九州大学-研究者情報 [清水宗治 (准教授) 工学研究院応用化学部門]

清水宗治（しみずそうじ）

データ更新日：2024.04.01

准教授　／　工学研究院応用化学部門

総説, 論評, 解説, 書評, 報告書等

1.	清水宗治, 大須賀篤弘, 新しいポルフィリンの化学--環拡張ポルフィリン, 現代化学, No.433, pp.47-53, 2007.04.
2.	Soji Shimizu, 5,15-Diheteroporphyrins synthesized from α,α'-dihalodipyrrin as a key building block, HETEROCYCLES, 10.3987/rev-20-927, 2020.04.
3.	Soji Shimizu, Aza-BODIPY synthesis towards vis/NIR functional chromophores based on a Schiff base forming reaction protocol using lactams and heteroaromatic amines, Chemical Communications, 10.1039/c9cc03365c, 2019.01, [URL], Aza-BODIPY is a class of heteroatom-containing BODIPY analogues targeting near infrared (NIR) chromophores and fluorophores. As a synthetic strategy towards aza-BODIPY structures, we have, recently, developed a Schiff base forming reaction using readily available lactams and heteroaromatic amines. Absorption and fluorescence of a series of compounds cover the whole range of the ultraviolet (UV)/visible (vis)/NIR regions. In addition, some compounds exhibit solid state emission, aggregation-induced emission enhancement, tunable fluorescence in the vis/NIR regions and non-linear optical properties. Furthermore, simple dimerization of aza-BODIPY chromophores caused unusual panchromatic absorption, whereas in combination with an N-confused porphyrin skeleton, multi-state NH tautomerism was achieved. In this Feature Article, wide applicability of this Schiff base forming reaction and optical and electrochemical properties of aza-BODIPY analogues thus synthesized are summarized including recent applications, such as bioimaging, photothermal cancer therapy and organic photovoltaics..
4.	Soji Shimizu, Recent Advances in Subporphyrins and Triphyrin Analogues: Contracted Porphyrins Comprising Three Pyrrole Rings, Chemical Reviews, 2016.10.
5.	Soji Shimizu, Hiroyuki Furuta, Core-modified phthalocyanines and subphthalocyanines: a synthetic strategy towards core-modification and novel properties arising from the inner ring-expansion, 2016.03.
6.	Soji Shimizu, Nagao Kobayashi, Structurally-modified subphthalocyanines: molecular design towards realization of expected properties from the electronic structure and structural features of subphthalocyanine, 2014.04.

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