Updated on 2025/06/29

Information

 

写真a

 
MAEDA NOBUTAKA
 
Organization
International Institute for Carbon-Neutral Energy Research Multiscale Science and Engineering for Energy and the Environment Thrust Associate Professor
Title
Associate Professor
Contact information
メールアドレス
Tel
0928026866

Research Areas

  • Nanotechnology/Materials / Green sustainable chemistry and environmental chemistry

Degree

  • PhD

Research History

  • 2007年 4 月 1 日 〜 2008 年 3 月 31 日 山梨大学クリーンエネルギー研究センター燃料電池部門、博士研究員(指導教員: 渡辺政廣 教授) 2008年4月1日 〜 2009 年 12 月31日 スイス連邦工科大学 、博士研究員(指導教員:Alfons Baiker教授) 2010年1月15日〜 2011年1月15日 イタリア工科大学、 シニア博士研究員 (指導教員:Liberato Manna教授) 2011年2月1日〜 2012年9月30日 スイス連邦工科大学 、博士研究員、兼サブグループリーダー 触媒・分光グループ (指導教員:Konrad Hungerbuhler教授) 2013年1月 9 日 〜 2019年2 月 28 日 大連理工大学 環境学院、准教授 2016年10月1日〜 2018年12月31日 大連化学物理研究所 金触媒研究センター 教授(上記、准教授職と正規雇用で兼任) 2019年4月 1 日 〜 2020年1 月 31 日 九州大学カーボンニュートラルエネルギー研究センター、WPI特任准教授(指導教員:山内美穂教授) 2020年4月1日〜2023年6月30日 チューリッヒ応用科学大学、シニア研究員、兼チームリーダー 触媒・分光チーム   

Education

  • Kanagawa University   工学研究科   応用科学専攻

    2004.4 - 2007.3

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    Country:Japan

    Notes:博士課程

  • Kanagawa University   工学研究科   応用科学専攻

    2002.4 - 2004.3

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    Country:Japan

    Notes:修士課程

  • Kanagawa University   工学部   応用化学科

    1998.4 - 2002.3

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    Country:Japan

Research Interests・Research Keywords

  • Research theme: Application of in situ/operando spectroscopy for carbon-neutral material conversion research

    Keyword: Modulation excitation spectroscopy, CO2 conversion

    Research period: 2024.4 - 2030.3

Papers

  • Reaction Mechanism Revisited: Oxidation of Propylene on Supported Palladium Catalyst Reviewed

    Hitoshi Mikami, Hiroto Tsuchiya, and Nobutaka Maeda

    Langmuir   41   11733 - 11736   2025.4

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.langmuir.5c01016

    Other Link: https://pubs.acs.org/doi/10.1021/acs.langmuir.5c01016

  • Surface Dynamics and Size Sensitivity of Pt-Catalyzed Methane Oxidation Probed by Modulation-Excitation X-ray Absorption Spectroscopy

    Al Abdulghani, AJ; Qian, YC; Shimizu, K; Sugiyama, T; Maeda, N

    JOURNAL OF PHYSICAL CHEMISTRY LETTERS   16 ( 18 )   4474 - 4479   2025.4   ISSN:1948-7185

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    Language:English   Publisher:Journal of Physical Chemistry Letters  

    In situ X-ray absorption spectroscopy (XAS) is a powerful tool to probe the electronic and structural properties of materials under operating conditions. However, its bulk-sensitive nature often obscures the surface-specific dynamics critical to understanding catalytic processes. We herein demonstrate successful extraction of surface dynamics from bulk XAS spectra by applying modulation excitation spectroscopy to XAS (ME-XAS). Methane oxidation over Pt/Al<inf>2</inf>O<inf>3</inf> was chosen as a model reaction to verify the strength of ME-XAS for extracting surface dynamics of Pt nanoparticles of different sizes. ME-XAS spectra revealed that during methane oxidation, only surface Pt atoms were repeatedly oxidized and reduced while the bulk Pt remained mostly metallic. Samples with low Pt loadings were more oxidizable and showed lower methane oxidation activity, in line with metallic Pt being more active for methane dissociation than Pt oxides. This study underscores the potential of ME-XAS to enhance our understanding of surface-bulk dynamics and rationalize catalytic phenomena, offering a pathway to the development of more efficient and selective catalysts.

    DOI: 10.1021/acs.jpclett.5c00380

    Web of Science

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    PubMed

  • Toward Low-Temperature Regeneration of CO<sub>2</sub> Capture Adsorbents: Functionalization of Polyethylenimine

    Al Abdulghani, AJ; Weisshar, F; Hack, J; Fajar, ATN; Lambard, G; Maeda, N

    ACS SUSTAINABLE CHEMISTRY & ENGINEERING   13 ( 17 )   6325 - 6332   2025.4   ISSN:2168-0485

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    Publisher:ACS Sustainable Chemistry and Engineering  

    This study aimed to design materials for CO<inf>2</inf> capture with low regeneration temperatures without compromising the adsorption capacity (AC). Branched polyethylenimine (BPEI) functionalized with acrylonitrile (AN), 2-ethylhexyl acrylate (EHA), and butyl acrylate (BA) was impregnated onto fumed silica and tested for its adsorption and desorption properties. Higher functionalization degrees led to decreased desorption temperatures (DTs) from 73 to 97 °C to as low as 25 °C, which was attributed to the higher percentages of secondary amines upon functionalization and changes in the CO<inf>2</inf> adsorption mechanism. However, the adsorption capacities also decreased with functionalization. Bayesian optimization using machine learning models predicted optimal compositions of adsorbents for high adsorption capacities at low regeneration temperatures. The isothermal operation of CO<inf>2</inf> capture and release was also demonstrated to lower the energy requirement for CO<inf>2</inf> capturing systems. The functionalized BPEI materials steadily adsorb and release CO<inf>2</inf> for 20 cycles under isothermal conditions without any deterioration of the performance. BPEI 10,000 functionalized with AN, EHA, and BA offers a promising balance between AC and DT, making it suitable for industrial applications.

    DOI: 10.1021/acssuschemeng.5c01250

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    Scopus

  • <i>In situ</i>/<i>operando</i> spectroscopic evidence on associative redox mechanism for periodic unsteady-state water-gas shift reaction on Au/CeO<sub>2</sub> catalyst

    Zhang, NQ; Li, LC; Jing, Y; Qian, YC; Chen, DT; Maeda, N; Murayama, T; Toyao, T; Shimizu, KI

    JOURNAL OF CATALYSIS   433   2024.5   ISSN:0021-9517 eISSN:1090-2694

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    Publisher:Journal of Catalysis  

    Cyclic and repeatable CO<inf>2</inf>/H<inf>2</inf> formation under periodic CO ↔ H<inf>2</inf>O feeds, that is unsteady-state water–gas shift reaction (uss-WGS), was found to be catalyzed by a gold nanoparticles-loaded CeO<inf>2</inf> (Au/CeO<inf>2</inf>) catalyst. Kinetics of the CO-reduction of Ce<sup>4+</sup> to Ce<sup>3+</sup> and Ce<sup>3+</sup> reoxidation by H<inf>2</inf>O in combination with transient CO<inf>2</inf>/H<inf>2</inf> formation over Au/CeO<inf>2</inf> were studied by operando ultraviolet–visible (UV–vis) and infrared (IR) spectroscopies at 175 °C. The Ce<sup>4+</sup>–OH species were reduced by CO to give Ce<sup>3+</sup>-□-Ce<sup>3+</sup> (□: oxygen vacancy) and gas phase products (H<inf>2</inf>, CO<inf>2</inf>). The Ce<sup>3+</sup>-□-Ce<sup>3+</sup> species were oxidized by H<inf>2</inf>O to give H<inf>2</inf> and Ce<sup>4+</sup>–OH species. The reduction and reoxidation rates of Ce<sup>4+</sup>/Ce<sup>3+</sup> redox couple were close to the rates of transient CO<inf>2</inf>/H<inf>2</inf> formation. The X-ray absorption spectroscopy results showed that the oxidation states of Au remained unchanged during the redox reactions. These results indicate that the uss-WGS is primary driven by the Ce<sup>4+</sup>/Ce<sup>3+</sup> redox couple. Combined with the observation of adsorbed carboxylate intermediates as a precursor of H<inf>2</inf> and CO<inf>2</inf>, associative redox mechanism is proposed as the main pathway for the unsteady-state WGS reaction on Au/CeO<inf>2</inf> at 175 °C.

    DOI: 10.1016/j.jcat.2024.115500

    Web of Science

    Scopus

  • Bifunctional electrochemical properties of La<sub>0.8</sub>Sr<sub>0.2</sub>Co<sub>0.8</sub>M<sub>0.2</sub>O<sub>3-<i>δ</i></sub> (M = Ni, Fe, Mn, and Cu): efficient elemental doping based on a structural and pH-dependent study

    Cheng, J; Ganesan, P; Wang, Z; Zhang, M; Zhang, G; Maeda, N; Matsuda, J; Yamauchi, M; Chi, B; Nakashima, N

    MATERIALS ADVANCES   3 ( 1 )   272 - 281   2022.1   eISSN:2633-5409

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    Publisher:Materials Advances  

    Perovskite oxides with a low cost and high catalytic activity are considered as suitable candidates for the oxygen evolution reaction (OER)/oxygen reduction reaction (ORR), but most of them favour only either the ORR or the OER. Besides, their underlying catalytic mechanisms are subject of an ongoing debate. Herein, La0.8Sr0.2CoO3-δ (LSC) was selected as a base perovskite oxide for doping different elements into its B-site to fabricate four different La0.8Sr0.2Co0.8M0.2O3-δ (LSCM; M = Ni, Fe, Mn, and Cu) perovskite oxides. Among the catalysts tested with and without multi-walled carbon nanotubes (MWNTs), La0.8Sr0.2Co0.8Fe0.2O3-δ (LSCF) outperformed any other catalysts in terms of both OER and ORR activity. The OER/ORR activity enhancement with LSCF is also discussed based on spectroscopic and microscopic analyses and lattice oxygen transportation.

    DOI: 10.1039/d1ma00632k

    Web of Science

    Scopus

Presentations

  • Development of Functionalised Polyethylenimine for CO2 Capture and Low-Temperature Regeneration International conference

    Abdullah Al Abdulghani, Nobutaka Maeda, Ken-ichi Shimizu

    2025 I2CNER Annual Symposium  2025.1 

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    Language:English   Presentation type:Poster presentation  

    Venue:九州大学   Country:Japan  

  • Installation of Modulation-Excitation IR/Raman/XAS/WAXS/SAXS for Catalysis Research International conference

    Nobutaka Maeda, Abdullah Al Abdulghani, Ken-ichi Shimizu

    2025 I2CNER Annual Symposium  2025.1 

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    Language:English   Presentation type:Poster presentation  

    Venue:九州大学   Country:Japan  

  • 変調励起分光法(IR、Raman、XAFS、WAXS/SAXS)の触媒研究への展開

    前田修孝、Abdullah Al Abdulghani、清水研一

    日本化学会 第105春季年会  2025.3 

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    Language:Japanese   Presentation type:Poster presentation  

    Venue:関西大学   Country:Japan  

  • アルミナ担持Cs触媒によるCO2吸蔵還元による連続的CO合成

    清水研一、Ningqiang Zhang、Cingcong Li、鳥屋尾隆、前田修孝

    第135回触媒討論会(春)  2025.3 

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    Language:Japanese   Presentation type:Poster presentation  

    Venue:大阪大学   Country:Japan  

  • セリア担持Au触媒上の水性ガスシフト反応機構のオペランド解析

    宮崎眞太、宮景琢充、安齊亮彦、前田修孝、鳥屋尾隆、清水研一

    第135回触媒討論会(春)  2025.3 

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    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:大阪大学   Country:Japan  

  • Extraction of Surface Dynamics by Modulation Excitation XAFS

    Abdullah Al Abdulghani、前田 修孝、清水 研一

    第135回触媒討論会(春)  2025.3 

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    Language:Japanese   Presentation type:Poster presentation  

    Venue:大阪大学   Country:Japan  

  • オペランド変調励起IR/Raman/XAFS/SAXS/WAXSの整備

    前田修孝、Abdullah Al Abdulghani、清水研一

    第135回触媒討論会(春)  2025.3 

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    Language:Japanese   Presentation type:Poster presentation  

    Venue:大阪大学   Country:Japan  

  • 機能する触媒を”観る”ためのオペランド変調励起分光拠点の構築 Invited

    前田修孝

    第135回触媒討論会(春)特別シンポジウム  2025.3 

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    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:大阪大学   Country:Japan  

  • Low-Energy Input CO2 Capture with Functionalized Polyethylenimine International conference

    Abdullah Al Abdulghani, Nobutaka Maeda, Adroit Fajar, Guillaume Lambard

    WPI-SKCM² and WPI-I²CNER Joint Research Symposium  2024.12 

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    Language:English   Presentation type:Poster presentation  

    Venue:九州大学   Country:Japan  

  • Modulation-Excitation IR and X-ray Absorption Spectroscopy for Carbon-Neutral Energy Research International conference

    Nobutaka Maeda, Abdullah Al Abdulghani, Ken-ichi Shimizu

    WPI-SKCM² and WPI-I²CNER Joint Research Symposium  2024.12 

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    Language:English   Presentation type:Poster presentation  

    Venue:九州大学   Country:Japan  

  • Modulation Excitation IR / XAS for Carbon Neutral Energy Research Invited International conference

    Nobutaka Maeda

    NEDO-GNS Science 2nd Workshop  2024.11 

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    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:九州大学   Country:Japan  

  • Operando Modulation-Excitation IR Spectroscopy at Elevated Temperature and Pressure for Catalytic CO2 Hydrogenation International conference

    Nobutaka Maeda

    ISSP International Workshop  2024.10 

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    Language:English   Presentation type:Oral presentation (general)  

    Venue:東京大学 物性研究所   Country:Japan  

  • オペランド変調励起赤外分光法による二酸化炭素水素化触媒反応のメタノール生成機構解明

    前田修孝

    第134回触媒討論会(秋)  2024.9 

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    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

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Professional Memberships

  • Catalysis Society of Japan

  • American Chemical Society

Research Projects

  • 尿素の電気化学的酸化反応を応用したグリーン水素生成の促進に向けた分光学と機械学習の統合アプローチ International coauthorship

    Grant number:JPMJNX25B5  2025.4 - 2028.3

    科学技術振興機構(JST)  NEXUS日本ータイ「グリーンテクノロジー」研究領域 

    前田修孝

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    Authorship:Principal investigator  Grant type:Competitive funding other than Grants-in-Aid for Scientific Research

  • 変調励起XAFSによる金属-担体界面ダイナミクスの観測

    Grant number:25ES0745  2025.4 - 2026.3

    触媒科学計測共同研究拠点   2025年度触媒科学計測共同研究拠点共同利用・共同研究公募(発展型)  

    前田修孝

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    Authorship:Principal investigator  Grant type:Competitive funding other than Grants-in-Aid for Scientific Research

  • 非定常オペランド赤外・X線吸収分光法による触媒反応活性種・活性点の選択的抽出

    Grant number:24DS0688  2024.11 - 2025.3

    触媒科学計測共同研究拠点   2024年度触媒科学計測共同研究拠点共同利用・共同研究公募(提案型)第二期  

    前田修孝

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    Authorship:Principal investigator  Grant type:Competitive funding other than Grants-in-Aid for Scientific Research

  • 非定常オペランド赤外分光法による触媒反応活性種の選択的抽出

    Grant number:24DS0555  2024.6 - 2024.10

    触媒科学計測共同研究拠点   2024年度触媒科学計測共同研究拠点共同利用・共同研究公募(提案型)第一期  

    前田修孝

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    Authorship:Principal investigator  Grant type:Competitive funding other than Grants-in-Aid for Scientific Research

  • 変調励起赤外分光法による高効率 CO2水素化反応触媒の探索

    2024.4 - 2025.3

    西部ガスグループ  西部ガスグループカーボンニュートラル2050  

    前田修孝

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    Authorship:Principal investigator  Grant type:Donation

Educational Activities

  • 該当なし

Visiting, concurrent, or part-time lecturers at other universities, institutions, etc.

  • 2025  北海道大学  Classification:Intensive course  Domestic/International Classification:Japan 

    Semester, Day Time or Duration:7月4日

  • 2025  理化学研究所  Domestic/International Classification:Japan 

  • 2025  北海道大学  Classification:Affiliate faculty  Domestic/International Classification:Japan 

Acceptance of Foreign Researchers, etc.

  • カーボンニュートラル・エネルギー国際研究所

    Acceptance period: 2024.9 - Present   (Period):1 month or more

    Nationality:Saudi Arabia

    Business entity:Ministry of education

Travel Abroad

  • 2024.6

    Staying countory name 1:Switzerland   Staying institution name 1:チューリッヒ応用科学大学