Kyushu University Academic Staff Educational and Research Activities Database
Researcher information (To researchers) Need Help? How to update
Motoki Toganoh Last modified date:2019.06.20

Assistant Professor / Organic Functional Molecular Chemistry
Department of Applied Chemistry
Faculty of Engineering


Graduate School
Administration Post
Other


E-Mail
Homepage
http://www.cstf.kyushu-u.ac.jp/~furutalab/
Items,Research,Member,Publication,Photos and Schedul are shown .
Phone
092-802-2867
Fax
092-802-2865
Academic Degree
PhD (Science)
Field of Specialization
Synthetic Organic Chemistry, Organometallic Chemistry
Research
Research Interests
  • Theoretical Study on Porphyrin Isomers and Related Macrocycles
    keyword : porphyrin,DFT
    2015.04.
  • Development of Bio-Probe based on Porphyrin Mutant
    keyword : porphyrin
    2006.04.
  • Development of Organic Materials Based on N-Fused Porphyrin
    keyword : porphyrin, near-IR light
    2004.04.
  • Synthesis and Application of Metal Complexes with Porphyrinoid Ligands
    keyword : Porphyrin,Metal Complex
    2003.10.
Academic Activities
Reports
1. Toganoh, M.; Furuta, H. , N-Fused Porphyrin: A Maverick Member of the Porphyrin Family , 2019.03.
2. Toganoh, M.; Furuta, H. , Blooming of confused porphyrinoid ~ fusion, expansion, contraction, and more confusion, Chem. Commun. 2012, 48, 937-954, 2011.09.
Papers
1. Motoki Toganoh, Hideaki Matsuo, Furuta, H, Ruthenocene-Type Complexes of N-Fused Porphyrins, CHEMISTRY-A EUROPEAN JOURNAL, 10.1002/chem.201600813, 22, 24, 8316-8322, 2016.06.
2. Motoki Toganoh, Yasunori Kawabe, Hidemitsu Uno, Hiroyuki Furuta, Unique Interaction between Directly Linked Laminated p Planes in the Benzonorrole Dimer, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 10.1002/anie.201203712, 51, 35, 8753-8756, 2012.08.
3. Motoki Toganoh, Takaaki Yamamoto, Takayoshi Hihara, Hisanori Akimaru, Hiroyuki Furuta, Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation, ORGANIC & BIOMOLECULAR CHEMISTRY, 10.1039/c2ob25351h, 10, 22, 4367-4374, 2012.04.
4. Toganoh, M.; Gokulnath, S.; Kawabe, Y.; Furuta, H., Synthesis and Reactivity of 5,10,15-Triaryl Doubly N-Confused Bilanes, Chem. Eur. J., 18, 14, 4380-4391, 2012.04.
5. Motoki Toganoh, Hiroyuki Furuta, Blooming of confused porphyrinoids-fusion, expansion, contraction, and more confusion, CHEMICAL COMMUNICATIONS, 10.1039/c1cc14633e, 48, 7, 937-954, 2012.01.
6. Toganoh, M.; Takayama, T.; Ritesh, N.; Kimizuka, N.; Furuta, H., Synthesis and Properties of Acetylene-Bridged N-Confused Porphyrin Dimers, Chem. Lett. , 40, 9, 1021-1023,
, 2011.09.
7. Toganoh, M.; Kawabe, Y.; Furuta, H. , C-Fused Norrole: A Fused Corrole Isomer Bearing A N,C-Linked Bipyrrole Unit, J. Org. Chem. , 76, 7618-7622, 2011.08.
8. Fujino, K.; Hirata, Y.; Kawabe, Y.; Morimoto, T.; Srinivasan, A.; Toganoh, M.; Miseki, Y.; Kudo, A.; Furuta, H., Confusion and Neo-Confusion: New Corrole Isomers with an NNNC Core, Angew. Chem. Int. Ed. , 50, 30, 6855-6859, 2011.07.
9. Ikeda, S.; Toganoh, M.; Furuta, H. , Synthesis, Reactivity, and Properties of N-Fused Porphyrin Manganese(I)Tricarbonyl Complexes, Inorg. Chem., 50, 13, 6029-6043, 2011.06.
10. Toganoh, M.; Sato, A.; Furuta, H. , Double-decker Ferrocene-type Complex of N-Fused Porphyrin: A Model of π-Extended Ferrocene?, Angew. Chem. Int. Ed. , 50, 12, 2752-2755, 2011.03.
11. Ikeda, S.; Toganoh, M.; Easwaramoorthi, S.; Lim, J. M.; Kim, D.; Furuta, H. , Synthesis and Photophysical Properties of N-Fused Tetraphenylporphyrin Derivatives: Near-Infrared Organic Dye of [18]Annulenic Compounds, J. Org. Chem. , 2010, 75, 8637-8649., 2010.11.
12. Toganoh, M.; Furuta, H., Theoretical study on conformation and electronic state of Hükel-aromatic multiply N-confused [26]hexaphyrins, J. Org. Chem., 2010, 75, 8213-8223., 2010.11.
13. Toganoh, M.; Hihara, Y.; Furuta, H. , N-Heterocyclic Carbene Embedded in an N-Confused Porphyrin Framework, Inorg. Chem., 2010, 49, 8182-8184., 2010.08.
14. Lim, J. M.; Lee, J. S.; Chung, H. W.; Bahng, H. W.; Yamaguchi, K.; Toganoh, M.; Furuta, H.; Kim, D. , Photophysical Properties of N-Confused Hexaphyrins: Effects of Confusion of Pyrrole Rings and Molecular Shape on Electronic Structures, Chem. Commun. , 2010, 46, 4357-4359.
, 2010.04.
15. Toganoh, M.; Harada, H.; Ikawa, Y.; Furuta, H. , Self-Assembly of Zn(II) Porphyrin-1,2,3-Triazole Conjugate with Alcohol Glue, Chem. Lett. , 2010, 39, 252-253.
, 2010.04.
16. Lee, J. S.; Lim, J. M.; Toganoh, M.; Furuta, H.; Kim, D. , Comparative Spectroscopic Studies on Porphyrin Derivatives: Electronic Perturbation of N-Confused and N-Fused Porphyrins, Chem. Commun., 46, 285-287., 2010.02.
17. Toganoh, M.; Furuta, H. , Theoretical Study on Rotation of Pyrrole Rings in Porphyrin and N-Confused Porphyrin, J. Phys. Chem. A. , 113, 13953-13963, 2009.10.
18. Toganoh, M.; Miyachi, H.; Akimaru, H.; Ito, F.; Nagamura, T.; Furuta, H , Anion Responsive Dyad System of Porphyrin and N-Confused Porphyrin, Org. Biomol. Chem., 6151-6158, 2009.07.
19. Toganoh, M.; Ogawa, H.; Morimoto, T.; Furuta, H. , Programmed Asymmetrical Trimer Formation of b-alkyk N-confused Porphyrin Zinc(II) Complexes, Supramol. Chem. , 21, 324-330, 2009.02.
20. Toganoh, M.; Hihara, T.; Yonekura K.; Ishikawa, Y.; Furuta, H. , Synthesis and Characterization of Novel Azo-embedded N-Confused Tetraphenylporphyrin, J. Porphyrins Phthalocyanines , 13, 215-222, 2009.02.
21. Srinivasan, A.; Toganoh, M.; Niino, T.; Osuka, A.; Furuta, H. , Synthesis of N-Confused Tetraphenylporphyrin Rhodium Complexes Having Versatile Metal Oxidation States, Inorg. Chem. , 47, 11305-11313, 2008.12.
22. Toganoh, M.; Kimura, T.; Furuta, H. , Endocyclic Extension of Porphyrin ケ-System by Interior Functionalization of N-Confused Porphyrins, Chem. Eur. J., 14, 34, 10585-10594, 2008.11.
23. Toganoh, M.; Kimura, T.; Uno, H.; Furuta, H. , Doubly N-Fused Porphyrin, Angew. Chem. Int. Ed. , 47, 46, 8913-8916 , 2008.11.
24. Toganoh, M.; Harada, N.; Furuta, H., Hydrogen-bonding Network in New Scorpionate-type Ligand Composed of Pyridine/Pyrrole Hybrid and Anion-binding Behavior of the Corresponding Rhodium Complexes in Alkyne Cyclotrimerization Reaction, J. Organomet. Chem., 693, 19, 3141-3150, 2008.09.
25. Toganoh, M.; Niino, T.; Furuta, H. , Luminescent gold(III) Organometallic Complex of N-Confused Tetraphenylporphyrin, Chem. Commun., 4070-4072, 2008.09.
26. Toganoh, M.; Fujino, K.; Ikeda, S.; Furuta, H. , Catalytic Deoxygenation of Pyridine N-Oxide with N-Fused Porphyrin Rhenium Complexes, Tetrahedron Lett. , 2008, 49, 1488-1491., 2008.02.
27. Toganoh, M.; Kimura, T.; Furuta, H. , Endocyclic Extension of Porphyrin ケ-System in Etheno-bridged N-Confused Tetraphenylporphyrin, Chem. Commun. , 102-104, 2008.01.
28. Toganoh, M.; Ikeda, S.; Furuta, H. , Synthesis, Reactivity, and Properties of N-Fused Porphyrin Rhenium(I) Tricarbonyl Complexes, Inorg. Chem. , 2007, 46. 10003-10015, 2007.07.
29. Toganoh, M.; Harada, N.; Morimoto, T.; Furuta, H., Experimental and theoretical studies on oligomer formation of N-confused porphyrin-zinc(II) complexes, Chem. Eur. J., 13 (8): 2257-2265, 2007.03.
30. Toganoh, M.; Niino, T.; Maeda, H.; Andrioletti, B.; Furuta, H., Unprecedented formation of a rhodium cluster triggered by rhodium-fastened N-confused gable porphyrin, Inorg. Chem., 45 (26): 10428-10430, 2006.12.
31. Toganoh, M.; Konagawa, J.; Furuta, H., Bis[iridium(I)] complex of inverted N-confused porphyrin, Inorg. Chem., 45 (10): 3852-3854, 2006.05.
32. Toganoh, M.; Ikeda, S.; Furuta, H., Re(VII) complex of N-fused tetraphenylporphyrin, Chem. Commun., 10.1039/b508208k, 36, 4589-4591, (36): 4589-4591, 2005.10.
33. Toganoh, M.; Furuta, H., Rhenium complexes of N-methyl N-confused tetraphenylporphyrin and its normal isomer, Chem. Lett., 10.1246/cl.2005.1034, 34, 7, 1034-1035, 34 (7): 1034-1035, 2005.07.
34. Toganoh, M.; Ishizuka, T.; Furuta, H., Synthesis and properties of rhenium tricarbonyl complex bearing N-fused tetraphenylporphyrin ligand, Chem. Commun., 10.1039/b406234e, 21, 2464-2465, (21): 2464-2465 , 2004.11.
35. Toganoh, M.; Matsuo, Y.; Nakamura, E., Synthesis of ferrocene/hydrofullerene hybrid and functionalized bucky ferrocenes, J. Am. Chem. Soc., 125 (46): 13974-13975, 2003.11.
36. Toganoh, M.; Matsuo, Y.; Nakamura, E., Rhenium-templated regioselective polyhydrogenation reaction of [60]fullerene, Angew. Chem. Int. Ed., 42 (30): 3530-3532, 2003.08.
37. Toganoh, M.; Suzuki, K.; Udagawa, R.; Hirai, A.; Sawamura, M.; Nakamura, E, Regioselective synthesis of [60]fullerene eta(5)-indenide R3C60- and eta(5)-cyclopentadienide R5C60- bearing different R groups, Org. Bioorg. Chem., 1 (14): 2604-2611, 2003.07.
38. Sawamura, M.;Kuninobu, Y.; Toganoh, M.; Matsuo, Y.; Yamanaka, M.; Nakamura, E., Hybrid of ferrocene and fullerene, 124 (32): 9354-9355, 2002.08.
39. Sawamura, M.; Toganoh, M.; Iikura, H.; Matsuo, Y.; Hirai, A.; Nakamura, E., Cu(I)-mediated regioselective tri-addition of Grignard reagent to [70]fullerene. Synthesis of indenyl-type metal ligand embedded into graphitic structure, J. Mater. Chem., 12 (7), 2109-2115, 2002.07.
40. M. NAKAMURA, M. TOGANOH, X. Q. WANG, S. YAMAGO, E. NAKAMURA, Intramolecular [3+2] Cycloaddition Reaction of Dipolar Trimethylenemethane, Chem. Lett., Vol. 29, No. 6, pp. 664-665, 2000.06.
41. M. SAWAMURA, M. TOGANOH, K. SUZUKI, A. HIRAI, H. IIKURA, E.NAKAMURA, Stepwise Synthesis of Fullerene Cyclopentadienide R5C60- and Indenide R3C60-. An Approach to Fully Unsymmetrically Substituted Derivatives, Org. Lett., Vol. 2, No. 13, pp. 1919-1921, 2000.06.
42. M. SAWAMURA, M. TOGANOH, Y. KUNINOBU, S. KATO, E. NAKAMURA, Synthesis of Pentamethyl-monohydro[60]fullerene C60Me5H and Its Use as, Chem. Lett., Vol. 29, No. 3, pp. 270-271, 2000.03.
43. M. NAKAMURA, M. TOGANOH, H. OHARA, E. NAKAMURA, Cycloaddition Reactions of Trimethylenemethane Radical Cation Generated from Methylenecyclopropanone Thioacetal, Org. Lett., Vol. 1, No. 1, pp. 7-9, 1999.07.
Presentations
1. Motoki Toganoh, Katsuya Noda, Hideaki Matsuo, Takumi Takayama, Yasunori Kawabe, Ayumi Sato, Hiroyuki Furuta, Construction of Extended π-System Based on Tetrapyrrolic N-Confused Porphyrinoids, 7th International Conference on Porphyrins and Phthalocyanines, 2012.07.