewed papers:0

  • 事務局

    第26回光電気化学研究会・2015年ヤングエレクトロケミスト研究会合同大会  ( Japan ) 2015.9

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    Type:Competition, symposium, etc. 

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Research Projects

  • Development of an Electrochemical Cell for Versatile Operando Measurement by Simultaneous Ink Jetting of Multiple Types of Particles

    Grant number:24K21811  2024.6 - 2026.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Challenging Research (Exploratory)

    本山 宗主, 渡邉 賢

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    Grant type:Scientific research funding

    無機固体電解質(SE)を利用したデバイスの実用化研究を進める中で、解析に適した実験系の構築は重要となる。合剤電極を用いた全固体電池(SEの両側に正極と負極を接合させた蓄電池)のoperando計測を微小スケールで行う場合は、合剤電極の一部のみを測定することになる。そのため、測定外領域の影響を考慮できない。本研究では、電極活物質とSEの異種粒子を混合分散させた溶液をインクに用い、基板上に負極、SE、正極が高精度に配置された微小固体電気化学セルを描画作製する。これにより、合剤電極を用いた系でも正極の端から負極の端にいたる全領域にわたり、ラマン分光装置などを用い、一括でoperando計測できる。

    CiNii Research

  • ⚫︎ JST 革新的GX技術創出事業(GteX):高エネルギー密度・高安全な硫化物型全固体電池の開発/全固体リチウム金属電池の高性能化に向けた材料力学的アプローチ

    2023.10

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    Authorship:Collaborating Investigator(s) (not designated on Grant-in-Aid) 

  • 全固体リチウム金属電池の高性能化に向けた材料力学的アプローチ

    2023 - 2033

    JST「革新的GX技術創出事業(GteX)」:高エネルギー密度・高安全な硫化物型全固体電池の開発

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    Authorship:Principal investigator  Grant type:Contract research

  • ⚫︎ JSPS科研費 基盤研究(B):Li/酸化物系固体電解質界面の電荷移動抵抗・親和性・電気化学的安定性の包括的理解

    2022.4 - 2025.3

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    Authorship:Principal investigator 

  • Comprehensive Understanding of Charge Transfer Resistance, Affinity, and Electrochemical Stability of the Li/Oxide-Solid-State Electrolyte Interface

    Grant number:23K23446  2022.4 - 2025.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

    本山 宗主

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    Grant type:Scientific research funding

    本研究課題で用いる“固体電解質(SE)”という言葉は、「Liイオン(Li+)が伝導する固体の無機化合物」を指す。本研究では、Li金属とSEから成る固固界面の「Li = Li+ + e- の反応のエネルギー障壁の高さ」、「界面の親和性」、「SEの耐還元性」の三つの性質の相関を原子・分子スケールの視点から理解する。実験には、Li2S-P2S5系ガラス電解質、アルジロダイト型Li6PS5ClなどのSEを用い、Li金属との界面に対し、高真空下での接触角測定などを行う。最終的に、Li金属とSEの界面の特徴を記述できる指標・変数を見出し、a priori な(経験に先立つ)界面設計の指針を構築する。

    CiNii Research

  • Li/酸化物系固体電解質界面の電荷移動抵抗・親和性・電気化学的安定性の包括的理解

    Grant number:22H02178  2022 - 2024

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

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    Authorship:Principal investigator  Grant type:Scientific research funding

  • Lithium Plating/Stripping Reactions at Solid/Solid Interfaces under Controlled Hydrostatic Pressures

    Grant number:22H04611  2022 - 2023

    Japan Society for the Promotion of Science・Ministry of Education, Culture, Sports, Science and Technology  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

    本山 宗主

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    Authorship:Principal investigator  Grant type:Scientific research funding

    本研究では電気化学測定を通じ、Li金属と無機固体電解質(SE)の界面近傍で起こる「空孔の発生・拡散・会合」、「空隙の生成・成長・消失」過程に及ぼす静水圧の影響を調べ、解析する。非平衡状態におけるミクロな空隙の動的振る舞いが、マクロな測定値(電流・電圧)に及ぼす影響を理解するための理論を導き、金属とSEから成る固固界面の電極反応速度論を体系化する。本研究の具体的な研究目標は以下の通りである。
    <BR>
    1)静水圧環境下で電気化学測定を行う実験手法の確立
    2)「空孔の発生・拡散・会合」、「空隙の生成・成長・消失」に及ぼす静水圧の影響を定量解析し、LiとSEから成る固固界面の電極反応速度に関する理論式を導出する。

    CiNii Research

  • ⚫︎ NEDO 電気自動車用革新型蓄電池開発(RISING3):フッ化物シャトル電池のための高性能合金電極活物質の設計と開発

    2021.4 - 2026.3

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    Authorship:Principal investigator 

  • フッ化物シャトル電池のための高性能合金電極活物質の設計と開発

    2021 - 2025

    NEDO「電気自動車用革新型蓄電池開発(RISING3)」

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    Authorship:Principal investigator  Grant type:Contract research

  • Li/酸化物系無機固体電解質界面の親和性発現機構の解明

    Grant number:20H05288  2020 - 2021

    Japan Society for the Promotion of Science・Ministry of Education, Culture, Sports, Science and Technology  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

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    Authorship:Principal investigator  Grant type:Scientific research funding

  • 第36回 公益財団法人 村田学術振興財団研究者海外派遣援助

    2020

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    Grant type:Donation

  • ALDで作製したナノ構造触媒電極の電子物性調査と燃料電池への応用

    2019 - 2021

    Japan Society for the Promotion of Science  Bilateral program

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    Authorship:Principal investigator  Grant type:Joint research

  • 公益財団法人 立松財団 2019年度海外調査研究助成

    2019

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    Grant type:Donation

  • ジョブシェアリング型金属電極活物質の設計と開発

    2018 - 2020

    NEDO「革新型蓄電池実用化促進基盤技術開発(RISING2)」

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    Authorship:Principal investigator  Grant type:Contract research

  • 公益財団法人 大幸財団 第33回海外学術交流研究助成

    2018

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    Grant type:Donation

  • 酸化物系固体電解質上における合金負極薄膜の充放電過程の解明

    Grant number:17H04894  2017 - 2019

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Young Scientists (A)

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    Authorship:Principal investigator  Grant type:Scientific research funding

  • 公益財団法人 八洲環境技術振興財団 平成27年度「国際会議・研究会等の参加およびシンポジウム等開催助成」

    2016

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    Grant type:Donation

  • ナノポーラス材に充填した液体金属の固体電池負極への応用

    2015

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    Grant type:Donation

  • 原子間力顕微鏡を用いた非平衡電位分布測定法の開発と固体電池解析への応用

    Grant number:26870272  2014 - 2016

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Young Scientists (B)

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    Authorship:Principal investigator  Grant type:Scientific research funding

  • 磁性ナノリング配列の電気化学プロセシング

    2008 - 2011

    Japan Society for the Promotion of Science  Postdoctoral Fellowships for Research Abroad

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    Authorship:Principal investigator  Grant type:Joint research

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Educational Activities

  • エネルギー研究教育機構、教育推進部門と協力し、(1) エネルギー教育プログラムの企画、開発、運営、(2) 本学教員や企業等との連携による大学院生、学術研究員等のキャリアパス形成支援、に取り組んでいます。

Class subject

  • 新エネルギー工学

    2023.12 - 2024.2   Winter quarter

  • 脱炭素エネルギー概論

    2023.4 - 2023.6   Spring quarter

FD Participation

  • 2023.10   Role:Participation   Title:先導物質化学研究所FD

    Organizer:[Undergraduate school/graduate school/graduate faculty]

  • 2023.2   Role:Participation   Title:先導物質化学研究所FD

    Organizer:[Undergraduate school/graduate school/graduate faculty]

  • 2022.4   Role:Participation   Title:令和4年度 第1回全学FD(新任教員の研修)

    Organizer:University-wide

Visiting, concurrent, or part-time lecturers at other universities, institutions, etc.

  • 2022  名古屋大学・工学部, 招へい教員  Domestic/International Classification:Japan 

Social Activities

  • 平成30年度 豊西総合大学

    愛知県立豊田西高等学校  2018.11

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    Audience:Infants, Schoolchildren, Junior students, High school students

    Type:Seminar, workshop

  • 平成30年度 豊西総合大学

    愛知県立豊田西高等学校  2018.11

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    Type:Seminar, workshop

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  • 技術情報協会主催セミナー「全固体電池、固体電解質の観察、評価技術」

    技術情報協会  2018.2

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    Audience:General, Scientific, Company, Civic organization, Governmental agency

    Type:Seminar, workshop

  • 技術情報協会主催セミナー「全固体電池、固体電解質の観察、評価技術」

    技術情報協会  2018.2

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    Type:Seminar, workshop

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Travel Abroad

  • 2009.2 - 2011.2

    Staying countory name 1:United States   Staying institution name 1:University of California, Berkeley

  • 2007.10 - 2012.12

    Staying countory name 1:United States   Staying institution name 1:Stanford University