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Noritaka Saito Last modified date:2022.11.08

Associate Professor / Physical Chemistry for Metallurgy
Department of Materials Science and Engineering
Faculty of Engineering


Graduate School
Undergraduate School
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Homepage
https://kyushu-u.pure.elsevier.com/en/persons/noritaka-saito
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Phone
092-802-2942
Fax
092-802-2942
Academic Degree
Ph.D. in Engineering
Field of Specialization
Physical Chemistry of High Temperature Melts and Development of Novel Sensing Technology for High-temperature Processing
Total Priod of education and research career in the foreign country
01years06months
Outline Activities
Steel, glass, ceramics. Most of the inorganic materials we can usually see are produced in a hot molten state. In our laboratory, we are promoting a wide range of research and development on the material creation process using this high temperature melt. For example, the physicochemical properties (viscosity, surface tension, etc.) of high-temperature metals and oxide melts that we measure and evaluate with high accuracy are not only the operations of the above-mentioned high-temperature processes, but also the characteristics of the finished products. It can be said that it is a factor that also controls the material industry and is the infrastructure of the material industry. In addition, based on the basic data obtained, research to further improve the efficiency of the ironmaking and steelmaking processes, which have been said to have no room for research, and mobile phones that are indispensable to our lives. Outputs that enrich human life, such as high-performance ceramic capacitors that are often used in electronic products such as PCs and PCs, and functionally graded materials aimed at high-power discharge lamps that allow you to enjoy movies even in bright rooms. I am always studying with this in mind.
Research
Research Interests
  • Property Evaluations of Oxide Melts characterized by AC Field
    keyword : oxide melt, structure, suspension, foam, emulsion
    2016.04~2026.03.
  • Partial liquid phase bonding of advanced ceramics and diffusion phenomena at the bonding interface
    keyword : PTLP bonding, refractory metal, UHTCs, Borides, Carbides
    2008.01.
  • Fabrication of translucent alumina and yttria ceramics
    keyword : translucent, pressure-less sintering
    2007.03~2013.03.
  • Evaluation of viscosity and crystallization behavior of oxide melts at high temperature
    keyword : silicate, multi-phases, viscosity, non-newtonian fluid, electric capacity
    2006.04.
Current and Past Project
  •  Eleven years have passed since the severe accident at the Fukushima Daiichi Nuclear Power Station (hereinafter referred to as "1F") of Tokyo Electric Power Holding Co. Eleven years have passed since the severe accident at the Fukushima Daiichi Nuclear Power Station (1F), and measures to remove fuel debris are now being considered in a manner consistent with the in-vessel damage status and debris distribution at each unit. The understanding of the in-vessel conditions and the refinement of accident scenarios are expected to serve as basic data for safe and as rapid decommissioning as possible. On the other hand, as the situation inside the accident reactor is gradually clarified through the progress of the 1F internal investigation and 1F sample analysis, it is becoming clear that the actual situation inside the 1F reactor is different from the "estimation from typical accident conditions" evaluated based on the analysis of the Three Mile accident in the United States, which was more than assumed in the past. The accident scenario analysis "Forward Analysis" using accident progression analysis codes, etc., which has been conducted in the past, has reached its limits in refining the understanding of such 1F-specific in-pile conditions. Therefore, there is a need for "Backward Analysis," which is based on field knowledge to identify critical accident events that have not been sufficiently studied in the past, to accurately understand and model the phenomena, and to acquire and verify more accurate and appropriate data through material experiments.
     In this study, as urgent issues in the current situation in the 1F reactor, we are investigating the Cs migration pathway during the accident to determine the cause of the high dose under the shield plugs in Units 1F Units 2 and 3, the state of Cs deposition and attachment to structural materials, and the characterization of metal-rich debris that is estimated to have melted down from the RPV to the PCV in Units 1F Units 2 and 3. Backward Analysis focusing on the characterization of metal-rich debris (evaluation of oxidation characteristics at the time of dissolution), which is presumed to have been dissolved from the RPV to the PCV in Units 1F2 and 3. In "Research Topic (1) Reducing the uncertainty of Cs distribution evaluation," the chemical environment and mass transport during the accident in the RPV and PCV were evaluated based on the results of MAAP analysis based on the most probable scenario of the accident progression in Units 2 and 3, and the changes in Cs chemical forms were preliminarily evaluated. In addition, thermal analysis tests were conducted in a steam atmosphere using Cs-containing samples, and the reaction tendency of Cs with steel and other materials was preliminarily investigated. In order to predict the influence of residual Cs in fuel debris on the flowability of oxide melts containing concrete components and their Cs release behavior during the MCCI process, we measured the viscosity of CeO2(-ZrO2)-CaO-Al2O3-SiO2 melts at high temperatures and also measured the viscosity of Cs2O-Fe2O3 aerosol formation phenomenon. These results indicate that even a small amount of residual Cs dramatically reduces the viscosity of oxide melts containing concrete components, but has only a very limited effect on accident propagation events because the Cs is immediately released due to increased flowability. Furthermore, the Cs2O-FeO system has high chemical affinity and melts easily, and depending on the in-core conditions, the reaction of residual Cs from the fuel debris with molten stainless steel may have generated a Cs-Fe-O aerosol, which was not previously expected and may have contributed to the high-dose conditions above the RPV. In "Research Topic (2) Evaluation of Oxidative Transformation of Metal Debris," the oxidative transformation of simulated metal debris was preliminarily evaluated by thermal analysis tests in a steam atmosphere. Preliminary experiments on molten Fe-Zr metal melts and ZrO2 equilibrium, which is the reaction basis of molten metal debris and oxide debris, were initiated, and the validity of the Zr activity measurement method necessary to determine the unoxidized Zr reaction contribution ratio in the metal melts, an important factor in clarifying the pressure vessel failure mechanism, was confirmed. Furthermore, we determined the conditions for measuring the viscosity of metal debris, which is indispensable for predicting the flow of solid-liquid coexisting metallic materials that will be discharged at the time of pressure vessel failure. Through these efforts, we established a method for extracting and measuring elemental parameters for analyzing the process of metallic debris remelting in the lower plenum and melting steel materials while being oxidized and transformed by water vapor, leading to the pressure vessel failure. In "Research Topic (3) Comprehensive Evaluation," the results of each research topic were comprehensively considered to identify events and scenarios to be studied intensively in this study. In order to reduce the uncertainty of Cs migration behavior in high dose situations, which has been an issue in the field, we focused on the Cs reaction in high temperature and steam depleted conditions and the migration to the top of the RPV focusing on the aerosol formation process during the release from the fuel debris, and on the Cs reaction and the aerosol formation process during the remelting of metallic debris. The pressure vessel failure event associated with the remelting of metallic debris is important to verify the elemental reactions in each of oxidation and transformation by water vapor (gas-liquid reaction) and steel melting (solid-liquid reaction), which are in a competitive relationship.
    As described above, in FY2021, we will start the development of the necessary infrastructure and preliminary experiments to promote the experimental research and simulation study on each elemental technology method, as well as to develop a mutual understanding of the two issues of Backward Analysis extracted in this study through mutual collaboration with Forward Analysis specialists. In addition, we discussed the policy to improve the understanding of the phenomena and the in-core situation through mutual collaboration with Forward Analysis experts on the two issues of Backward Analysis identified in this study. As a result, we were able to share our understanding of the chemical state changes and migration pathways of fuel debris and Cs with reference to the most probable scenario of accident progression, and we made a prospect for future research development.
    In addition, this study aims to utilize the cooperative relationship with St. Petersburg University in Russia, which is well known for thermodynamic evaluation of multi-systems including FP-derived oxides, to improve the evaluation for reducing uncertainty in estimating the in-core contamination status. In Russia, as part of nuclear safety research against the background of the 1F accident, the advancement of Cs evaporation transfer models and MCCI analysis methods for accident progression is being considered. Therefore, in order to expand the knowledge on the adsorption and re-evaporation of Cs once evaporated into ex-vessel debris, Cs2O -SrO-Al2O3-SiO2 system including Cs oxides and concrete components. On the Japanese side, in addition to the Cs physical property data at high temperatures among the data acquired at St. Petersburg University, the objective is to evaluate the effect of Sr on the FP contamination status in the reactor by utilizing the physical property data of Sr with moderate evaporability, which we do not directly conduct.
     In FY2021, we determined the test conditions to start with data acquisition for the Cs2O-Al2O3 and SrO-Al2O3 binary systems, which are the subsystems of the multi-system system we are targeting. Next, as preliminary experiments, two samples were prepared for the Cs2O-Al2O3 system and three samples for the SrO-Al2O3 system, and phase identification of the microstructures in the fabricated samples was conducted by powder XRD analysis.
     In addition, a literature survey was conducted on how to conduct high-temperature experiments (up to 2700 K) on Cs- and Sr-containing multinary systems for full-scale tests scheduled to begin in FY2022. The thermodynamic evaluation experiment at St. Petersburg University is based on high-temperature mass spectrometry using a Knudsen cell. The sample is held at elevated temperatures up to the target temperature, and the data from the ionization of the gas produced by the instrument is analyzed to determine the vapor pressure of the gassed compound. Therefore, it was reported that preliminary experiments determine the compound form that is generated and ionized when the target system is gasified.
  • Specialty steels and alloy steels are important products of Japan with excellent strength, toughness, corrosion resistance, etc. Japan's great strength lies in its ability to stably supply products with few impurities and defects. Many special steels and alloy steels use chromium, which is more easily oxidized than iron, and the slag from the melting of chromium steel contains chromium oxide. It is necessary to ensure the safety and security of the products for long-term use in changing environments and to develop new applications. To this end, it is ideal to develop a smelting process that produces slag with a low concentration of chromium oxide and easy processing, while achieving a highly efficient smelting reaction, to clarify the conditions under which trivalent chromium in the slag is stable, and to reduce the content of chromium oxide in the slag to a level where it is not a problem.
    Reduction of chromium oxide in the slag while conducting highly efficient refining through slag control to obtain slag with low chromium oxide concentration that is easy to process. A cascade process that maximizes the reducing power of aluminum, silicon, carbon, and other elements is used to achieve highly efficient reduction of chromium oxide in the slag, recover almost all of the chromium, and obtain a chromium-oxide-free slag. In Japan, about 80% of ferrochrome, or 590,000 tons of net chromium content, is used in stainless steel (JOGMEC), and it is reported that 8.3% of chromium is discharged outside the system in the conventional process (Kato et al: Nippon Steel Technical Report, 414 (2019), 124). If this process is realized, it will have a significant ripple effect on chromium supply and demand.
  • n the metal materials industry, the by-product of the oxide melt melted at high temperature does not form a uniform liquid phase, but forms a complex fluid in which oxide solids and the like are dispersed. Therefore, the applicants have constructed a prediction model for the rheological properties of these high-temperature oxide suspensions by combining high-temperature experiments and machine learning. However, at present, the effect of the repulsive force due to the "charge" at the interface between the oxide solid and the oxide melt having a huge relative permittivity on the macro-rheological properties cannot be considered. Therefore, in this application, the interfacial charge between the high-temperature oxide melt and the solid is quantitatively measured using the AC impedance method, and the change in rheological characteristics due to the charge is measured with high accuracy. Furthermore, the rheological characteristic prediction model that has been constructed will be improved in accuracy and robustness from the viewpoint of interfacial charge.
  • In the steel refining process, the slag by-product is not basically a homogeneous melt, but a complex mixture of solids such as untreated CaO and coal, gases such as CO gas generated by the reaction between hot metal and slag, and liquids such as hot metal entrained by forming slag, forming a high temperature fluid. These fluids form a complex mixture of high-temperature fluids, and there are a number of problems that are closely related to them. For example, the non-negligible amount of grain iron loss caused by the forming slag produced in the hot metal pretreatment process, the un-tailings CaO caused by excessive input of refining agents to ensure steel quality, and the increasing density of the forming slag to add value to the discharged slag, these problems are caused by the following factors The problems are thought to be caused by the lack of understanding of the behavior of the second phase in the slag matrix at high temperatures. In this study group, we will form a research platform that contributes to solving the above-mentioned problems by visualizing the flow and mass transfer phenomena of multi-phase slag through high-temperature experiments using new methods and computational science, including machine learning.
  • Transient-Liquid-Phase Bonding of UHTCs using Refractory-metal-based Interlayer for High-efficiency Energy-generation Applications
Academic Activities
Papers
1. Noritaka SAITO, Daigo HARA, Seiyu TERUYA, and Kunihiko NAKASHIMA, “Viscosity of Slag Suspensions with a Polar Liquid Matrix”, ISIJ International, 60 [12] pp.2807-2818 (2020), 2020.12.
2. Noritaka SAITO, “Estimation of Rheological Characteristics of Dual Phase Fluid at High Temperature utilizing Transfer Learning”, Impact, 2020 [1] pp. 82-84 (2020), 2020.02.
3. Sohei SUKENAGA, Pierre FLORIAN, Koji KANEHASHI, Hiroyuki SHIBATA, Noritaka SAITO, Kunihiko NAKASHIMA, Dominique MASSIOT, Oxygen Speciation in Multicomponent Silicate Glasses Using Through Bond Double Resonance NMR Spectroscopy, The Journal of Physical Chemistry Letters , 8, 2274-2279, 2017.01.
4. Yusuke HARADA, Kakeru KUSADA, Sohei SUKENAGA, Hideaki YAMAMURA, Yoshiyuki UESHIMA, Toshiaki MIZOGUCHI, Noritaka SAITO, Kunihiko NAKASHIMA, Effects of Agitation and Morphology of Primary Crystalline Phase on Crystallization Behavior of CaO–SiO2–CaF2 Supercooled Melts, ISIJ International, 54, [9], 2071-2076, 2014.09.
5. Noritaka SAITO, Kakeru KUSADA, Sohei SUKENAGA, Yoshio OHTA, and Kunihiko NAKASHIMA, Effect of Agitation on Crystallization Behavior of CaO–SiO2–R2O (R = Li, Na, or K) System Characterized by Electrical Capacitance Measurement, ISIJ International, 52, [12], pp.2123-2129, 2012.12.
6. Noritaka SAITO, Hiroyuki IKEDA, Andreas M. GLAESER, Kunihiko NAKASHIMA, Wettability and transient liquid phase bonding of hafnium diboride composite with Ni-Nb alloys, Journal of Materials Science, 10.1007/s10853-012-6778-3, 47, [24], pp.8454-8463, 2012.10.
7. Sung M. HONG, Christopher C. BARTLOW, Thomas B. REYNOLDS, Noritaka SAITO and Andreas M. GLAESER, Ultrarapid Transient-Liquid-Phase Bonding of Advanced Ceramics, Advances in Science and Technology vol.64 Proceedings of CIMTEC 2010 12th International Ceramics Congress, 64, pp.88-97, 2010.10.
8. Noritaka SAITO, Shin-ichi NISHIMURA, Michio KAWANO, Shin-ichi ARAKI, Sohei SUKENAGA and Kunihiko NAKASHIMA, Fabrication of Nitrogen Containing Cordierite Ceramics, Journal of American Ceramic Society, 2010.08.
9. Noritaka SAITO, Kentaro KAI, Shingo FURUSHO, Kunihiko NAKASHIMA, Fumiyuki SHIMIZU and Katsumi MORI, Properties of Nitrogen-Containing Yttria-Alumina-Silica Melts and Glasses, Journal of American Ceramic Society, 86, 4, 711-716, 86 [4] pp.711-716, 2003.04.
Presentations
1. Noritaka SAITO, “Crystallization of Mold Flux characterized under AC Field”, CSST 2021, 2021 China Symposium on Sustainable Iron- and Steelmaking Technology, 2021.12, Oxides employed in steelmaking processes, such as mold flux, undergo a phase transition from a homogeneous molten state to a thermodynamically stable crystalline state after undercooling below the liquidus temperature. In the molten state, silicate-based oxides are composed of anions that have a network structure and cations that modify the network structure, making them a sea of ions, so to speak, with high electrical conductivity and relative permittivity. On the other hand, oxide crystals are generally insulators and are known to have a low relative permittivity. The author's research group has been attempting to use the difference in the AC electric field characteristics of these oxide melts and solids as a sensitive indicator of the emergence of solids from the melts, i.e., crystallization, for the past decade. In this presentation, I would like to outline the findings and discuss future prospects.
The response of a calcium silicate melt melted at 1873 K to a 10 kHz AC electric field was continuously monitored while the melt was cooled at a constant rate using concentric cylindrical platinum alloy electrodes. As a result, it was found that the electric capacitance value calculated from the imaginary part of the impedance decreased by two or three orders of magnitude at the crystallization temperature. Two-step crystallization behaviors such as primary crystallization and eutectic reaction, as well as accelerated crystallization of undercooled oxide melts by rotational stirring, were detected. In addition, a physical model to estimate the solidus ratio of the crystallized crystalline phase based on the capacitance model formulated from the electrode size and the relative permittivity model of the two-phase mixture was proposed, and it was confirmed that the model reproduced the experimental data very well. Furthermore, we have developed a prototype device that can simultaneously perform viscosity measurements using these new methods using AC electric fields and the crucible rotation method, which enable us to simultaneously evaluate the viscosity increase due to crystallization during the cooling process and the solidus fraction in the undercooled melt..
2. During steel refining, the slag by-product is not a uniform melt, it contains solids like undissolved calcium oxide (CaO) or carbonaceous material and gases like Carbon monoxide (CO) generated by the interfacial reaction between hot metal and slag. Furthermore, the liquid entangled in the hot metal when forming slag creates a complex high-temperature fluid which has some closely-related problems. For example, significant amounts of molten iron loss from slag forming in the pre-treatment process of hot metal and also undissolved CaO due to the excessive refining agent added to ensure the quality of steel and high-density forming slag due to the excessive value of discharged slag. These problems are generated by processes in the second phase, in which the high-temperature slag matrix can’t be ascertained. Here, the viscosity of suspensions of CaO or MgO particles dispersed in a matrix of CaO-Al2O3-SiO2-MgO slag at 1773 K was measured. The trend of increasing viscosity of the molten slag suspensions with dispersed CaO or MgO particles was similar to that of the room-temperature suspensions, exhibiting Bingham non-Newtonian behavior. The viscosity model composed with the results from the glycerol aqueous suspensions underestimated the slag viscosity, which can be attributed to the repulsive forces in the high-polarity liquid matrix.
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3. Noritaka SAITO, “Recent Activities of High Temperature Melt Group at Kyushu University”, Austro-Japanese Ironmaking Summit 2018, 2018.09.
4. Noritaka SAITO, “Behavior of Silicate Melts under an Alternating Current Field”, Yonsei Emerging Steel Innovation Forum 2017, 2017.02.
5. Noritaka SAITO, Kunihiko NAKASHIMA, “Wetting Behavior and Joining of UHTC Boride Composite”, ATPC2016, The 11th Asian Thermophysical Properties Conference, 2016.10.
6. Noritaka SAITO, Kunihiko NAKASHIMA, Laura ESPOSITO, “Joining of UHTC Borides utilizing Interfacial Reaction against Metallic Interlayer”, ICC6, The 6th International Congress on Ceramics, 2016.08.
7. Noritaka SAITO, Yusuke HARADA, Sohei SUKENAGA, Kunihiko NAKASHIMA, “Electrical Capacitance Measurement of Calcium Silicate based Slags for Detection and Evaluation of Crystallization Behavior”, MOLTEN2016, 10th International Conference on Molten Slags, Fluxes and Salts, 2017.05.
8. Noritaka SAITO, Kakeru KUSADA, Sohei SUKENAGA, and Kunihiko NAKASHIMA, Effect of Shear Stress on Crystallization Behavior of Calcium Silicate based Melts, ICS2012 5th International Congress on the Science and Technology of Steelmaking 2012, 2012.10.
Membership in Academic Society
  • The Iron and Steel Institute of Japan
  • The Minerals, Metals & Materials Society (TMS)
  • The American Ceramic Society
  • Japan Society of Thermophysical Properties
  • The Japan Institute of Metals
  • The Ceramic Society of Japan
  • The Mining and Materials Proceessing Institute of Japan
Educational
Educational Activities
Universities always keep in mind that they are "educational institutions" before they are research institutes. This is the reason why we are studying the area that has both basic and applied aspects of "high temperature melt physical properties and material creation". In other words, through weekly meetings and meetings with companies (students are also present), (idea / idea) → (experiment / observation) → (discussion / analysis) → (presentation / publication) → (idea ... The goal is to build an educational environment that can absorb the knowledge and wisdom of a wide range of fields of steel, glass, and ceramics related to high-temperature processes from the research of both myself and my colleagues. In a company where most of the work is completely different from the field in which I was involved in the master's thesis, I hope that the series of research flow, way of thinking, and way of proceeding acquired in the laboratory will be a great force for confidence.