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Motoki Toganoh Last modified date:2021.06.23

Assistant Professor / Organic Functional Molecular Chemistry
Department of Applied Chemistry
Faculty of Engineering


Graduate School
Administration Post
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Homepage
https://kyushu-u.pure.elsevier.com/en/persons/motoki-toganoh
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http://www.cstf.kyushu-u.ac.jp/~furutalab/
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Phone
092-802-2867
Fax
092-802-2865
Academic Degree
PhD (Science)
Field of Specialization
Synthetic Organic Chemistry, Organometallic Chemistry
Research
Research Interests
  • Theoretical Study on Porphyrin Isomers and Related Macrocycles
    keyword : porphyrin,DFT
    2015.04.
  • Development of Bio-Probe based on Porphyrin Mutant
    keyword : porphyrin
    2006.04.
  • Development of Organic Materials Based on N-Fused Porphyrin
    keyword : porphyrin, near-IR light
    2004.04.
  • Synthesis and Application of Metal Complexes with Porphyrinoid Ligands
    keyword : Porphyrin,Metal Complex
    2003.10.
Academic Activities
Reports
1. Motoki Toganoh, Hiroyuki Furuta, N-fused porphyrin
A maverick member of the porphyrin family
, Chemistry Letters, 10.1246/cl.190250, 2019.01, Fusion is a relatively new concept to produce unique members of the porphyrin family. A representative compound formed by fusion is Nfused porphyrin, which is synthesized from N-confused porphyrin. N-Fused porphyrin has an unusually narrow HOMOLUMO energy gap and exhibits absorption in the near infrared region up to 1100 nm. Moreover, N-fused porphyrin serves as a versatile mononegative tridentate ligand, which can bind a variety of metal centers tightly. While inner-core fusion is rare in tetrapyrrolic porphyrinoids, it becomes more common in expanded porphyrins, where a variety of novel structures are produced unanticipatedly..
2. Toganoh, M.; Furuta, H. , Blooming of confused porphyrinoid ~ fusion, expansion, contraction, and more confusion, Chem. Commun. 2012, 48, 937-954, 2011.09.
Papers
1. Motoki Toganoh, Hideaki Matsuo, Furuta, H, Ruthenocene-Type Complexes of N-Fused Porphyrins, CHEMISTRY-A EUROPEAN JOURNAL, 10.1002/chem.201600813, 22, 24, 8316-8322, 2016.06.
2. Motoki Toganoh, Yasunori Kawabe, Hidemitsu Uno, Hiroyuki Furuta, Unique Interaction between Directly Linked Laminated p Planes in the Benzonorrole Dimer, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 10.1002/anie.201203712, 51, 35, 8753-8756, 2012.08.
3. Motoki Toganoh, Takaaki Yamamoto, Takayoshi Hihara, Hisanori Akimaru, Hiroyuki Furuta, Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation, ORGANIC & BIOMOLECULAR CHEMISTRY, 10.1039/c2ob25351h, 10, 22, 4367-4374, 2012.04.
4. Motoki Toganoh, Hiroyuki Furuta, Blooming of confused porphyrinoids-fusion, expansion, contraction, and more confusion, CHEMICAL COMMUNICATIONS, 10.1039/c1cc14633e, 48, 7, 937-954, 2012.01.
5. Toganoh, M.; Niino, T.; Furuta, H. , Luminescent gold(III) Organometallic Complex of N-Confused Tetraphenylporphyrin, Chem. Commun., 4070-4072, 2008.09.
6. Toganoh, M.; Ikeda, S.; Furuta, H., Re(VII) complex of N-fused tetraphenylporphyrin, Chem. Commun., 10.1039/b508208k, 36, 4589-4591, (36): 4589-4591, 2005.10.
7. Toganoh, M.; Furuta, H., Rhenium complexes of N-methyl N-confused tetraphenylporphyrin and its normal isomer, Chem. Lett., 10.1246/cl.2005.1034, 34, 7, 1034-1035, 34 (7): 1034-1035, 2005.07.
8. Toganoh, M.; Ishizuka, T.; Furuta, H., Synthesis and properties of rhenium tricarbonyl complex bearing N-fused tetraphenylporphyrin ligand, Chem. Commun., 10.1039/b406234e, 21, 2464-2465, (21): 2464-2465 , 2004.11.
Presentations
1. Motoki Toganoh, Katsuya Noda, Hideaki Matsuo, Takumi Takayama, Yasunori Kawabe, Ayumi Sato, Hiroyuki Furuta, Construction of Extended π-System Based on Tetrapyrrolic N-Confused Porphyrinoids, 7th International Conference on Porphyrins and Phthalocyanines, 2012.07.