Kyushu University Academic Staff Educational and Research Activities Database
List of Papers
Matsumoto Hikaru Last modified date:2024.06.03

Assistant Professor / Department of Chemical Engineering / Faculty of Engineering


Papers
1. Hikaru Matsumoto, Yu Hoshino, Tomohiro Iwai, Masaya Sawamura, Yoshiko Miura, Sheltering Mono‐P‐Ligated Metal Complexes in Porous Polystyrene Monolith: Effect of Aryl Pendant Stabilizers on Catalytic Durability, Chemistry – A European Journal, 10.1002/chem.202301847, 2023.10.
2. Tomoki Imoto, Hikaru Matsumoto, Seiya Nonaka, Keita Shichijo, Masanori Nagao, Hisashi Shimakoshi, Yu Hoshino, yoshiko miura, 4-Amino-TEMPO-Immobilized Polymer Monolith: Preparations, and Recycling Performance of Catalyst for Alcohol Oxidation, Polymers, 10.3390/polym14235123, 14, 23, 5123-5123, 2022.11,

Continuous flow reactors with immobilized catalysts are in great demand in various industries, to achieve easy separation, regeneration, and recycling of catalysts from products. Oxidation of alcohols with 4-amino-TEMPO-immobilized monolith catalyst was investigated in batch and continuous flow systems. The polymer monoliths were prepared by polymerization-induced phase separation using styrene derivatives, and 4-amino-TEMPO was immobilized on the polymer monolith with a flow reaction. The prepared 4-amino-TEMPO-immobilized monoliths showed high permeability, due to their high porosity. In batch oxidation, the reaction rate of 4-amino-TEMPO-immobilized monolith varied with stirring. In flow oxidation, the eluent permeated without clogging, and efficient flow oxidation was possible with residence times of 2–8 min. In the recycling test of the flow oxidation reaction, the catalyst could be used at least six times without catalyst deactivation.

.
3. Jiamin Cheng, Hikaru Matsumoto, Keita Shichijo, Yoshiko Miura, Hisashi Shimakoshi, Effect of Catalyst Support in B12-Based Heterogeneous Catalysts for Catalytic Alkane Oxidations, Bulletin of the Chemical Society of Japan, 10.1246/bcsj.20220161, 95, 8, 1250-1252, 2022.08.
4. Hikaru Matsumoto, Yu Hoshino, Tomohiro Iwai, Masaya Sawamura, yoshiko miura, Polystyrene-Cross-Linking Triphenylphosphine on a Porous Monolith: Enhanced Catalytic Activity for Aryl Chloride Cross-Coupling in Biphasic Flow, Industrial & Engineering Chemistry Research, 10.1021/acs.iecr.0c02404, 59, 34, 15179-15187, 2020.08.
5. 服部春香, 松本光, 星野友, 三浦佳子, 有機分子触媒L-Prolineを固定化した多孔質高分子モノリスの開発およびフロー不斉アルドール付加反応への応用, 化学工学論文集, 10.1252/kakoronbunshu.46.77, 46, 3, 77-83, 2020.05.
6. Hikaru Matsumoto, Yu Hoshino, Tomohiro Iwai, Masaya Sawamura, Yoshiko Miura, Polystyrene‐Supported PPh 3 in Monolithic Porous Material: Effect of Cross‐Linking Degree on Coordination Mode and Catalytic Activity in Pd‐Catalyzed C−C Cross‐Coupling of Aryl Chlorides, ChemCatChem, 10.1002/cctc.202000651, 12, 16, 4034-4037, 2020.08.
7. Hirokazu Seto, Hikaru Matsumoto, yoshiko miura, Preparation of palladium-loaded polymer hydrogel catalysts with high durability and recyclability, Polymer Journal, 10.1038/s41428-020-0323-z, 52, 7, 671-679, 2020.07.
8. Ashkan Mokhtar, Tomoya Nishioka, Hikaru Matsumoto, Soma Kitada, Nonoka Ryuno, Tadashi Okobira, Novel biodegradation system for bisphenol A using laccase-immobilized hollow fiber membranes, International Journal of Biological Macromolecules, 10.1016/j.ijbiomac.2019.03.004, 130, 1, 737-744, 2019.06.
9. Hikaru Matsumoto, Takanori Akiyoshi, Yu Hoshino, Hirokazu Seto, yoshiko miura, Size-tuned hydrogel network of palladium-confining polymer particles: a highly active and durable catalyst for Suzuki coupling reactions in water at ambient temperature, Polymer Journal, 10.1038/s41428-018-0102-2, 50, 12, 1179-1186, 2018.12.
10. Hikaru Matsumoto, Hirokazu Seto, Takanori Akiyoshi, Makoto Shibuya, Yu Hoshino, yoshiko miura, Macroporous Gel with a Permeable Reaction Platform for Catalytic Flow Synthesis, ACS Omega, 10.1021/acsomega.7b00909, 2, 12, 8796-8802, 2017.12.
11. Hikaru Matsumoto, Hirokazu Seto, Takanori Akiyoshi, Makoto Shibuya, Yu Hoshino, Yoshiko Miura, Macroporous Monolith with Polymer Gel Matrix as Continuous-flow Catalytic Reactor, Chemistry Letters, 10.1246/cl.170360, 46, 8, 1065-1067, 2017.08.
12. Hirokazu Seto, Makoto Shibuya, Hikaru Matsumoto, Yu Hoshino, yoshiko miura, Glycopolymer monoliths for affinity bioseparation of proteins in a continuous-flow system: glycomonoliths, Journal of Materials Chemistry B, 10.1039/c6tb02930b, 5, 6, 1148-1154, 2017.01,

Macroporous materials, called glycomonoliths, were prepared from saccharide-containing monomers, and applied for affinity bioseparation of proteins in a continuous-flow system.

.
13. Hirokazu Seto, Hikaru Matsumoto, Makoto Shibuya, Takanori Akiyoshi, Yu Hoshino, Yoshiko Miura, Poly(N-isopropylacrylamide) gel-based macroporous monolith for continuous-flow recovery of palladium(II) ions, Journal of Applied Polymer Science, 10.1002/app.44385, 134, 4, 2017.01.
14. Tadashi Okobira, Ai Matsuo, Hikaru Matsumoto, Takanori Tanaka, Kazuya Kai, Chie Minari, Muneharu Goto, Hidetaka Kawakita, Kazuya Uezu, Enhancement of immobilized lipase activity by design of polymer brushes on a hollow fiber membrane, Journal of Bioscience and Bioengineering, 10.1016/j.jbiosc.2015.01.009, 120, 3, 257-262, 2015.09.