


Kazunari SASAKI | Last modified date:2022.11.02 |

Professor /
Hydrogen Utilization Processes
Department of Mechanical Engineering
Faculty of Engineering
Department of Mechanical Engineering
Faculty of Engineering
Graduate School
Undergraduate School
Other Organization
Administration Post
Vice President
Director of International Research Center for Hydrogen Energy
Director of Next-Generation Fuel Cell Research Center
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Homepage
https://kyushu-u.pure.elsevier.com/en/persons/kazunari-sasaki
Reseacher Profiling Tool Kyushu University Pure
http://www.mech.kyushu-u.ac.jp/~hup/english_top.html
Homepage of Prof. Kazunari SASAKI`s Laboratory .
http://h2.kyushu-u.ac.jp/english/index.html
Homepage of International Research Center for Hydrogen Energy .
Phone
092-802-3143
Fax
092-802-3223
Academic Degree
Dr. sc. techn. ETH
Country of degree conferring institution (Overseas)
Yes
Field of Specialization
Fuel cell science and engineering, Hydrogen technology, Inorganic materials chemistry, Electrochemistry
ORCID(Open Researcher and Contributor ID)
0000-0002-3174-9087
Total Priod of education and research career in the foreign country
08years10months
Outline Activities
In the research group of Dr. Kazunari Sasaki, we focus on the R&D of fuel cell materials. Two major activities, on polymer electrolyte fuel cells (PEFC) and on solid oxide fuel cells (SOFC), are both supported by several research fundings, including national R&D project of SOFCs and PEFCs.
In our reserach group, we have various facilities including 60 evaluation systems of fuel cell electrchemical performance/properties (with Solartron impedance analyzers, Potentiostat/Galvanostat, CVs, multimeters), microscopes (High-resolution FESEM-EDX-STEM, SEM-EDX, AFM, STM, KFM), materials evaluation apparatus (XRD, XPS, BET, TG-DTA, TG-MS etc.), several gas chromatographs and GC-MS, as well as preparation apparatus for electrode catalysts and fuel cells. Thus our graduate students and research staffs can prepare FC-related materials and fuel cells and can analyze their performanece by themselves.
(1) Nano-structured Electrode Catalysts for PEFCs
Polymer electrolyte fuel cells (PEFCs) are promising energy systems with several advantages including high energy density, low-temperature operation, short start-up time etc., so that automobile, portable, as well as stationary applications are of technological interest. However, in the state-of-the-art cells, a large amount of noble metals should be used, leading to too high cost of fuel cell systems. A higher performance of electrode catalysts using less amount of noble metals, especially platinum, is essential, and this is one of the most relevant technological tasks in PEFC research and development.
In this research period, we focus on carbon support materials and oxide-based additives for electrode catalysts. Various types of carbon materials were applied and the influence of carbon nanostructure on electrochemical properties was analyzed to realize higher power generation characteristics and a reduction of noble metal loading of the electrode catalysts. Downsizing of electrode catalysts, Pt, was also carried out. We have succeeded, via colloidal processes, to prepare Pt nanoparticles with a crystallite size of ca. 3 nm. Effect of nanostructuring on electrochemical properties are also analyzed to establish materials design strategies of PEFC/DMFC electrode catalysts.
(2) Multi-Fuel Capable SOFCs
In our institution, we systematically characterize electrochemical performance, relevant transport properties of ceramic materials, the interactions between the fuel cell components and the fuel gas species, and equilibria in fuel gases. We wish to contribute to solid oxide fuel cells (SOFC) development and commercialization based on our fundamental research activities, e.g. by establishing optimum operational conditions of fuel cells, proposing alternative materials, and analyzing electrochemical reaction phenomena. We have focused on power generation characteristics of SOFCs operated with various kinds of fuel gases (including lower and higher hydrocarbons, alcohols, biogases, coal gases, GTL fuels, and fuels with various impurities), as one of the most advantageous features of SOFCs is their flexibility for fuel selections. Based on these advantages, we may realize e.g. zero-emission renewable energy systems with SOFCs. We have also developed sulfur-tolerant SOFCs with chemically modified fuel electrodes.
Such research activities are conducted as the Director of International Research Center for Hydrogen Energy, the Director of Next-Generation Fuel Cell Research Center, and a Distingished Professor. Educational activities are made in Department of Hydrogen Energy Systems (Graduate School of Engineering), and Department of Mechanical and Aerospace Engineering (School of Engineering).
In addition, based on various experiences with industry and public sectors, Prof. Sasaki is currently acting as a Senior Vice President, as well as various committee members in the central and local Governments.
In our reserach group, we have various facilities including 60 evaluation systems of fuel cell electrchemical performance/properties (with Solartron impedance analyzers, Potentiostat/Galvanostat, CVs, multimeters), microscopes (High-resolution FESEM-EDX-STEM, SEM-EDX, AFM, STM, KFM), materials evaluation apparatus (XRD, XPS, BET, TG-DTA, TG-MS etc.), several gas chromatographs and GC-MS, as well as preparation apparatus for electrode catalysts and fuel cells. Thus our graduate students and research staffs can prepare FC-related materials and fuel cells and can analyze their performanece by themselves.
(1) Nano-structured Electrode Catalysts for PEFCs
Polymer electrolyte fuel cells (PEFCs) are promising energy systems with several advantages including high energy density, low-temperature operation, short start-up time etc., so that automobile, portable, as well as stationary applications are of technological interest. However, in the state-of-the-art cells, a large amount of noble metals should be used, leading to too high cost of fuel cell systems. A higher performance of electrode catalysts using less amount of noble metals, especially platinum, is essential, and this is one of the most relevant technological tasks in PEFC research and development.
In this research period, we focus on carbon support materials and oxide-based additives for electrode catalysts. Various types of carbon materials were applied and the influence of carbon nanostructure on electrochemical properties was analyzed to realize higher power generation characteristics and a reduction of noble metal loading of the electrode catalysts. Downsizing of electrode catalysts, Pt, was also carried out. We have succeeded, via colloidal processes, to prepare Pt nanoparticles with a crystallite size of ca. 3 nm. Effect of nanostructuring on electrochemical properties are also analyzed to establish materials design strategies of PEFC/DMFC electrode catalysts.
(2) Multi-Fuel Capable SOFCs
In our institution, we systematically characterize electrochemical performance, relevant transport properties of ceramic materials, the interactions between the fuel cell components and the fuel gas species, and equilibria in fuel gases. We wish to contribute to solid oxide fuel cells (SOFC) development and commercialization based on our fundamental research activities, e.g. by establishing optimum operational conditions of fuel cells, proposing alternative materials, and analyzing electrochemical reaction phenomena. We have focused on power generation characteristics of SOFCs operated with various kinds of fuel gases (including lower and higher hydrocarbons, alcohols, biogases, coal gases, GTL fuels, and fuels with various impurities), as one of the most advantageous features of SOFCs is their flexibility for fuel selections. Based on these advantages, we may realize e.g. zero-emission renewable energy systems with SOFCs. We have also developed sulfur-tolerant SOFCs with chemically modified fuel electrodes.
Such research activities are conducted as the Director of International Research Center for Hydrogen Energy, the Director of Next-Generation Fuel Cell Research Center, and a Distingished Professor. Educational activities are made in Department of Hydrogen Energy Systems (Graduate School of Engineering), and Department of Mechanical and Aerospace Engineering (School of Engineering).
In addition, based on various experiences with industry and public sectors, Prof. Sasaki is currently acting as a Senior Vice President, as well as various committee members in the central and local Governments.
Research
Research Interests
Membership in Academic Society
- Electrode materials for SOFCs
keyword : Fuel cells, SOFC, Electrode materials, durability, poisoning
1989.09. - Advanced Electrocatalysts for Polymer Electrolyte Fuel Cells
keyword : Fuel Cells, PEFC, Electrocatalyst, Catalyst support materials, Carbon materials, Oxide electronic conductors
1999.10. - Alternative Electrolyte Materials for Fuel Cell Applications
keyword : Hydrogen Energy, Fuel Cells, Solid State Ionics
1995.04. - Fuel Cell Materials Design by Nanostructuring
keyword : Colloidal processes, Nano-size effects, Interfacial effects
1995.04. - Defect Chemistry of Functional Ceramics
keyword : Defect chemistry,Chemical Thermodynamics, Electrical conductors
1995.04.
- SOFCs are the most flexible fuel cells with respect to fuel selection. However, various impurities in practical fuels and/or from SOFC system components can cause poisoning of fuel electrodes and thus degradation of electrochemical performance. Impurity tolerance of SOFCs has been analyzed by using various impurity-containing gases with respect to operational conditions to understand poisoning mechanisms and to improve long-term durability of SOFC systems.
- Higher performance and long-term durability of electrocatalysts are essential for polymer electrolyte fuel cells (PEFCs), where electrocatalyst support materials act as a very important role. In this study, as alternatives to conventional carbon black catalyst support, semiconducting oxides and carbon nanofibers have been applied. In-situ colloidal impregnation enables to prepare highly-dispersed Pt catalysts on such support materials. Principles for electrocatalyst design using alternative catalyst supports are discussed.
Papers
- The Society of Automotive Engineers of Japan, Inc.
- Hydrogen Energy Systems Society of Japan
- The Japan Society of Mechanical Engineers
- As the Director of International Research Center for Hydrogen Energy, a ministrial award for the Kyushu University hydrogen project was given from the Miniter of the Environment.
- Research on Degradation Mechanisms in Solid Oxide Fuel Cells
- PEFC electrocatalysts supported on semiconducting oxides
Educational


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