Updated on 2025/06/15

Information

 

写真a

 
OGIWARA NAOKI
 
Organization
Center of Advanced Instrumental Analysis Associate Professor
Interdisciplinary Graduate School of Engineering Sciences Department of Interdisciplinary Engineering Sciences(Concurrent)
Title
Associate Professor
Contact information
メールアドレス
Tel
0925837149
Profile
【研究】 無機・錯体材料に対して、機器分析を駆使することで、新奇機能・物性の発現を目指しています。具体的には、金属酸化物クラスター、多孔性金属錯体、金属ナノ粒子等の分子・結晶構造や電子状態の解析により、構造―機能の相関を理解することで、分子やイオンの吸着・伝導・変換への応用を試みています。 【センター運営】 機器利用ユーザーの満足度の向上のために、装置のアップデート、装置マニュアルの作成、利用システムのDX化等を進めています。またセンター装置の外部利用増加の促進に向けて、センターの広報活動も行っています。

Research Areas

  • Nanotechnology/Materials / Inorganic/coordination chemistry

  • Nanotechnology/Materials / Inorganic compounds and inorganic materials chemistry

  • Nanotechnology/Materials / Nanomaterials

Degree

  • Doctor of Science (DSc) ( 2019.3 Kyoto University )

  • 修士(工学) ( 2016.3 Kyoto University )

  • 学士(工学) ( 2014.3 Kyoto University )

Research History

  • The University of Tokyo Graduate School of Arts and Sciences Assistant Professor 

    2020.4 - 2024.3

  • Tokyo Institute of Technology  Institute of Innovative Research Postdoctoral Researcher 

    2019.4 - 2020.3

  • 日本学術振興会   特別研究員 DC2  

    2017.4 - 2019.3

Education

  • Kyoto University   Graduate School of Science   Department of Chemistry

    2016.4 - 2019.3

  • Kyoto University   Graduate School of Engineering   department of Synthetic Chemistry and Biological Chemistry

    2014.4 - 2016.3

  • Kyoto University   Faculty of Engineering   Department of Industrial Chemistry

    2010.4 - 2014.3

Research Interests・Research Keywords

  • Research theme: Nanocomposite-based Catalysts

    Keyword: 酸化物クラスター、ナノ金属、触媒

    Research period: 2017 - Present

  • Research theme: Adsorption Behavior in Nanoconfined Spaces

    Keyword: 多孔性金属錯体、吸着

    Research period: 2015 - Present

  • Research theme: Design of Ion Conductors and Elucidation of Molecular Dynamics

    Keyword: イオン伝導、固体NMR

    Research period: 2014 - Present

Awards

  • Excellent Presentation Award

    2024.10   The 1st International Frontier Interdisciplinary Forum on Crystalline Porous Particles,CCPT13(Chinese Society of Particuology)   Polyoxometalate-Based Porous Materials for Catalysis and Adsorption

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    Award type:Award from international society, conference, symposium, etc. 

  • 36th Inoue Research Award for Young Scientists

    2019.2   Inoue Foundation for Science   金属ナノ粒子と多孔性金属錯体の複合化による水の反応性の制御

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    Award type:Award from publisher, newspaper, foundation, etc. 

  • Best Poster Award

    2018.10   Americas International Meeting on Electrochemistry and Solid State Science (AiMES2018)   Water-Gas Shift Reaction Activity of Pt Nanoparticles Hybridized with Metal Organic Frameworks

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    Award type:Award from international society, conference, symposium, etc. 

  • Journal of Materials Chemistry A poster prizes

    2018.8   43rd International Conference on Coordination Chemistry (ICCC 2018)   Water-Gas Shift Reaction Activity of Pt Nanocrystals Hybridized with Metal Organic Frameworks

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    Award type:Award from international society, conference, symposium, etc. 

Papers

  • Flexible organic–inorganic hybrid crystals of tin(iv) chloride and naphthalenediimide: exploring elasticity, mechanochromism, and photothermal conversion

    Sotaro Kusumoto, Shunya Masuda, Ryo Suzuki, Masaru Tachibana, Masaya Shimabukuro, Mamiko Kobayashi, Naoki Ogiwara, Sayaka Uchida, Tomoya Fukui, Yuta Tsuji, Masaya Okamura, Shiro Hikichi, Yang Kim, Yoshihiro Koide

    Journal of Materials Chemistry C   13 ( 17 )   8470 - 8478   2025.3   ISSN:2050-7526 eISSN:2050-7534

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    Publishing type:Research paper (scientific journal)   Publisher:Journal of Materials Chemistry C  

    Organic-inorganic hybrid metal halides (OIMHs) are emerging functional materials with diverse applications. However, the exploration of mechanically soft OIMHs remains limited. This study introduces tin(iv) OIMH crystals (1 and 1w), incorporating a naphthalenediimide (NDI)-based organic cation (3pmNDI), which exhibit elastic flexibility, mechanochromism, and photothermal conversion. The unique one-dimensional (1D) slip-stacked assembly of 3pmNDI cations, influenced by the presence or absence of lattice water (1wvs.1), dictates their mechanical properties and chromic behavior. Compound 1 exhibits an exceptionally low elastic modulus (Er = 1.84 ± 0.21 GPa), as measured by nanoindentation, and a photothermal conversion efficiency of 63%. These findings showcase the potential of OIMHs as multifunctional flexible crystals.

    DOI: 10.1039/d5tc00891c

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  • Solid-state stepwise temperature-programmable synthesis of bioinspired Fe-N-C oxygen reduction electrocatalyst featuring Fe-N5 configuration

    Sang, W; Chaemchuen, S; Zhang, LY; Wang, ZC; Li, XC; Nagasaka, CA; Xiong, M; Ogiwara, N; Chen, C; Wang, Z; Zhang, J; Verpoort, F; Mu, SC; Kou, ZK; Wang, TT

    NANO RESEARCH   18 ( 3 )   2025.3   ISSN:1998-0124 eISSN:1998-0000

  • Mechanistic characterization of polyethylene by incorporating fly ash

    Ririt Aprilin Sumarsono, Yuya Sakai, Naoki Ogiwara, Sayaka Uchida, Shintaro Nakagawa, Naoko Yoshie

    Composites Part B: Engineering   287   2024.12   ISSN:1359-8368 eISSN:1879-1069

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    DOI: 10.1016/j.compositesb.2024.111864

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  • Simultaneous productions of high-purity calcium carbonate and amorphous nanosized silica-rich gel from waste concrete powder by alkaline treatment and carbonation

    Lei Liu, Guangfeng Ou, Lei Xu, Naoki Ogiwara, Sayaka Uchida, Huaming Yang, Yuya Sakai

    Journal of Environmental Management   372   123319 - 123319   2024.12   ISSN:0301-4797 eISSN:1095-8630

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.jenvman.2024.123319

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  • The Nature of Structural Defects in ZIF‐8 Revealed with <sup>1</sup>H and <sup>31</sup>P MAS NMR and X‐Ray Absorption Spectroscopy

    Anton A. Gabrienko, Somboon Chaemchuen, Zongkui Kou, Naoki Ogiwara, Hiroshi Kitagawa, Alexander E. Khudozhitkov, Alexander G. Stepanov, Daniil I. Kolokolov, Francis Verpoort

    Angewandte Chemie International Edition   64 ( 2 )   e202414823   2024.11   ISSN:1521-3773 eISSN:1521-3773

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.202414823

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  • Pore design of POM@MOF hybrids for enhanced methylene blue capture

    Shotaro Miyazaki, Naoki Ogiwara, Cocoro A Nagasaka, Kanta Takiishi, Miki Inada, Sayaka Uchida

    Bulletin of the Chemical Society of Japan   97 ( 10 )   2024.10   ISSN:0009-2673 eISSN:1348-0634

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    Publishing type:Research paper (scientific journal)   Publisher:Bulletin of the Chemical Society of Japan  

    Adsorption of methylene blue from aqueous effluents is a key technique to treat wastewater discharge from chemical industries. Toward methylene blue adsorption, porous metal-organic frameworks have been promising owing to their high surface areas and tunable porosity. The incorporation of polyoxometalates (POMs) into metal-organic frameworks has been found to facilitate methylene blue adsorption due to electrostatic interactions between the anionic polyoxometalate and the cationic methylene blue. However, it remains unclear how the customizable pore of POM@MOF hybrids affects the capture of methylene blue. In this work, we study the effect of the size and environment of metal-organic frameworks on the property of methylene blue capture for [Zr6O4(OH)4(1,4-benzenedicarboxylate)6] (UiO-66) embedding an αKeggin-type polyoxometalate [α-SiW12O40]4− (SiW12). Tuning pore size and environment based on ligand engineering of the metal-organic frameworks suggests that (i) lengthening the organic linkers and (ii) functionalization of the linker with −NO2 groups could enhance the methylene blue uptakes. Notably, an increase in the loading amounts of SiW12 on UiO-66 functionalized with −NO2 groups led to outstanding methylene blue capture, comparable to that of representative zeolites such as ZSM-5 and zeolite Y.

    DOI: 10.1093/bulcsj/uoae105

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  • Assembled Structures and Electrical Conductivities of Salts Comprised of Cationic Sandwich Complexes and Polyoxometalates

    Ryota Inoue, Naoki Ogiwara, Sayaka Uchida, Tomoyuki Mochida

    Inorganic Chemistry   63 ( 40 )   18830 - 18837   2024.10   ISSN:0020-1669 eISSN:1520-510X

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    DOI: 10.1021/acs.inorgchem.4c02890

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  • Tuning Proton Conduction by Staggered Arrays of Polar Preyssler-Type Oxoclusters

    Tsukasa Iwano, Daiki Akutsu, Hiroki Ubukata, Naoki Ogiwara, Yuji Kikukawa, Shuo Wang, Li-Kai Yan, Hiroshi Kageyama, Sayaka Uchida

    Journal of the American Chemical Society   146 ( 38 )   26113 - 26120   2024.8   ISSN:0002-7863 eISSN:1520-5126

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    DOI: 10.1021/jacs.4c06743

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  • Dynamics of Linkers in Metal–Organic Framework Glasses

    Alexander E. Khudozhitkov, Naoki Ogiwara, Masaki Donoshita, Hirokazu Kobayashi, Alexander G. Stepanov, Daniil I. Kolokolov, Hiroshi Kitagawa

    Journal of the American Chemical Society   146 ( 19 )   12950 - 12957   2024.5   ISSN:0002-7863 eISSN:1520-5126

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Journal of the American Chemical Society  

    Metal-organic framework (MOF) glasses have emerged as a new class of organic-inorganic hybrid glass materials. Considerable efforts have been devoted to unraveling the macroscopic dynamics of MOF glasses by studying their rheological behavior; however, their microscopic dynamics remain unclear. In this work, we studied the effect of vitrification on linker dynamics in ZIF-62 by solid-state 2H nuclear magnetic resonance (NMR) spectroscopy. 2H NMR relaxation analysis provided a detailed picture of the mobility of the ZIF-62 linkers, including local restricted librations and a large-amplitude twist; these details were verified by molecular dynamics. A comparison of ZIF-62 crystals and glasses revealed that vitrification does not drastically affect the fast individual flipping motions with large-amplitude twists, whereas it facilitates slow cooperative large-amplitude twist motions with a decrease in the activation barrier. These observations support the findings of previous studies, indicating that glassy ZIF-62 retains permanent porosity and that short-range disorder exists in the alignment of ligands because of distortion of the coordination angle.

    DOI: 10.1021/jacs.3c13156

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  • Reduction‐Induced Uptake of Cs+ in Metal–Organic Frameworks Loaded with Polyoxometalates

    Cocoro A. Nagasaka, Naoki Ogiwara, Shunsuke Kobayashi, Sayaka Uchida

    Small   20 ( 17 )   e2307004   2024.4   ISSN:1613-6810 eISSN:1613-6829

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    DOI: 10.1002/smll.202307004

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  • Cationic Al oxo-hydroxide clusters: syntheses, molecular structures, and functional applications

    Naoki Ogiwara, Wei Zhou, Sayaka Uchida

    Chemical Science   15 ( 46 )   19212 - 19224   2024   ISSN:2041-6520 eISSN:2041-6539

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    DOI: 10.1039/D4SC05707D

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  • Role of thermo-alkaline-oxidized kraft lignin aided by concrete waste as a potential reinforcement material in botanical concrete

    Ren Wei, Yuya Sakai, Naoki Ogiwara, Sayaka Uchida

    Construction and Building Materials   406   2023.11   ISSN:0950-0618 eISSN:1879-0526

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    DOI: 10.1016/j.conbuildmat.2023.133434

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  • Surpassing Pt hydrogen production from {200} facet-riched polyhedral Rh2P nanoparticles by one-step synthesis

    Hongqiang Xin, Lan Sun, Yiwei Zhao, Zhengfei Dai, Qiaomei Luo, Shengwu Guo, Danyang Li, Ya Chen, Naoki Ogiwara, Hiroshi Kitagawa, Bo Huang, Fei Ma

    Applied Catalysis B: Environmental   330   122645 - 122645   2023.8   ISSN:0926-3373 eISSN:1873-3883

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    DOI: 10.1016/j.apcatb.2023.122645

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  • Direct synthesis of construction material from low-quality sand reacted with KOH and ethanol

    Pengcheng QIU, Yuya Sakai, Yuki Tamura, Naoki Ogiwara, Sayaka Uchida

    Construction and Building Materials   392   131906 - 131906   2023.8   ISSN:0950-0618 eISSN:1879-0526

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    DOI: 10.1016/j.conbuildmat.2023.131906

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  • Metal–oxo-cluster-based crystals as solid catalysts

    Naoki Ogiwara, Sayaka Uchida

    Chem Catalysis   3 ( 7 )   100607 - 100607   2023.7   ISSN:2667-1093

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    DOI: 10.1016/j.checat.2023.100607

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  • Bismuth Substitution in HSbOI with Positively-charged Oxide Clusters

    Yuki Watanabe, Tatsuhiko Goto, Jingxin Xia, Naoki Ogiwara, Hiroyasu Tabe, Satoshi Horike, Yasuto Noda, Sayaka Uchida, Hiroshi Kageyama

    Chemistry Letters   52 ( 6 )   430 - 433   2023.6   ISSN:0366-7022 eISSN:1348-0715

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    DOI: 10.1246/cl.230077

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  • Size‐Controlled Synthesis of Luminescent Few‐Atom Silver Clusters via Electron Transfer in Isostructural Redox‐Active Porous Ionic Crystals

    Naoya Haraguchi, Naoki Ogiwara, Yoshitaka Kumabe, Soichi Kikkawa, Seiji Yamazoe, Takashi Tachikawa, Sayaka Uchida

    Small   19 ( 23 )   e2300743   2023.6   ISSN:1613-6810 eISSN:1613-6829

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    DOI: 10.1002/smll.202300743

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  • A redox-active inorganic crown ether based on a polyoxometalate capsule

    Nanako Tamai, Naoki Ogiwara, Eri Hayashi, Keigo Kamata, Toshiyuki Misawa, Takeru Ito, Tatsuhiro Kojima, Mireia Segado, Enric Petrus, Carles Bo, Sayaka Uchida

    Chemical Science   14 ( 20 )   5453 - 5459   2023   ISSN:2041-6520 eISSN:2041-6539

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    DOI: 10.1039/D3SC01077E

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  • Bonding mechanism of botanical concrete: Microstructural changes between waste concrete powder and wood

    Ren Wei, Yuya Sakai, Naoki Ogiwara, Sayaka Uchida

    Journal of Cleaner Production   378   2022.12   ISSN:0959-6526 eISSN:1879-1786

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    DOI: 10.1016/j.jclepro.2022.134505

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  • Proton conduction in ionic crystals based on polyoxometalates

    Naoki Ogiwara, Tsukasa Iwano, Takeru Ito, Sayaka Uchida

    Coordination Chemistry Reviews   462   214524 - 214524   2022.7   ISSN:0010-8545 eISSN:1873-3840

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    DOI: 10.1016/j.ccr.2022.214524

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  • Polyoxocationic antimony oxide cluster with acidic protons

    Yuki Watanabe, Kim Hyeon-Deuk, Takafumi Yamamoto, Masayoshi Yabuuchi, Olesia Karakulina, Yasuto Noda, Takuya Kurihara, I-Ya Chang, Masanobu Higashi, Osamu Tomita, Cedric Tassel, Daichi Kato, Jingxin Xia, Tatsuhiko Goto, Craig M. Brown, Yuto Shimoyama, Naoki Ogiwara, Joke Hadermann, Artem Abakumov, Sayaka Uchida, Ryu Abe, Hiroshi Kageyama

    Science Advances   8 ( 24 )   eabm5379   2022.6   ISSN:2375-2548

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Association for the Advancement of Science ({AAAS})  

    <jats:p>
    The success and continued expansion of research on metal-oxo clusters owe largely to their structural richness and wide range of functions. However, while most of them known to date are negatively charged polyoxometalates, there is only a handful of cationic ones, much less functional ones. Here, we show an all-inorganic hydroxyiodide [H
    <jats:sub>10.7</jats:sub>
    Sb
    <jats:sub>32.1</jats:sub>
    O
    <jats:sub>44</jats:sub>
    ][H
    <jats:sub>2.1</jats:sub>
    Sb
    <jats:sub>2.1</jats:sub>
    I
    <jats:sub>8</jats:sub>
    O
    <jats:sub>6</jats:sub>
    ][Sb
    <jats:sub>0.76</jats:sub>
    I
    <jats:sub>6</jats:sub>
    ]
    <jats:sub>2</jats:sub>
    ·25H
    <jats:sub>2</jats:sub>
    O (
    <jats:bold>HSbOI</jats:bold>
    ), forming a face-centered cubic structure with cationic Sb
    <jats:sub>32</jats:sub>
    O
    <jats:sub>44</jats:sub>
    clusters and two types of anionic clusters in its interstitial spaces. Although it is submicrometer in size, electron diffraction tomography of
    <jats:bold>HSbOI</jats:bold>
    allowed the construction of the initial structural model, followed by powder Rietveld refinement to reach the final structure. The cationic cluster is characterized by the presence of acidic protons on its surface due to substantial Sb
    <jats:sup>3+</jats:sup>
    deficiencies, which enables
    <jats:bold>HSbOI</jats:bold>
    to serve as an excellent solid acid catalyst. These results open up a frontier for the exploration and functionalization of cationic metal-oxo clusters containing heavy main group elements.
    </jats:p>

    DOI: 10.1126/sciadv.abm5379

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  • Syntheses, Polymorphic Transformations, and Functions of Ionic Crystals Based on Mononuclear Bismuth(III) Complexes and Polyoxometalates

    Tsukasa Iwano, Daiki Akutsu, Zhewei Weng, Naoki Ogiwara, Sayaka Uchida

    ChemNanoMat   8 ( 5 )   2022.5   ISSN:2199-692X

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/cnma.202100479

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  • Phase Control of Solid-Solution Nanoparticles beyond the Phase Diagram for Enhanced Catalytic Properties

    Dongshuang Wu, Kohei Kusada, Susan Meñez Aspera, Hiroshi Nakanishi, Yanna CHEN, Okkyun SEO, Chulho Song, Jaemyung Kim, Satoshi Hiroi, Osami Sakata, Tomokazu Yamamoto, Syo Matsumura, Yusuke Nanba, Michihisa Koyama, Naoki Ogiwara, Shogo Kawaguchi, Yoshiki Kubota, Hiroshi Kitagawa

    ACS Materials Au   2 ( 2 )   110 - 116   2022.3   ISSN:2694-2461 eISSN:2694-2461

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    The crystal structure, which intrinsically affects the properties of solids, is determined by the constituent elements and composition of solids. Therefore, it cannot be easily controlled beyond the phase diagram because of thermodynamic limitations. Here, we demonstrate the first example of controlling the crystal structures of a solid-solution nanoparticle (NP) entirely without changing its composition and size. We synthesized face-centered cubic (fcc) or hexagonal close-packed (hcp) structured PdxRu1-x NPs (x = 0.4, 0.5, and 0.6), although they cannot be synthesized as bulk materials. Crystal-structure control greatly improves the catalytic properties; that is, the hcp-PdxRu1-x NPs exceed their fcc counterparts toward the oxygen evolution reaction (OER) in corrosive acid. These NPs only require an overpotential (η) of 200 mV at 10 mA cm-2, can maintain the activity for more than 20 h, greatly outperforming the fcc-Pd0.4Ru0.6 NPs (η = 280 mV, 9 min), and are among the most efficient OER catalysts reported. Synchrotron X-ray-based spectroscopy, atomic-resolution electron microscopy, and density functional theory (DFT) calculations suggest that the enhanced OER performance of hcp-PdRu originates from the high stability against oxidative dissolution.

    DOI: 10.1021/acsmaterialsau.1c00048

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  • Oxygen Evolution Reaction Driven by Charge Transfer from a Cr Complex to Co-Containing Polyoxometalate in a Porous Ionic Crystal

    Yuto Shimoyama, Naoki Ogiwara, Zhewei Weng, Sayaka Uchida

    Journal of the American Chemical Society   144 ( 7 )   2980 - 2986   2022.2   ISSN:0002-7863 eISSN:1520-5126

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    DOI: 10.1021/jacs.1c10471

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  • Vanadium-substituted polycationic Al-oxo cluster in a porous ionic crystal exhibiting Lewis acidity

    Wei Zhou, Naoki Ogiwara, Zhewei Weng, Congcong Zhao, Likai Yan, Yuji Kikukawa, Sayaka Uchida

    Chemical Communications   58 ( 90 )   12548 - 12551   2022   ISSN:1359-7345 eISSN:1364-548X

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    DOI: 10.1039/D2CC03545F

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  • Basicity of isostructural porous ionic crystals composed of Nb/Ta-substituted Keggin-type polyoxotungstates

    Zhewei Weng, Naoki Ogiwara, Daisuke Yokogawa, Takashi Kitao, Yuji Kikukawa, Sayaka Uchida

    Dalton Transactions   51 ( 21 )   8186 - 8191   2022   ISSN:1477-9226 eISSN:1477-9234

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D2DT00478J

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  • Recording the Pt-beyond hydrogen production electrocatalysis by dirhodium phosphide with an overpotential of only 4.3 mV in alkaline electrolyte

    Hongqiang Xin, Zhengfei Dai, Yiwei Zhao, Shengwu Guo, Jun Sun, Qiaomei Luo, Pengfei Zhang, Lan Sun, Naoki Ogiwara, Hiroshi Kitagawa, Bo Huang, Fei Ma

    Applied Catalysis B: Environmental   297   120457 - 120457   2021.11   ISSN:0926-3373

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    Publishing type:Research paper (scientific journal)   Publisher:Elsevier {BV}  

    DOI: 10.1016/j.apcatb.2021.120457

  • Fabrication of Integrated Copper‐Based Nanoparticles/Amorphous Metal–Organic Framework by a Facile Spray‐Drying Method: Highly Enhanced CO 2 Hydrogenation Activity for Methanol Synthesis

    Yuko Mitsuka, Naoki Ogiwara, Megumi Mukoyoshi, Hiroshi Kitagawa, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Masaaki Haneda, Shogo Kawaguchi, Yoshiki Kubota, Hirokazu Kobayashi

    Angewandte Chemie International Edition   60 ( 41 )   22283 - 22288   2021.9   ISSN:1433-7851

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.202110585

  • Formation of Mixed‐Valence Luminescent Silver Clusters via Cation‐Coupled Electron‐Transfer in a Redox‐Active Ionic Crystal Based on a Dawson‐type Polyoxometalate with Closed Pores

    Naoya Haraguchi, Tomoki Okunaga, Yuto Shimoyama, Naoki Ogiwara, Soichi Kikkawa, Seiji Yamazoe, Miki Inada, Takashi Tachikawa, Sayaka Uchida

    European Journal of Inorganic Chemistry   2021 ( 16 )   1531 - 1535   2021.4

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/ejic.202100101

  • Ultrahigh Proton Conduction via Extended Hydrogen-Bonding Network in a Preyssler-Type Polyoxometalate-Based Framework Functionalized with a Lanthanide Ion

    Tsukasa Iwano, Kota Shitamatsu, Naoki Ogiwara, Masanari Okuno, Yuji Kikukawa, Satoru Ikemoto, Sora Shirai, Satoshi Muratsugu, Paul G. Waddell, R. John Errington, Masahiro Sadakane, Sayaka Uchida

    ACS Applied Materials & Interfaces   13 ( 16 )   19138 - 19147   2021.4   ISSN:1944-8244

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acsami.1c01752

  • Isomeric effects on the acidity of Al13 Keggin clusters in porous ionic crystals

    Wei Zhou, Naoki Ogiwara, Zhewei Weng, Nanako Tamai, Congcong Zhao, Li-Kai Yan, Sayaka Uchida

    Chemical Communications   2021

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D1CC03600A

  • Incorporating highly basic polyoxometalate anions comprising Nb or Ta into nanoscale reaction fields of porous ionic crystals

    Zhewei Weng, Naoki Ogiwara, Takashi Kitao, Yuji Kikukawa, Yu Gao, Likai Yan, Sayaka Uchida

    Nanoscale   2021

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D1NR04762K

  • Integrating molecular design and crystal engineering approaches in non-humidified intermediate-temperature proton conductors based on a Dawson-type polyoxometalate and poly(ethylene glycol) derivatives

    Naoki Ogiwara, Masahiro Tomoda, Shotaro Miyazaki, Zhewei Weng, Hiroshi Takatsu, Hiroshi Kageyama, Toshiyuki Misawa, Takeru Ito, Sayaka Uchida

    Nanoscale   2021

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D1NR01220G

  • Probing dynamics of carbon dioxide in a metal–organic framework under high pressure by high-resolution solid-state NMR

    Munehiro Inukai, Takuya Kurihara, Yasuto Noda, Weiming Jiang, Kiyonori Takegoshi, Naoki Ogiwara, Hiroshi Kitagawa, Koichi Nakamura

    Physical Chemistry Chemical Physics   2020

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D0CP01216E

  • Isostructural mesoporous ionic crystals as a tunable platform for acid catalysis

    Yuto Shimoyama, Zhewei Weng, Naoki Ogiwara, Takashi Kitao, Yuji Kikukawa, Sayaka Uchida

    Dalton Transactions   2020

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D0DT01202E

  • Crystalline to amorphous transformation in solid-solution alloy nanoparticles induced by boron doping

    Keigo Kobayashi, Kohei Kusada, Dongshuang Wu, Naoki Ogiwara, Hirokazu Kobayashi, Mitsutaka Haruta, Hiroki Kurata, Satoshi Hiroi, Okkyun Seo, Chulho Song, Yanna Chen, Jaemyung Kim, Akhil Tayal, Osami Sakata, Koji Ohara, Tetsuo Honma, Hiroshi Kitagawa

    Chemical Communications   2020

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/D0CC05418F

  • Missing-linker metal-organic frameworks for oxygen evolution reaction

    Ziqian Xue, Kang Liu, Qinglin Liu, Yinle Li, Manrong Li, Cheng-Yong Su, Naoki Ogiwara, Hirokazu Kobayashi, Hiroshi Kitagawa, Min Liu, Guangqin Li

    Nature Communications   2019.11

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41467-019-13051-2

  • The First Study on the Reactivity of Water Vapor in Metal–Organic Frameworks with Platinum Nanocrystals

    Naoki Ogiwara, Hirokazu Kobayashi, Patricia Concepción, Fernando Rey, Hiroshi Kitagawa

    Angewandte Chemie International Edition   58 ( 34 )   11731 - 11736   2019.8

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.201905667

  • Coating of 2D Flexible Metal–Organic Frameworks on Metal Nanocrystals

    Naoki Ogiwara, Hirokazu Kobayashi, Keigo Kobayashi, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Hiroshi Kitagawa

    Chemistry Letters   48 ( 2 )   173 - 176   2019.2   ISSN:0366-7022

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    Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    DOI: 10.1246/cl.180931

  • The effect of amorphization on the molecular motion of the 2-methylimidazolate linkers in ZIF-8

    Naoki Ogiwara, Daniil I. Kolokolov, Masaki Donoshita, Hirokazu Kobayashi, Satoshi Horike, Alexander G. Stepanov, Hiroshi Kitagawa

    Chemical Communications   2019

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/C9CC02673H

  • Ligand-Functionalization-Controlled Activity of Metal–Organic Framework-Encapsulated Pt Nanocatalyst toward Activation of Water

    Naoki Ogiwara, Hirokazu Kobayashi, Munehiro Inukai, Yusuke Nishiyama, Patricia Concepción, Fernando Rey, Hiroshi Kitagawa

    Nano Letters   20 ( 1 )   426 - 432   2019   ISSN:1530-6984

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acs.nanolett.9b04124

  • Solid-solution alloy nanoparticles of a combination of immiscible Au and Ru with a large gap of reduction potential and their enhanced oxygen evolution reaction performance

    Quan Zhang, Kohei Kusada, Dongshuang Wu, Naoki Ogiwara, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Shogo Kawaguchi, Yoshiki Kubota, Tetsuo Honma, Hiroshi Kitagawa

    Chemical Science   10 ( 19 )   5133 - 5137   2019   ISSN:2041-6520

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/c9sc00496c

  • Conductive metal–organic framework nanowire arrays for electrocatalytic oxygen evolution

    Wen-Hua Li, Jiangquan Lv, Qiaohong Li, Jiafang Xie, Naoki Ogiwara, Yiyin Huang, Huijie Jiang, Hiroshi Kitagawa, Gang Xu, Yaobing Wang

    Journal of Materials Chemistry A   7 ( 17 )   10431 - 10438   2019   ISSN:2050-7488

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/c9ta02169h

  • Charge transfer dependence on CO2 hydrogenation activity to methanol in Cu nanoparticles covered with metal–organic framework systems

    Hirokazu Kobayashi, Jared M. Taylor, Yuko Mitsuka, Naoki Ogiwara, Tomokazu Yamamoto, Takaaki Toriyama, Syo Matsumura, Hiroshi Kitagawa

    Chemical Science   10 ( 11 )   3289 - 3294   2019   ISSN:2041-6520

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/c8sc05441j

  • Lanthanide-Based Porous Coordination Polymers: Syntheses, Slow Relaxation of Magnetization, and Magnetocaloric Effect

    Chinmoy Das, Apoorva Upadhyay, Kamal Uddin Ansari, Naoki Ogiwara, Takashi Kitao, Satoshi Horike, Maheswaran Shanmugam

    Inorganic Chemistry   57 ( 11 )   6584 - 6598   2018.5   ISSN:0020-1669

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acs.inorgchem.8b00720

  • Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels

    Shuto Mochizuki, Naoki Ogiwara, Masayoshi Takayanagi, Masataka Nagaoka, Susumu Kitagawa, Takashi Uemura

    Nature Communications   2018.1

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41467-017-02736-1

  • Mechanical Alloying of Metal-Organic Frameworks

    Tamas Panda, Satoshi Horike, Keisuke Hagi, Naoki Ogiwara, Kentaro Kadota, Tomoya Itakura, Masahiko Tsujimoto, Susumu Kitagawa

    Angewandte Chemie International Edition   56 ( 9 )   2413 - 2417   2017.1   ISSN:1433-7851

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.201612587

  • Imidazolium cation transportation in a 1-D coordination polymer

    Wenqian Chen, Naoki Ogiwara, Kentaro Kadota, Kitt Panyarat, Susumu Kitagawa, Satoshi Horike

    Dalton Transactions   46 ( 33 )   10798 - 10801   2017   ISSN:1477-9226

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/c7dt02625k

  • Encapsulating Mobile Proton Carriers into Structural Defects in Coordination Polymer Crystals: High Anhydrous Proton Conduction and Fuel Cell Application

    Munehiro Inukai and Satoshi Horike and Tomoya Itakura and Ryota Shinozaki and Naoki Ogiwara and Daiki Umeyama and Sanjog Nagarkar and Yusuke Nishiyama and Michal Malon and Akari Hayashi and Takashi Ohhara and Ryoji Kiyanagi and Susumu Kitagawa

    Journal of the American Chemical Society   138 ( 27 )   8505 - 8511   2016.7   ISSN:0002-7863

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    Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/jacs.6b03625

  • Fast Conduction of Organic Cations in Metal Sulfate Frameworks

    Naoki Ogiwara, Munehiro Inukai, Tomoya Itakura, Satoshi Horike, Susumu Kitagawa

    Chemistry of Materials   28 ( 11 )   3968 - 3975   2016.5   ISSN:0897-4756

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acs.chemmater.6b01284

  • Direct Synthesis of Hierarchically Porous Metal–Organic Frameworks with High Stability and Strong Brønsted Acidity: The Decisive Role of Hafnium in Efficient and Selective Fructose Dehydration

    Zhigang Hu, Yongwu Peng, Yongjun Gao, Yuhong Qian, Shaoming Ying, Daqiang Yuan, Satoshi Horike, Naoki Ogiwara, Ravichandar Babarao, Yuxiang Wang, Ning Yan, Dan Zhao

    Chemistry of Materials   28 ( 8 )   2659 - 2667   2016.4   ISSN:0897-4756

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acs.chemmater.6b00139

  • Glass Formation of a Coordination Polymer Crystal for Enhanced Proton Conductivity and Material Flexibility

    Wenqian Chen, Satoshi Horike, Daiki Umeyama, Naoki Ogiwara, Tomoya Itakura, Cédric Tassel, Yoshihiro Goto, Hiroshi Kageyama, Susumu Kitagawa

    Angewandte Chemie International Edition   55 ( 17 )   5195 - 5200   2016.4   ISSN:1433-7851

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.201600123

  • A pH-responsive phase transformation of a sulfonated metal–organic framework from amorphous to crystalline for efficient CO2capture

    Zhigang Hu, Jiajin Lin, Naoki Ogiwara, Alvaro Rodriguez, Yongwu Peng, Yuxiang Wang, Satoshi Horike, Dan Zhao

    CrystEngComm   18 ( 16 )   2803 - 2807   2016   ISSN:1466-8033

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/c6ce00369a

  • Crystal engineering of a family of hybrid ultramicroporous materials based upon interpenetration and dichromate linkers

    Hayley S. Scott, Naoki Ogiwara, Kai-Jie Chen, David G. Madden, Tony Pham, Katherine Forrest, Brian Space, Satoshi Horike, John J. Perry IV, Susumu Kitagawa, Michael J. Zaworotko

    Chemical Science   7 ( 8 )   5470 - 5476   2016   ISSN:2041-6520

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/c6sc01385f

  • Control of Molecular Rotor Rotational Frequencies in Porous Coordination Polymers Using a Solid-Solution Approach

    Munehiro Inukai, Tomohiro Fukushima, Yuh Hijikata, Naoki Ogiwara, Satoshi Horike, Susumu Kitagawa

    Journal of the American Chemical Society   137 ( 38 )   12183 - 12186   2015.9   ISSN:0002-7863

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/jacs.5b05413

  • Formation of Foam-like Microstructural Carbon Material by Carbonization of Porous Coordination Polymers through a Ligand-Assisted Foaming Process

    Kanokwan Kongpatpanich, Satoshi Horike, Yu-ichi Fujiwara, Naoki Ogiwara, Hirotomo Nishihara, Susumu Kitagawa

    Chemistry - A European Journal   21 ( 38 )   13278 - 13283   2015.8   ISSN:0947-6539

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/chem.201501988

  • Pressure-induced amorphization of a dense coordination polymer and its impact on proton conductivity

    Daiki Umeyama, Satoshi Horike, Cedric Tassel, Hiroshi Kageyama, Yuji Higo, Keisuke Hagi, Naoki Ogiwara, Susumu Kitagawa

    APL Materials   2 ( 12 )   124401 - 124401   2014   ISSN:2166-532X

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    Publishing type:Research paper (scientific journal)   Publisher:{AIP} Publishing  

    DOI: 10.1063/1.4898806

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Presentations

  • Isomeric Effects of Al13 Keggin Clusters as Catalytic Support on Oxidation Reactions

    Naoki Ogiwara, Atsunobu Tateno, Wei Zhou, Sayaka Uchida

    日本化学会 第105春季年会  2025.3  日本化学会

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    Event date: 2025.3

    Presentation type:Oral presentation (general)  

    Venue:関西大学 千里キャンパス  

  • Polyoxometalate-Based Porous Materials for Catalysis and Adsorption Invited International conference

    Naoki Ogiwara

    The 1st International Frontier Interdisciplinary Forum on Crystalline Porous Particles,CCPT13  2024.10  Chinese Society of Particuology

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    Event date: 2024.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Suzhou International Conference Hotel   Country:China  

  • Pore Design of POM@MOF Hybrids for Enhanced Methylene Blue Capture

    Naoki Ogiwara, Shotaro Miyazaki, Cocoro A. Nagasaka, Sayaka Uchida

    錯体化学会 第74回討論会  2024.9  錯体化学会

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    Event date: 2024.9

    Language:English   Presentation type:Poster presentation  

    Venue:岐阜大学  

  • Reduction-Induced Uptake of Cs+ in Metal–Organic Frameworks Loaded with Polyoxometalates International conference

    Naoki Ogiwara, Cocoro A. Nagasaka, Sayaka Uchida

    The 9th International Conference on Metal-Organic Frameworks and Open Framework Compounds (MOF2024)  2024.7 

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    Event date: 2024.7

    Language:English   Presentation type:Poster presentation  

    Venue:Suntec Singapore International Convention and Exhibition Centre   Country:Singapore  

  • ポリオキソメタレートを内包した多孔性金属錯体を利用したメチレンブルー吸着

    荻原 直希、宮崎 翔太郎、内田 さやか

    日本化学会 第104春季年会  2024.3  日本化学会

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    Event date: 2024.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:日本大学理工学部 船橋キャンパス  

  • Reduction-Induced Uptake of Cs+ in Metal–Organic Frameworks Loaded with Polyoxometalates

    Naoki Ogiwara, Cocoro A. Nagasaka, Sayaka Uchida

    錯体化学会 第73回討論会  錯体化学会

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    Event date: 2023.9

    Language:English   Presentation type:Oral presentation (general)  

    Venue:水戸市民会館  

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MISC

Industrial property rights

Patent   Number of applications: 2   Number of registrations: 0
Utility model   Number of applications: 0   Number of registrations: 0
Design   Number of applications: 0   Number of registrations: 0
Trademark   Number of applications: 0   Number of registrations: 0

Professional Memberships

  • The Chemical Society of Japan

    2013.11 - Present

  • Japan Society of Coordination Chemistry

    2020.3 - Present

  • The Japan Society for Analytical Chemistry

    2025.5 - Present

Committee Memberships

  • 触媒学会若手会   世話人(委員)   Domestic

    2020.4 - 2025.3   

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    Committee type:Academic society

  • 錯体化学若手の会    世話人(近畿支部)   Domestic

    2016.1 - 2019.3   

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    Committee type:Academic society

Research Projects

  • イオン性無機ナノ構造体を利用した物質変換

    Grant number:25K00070  2025.4 - 2028.3

    JSPS  Grant-in-Aid for Scientific Research (B) 

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    Authorship:Principal investigator  Grant type:Scientific research funding

  • POM@MOF超セラミックスの創製:イオンの吸脱着・輸送の場として

    Grant number:25H01646  2025.4 - 2027.3

    JSPS  Grant-in-Aid for Transformative Research Areas (A) 

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    Authorship:Principal investigator  Grant type:Scientific research funding

  • NMRを利用したMOFのガラス相におけるダイナミクス解析 International coauthorship

    Grant number: 23K13759  2023.4 - 2025.3

    JSPS  Grant-in-Aid for Early-Career Scientists 

    Naoki Ogiwara

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    Authorship:Principal investigator  Grant type:Scientific research funding

  • POM@MOF超セラミックスが拓く電子・イオンの協奏機能

    Grant number:23H04613  2023.4 - 2025.3

    JSPS  Grant-in-Aid for Transformative Research Areas (A) 

    Naoki Ogiwara

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    Grant type:Scientific research funding

  • Functional Nanomaterials based on Porous Ionic Crystals and Metal Nanoparticles/Nanoclusters

    Grant number:21K14639  2021.4 - 2023.3

    JSPS  Grant-in-Aid for Early-Career Scientists 

    Naoki Ogiwara

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    Authorship:Principal investigator  Grant type:Scientific research funding

  • On the Reactivity of Ammonia in Metal-Organic Frameworks

    Grant number:19K23648  2019.8 - 2021.3

    JSPS  Grant-in-Aid for Research Activity Start-up 

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    Authorship:Principal investigator  Grant type:Scientific research funding

  • MOF/金属ナノ粒子界面の構造解析に基づく相乗的機能の発現 International coauthorship

    Grant number:17J10099  2017.4 - 2019.3

    JSPS  Grant-in-Aid for JSPS Fellows 

    Naoki Ogiwara

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    Grant type:Scientific research funding

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Educational Activities

  • 【講義】 材料機器分析学の講義では、正確な分析のための原理・測定手法の説明に加え、最先端材料の分析事例を紹介することで、院生が所属研究室等で材料研究を行う際に実践的に役立つ分析技術を習得することを目指しています。 【研究室教育】 無機材料の合成・測定・解析を通して、器具の取扱いや測定データの解釈に至るまで、材料研究のノウハウを学生に伝授していきます。またゼミ等を通じて専門的な基礎学力や論理的な思考力、プレゼン能力の習得にも努めていきます。学生との対話を重視し、学生自らが研究の問題点を考えて解決できるように導きます。さらに国内外の学会・セミナーへの参加を促し、産官学を問わず異分野研究者との触れ合いを推奨することで、研究の視野を広げる手助けをしていきたいです。また留学生を受け入れ、国際協同も試みます。これにより、材料研究者としての高い専門性と「総合知」による新しい価値を兼ね備えた人材の育成に貢献していきたいと考えています。

Award for Educational Activities

  • 第2回 相関基礎科学系研究教育奨励賞

    2024.1   東京大学  

  • オンライン授業・ハイブリッド授業のグッドプラクティス 総長表彰

    2021.3   東京大学  

Class subject

  • 材料機器分析学

    2025.4   First semester

FD Participation

  • 2025.4   Role:Participation   Title:令和7年度 第1回全学FD(新任教員FDの研修)The 1st All-University FD (training for new faculty members) in FY2025

    Organizer:University-wide

Social Activities

  • 群馬県立前橋女子高等学校の生徒に向けた講演会・デモ実験

    Role(s):Lecturer, Advisor

    2024.11

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    Audience:High school students

    Type:Seminar, workshop

  • 学術変革A「超セラミックス」の若手スクールにて講演

    Role(s):Lecturer

    超セラミックス  2024.1

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    Audience:College students, Graduate students, Researchesrs

    Type:Seminar, workshop

  • 芝浦工業大学柏中学高等学校にてアンモニア合成のデモ実験

    Role(s):Demonstrator

    2019.11

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    Audience:High school students

    Type:Visiting lecture

  • 奈良県立奈良高等学校化学部への研究指導

    Role(s):Advisor

    2016.12

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    Audience:High school students

    Type:Research consultation

Activities contributing to policy formation, academic promotion, etc.

  • 2023.4 - Present  

    文部科学省 科学技術・学術政策研究所(NISTEP)科学技術予測・政策基盤調査研究センター 科学技術専門家ネットワーク 専門調査員

Travel Abroad

  • 2024.10

    Staying countory name 1:China   Staying institution name 1:上海大学

  • 2024.10

    Staying countory name 1:China   Staying institution name 1:The 1st International Frontier Interdisciplinary Forum on Crystalline Porous Particles,CCPT13 (Chinese Society of Particuology)

  • 2024.10

    Staying countory name 1:China   Staying institution name 1:東華大学

  • 2024.7

    Staying countory name 1:Singapore   Staying institution name 1:The 9th International Conference on Metal-Organic Frameworks and Open Framework Compounds (MOF2024)

  • 2018.11

    Staying countory name 1:Spain   Staying institution name 1:Instituto de Tecnología Química (ITQ)

  • 2018.10

    Staying countory name 1:Mexico   Staying institution name 1:Americas International Meeting on Electrochemistry and Solid State Science (AiMES2018)

  • 2017.6 - 2017.7

    Staying countory name 1:Germany   Staying institution name 1:Lindau Nobel Laureate Meetings

  • 2016.9

    Staying countory name 1:Russian Federation   Staying institution name 1: International Workshop on Porous Coordination Compounds

  • 2015.1 - 2015.2

    Staying countory name 1:Ireland   Staying institution name 1:University of Limerick

  • 2014.11

    Staying countory name 1:India   Staying institution name 1:Indian Institute of Technology, Bombay

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