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Masahiro Kishida Last modified date:2023.09.28

Professor / Molecular System and Biosystem Engineering Laboratory
Department of Chemical Engineering
Faculty of Engineering


Graduate School
Undergraduate School


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Homepage
https://kyushu-u.elsevierpure.com/en/persons/masahiro-kishida
 Reseacher Profiling Tool Kyushu University Pure
http://www.chem-eng.kyushu-u.ac.jp/
See Kishida Lab. .
Academic Degree
Doctoral Degree of Engineering
Country of degree conferring institution (Overseas)
No
Field of Specialization
Chemical Engineering, Catalyitc Reaction Engineering, Material Engineering
Total Priod of education and research career in the foreign country
01years00months
Outline Activities
The following studies have been carried out:
1) Application of supported metal catalysts onto oxidation/reduction of toxic metal ions in aqueous phase.
2) Preparation of silica nanocapsules containing various organic compound (ex. homogeneous catalysts).
3) Mechanism elucidation of new exothermic phenomenon in alloys in hydrogen

I teach the following subjects:
1) "Experimentation No.3 on Materials Science and Engineering"
2) "Reaction Engineerings 1 and 2" for 2nd grader and 3rd grader
3) "Functionalized Chemical Materials" and "Material Process Engineering" for graduate students

I possitively participate various research projects and accept researches trusted by companies.
Research
Research Interests
  • Development of supported Pt catalysts for dehydrogenation of methylcyclohexane
    keyword : dehydrogenation, hydrogen production, platinum catalyst
    2018.04~2023.03The following studies have been carried out: 1) Synthesis and silica-coating of nanoparticles (1-10nm) by using micellar method. 2) Nano-coating of submicron-sized inorganic particles with nano-scaled silica layer 3) Synthesis of monodispersed nanoparticles (50-100nm) by using a novel technique..
  • Verification of anomalous heating phenomena from metal alloy in hydrogen
    keyword : anormalous heat, hydrogen, metal alloy
    2016.10~2023.03The following studies have been carried out: 1) Synthesis and silica-coating of nanoparticles (1-10nm) by using micellar method. 2) Nano-coating of submicron-sized inorganic particles with nano-scaled silica layer 3) Synthesis of monodispersed nanoparticles (50-100nm) by using a novel technique..
  • Oxidation/Reduction of toxic metal ions over supported metal catalysts in aqueous solution
    keyword : toxic metal, supported metal catalyst, oxidation/reduction
    2015.04~2023.03The following studies have been carried out: 1) Synthesis and silica-coating of nanoparticles (1-10nm) by using micellar method. 2) Nano-coating of submicron-sized inorganic particles with nano-scaled silica layer 3) Synthesis of monodispersed nanoparticles (50-100nm) by using a novel technique..
  • Preparation of silica nanocapsules involving various organic molecules
    keyword : nanocapsules, involving organic molecules, silica
    2011.04~2016.03The following studies have been carried out: 1) Synthesis and silica-coating of nanoparticles (1-10nm) by using micellar method. 2) Nano-coating of submicron-sized inorganic particles with nano-scaled silica layer 3) Synthesis of monodispersed nanoparticles (50-100nm) by using a novel technique..
  • Development of electrocatalysts in PEFC by using silica-coating
    keyword : Long life, Electrocatalyst, Fuel cell, Polymer electrolyte, Platinum
    2005.04~2016.03The following studies have been carried out: 1) Novel catalytic behavior of silica-coated metal nanoparticles for hydrogen-production reactions. 2) Development of electrode catalysts for PEFC using silica-coated Pt nanoparticles. 3) Preparation of magnetic silica nanobeads with an enzyme, of which activity can be maintained in organic solvent..
  • Study on synthesis of metal nanoparticles and their coating with silica
    keyword : nanoparticles, silica-coating
    1999.04~2016.03The following studies have been carried out: 1) Synthesis and silica-coating of nanoparticles (1-10nm) by using micellar method. 2) Nano-coating of submicron-sized inorganic particles with nano-scaled silica layer 3) Synthesis of monodispersed nanoparticles (50-100nm) by using a novel technique..
  • Development of catalytic performance of supported metal catalysts by using silica-coating
    keyword : silica-coating, supported catalysts, long life
    2002.04~2016.03The following studies have been carried out: 1) Novel catalytic behavior of silica-coated metal nanoparticles for hydrogen-production reactions. 2) Development of electrode catalysts for PEFC using silica-coated Pt nanoparticles. 3) Preparation of magnetic silica nanobeads with an enzyme, of which activity can be maintained in organic solvent..
  • Differentiation Dynamics of ES Cells Suspended with Optical Tweezers Using Single Cell Observation
    keyword : optical tweezers, ES Cells, Differentiation Dynamics
    2005.04~2009.03Differentiation Dynamics of ES Cells Suspended with Optical Tweezers Using Single Cell Observation. We have constructed the system required for the observation of a single cell trapped with optical tweezers. (Figure 1) The optical tweezers consists of Nd3+:YAG laser beams (λ = 1064 nm) that goes through a microscope objective into the chamber that allows a continuous flow of a medium for cultivating ES cells. We trapped a single ES cell and kept it suspended in a culture medium without touching to a support or the other cells, and subsequently monitored the behavior of the single ES cell after supplementing a variety of chemicals into a flow chamber. The single cell trapped with the optical tweezers kept moving without escaping from the tweezers during the cultivation. After 24h, a single ES cell divided into two cells, which indicates laser tweezers did not do any harm to the trapped cell..
Current and Past Project
  • Elucidation of various reactions in hydrogen strage metals at storing/desorbing processes of hydrogen
Academic Activities
Reports
1. Sakae Takenaka, Masahiro Kishida, Functinalzation of carbon nanotube-supported precious metal catalysts by coverage with metal oxide layers, Catal. Survey from Asia, 17, 71-84, 2013.01.
Papers
1. Hiroya Ito, Kazumasa Oshima, Tsuyoshi Yamamoto, Kah Wei Ting, Takashi Toyao, Takeharu Sugiyama, Yuzuru Kato, Kentaro Morita, Asuka Ohashi, Masahiro Kishida, Improved catalytic stability of Pt/TiO2 catalysts for methylcyclohexane dehydrogenation via selenium addition, International Journal of Hydrogen Energy, https://doi.org/10.1016/j.ijhydene.2022.09.055, 47, 91, 38635-38643, 2022.11.
2. Kazumasa Oshima, Kyogo Ito, Eriko Konishi, Tsuyoshi Yamamoto, Jun Fukai, Toshihisa Kajiwara, Masahiro Kishida, Reductive removal of selenate (VI) in aqueous solution using rhodium metal particles supported on TiO2, RSC Advances, 12, 17655-17660, 2022.05.
3. Kazumasa Oshima, Hiromichi Kondo, Eriko Konishi, Tsuyoshi Yamamoto, Yoshifumi Tsuge, Takayuki Watanabe, Masahiro Kishida, As(III) removal through catalytic oxidation and Fe(III) precipitation, RSC Advances, 12, 16843-16846, 2022.05.
4. Hamdy Farag, Abdel-Nasser A. El-Hendawy, Masahiro Kishida, Kinetic Modelling of the Influence of H2S on Dibenzothiophene Hydrodesulfurization in a Batch System over Nano-MoS2, Advances in Chemical Engineering and Science, 10, 3, 135-148, doi: 10.4236/aces.2020.103010., 2020.07, In this work, the possibility of enhanced activity during the hydrodesulfurization of dibenzothiophene over certain nano-MoS2 catalyst due to the presence of H2S was examined by focusing on the reaction kinetics. With H2S generated in situ, the overall reaction followed the autocatalytic rate law; while in the absence of H2S the kinetics indicated a pseudo-first-order reaction. H2S appears to modify the relative contributions of parallel hydrogenation and desulfurization reactions by drastically increasing the hydrogenation rate. Kinetic models were developed that describe the hydrodesulfurization reaction at various H2S concentrations, and the kinetic parameters and adsorption equilibrium constants associated with this process were estimated by fitting the experimental data. The results suggest that the promotion and/or inhibition of hydrodesulfurization by H2S likely result from the same overall reaction mechanism..
5. Hideki Matsune, Tomoya Ono, Ryoya Yoshida, Tsuyoshi Yamamoto, Masahiro Kishida, Glutathione-responsive Nanoparticle Consisting of an Amino-functionalized Silsesquioxane Network Cross-linked by Zinc Ions for a Promising Drug Carrier, Chemistry Letters, https://doi.org/10.1246/cl.190353, 2019, 1058-1061, 2019.07, A new class of nanoparticle (NP) is fabricated by cross-linking amino-functionalized silsesquioxane units with zinc ions via coordination bonds to create a drug delivery nanocarrier exhibiting rapid drug-release together with self-decomposition in response to glutathione (GSH). Regarding doxorubicin-loaded NPs, characterization of the nanostructures, their responsiveness to GSH and their cellular uptake by HeLa cells are examined..
6. Hamdy Farag, Abd-Alrahman Embaby, Masahiro Kishida, Abdel-Nasser A. Mohamed Mahmoud Nasef, Highly Active Low Cobalt Content-Based Bulk MoS2 Hydrodesulfurization Catalysts with a Unique Impact of H2S, Journal of Chemistry, https://doi.org/10.1155/2018/8076534, 2018, Article ID: 8076534, 2018.09, A series of unsupported MoS 2 , Co 9 S 8 , and Co-promoted MoS 2 catalysts have been synthesized by tuned impregnation and successive thermal annealing methods using a continuous flow of a mixture of H 2 and H 2 S gases. The resulting catalysts were evaluated in terms of their activity and selectivity for the hydrodesulfurization of dibenzothiophene (DBT) both in the absence and the presence of H 2 S. The inclusion of Co onto MoS 2 affected both the hydrogenation and direct desulfurization reactions, with the latter (production of biphenyl) being magnified to a much greater degree than the former. Interestingly, low cobalt/molybdenum ratio of ca. 0.05 of the catalyst exhibited outstanding promotion efficiency in the hydrodesulfurization reaction. However, as cobalt is added, the synergy effect drastically decreased. H 2 S in the reaction mixture led to a remarkable step up in the product from the direct desulfurization reaction route with the most notable increases occurring for the product from the hydrogenation reaction pathway. The HDS activity of such catalysts was much higher than that of the commercial CoMo/Al 2 O 3 . The promotion by H 2 S was discussed..
7. Sakae Takenaka, Masaki Goto, Yasuyuki Masuda, Shoichiro Emura, Masahiro Kishida, Improvement in the durability of carbonblack-supported Pt cathode catalysts bysilica-coating for use in PEFCs, International Journal of Hydrogen Energy, 43, 7473-7482, 2018.04.
8. Kyoso Masuda, Matsune Hideki, Takenaka Sakae, Kishida Masahiro, Synthesis of silica-coated AgCl nanoparticles in aqueous poly(vinylpyrrolidone) solution, Bull. Chem. Soc. Jpn(Bulletin of the Chemical Society of Japan), 84, 573-575, 2014.02.
9. Takenaka Sakae, Hiroaki Miyamoto, Yutaka Utsunomiya, Matsune Hideki, Kishida Masahiro, Catalytic activity of highly durable Pt/CNT catalysts covered with hydrophobic silica layers for the oxygen reduction reaction in PEFCs, J. Phys Chem. C(The Journal of Physical Chemistry C), 118, 774-783, 2014.01.
10. Takenaka Sakae, Shintaro Ida, Matsune Hideki, Kishida Masahiro, Bottom-up synthesis of titania and zirconia nanosheets and their composites with graphene, Chem. Lett., (Editor’s Choice), 42, 10, 1188-1190, 2013.08.
11. Takenaka Sakae, Tomoharu Tsukamoto, Matsune Hideki, Kishida Masahiro, Carbon nanotube-supported Pd-Co catalysts covered with silica layers as active and stable cathode catalysts for polymer electrolyte fuel cells, Catal. Sci. Technol., (Hot Paper), 3, 2723-2731, 2013.07.
12. Takenaka Sakae, Hiroyuki Miyata, Tomoharu Tsukamoto, Matsune Hideki, Kishida Masahiro, Improvement in activity of highly durable silica-coated Pd/CNT cathode catalysts for PEFC by addition of Cu, ECS trans.(ECS Transactions), 50, 1715-1722, 2013.04.
13. Takenaka Sakae, Atsuro Iga, Kayoung Park, Eishi Tanabe, Matsune Hideki, Kishida Masahiro, Carbon nanofiber supports for the preparation of Pt-based metal nanoparticles with high tolerance to sintering, Appl. Catal. A: Gen. (Applied Catalysis A: General), 450, 211-221, 2013.01.
14. Sakae Takenaka, Takafumi Arike, Hideki Matsune, Masahiro Kishida, Coverage of carbon nanotubes with titania nanoparticles for the preparation of active titania-based photocatalysts, Appl. Catal., B, Environ. (Applied Catalysis B: Environmental), Vol.125, 358-366, 2012.08.
15. Mardwita, Hideki Matsune, Sakae Takenaka, Masahiro Kishida, Chromium Addition to Alumina-supported Platinum Catalysts and Effect on Catalytic Activity in Methane Combustion, J. Chem. Eng. Jpn. (Journal of Chemical Engineering of Japan), Vol.45, 493-497, 2012.07.
16. Keizo Nakagawa, Tetsuya Okayama, Yusuke Tanimoto, Kenichiro Sotowa, Shigeru Sugiyama, Toshihiro Moriga, Sakae Takenaka Masahiro Kishida, Preparation of carbon-supported Pt catalysts covered with microporous silica layers using organosilanes: Sintering resistance and superior catalytic performance for cyclohexane dehydrogenation, Appl. Catal. A: Gen. (Applied Catalysis A: General), Vol.419-420, pp.13-21, 2012.03.
17. Sakae Takenaka, Arike takafumi, Miyazaki Takahiro, Hideki Matsune, Masahiro Kishida, Preparation of TiO2-Carbon Nanotube Composite Catalysts for Improvement of the Photocatalytic Activity of TiO2, Chem. Lett., Vol.41, 617-619, 2012.01.
18. Sakae Takenaka, Hiroshi Matsumori, Hideki Matsune, Masahiro Kishida, Highly durable Pt cathode catalysts for polymer electrolyte fuel cells; coverage of carbon black-supported Pt catalysts with silica layers, Appl. Catal. A: Gen. (Applied Cataltsis A: General), Vol.409-410, pp.248-256, 2011.12.
19. Sakae Takenaka, Hiroaki Miyamoto, Naoto Susuki, Hideki Matsune, Masahiro Kishida, Highly durable carbon nanotube-supported Pd cathode catalysts covered with silica layers for polymer electrolyte fuel cells: Effect of silica layer thickness on the catalytic performance, ECS Trans.(ECS Transactions), Vol.41, pp.2305-2312, 2011.10.
20. Sakae Takenaka, Toshiyuki Iguchi, Eishi Tanabe, Hideki Matsune, Masahiro Kishida, Catalytic performance of Pt metal particles at the tips of carbon nanotubes, Catal. Letters. (Catalysis Letters), Vol.141, pp.821-825, 2011.06.
21. Sakae Takenaka, Naoto Susuki, Hiroaki Miyamoto, Eishi Tanabe, Hideki Matsune, Masahiro Kishida, Highly durable carbon nanotube-supported Pd catalysts covered with silica layers for the oxygen reduction reaction, J. Catal.(Journal of Catalysis), Vol.279, pp.381-388, 2011.04.
22. Sakae Takenaka, Aiko Hirata, Eishi Tanabe, Hideki Matsune, Masahiro Kishida, Preparation of supported Pt-Co alloy nanoparticle catalysts for the oxygen reduction reaction by coverage with silica, J. Catal.(Journal of Catalysis), Vol.274, pp.228-238, 2011.04.
23. Sakae Takenaka, Naoto Susuki, Hiroaki Miyamoto, Eishi Tanabe, Hideki Matsune, Masahiro Kishida, Highly durable Pd metal catalysts for the oxygen reduction reaction in fuel cells; Coverage of Pd metal with silica, Chem. Commun.(Chemistry Communication), 46, 8950-8952, 2010.12.
24. Takafumi Arike, Sakae Takenaka, Hideki Matsune, Masahiro Kishida, Improvement in the durability of carbon nanotube-supported ruthenium catalysts by coverage with silica layers, Bull. Chem Soc. Jpn(Bulletin of the Chemical Society of Japan), Vol.83, No.8, pp.953-959, 2010.12.
25. Keizo Nakagawa, Sakae Takenaka, Hideki Matsune, Masahiro Kishida, Preparation of silica-coated Pt-Ni alloy nanoparticles using microemulsion and formation of carbon nanofibers by ethylene decomposition, Stud. Surf. Sci. Catal.(Studies in Surface Science and Catalysis), Vol.175, pp.793-796, 2010.07.
26. Hideki Matsune, Yudai Kuramitsu, Sakae Takenaka, Masahiro Kishida, Chemical synthesis of silver nanowires using N,N-dimethyldodecylamine oxide, Chem. Lett.(Chemistry Letters), Vol.39, pp.717-719, 2010.06.
27. Sakae Takenaka, Aiko Hirata, Hideki Matsune, Masahiro Kishida,, Preparation of carbon-supported Pt-Co alloy nanoparticles for oxygen reduction reaction: Promotion of Pt-Co alloy formation by coverage with silica, Chem.Lett.(Chemistry Letters), Vol.39, pp.458-459, 2010.05.
28. Keizo Nakagawa, Yusuke Tanimoto, Tetsuya Okayama, Ken-ichiro Sotowa, Shigeru Sugiyama, Sakae Takenaka, Masahiro Kishida, Sintering resistance and catalytic activity of Platinum nanoparticles covered with a microporous silica layer using methyltriethoxysilane, Catal.Letters. (Catalysis Letters), Vol.136, pp.71-76, 2010.05.
29. Hiroshi Matsumori, Sakae Takenaka, Hideki Matsune, Masahiro Kishida, Preparation of carbon nanotube-supported Pt catalysts covered with silica layers; application to cathode catalysts for PEFC, Appl.Catal.A.Gen (Applied Catalysis A: General), Vol.373, pp.176-185, 2010.01.
Presentations
1. Eriko Konishi, Kyogo Ito, Kazumasa Oshima, Tsuyoshi Yamamoto, Masahiro Kishida, Reduction of selenate over supported noble metal catalyst in aqueous solution, The 9th Tokyo Conference on Advanced Catalytic Science and Technology, 2022.07.
2. Hiromichi Kondo, Takayuki Urata, Kazumasa Oshima, Tsuyoshi Yamamoto, Masahiro Kishida, Kinetic analysis of oxidation of arsenite in water using a plug-flow reactor filled with platinum catalyst, The 9th Tokyo Conference on Advanced Catalytic Science and Technology, 2022.07.
3. 松根 英樹,小野智也,吉田涼矢,山本剛,岸田 昌浩, Glutathione-responsive nanoparticle consisting of an amino-functionalized silsesquioxane network cross-linked by zinc ions for a promising drug carrier, 2019 Japan/Taiwan/Korea Chemical Engineering Conference, 2019.11.
4. 岸田 昌浩,浦田誉幸,松根英樹,山本剛, Catalytic oxidation of arsenite to arsenate over supported Pt catalysts for wastewater treatment, Asian Pacific Confederation of Chemical Engineering 2019 (APCChE2019), 2019.09.
5. 岸田 昌浩, 趙 金仙, 松根 英樹, 竹中 壮, Oxidation of Arsenious Acid over Supported-platinum Catalysts in Aqueous Solution (2)
担持白金触媒を用いた亜ヒ酸の水中酸化反応特性(2), 化学工学会 第82年会, 2017.03.
6. 柳 登貴人 ,金 剛山,吉田 和晃,松根 英樹,岸田 昌浩, Development of Pt catalysts for dehydrogenation of alkane, The 29th International Symposium on Chemical Engineering, 2016.12.
7. 中谷 憲人,松根 英樹,岸田 昌浩, 竹中壮, Preparation of Free Standing Pt Nanofilms Using Graphene Oxides as Templates, The 29th International Symposium on Chemical Engineering, 2016.12.
8. 北野 拓真,松根英樹,岸田昌浩,井上元,竹中壮, Catalytic performance of silica-coated Pt cathode catalysts in a PEFC single cell, The 29th International Symposium on Chemical Engineering, 2016.12.
9. 井田 涼,松根 英樹,岸田 昌浩, 竹中壮, Preparation of composite catalysts composed of metal oxide nanofilms and Pt nanoparticles, The 29th International Symposium on Chemical Engineering, 2016.12.
10. 増田 恭三, 松根 英樹, 竹中 壮, 岸田 昌浩, Synthesis and Characterization of Silica-coated Ag and AgCl Particles, 第25回化学工学に関する国際シンポジウム, 2012.12.
11. 宮本 幸太郎, 松根 英樹, 竹中 壮, 岸田 昌浩, Novel preparation for silica nanocapsules ccontaining tetraphenylporphyrincobalt(Ⅱ) catalysts, 第25回化学工学に関する国際シンポジウム, 2012.12.
12. Kotaro Miyamoto, Hideki Matsune, Sakae Takenaka, Masahiro Kishida, Entrapment of cobalt(II) tetraphenylporphyrin aggregates in silica nanocapsule, 10th Japan-Korea Symopsium on Material&Interfaces -International Symposium on Frontiers in Chemical Engineering-, 2012.11.
Awards
  • Development of Apparatus for Decomposition of Fluorine-type Global Warming Gas
Educational
Educational Activities
I teach the following subjects:
1) "Chemical Thermodynamics" for 2nd grader
2) "Reaction Engineerings 1 and 2" for 2nd grader and 3rd grader, respectively
3) "Experimentation No.3 on Materials Science and Engineering"
4) "Functionalized Chemical Materials" and "Advanced Chemical Reaction Engineering" for graduate students.
Social
Professional and Outreach Activities
I possitively participate various research projects and accept researches trusted by companies..