Updated on 2024/09/25

写真a

 
OUE SATOSHI
 
Organization
Faculty of Engineering Department of Materials Science and Engineering Assistant Professor
School of Engineering (Concurrent)
Title
Assistant Professor
Profile
一般的な防食技術であるめっきのうち「電気めっき」を研究している。 電解条件の変化による電析挙動の変化およびそこから生成される電析物の 組織や構造の変化を研究する。
External link

Degree

  • Master

Research Interests・Research Keywords

  • Research theme: Electroplating

    Keyword: Electroplating

    Research period: 1993.4

Awards

  • 第44回論文賞

    2019.3   資源・素材学会   Effect of Chloride Ions in Electrowinning Solutions on Zinc Deposition Behavior and Crystal Texture という論文において資源・素材学会表彰規定に定める論文賞の授与にふさわしいと認められた。

  • 論文賞

    2010.3   資源・素材学会   「亜鉛電解採取における高分子添加剤の経時劣化」という論文において,論文賞に匹敵すると賞された。

  • 奨励賞

    2009.3   資源・素材学会   本会は,表彰・奨学委員会の審議を経て,貴殿の「湿式銅,亜鉛精錬の電解工程におけるカソード表面性状に関する研究」が奨励賞にふさわしいものと認め,第34会奨励賞受賞者と決定しました。ここに,本会表彰規程第8条により資源・素材学会奨励賞を贈呈します

  • 論文賞

    2007.2   表面技術協会   Quantification og Adhesion Property of Electrodeposited Film - Adhesion of Ni Electrodeposited from Sulfamate Solution -

  • 資源・素材学会 第30回論文賞

    2005.3   資源・素材学会   「銅電解精製における高分子添加剤の影響」 〔資源と素材 第119巻10・11号,663?667(2003年)〕 九州大学 中野 博昭・大上 悟 スイス連邦工科大学ローザンヌ校 大貝 猛 東洋鋼鈑⑭ 泉 孝平 九州産業大学 秋山 徹也 九州大学 福島 久哲

Papers

  • 電析亜鉛と下地鉄の面方位関係に及ぼす鉄表面性状の影響 Reviewed

    #久保 文吾, @大上 悟, @二葉 敬士, @小林 亜暢, @後藤 靖人, @中野 博昭

    鉄と鋼   104 ( 6 )   322 - 330   2018.6

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)  

    : Zn deposition was performed galvanostatically at 1500 A/m2

    and a charge of 1.48×104
    C/m2
    onto both the high purity electrolytic iron and the

    cold rolled steel sheets in an agitated sulfate solution at 40 °C to investigate the effect of surface textures of Fe on the crystal orientation rela-
    tionship between Fe and Zn. Zn deposited on the high purity electrolytic iron with large grain size showed the orientation relationship of {110}

    Fe//{0001}Zn. However, with increasing the angle of inclination of {110} Fe plane from the surface of substrate, the deviation of orientation
    relationship of {110}Fe//{0001}Zn increased. This result suggests that the orientation relationship of {110}Fe//{0001}Zn is difficult to be
    completed in the middle of deposition with increasing the angle of inclination of {110} Fe plane from the surface of substrate, as a result, the
    epitaxial growth of Zn easily changes to random growth. On the other hand, Zn deposited on the cold rolled steel sheets with small grain size
    showed preferred orientation of {0001} regardless of orientation of Fe, which indicates that the orientation of deposited Zn is more affected
    by deposition overpotential than by the orientation of Fe substrate. Although the strain was introduced to the high purity electrolytic iron with
    sandblasting, the orientation relationship of {110}Fe//{0001}Zn hardly changed with sandblasting, showing that the strain of Fe substrate has
    scarcely effect on the orientation relationship between Fe and deposited Zn.

    DOI: https://www.jstage.jst.go.jp/article/tetsutohagane/104/6/104_TETSU-2017-097/_article/-char/ja/

  • Effect of Structure of Organic Additives on Electrodeposition Behavior of Zn from Alkaline Zincate Solution and Its Crystal Morphology

    Imatani Tomoki, Oue Satoshi, Taninouchi Yu-ki, Aoki Yasunori, Nakano Hiroaki

    Journal of the Japan Institute of Metals and Materials   88 ( 3 )   58 - 67   2024.3   ISSN:00214876 eISSN:18806880

     More details

    Language:Japanese   Publisher:The Japan Institute of Metals and Materials  

    <p>The effect of structure of organic additives on the electrodeposition behavior of Zn from alkaline zincate solution and its crystal morphology was investigated. Zn was electrodeposited on an Fe electrode at 20-1000 A·m<sup>−2</sup>, 2.4 × 10<sup>4</sup> C·m<sup>−2</sup>, 300 K from unagitated zincate solutions containing the various organic additives as a leveling agent. The suppression effect of additives on the charge transfer and diffusion of ZnO<sub>2</sub><sup>2−</sup> ions in Zn electrodeposition corresponded to the number of adsorption site per a straight chain molecule of polymer. The effect of polymer alone on the decrease in size of Zn platelets crystals was small, but the crystal size significantly decreased with coexistence of low molecular additive. The crystal size of deposited Zn decreased in spite of small suppression effect on Zn deposition, showing that the crystal size of deposited Zn doesn’t depend on the overpotential for deposition. With coexistence of low molecular additive with polymer, the crystal of deposited Zn was fine regardless of kind of polymer even though Zn deposited at the diffusion control of ZnO<sub>2</sub><sup>2−</sup> ions.</p>

    DOI: 10.2320/jinstmet.j2023018

    Scopus

    CiNii Research

  • Effect of Structure of Organic Additives on Electrodeposition Behavior of Zn from Alkaline Zincate Solution and Its Crystal Morphology

    Imatani Tomoki, Oue Satoshi, Taninouchi Yu-ki, Aoki Yasunori, Nakano Hiroaki

    MATERIALS TRANSACTIONS   advpub ( 0 )   1141 - 1151   2024   ISSN:13459678 eISSN:13475320

     More details

    Language:English   Publisher:The Japan Institute of Metals and Materials  

    <p>The effect of structure of organic additives on the electrodeposition behavior of Zn from alkaline zincate solution and its crystal morphology was investigated. Zn was electrodeposited on an Fe electrode at 20–1000 A·m<sup>−2</sup>, 2.4 × 10<sup>4</sup> C·m<sup>−2</sup>, 300 K from unagitated zincate solutions containing the various organic additives as a leveling agent. The suppression effect of additives on the charge transfer and diffusion of ZnO<sub>2</sub><sup>2−</sup> ions in Zn electrodeposition corresponded to the number of adsorption site per a straight chain molecule of polymer. The effect of polymer alone on the decrease in size of Zn platelets crystals was small, but the crystal size significantly decreased with coexistence of low molecular additive. The crystal size of deposited Zn decreased in spite of small suppression effect on Zn deposition, showing that the crystal size of deposited Zn doesn’t depend on the overpotential for deposition. With coexistence of low molecular additive with polymer, the crystal of deposited Zn was fine regardless of kind of polymer even though Zn deposited at the diffusion control of ZnO<sub>2</sub><sup>2−</sup> ions.</p><p> </p><p>This Paper was Originally Published in Japanese in J. Japan Inst. Met. Mater. <b>88</b> (2024) 58–67.</p>

    DOI: 10.2320/matertrans.mt-m2024070

    Web of Science

    Scopus

    CiNii Research

  • Effect of Structure of Organic Additives on Electrodeposition Behavior of Zn from Alkaline Zincate Solution and Its Crystal Morphology

    Imatani, T; Oue, S; Taninouchi, YK; Aoki, Y; Nakano, H

    JOURNAL OF THE JAPAN INSTITUTE OF METALS AND MATERIALS   88 ( 3 )   58 - 67   2024   ISSN:0021-4876 eISSN:1880-6880

  • Micro Structure and Corrosion Resistance of Zn Composites Films Produced by Pulse Electrolysis from a Insoluble Particle-free Solution Containing Zr Ions

    Toyokuni Sota, Oue Satoshi, Taninouchi Yu-ki, Nakano Hiroaki

    ISIJ International   63 ( 11 )   1908 - 1918   2023.11   ISSN:09151559 eISSN:13475460

     More details

    Language:English   Publisher:The Iron and Steel Institute of Japan  

    <p>The electrodeposition of an Zn–Zr compound composite is performed under pulsed and double-pulsed current conditions at 313 K in unagitated pH 2 sulfate solutions containing Zn<sup>2+</sup> and ZrO<sup>2+</sup> ions and polyethylene glycol. Under constant-current electrolysis at 5000 A·m<sup>−2</sup>, coarse granular partial deposits containing Zr compounds are observed. Under pulse electrolysis, such coarse deposits are observed rarely; however, both deposited films containing Zr compounds and exfoliated films are observed. On the contrary, in double-pulse electrolysis at high (5000 A·m<sup>−2</sup>) and low (500 A·m<sup>−2</sup>) current densities, coarse deposits are not observed while fine-particle deposits containing Zr compounds are observed. In double-pulse electrolysis at low current densities, the rate of hydrogen evolution decreases and Zn is deposited without the codeposition of Zr compounds; therefore, the continuous hydrogen evolution is suspended in some areas. That is, the area of hydrogen evolution appears to be random. Although Zr compounds are usually concentrated at the upper regions of the deposited films, regardless of the electrolysis method, it is found to have been codeposited even in the inner regions under double-pulse electrolysis. The corrosion current density in 3 mass% NaCl solution is the smallest for the films produced by double-pulse electrolysis, when comparing with the films obtained by pulse electrolysis and constant-current electrolysis. This can be attributed to the suppression of the reduction reaction of dissolved oxygen.</p>

    DOI: 10.2355/isijinternational.isijint-2023-270

    Web of Science

    Scopus

    CiNii Research

▼display all

Presentations

  • 電解採取浴からの亜鉛の電析挙動に及ぼすハロゲン化物イオンの影響

    #永島 彰人, @大上 悟, @中野 博昭

    資源・素材学会  2020.3 

     More details

    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:千葉工業大学   Country:Japan  

    電解採取液からのZn電析挙動に及ぼすハロゲン化物イオン(Cl-, Br-, I-)の影響を明らかにするために,Zn2+ 1.07 mol/L, H2SO41.80 mol/Lの溶液にハロゲン化物イオンを0.01〜0.4 mol/L添加し,浴温45 ℃,攪拌100 rpmにて電解を行い,Zn電析および水素発生の部分分極曲線, 電流効率,交流インピーダンス,電析Znの形態を調査した。ハロゲン化物イオンが共存するとZn電析の部分分極曲線は明らかに復極し,その復極の程度は,I-添加の場合が最も大きく,Cl-, Br-添加では同程度であった。水素発生の部分分極曲線は,ハロゲン化物イオンを共存させると若干復極した。交流インピーダンスより求めたZn電析の分極抵抗は,I-を添加すると最も小さくなり,Cl-, Br-添加による減少は同程度であった。その結果,Zn電析の電流効率は,ハロゲン化物イオンを添加することにより,Zn膜厚2.1μmの電析初期で5〜10%程度増加した。電流効率増加の程度は,I-添加の場合が最も大きく,Cl-, Br-添加で同程度であった。

  • 鋼鈑の水素透過に及ぼすNi電析膜の影響

    #山根達哉, @大上悟, @中野博昭

    表面技術協会  2020.3 

     More details

    Event date: 2020.3

    Language:Japanese  

    Venue:首都大学東京   Country:Japan  

  • マグネシウム合金へのリン酸系化成処理におけるアルカリ土類金属の効果

    古賀弘毅, 中野 博昭, 大上 悟

    表面技術協会  2013.3 

     More details

    Event date: 2013.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:埼玉県 日本工業大学   Country:Japan  

  • 不純物として Fe を含む Al 合金の耐孔食性に及ぼす巨大ひずみ加工 HPT 処理の影響

    山田遥平, 大上 悟, 中野 博昭, 福島 久哲, 小林繁夫

    表面技術協会  2013.3 

     More details

    Event date: 2013.3

    Language:Japanese  

    Venue:埼玉県 日本工業大学   Country:Japan  

  • 濃厚塩化物水溶液からのCr 電析に及ぼすH3BO3の影響

    #中村皓聖,@大上悟,@谷ノ内勇樹,@中野博昭

    西日本腐蝕防蝕研究会  2023.12 

     More details

    Event date: 2023.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:九州産業大学   Country:Japan  

▼display all

MISC

  • EBSDによる各種めっき皮膜断面の結晶方位測定について

    大上 悟

    表面技術   2015.12

     More details

    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

Industrial property rights

Patent   Number of applications: 3   Number of registrations: 2
Utility model   Number of applications: 0   Number of registrations: 0
Design   Number of applications: 0   Number of registrations: 0
Trademark   Number of applications: 0   Number of registrations: 0

Professional Memberships

  • 日本鉄鋼協会

  • 表面技術協会

  • 資源素材学会

  • 腐食防食協会

Committee Memberships

  • 表面技術協会秋期講演大会実行委員   実行委員   Domestic

    2013.1 - 2013.9   

  • 西日本腐蝕防蝕研究会   運営委員   Domestic

    2010.4 - 2024.3   

  • 腐食防食協会   九州支部事務局   Domestic

    2010.4 - 2020.3   

  • 表面技術協会   九州支部事務局   Domestic

    2010.4 - 2020.3   

  • 資源・素材学会   広報幹事   Domestic

    2010.4 - 2017.3   

▼display all

Academic Activities

  • Screening of academic papers

    Role(s): Peer review

    2018

     More details

    Type:Peer review 

    Number of peer-reviewed articles in Japanese journals:1

  • 司会(Moderator)

    資源・素材学会  ( Japan ) 2017.3

     More details

    Type:Competition, symposium, etc. 

  • Screening of academic papers

    Role(s): Peer review

    2017

     More details

    Type:Peer review 

    Number of peer-reviewed articles in Japanese journals:1

  • 座長(Chairmanship)

    表面技術協会  ( Japan ) 2016.9

     More details

    Type:Competition, symposium, etc. 

  • 司会(Moderator)

    資源・素材学会  ( Japan ) 2016.3

     More details

    Type:Competition, symposium, etc. 

▼display all

Other

  • 日本金属学会の学会誌Metal Transaction ISIJの表紙に論文中の写真が使用された

    2009.9

  • 日本金属学会の学会誌Metal Transaction ISIJの表紙に論文中の写真が使用された

    2008.8

  • 日本金属学会の学会誌Metal Transaction ISIJの表紙に論文中の写真が使用された

    2006.7

Research Projects

  • 金属の電解析出における水素発生反応を制御した次世代型機能性表面処理膜の開発

    Grant number:24K01217  2024.4 - 2027.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

    中野 博昭, 谷ノ内 勇樹, 大上 悟

      More details

    Grant type:Scientific research funding

    ①Zn-活性金属水酸化物膜,Ni-Ni(OH)2,Ni-活性金属水酸化物膜において,電解方法,電析条件,添加剤によりH2発生サイトを制御して水酸化物の分布を設計する手法を確立する)。
    ②Zn-活性金属水酸化物の多層膜,均一組成膜を有する鋼板の耐食性を評価し,犠牲防食能と耐久性に及ぼす皮膜構造の影響を明らかにする。更に耐食性,耐摩耗性,加工性,塗装性,外観等の諸特性の観点から,最適な電析膜の構造を明確にする。
    ③Ni-Ni(OH)2, Ni-活性金属水酸化物膜において,アルカリ水電解からのH2発生挙動を解析し,H2発生触媒能と膜構造の関係を明らかにする。

    CiNii Research

  • Creation of composition-modulated Zn-based composite films electrodeposited on steel sheets for next generation high corrosion resistance

    Grant number:21H01672  2021 - 2024

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

    中野 博昭, 大上 悟

      More details

    Authorship:Coinvestigator(s)  Grant type:Scientific research funding

    1) ダブルパルス電解法,電流走査法により,電流密度を制御することにより電析膜の膜厚方向で活性金属酸化物の含有率を周期的に変動させる多層膜および酸化物の含有率を連続的に変化させる傾斜組成膜の作製条件を確立する。
    2) Zn-活性金属酸化物の多層膜および傾斜組成膜を有する複合電析鋼板の耐食性を評価し,犠牲防食能と耐久性に及ぼす皮膜構造の影響を明らかにする。更に耐食性,耐摩耗性,加工性,塗装性,外観等の諸特性の観点から,最適な電析膜の構造を明確にする。
    3) PEGの分子量,活性金属が加水分解するpH,活性金属酸化物のζ電位等の各種因子について,活性金属酸化物の共析挙動に及ぼす影響を明らかにする。

    CiNii Research

  • Challenge to novel copper electrolysis process of super power saving type using resources circulation type recycling materials

    Grant number:21K18829  2021 - 2023

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Challenging Research(Exploratory)

    Nakano Hiroaki

      More details

    Authorship:Coinvestigator(s)  Grant type:Scientific research funding

    The effect of impurities and additives in solution on the passivation of Cu anode with purity of 78.7 mass% was clarified. The passivation was significantly easy to occur with an addition of 0.596 mol・dm-3 of Ni2+ ions, and was easy to occur with the addition of As5+ and Bi3+ ions. With an addition of Ni2+ ions, the viscosity of solution increased and the diffusion coefficient of Cu2+ ions decreased. As5+ and Bi3+ ions formed the compounds of As-Sb-O and As-Bi-O system in the slime, resulting in increase in compactness of slime. The passivation was significantly promoted with an addition of Cl- ions above 1.13 mmol・dm-3. Cl- ions formed the CuCl at the upper area of slime and increased the compactness of slime, resulting in promotion of passivation.

    CiNii Research

  • 使途特定寄附金

    2021

      More details

    Grant type:Donation

  • ポリエチレンイミンと活性金属ナノ微粒子を共析させた高耐食性亜鉛複合電析鋼板の開発

    Grant number:18H01753  2018 - 2020

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

      More details

    Authorship:Coinvestigator(s)  Grant type:Scientific research funding

▼display all

Class subject

  • 物質化学工学実験第二

    2024.6 - 2024.8   Summer quarter

  • 物質化学工学実験第二

    2023.6 - 2023.8   Summer quarter

  • 物質化学工学実験第二

    2022.4 - 2022.9   First semester

  • 物質化学工学実験第二

    2021.4 - 2021.9   First semester

  • 物質化学工学実験第二

    2020.4 - 2020.9   First semester

▼display all

FD Participation

  • 2024.9   Role:Participation   Title:薬物依存対策研修会

    Organizer:University-wide

  • 2024.5   Role:Participation   Title:安全衛生に関するFD

    Organizer:Undergraduate school department

  • 2024.3   Role:Participation   Title:M2Bシステムの使い方

    Organizer:University-wide

  • 2023.6   Role:Participation   Title:ハラスメント防止講習

    Organizer:Undergraduate school department

  • 2022.3   Role:Participation   Title:全学FD)2021年度全学FDメンタルヘルス 講演会

    Organizer:University-wide

▼display all

Outline of Social Contribution and International Cooperation activities

  • なし

Social Activities

  • インテリジェント中核人材育成

    飯塚研究開発機構  九州産業大学  2012.12

     More details

    Audience:General, Scientific, Company, Civic organization, Governmental agency

    Type:Seminar, workshop

  • めっき処理技術者人材育成

    飯塚研究開発機構  九州産業大学  2012.9

     More details

    Audience:General, Scientific, Company, Civic organization, Governmental agency

    Type:Seminar, workshop

  • インテリジェントめっき技術中核人材育生事業 実験講師

    経済産業省  九州産業大学  2011.10

     More details

    Audience:General, Scientific, Company, Civic organization, Governmental agency

    Type:Seminar, workshop

  • インテリジェントめっき技術中核人材育生事業 実験講師

    経済産業省  九州産業大学  2010.9

     More details

    Audience:General, Scientific, Company, Civic organization, Governmental agency

    Type:Seminar, workshop

  • インテリジェントめっき技術中核人材育生事業 実験講師

    経済産業省  九州産業大学  2009.9

     More details

    Audience:General, Scientific, Company, Civic organization, Governmental agency

    Type:Seminar, workshop

▼display all

Travel Abroad

  • 2007.5

    Staying countory name 1:Korea, Republic of   Staying institution name 1:ICEC2007